Styrene Monomer-MSDS

SAFETY DATA SHEET
Styrene Monomer
Version 5.7 Revision Date 01.10.2020 Print Date 03.09.2022
1. PRODUCT AND COMPANY IDENTIFICATION
Product name : Styrene Monomer
Product code : Q9211, Q9215, Q9257
Synonyms : Phenyl ethene, Phenyl ethylene, Vinyl benzene

CAS-No. : 100-42-5
Manufacturer or supplier's details
Supplier :
SHELL EASTERN CHEMICALS (S)
A REGISTERED BUSINESS OF SHELL EASTERN
TRADING (PTE) LTD (UEN:198902087C)
9 North Buona Vista Drive , #07-01
The Metropolis Tower 1
Singapore 138588
Singapore
Telephone : +65 6384 8737
Telefax : +65 6384 8454
Emergency telephone : +800 2537 8747 ( ALERT SGS- toll Free) or +65 6542 9595
number (ALERT SGS)
Recommended use of the chemical and restrictions on use

Recommended use : Base chemical for the production of polystyrene, rubbers and
resins.
Restrictions on use : Restricted to professional users., This product must not be

used in applications other than the above without first seeking
the advice of the supplier.
2. HAZARDS IDENTIFICATION
GHS Classification
Flammable liquids : Category 3
Aspiration hazard : Category 1
Skin irritation : Category 2
Eye irritation : Category 2A
Acute toxicity (Inhalation) : Category 4
Specific target organ toxicity - : Category 3 (Respiratory Tract)
single exposure
Specific target organ toxicity - : Category 1 (Auditory system)
repeated exposure
Short-term (acute) aquatic : Category 2
hazard
Long-term (chronic) aquatic : Category 3
hazard
GHS label elements
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Hazard pictograms :
Signal word : Danger
Hazard statements : PHYSICAL HAZARDS:

H226 Flammable liquid and vapour.
HEALTH HAZARDS:
H304 May be fatal if swallowed and enters airways.
H315 Causes skin irritation.
H319 Causes serious eye irritation.
H332 Harmful if inhaled.
H335 May cause respiratory irritation.
H372 Causes damage to organs (Auditory system) through
prolonged or repeated exposure if inhaled.
ENVIRONMENTAL HAZARDS:
H401 Toxic to aquatic life.
H412 Harmful to aquatic life with long lasting effects.
Precautionary statements :
Prevention:
P210 Keep away from heat/ sparks/ open flames/ hot surfaces.
No smoking.
P240 Ground/bond container and receiving equipment.
P241 Use explosion-proof electrical/ ventilating/ lighting
equipment.
P242 Use only non-sparking tools.
P243 Take precautionary measures against static discharge.
P260 Do not breathe dust/ fume/ gas/ mist/ vapours/ spray.
P264 Wash hands thoroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P271 Use only outdoors or in a well-ventilated area.
P280 Wear protective gloves/ protective clothing/ eye
protection/ face protection.
P273 Avoid release to the environment.
Response:
P303 + P361 + P353 IF ON SKIN (or hair): Take off
immediately all contaminated clothing. Rinse skin with water/
shower.
P370 + P378 In case of fire: Use appropriate media to
extinguish.
P301 + P310 IF SWALLOWED: Immediately call a POISON
CENTER/doctor.
P331 Do NOT induce vomiting.
P332 + P313 If skin irritation occurs: Get medical advice/
attention.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water
for several minutes. Remove contact lenses, if present and
easy to do. Continue rinsing.
P337 + P313 If eye irritation persists: Get medical advice/
attention.
P304 + P340 IF INHALED: Remove person to fresh air and
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keep comfortable for breathing.
P312 Call a POISON CENTER/ doctor if you feel unwell.
Storage:
P403 + P233 Store in a well-ventilated place. Keep container
tightly closed.
P235 Keep cool.
P405 Store locked up.
Disposal:
P501 Dispose of contents/ container to an approved waste
disposal plant.
Other hazards which do not result in classification

Vapours are heavier than air. Vapours may travel across the ground and reach remote ignition
sources causing a flashback fire danger.Highly reactive.Maintain dissolved oxygen and inhibitor
at proper levels to prevent runaway polymerisation.May form flammable/explosive vapour-air
mixture.This material is a static accumulator.Even with proper grounding and bonding, this
material can still accumulate an electrostatic charge.If sufficient charge is allowed to accumulate,
electrostatic discharge and ignition of flammable air-vapour mixtures can occur.
3. COMPOSITION/INFORMATION ON INGREDIENTS
Substance / Mixture : Substance
Hazardous components
Chemical name CAS-No. Classification Concentration (%
w/w)
styrene 100-42-5 Flam. Liq.3; H226 99 - 100
Acute Tox.4; H332
Asp. Tox.1; H304
Skin Irrit.2; H315
Eye Irrit.2A; H319
STOT SE3; H335
STOT RE1; H372
Aquatic Acute2;
H401
Aquatic Chronic3;
H412
Stabilised with tertiary butyl catechol., 10-15 ppm.
For explanation of abbreviations see section 16.
4. FIRST-AID MEASURES
General advice : Not expected to be a health hazard when used under normal
conditions.
If inhaled : Call emergency number for your location / facility.

