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Revision Date 10/09/2014 Revision

SAFETY DATA SHEET

Ink, 750ml Black MEK
According to Regulation (EU) No 453/2010

SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING

1.1. Product identifier

Product name Ink, 750ml Black MEK
Product No. 302-1001-002

1.2. Relevant identified uses of the substance or mixture and uses advised against
Identified uses Printing ink.

1.3. Details of the supplier of the safety data sheet

Supplier Citronix
2241 S. Watson Rd. Bldg 200 Ste 111
Arlington
Texas 76010
Tel: 817-633-3200
Fax: 817-633-3207
[email protected]

1.4. Emergency telephone number

CHEMTREC – (800)-424-9300 (U.S. calls) 001-703-527-3887 (International calls)

SECTION 2: HAZARDS IDENTIFICATION

2.1. Classification of the substance or mixture

Classification (EC 1272/2008)
Physical and Chemical Hazards Flam. Liq. 2 - H225
Human health EUH066;Eye Irrit. 2 - H319;STOT SE 3 - H336
Environment Aquatic Chronic 3 - H412
Classification (1999/45/EEC) Xi;R36. F;R11. R52/53, R66, R67.
The Full Text for all R-Phrases and Hazard Statements are Displayed in Section 16.
Human health
See section 11 for additional information on health hazards.
Environment
The product contains a substance which may cause long term adverse effects in the aquatic environment.
Physical and Chemical Hazards
Vapours are heavier than air and may travel along the floor and in the bottom of containers.

2.2. Label elements

Label In Accordance With (EC) No. 1272/2008

Signal Word Danger

Hazard Statements
H225 Highly flammable liquid and vapour.
H319 Causes serious eye irritation.
H336 May cause drowsiness or dizziness.
H412 Harmful to aquatic life with long lasting effects.
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Precautionary Statements
P210 Keep away from open flames and hot surfaces. No smoking.
P271 Use only outdoors or in a well-ventilated area.
P280 Wear protective clothing and gloves.
P305+351+338 IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing.
P313 Get medical advice/attention.
P501 Dispose of contents/container in accordance with local regulations.
Supplementary Precautionary Statements
P233 Keep container tightly closed.
P240 Ground/bond container and receiving equipment.
P242 Use only non-sparking tools.
P243 Take precautionary measures against static discharge.
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P273 Avoid release to the environment.
P264 Wash contaminated skin thoroughly after handling.
P370+378 In case of fire: Use foam, carbon dioxide, dry powder or water fog for
extinction.
P303+361+353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated
clothing. Rinse skin with water/shower.
P304+340 IF INHALED: Remove victim to fresh air and keep at rest in a position
comfortable for breathing.
P312 Call a POISON CENTER or doctor/physician if you feel unwell.
P337 If eye irritation persists:
P403+233 Store in a well-ventilated place. Keep container tightly closed.
P403+235 Store in a well-ventilated place. Keep cool.
P405 Store locked up.
Supplemental label information
EUH066 Repeated exposure may cause skin dryness or cracking.

2.3. Other hazards

This product does not contain any PBT or vPvB substances.

SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS

3.2. Mixtures

2-METHYLPROPAN-2-OL < 1%

CAS-No.: 75-65-0 EC No.: 200-889-7

Classification (EC 1272/2008) Classification (67/548/EEC)

Flam. Liq. 2 - H225 F;R11
Acute Tox. 4 - H332 Xn;R20
Eye Irrit. 2 - H319 Xi;R36/37
STOT SE 3 - H335

BUTANONE 50-70%

CAS-No.: 78-93-3 EC No.: 201-159-0 Registration Number: 01-2119457290-43-XXXX

Classification (EC 1272/2008) Classification (67/548/EEC)

Flam. Liq. 2 - H225 F;R11
EUH066 Xi;R36
Eye Irrit. 2 - H319 R66
STOT SE 3 - H336 R67
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Ink, 750ml Black MEK

C.I. SOLVENT BLACK 29 5-10%

CAS-No.: 61901-87-9 EC No.:

Classification (EC 1272/2008) Classification (67/548/EEC)

Aquatic Chronic 2 - H411 N;R51/53.

ETHANOL 10-30%

CAS-No.: 64-17-5 EC No.: 200-578-6 Registration Number: 01-2119457610-43-xxxx

Classification (EC 1272/2008) Classification (67/548/EEC)

Flam. Liq. 2 - H225 F;R11

The Full Text for all R-Phrases and Hazard Statements are Displayed in Section 16.

Composition Comments
The product contains organic solvents.

SECTION 4: FIRST AID MEASURES

4.1. Description of first aid measures

General information
NOTE! Keep affected person away from heat, sparks and flames!
Inhalation
Move the exposed person to fresh air at once. Perform artificial respiration if breathing has stopped. Keep the affected person warm and
at rest. Get prompt medical attention.
Ingestion
NEVER MAKE AN UNCONSCIOUS PERSON VOMIT OR DRINK FLUIDS! DO NOT INDUCE VOMITING! Get medical attention
immediately!
Skin contact
Remove affected person from source of contamination. Wash the skin immediately with soap and water. Get medical attention if any
discomfort continues.
Eye contact
Promptly wash eyes with plenty of water while lifting the eye lids. Continue to rinse for at least 15 minutes. Immediately transport to
hospital or eye specialist.

4.2. Most important symptoms and effects, both acute and delayed
General information
The severity of the symptoms described will vary dependant of the concentration and the length of exposure.
Inhalation
Vapours may cause headache, fatigue, dizziness and nausea.
Ingestion
May cause nausea, headache, dizziness and intoxication.
Skin contact
Prolonged contact may cause redness, irritation and dry skin.
Eye contact
May cause severe irritation to eyes.

4.3. Indication of any immediate medical attention and special treatment needed
No recommendation given, but first aid may still be required in case of accidental exposure, inhalation or ingestion of this chemical. If in
doubt, GET MEDICAL ATTENTION PROMPTLY!

SECTION 5: FIREFIGHTING MEASURES

5.1. Extinguishing media

Extinguishing media
Extinguish with alcohol-resistant foam, carbon dioxide or dry powder. Water spray.
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5.2. Special hazards arising from the substance or mixture
Hazardous combustion products
Thermal decomposition or combustion may liberate carbon oxides and other toxic gases or vapours.
Unusual Fire & Explosion Hazards
Take precautionary measures against static discharges.
Specific hazards
Fire creates: Toxic gases/vapours/fumes of: Carbon monoxide (CO). Carbon dioxide (CO2).

5.3. Advice for firefighters

Special Fire Fighting Procedures
Keep run-off water out of sewers and water sources. Dike for water control. If risk of water pollution occurs, notify appropriate authorities.
Use water to keep fire exposed containers cool and disperse vapours. Move container from fire area if it can be done without risk.

SECTION 6: ACCIDENTAL RELEASE MEASURES

6.1. Personal precautions, protective equipment and emergency procedures

Wear protective clothing as described in Section 8 of this safety data sheet.

6.2. Environmental precautions

Do not discharge into drains, water courses or onto the ground.

6.3. Methods and material for containment and cleaning up

Extinguish all ignition sources. Avoid sparks, flames, heat and smoking. Ventilate. Clean-up personnel should use respiratory and/or liquid
contact protection. Runoff or release to sewer, waterway or ground is forbidden. Small Spillages: Collect with absorbent,
non-combustible material into suitable containers. Large Spillages: Absorb in vermiculite or dry sand and dispose of at a licenced
hazardous waste collection point. Inform Authorities if large amounts are involved.

6.4. Reference to other sections

Wear protective clothing as described in Section 8 of this safety data sheet. See section 11 for more detailed information on health effects
and symptoms. For waste disposal, see section 13.

SECTION 7: HANDLING AND STORAGE

7.1. Precautions for safe handling

Keep away from heat, sparks and open flame. Avoid spilling, skin and eye contact. Ventilate well, avoid breathing vapours. Use
approved respirator if air contamination is above accepted level. Risk of vapour concentration on the floor and in low-lying areas. Static
electricity and formation of sparks must be prevented.

7.2. Conditions for safe storage, including any incompatibilities

Flammable/combustible - Keep away from oxidisers, heat and flames. Store in tightly closed original container in a dry, cool and
well-ventilated place. Keep in original container.
Storage Class
Flammable liquid storage.

7.3. Specific end use(s)

The identified uses for this product are detailed in Section 1.2.

SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION

8.1. Control parameters

Name STD TWA - 8 Hrs STEL - 15 Min Notes

2-METHYLPROPAN-2-OL WEL 100 ppm 308 mg/m3 150 ppm 462 mg/m3

BUTANONE WEL 200 ppm 600 mg/m3 300 ppm 899 mg/m3 Sk

ETHANOL WEL 1000 ppm 1920 mg/m3

WEL = Workplace Exposure Limit.

Sk = Can be absorbed through skin.

CELLULOSE ACETATE BUTYRATE (CAS: 9004-36-8)

Ingredient Comments
WEL = Workplace Exposure Limits
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8.2. Exposure controls
Protective equipment

Process conditions
Use engineering controls to reduce air contamination to permissible exposure level. Provide eyewash station.
Engineering measures
Well-ventilated area.
Respiratory equipment
No specific recommendation made, but respiratory protection must be used if the general level exceeds the recommended occupational
exposure limit.
Hand protection
Protective gloves must be used if there is a risk of direct contact or splash. Be aware that the liquid may penetrate the gloves. Frequent
change is advisable.
Eye protection
Wear splash-proof eye goggles to prevent any possibility of eye contact.
Other Protection
Wear appropriate clothing to prevent any possibility of skin contact.
Hygiene measures
DO NOT SMOKE IN WORK AREA! Promptly remove any clothing that becomes wet or contaminated. Wash promptly if skin becomes wet
or contaminated. Use appropriate hand lotion to prevent defatting and cracking of skin. When using do not eat, drink or smoke. Wash
hands at the end of each work shift and before eating, smoking and using the toilet.
Environmental Exposure Controls
Keep container tightly sealed when not in use.

SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES

9.1. Information on basic physical and chemical properties

Appearance Liquid
Colour Black.
Odour Ketonic.
Solubility Slightly soluble in water. Soluble in: Organic solvents.
Initial boiling point and boiling range ~75-85°C @ 760 mm Hg
(°C)
Relative density 0.859 @ 20°C
Vapour density (air=1) >1
Evaporation rate <1 BuAc=1
Viscosity 3.75-4.25 cP @ 25°C
Flash point (°C) -6°C CC (Closed cup).

9.2. Other information

Not determined.

SECTION 10: STABILITY AND REACTIVITY

10.1. Reactivity
There are no known reactivity hazards associated with this product.

10.2. Chemical stability

Stable under normal temperature conditions.

10.3. Possibility of hazardous reactions

Not available.

10.4. Conditions to avoid

Avoid contact with strong oxidisers.
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Ink, 750ml Black MEK
10.5. Incompatible materials
Materials To Avoid
Strong oxidising substances.

10.6. Hazardous decomposition products

Fire creates: Toxic gases/vapours/fumes of: Carbon monoxide (CO). Carbon dioxide (CO2).

SECTION 11: TOXICOLOGICAL INFORMATION

11.1. Information on toxicological effects

Toxicological information
No information available.

Acute toxicity:
Acute Toxicity (Oral LD50)
Not determined.
Acute Toxicity (Dermal LD50)
Not determined.
Acute Toxicity (Inhalation LC50)
Not determined.

Germ cell mutagenicity:

Genotoxicity - In Vitro
Not determined.

Carcinogenicity:
Carcinogenicity
Not determined.

Reproductive Toxicity:
Reproductive Toxicity - Fertility
Not determined.

Specific target organ toxicity - single exposure:

STOT - Single exposure
No information available.

Specific target organ toxicity - repeated exposure:

STOT - Repeated exposure
No information available.

Aspiration hazard:

Not anticipated to present an aspiration hazard based on chemical structure.

Inhalation
Vapours may cause headache, fatigue, dizziness and nausea.

Ingestion
May cause nausea, headache, dizziness and intoxication.

Skin contact
Acts as a defatting agent on skin. May cause cracking of skin, and eczema.

Eye contact
Irritating to eyes.

Route of entry
Ingestion. Skin absorption. Inhalation.
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Medical Symptoms
NERVOUS SYSTEM. Drowsiness, dizziness, disorientation, vertigo. Mild intoxication (incl. fatigue, lassitude, irritability, headache,
nausea).

SECTION 12: ECOLOGICAL INFORMATION

Ecotoxicity
Dangerous for the environment: May cause long-term adverse effects in the aquatic environment.

12.1. Toxicity
Acute Fish Toxicity
Avoid discharge to the aquatic environment.

12.2. Persistence and degradability

Degradability
There are no data on the degradability of this product.

12.3. Bioaccumulative potential

Bioaccumulative potential
No data available on bioaccumulation.

12.4. Mobility in soil

Mobility:
The product contains volatile organic compounds (VOC) which will evaporate easily from all surfaces.

12.5. Results of PBT and vPvB assessment

Not Classified as PBT/vPvB by current EU criteria.

12.6. Other adverse effects

Not determined.

SECTION 13: DISPOSAL CONSIDERATIONS

General information
Waste is classified as hazardous waste. Disposal to licensed waste disposal site in accordance with the local Waste Disposal Authority.

13.1. Waste treatment methods

Dispose of waste and residues in accordance with local authority requirements.

SECTION 14: TRANSPORT INFORMATION

14.1. UN number

UN No. (ADR/RID/ADN) 1210

UN No. (IMDG) 1210

UN No. (ICAO) 1210

14.2. UN proper shipping name

Proper Shipping Name PRINTING INK

14.3. Transport hazard class(es)

ADR/RID/ADN Class 3

ADR/RID/ADN Class Class 3: Flammable liquids.

ADR Label No. 3

IMDG Class 3

ICAO Class/Division 3

Transport Labels
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Ink, 750ml Black MEK

FLAMMABLE
LIQUID
3

14.4. Packing group

ADR/RID/ADN Packing group II

IMDG Packing group II

ICAO Packing group II

14.5. Environmental hazards

Environmentally Hazardous Substance/Marine Pollutant

No.

14.6. Special precautions for user

EMS F-E, S-D

Emergency Action Code •3YE

Hazard No. (ADR) 33

Tunnel Restriction Code (D/E)

14.7. Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code

Not applicable.

SECTION 15: REGULATORY INFORMATION

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
Approved Code Of Practice
Safety Data Sheets for Substances and Preparations. Classification and Labelling of Substances and Preparations Dangerous for Supply.
Guidance Notes
Workplace Exposure Limits EH40.
EU Legislation
Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18 December 2006 concerning the Registration,
Evaluation, Authorisation and Restriction of Chemicals (REACH), establishing a European Chemicals Agency, amending Directive
1999/45/EC and repealing Council Regulation (EEC) No 793/93 and Commission Regulation (EC) No 1488/94 as well as Council Directive
76/769/EEC and Commission Directives 91/155/EEC, 93/67/EEC, 93/105/EC and 2000/21/EC, including amendments.

15.2. Chemical Safety Assessment

No chemical safety assessment has been carried out.

SECTION 16: OTHER INFORMATION

Information Sources
Croner´s: Substances Hazardous to Health. Croner´s: Emergency First Aid Guide.
Revision Date 10/09/2014
Risk Phrases In Full
R20 Harmful by inhalation.
R52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
R11 Highly flammable
R36/37 Irritating to eyes and respiratory system.
R36 Irritating to eyes.
R66 Repeated exposure may cause skin dryness or cracking.
R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
R67 Vapours may cause drowsiness and dizziness.
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Hazard Statements In Full
H319 Causes serious eye irritation.
H332 Harmful if inhaled.
H412 Harmful to aquatic life with long lasting effects.
H225 Highly flammable liquid and vapour.
H336 May cause drowsiness or dizziness.
H335 May cause respiratory irritation.
EUH066 Repeated exposure may cause skin dryness or cracking.
H411 Toxic to aquatic life with long lasting effects.

Disclaimer
This information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in
any process. Such information is, to the best of the company''s knowledge and belief, accurate and reliable as of the date indicated. However, no
warranty guarantee or representation is made to its accuracy, reliability or completeness. It is the user''s responsibility to satisfy himself as to the
suitability of such information for his own particular use.