Remove to fresh air. Do not attempt to rescue the victim
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unless proper respiratory protection is worn. If the victim has
difficulty breathing or tightness of the chest, is dizzy, vomiting,
or unresponsive, give 100% oxygen with rescue breathing or
Cardio-Pulmonary Resuscitation as required and transport to
the nearest medical facility.
In case of skin contact : Remove contaminated clothing. Immediately flush skin with
large amounts of water for at least 15 minutes, and follow by
washing with soap and water if available. If redness, swelling,
pain and/or blisters occur, transport to the nearest medical
facility for additional treatment.
In case of eye contact : Immediately flush eye(s) with plenty of water.

Remove contact lenses, if present and easy to do. Continue
rinsing.
Transport to the nearest medical facility for additional
treatment.
If swallowed : Call emergency number for your location / facility.

If swallowed, do not induce vomiting: transport to nearest
medical facility for additional treatment. If vomiting occurs
spontaneously, keep head below hips to prevent aspiration.
If any of the following delayed signs and symptoms appear
within the next 6 hours, transport to the nearest medical
facility: fever greater than 101° F (38.3°C), shortness of
breath, chest congestion or continued coughing or wheezing.
Most important symptoms : Respiratory irritation signs and symptoms may include a
and effects, both acute and temporary burning sensation of the nose and throat, coughing,
delayed and/or difficulty breathing.
Skin irritation signs and symptoms may include a burning

sensation, redness, swelling, and/or blisters.
Eye irritation signs and symptoms may include a burning

sensation, redness, swelling, and/or blurred vision.
If material enters lungs, signs and symptoms may include

coughing, choking, wheezing, difficulty in breathing, chest
congestion, shortness of breath, and/or fever.
If any of the following delayed signs and symptoms appear
within the next 6 hours, transport to the nearest medical
facility: fever greater than 101° F (38.3°C), shortness of
breath, chest congestion or continued coughing or wheezing.
Defatting dermatitis signs and symptoms may include a

burning sensation and/or a dried/cracked appearance.
Auditory system effects may include temporary hearing loss
and/or ringing in the ears.
Visual system disturbances may be evidenced by decreases
in the ability to discriminate between colours.
Protection of first-aiders : When administering first aid, ensure that you are wearing the
appropriate personal protective equipment according to the
incident, injury and surroundings.
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Notes to physician : IMMEDIATE TREATMENT IS EXTREMELY IMPORTANT!

Call a doctor or poison control center for guidance.
Potential for chemical pneumonitis.
Treat symptomatically.
5. FIRE-FIGHTING MEASURES
Suitable extinguishing media : Foam, water spray or fog. Dry chemical powder, carbon
dioxide, sand or earth may be used for small fires only.
Unsuitable extinguishing : Do not use water in a jet.

media
Specific hazards during : Flammable vapours may be present even at temperatures

firefighting below the flash point.
Sustained fire attack on vessels may result in a Boiling Liquid
Expanding Vapor Explosion (BLEVE).
The vapour is heavier than air, spreads along the ground and
distant ignition is possible.
Will float and can be reignited on surface water.
Hazardous combustion products may include:
Carbon monoxide.
Formaldehyde
Specific extinguishing : Standard procedure for chemical fires.

methods Clear fire area of all non-emergency personnel.
All storage areas should be provided with adequate fire
fighting facilities.
Keep adjacent containers cool by spraying with water.
Special protective equipment : Proper protective equipment including chemical resistant

for firefighters gloves are to be worn; chemical resistant suit is indicated if
large contact with spilled product is expected. Self-Contained
Breathing Apparatus must be worn when approaching a fire in
a confined space. Select fire fighter's clothing approved to
relevant Standards (e.g. Europe: EN469).
6. ACCIDENTAL RELEASE MEASURES
Personal precautions, : Observe all relevant local and international regulations.

protective equipment and Notify authorities if any exposure to the general public or the
emergency procedures environment occurs or is likely to occur.
Local authorities should be advised if significant spillages
cannot be contained.
: Isolate hazard area and deny entry to unnecessary or

unprotected personnel.
Avoid contact with skin, eyes and clothing.
Be ready for fire or possible exposure.
Do not operate electrical equipment.
Stay upwind and out of low areas.
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Environmental precautions : Shut off leaks, if possible without personal risks. Remove all
possible sources of ignition in the surrounding area. Use
appropriate containment to avoid environmental
contamination. Prevent from spreading or entering drains,
ditches or rivers by using sand, earth, or other appropriate
barriers. Attempt to disperse the vapour or to direct its flow to
a safe location for example by using fog sprays. Take
precautionary measures against static discharge. Ensure
electrical continuity by bonding and grounding (earthing) all
equipment.
Monitor area with combustible gas indicator.
Methods and materials for : For small liquid spills (< 1 drum), transfer by mechanical
containment and cleaning up means to a labeled, sealable container for product recovery or
safe disposal. Allow residues to evaporate or soak up with an
appropriate absorbent material and dispose of safely. Remove
contaminated soil and dispose of safely.
For large liquid spills (> 1 drum), transfer by mechanical
means such as vacuum truck to a salvage tank for recovery or
safe disposal. Do not flush away residues with water. Retain
as contaminated waste. Allow residues to evaporate or soak
up with an appropriate absorbent material and dispose of
safely. Remove contaminated soil and dispose of safely
Additional advice : For guidance on selection of personal protective equipment

see Section 8 of this Safety Data Sheet.
For guidance on disposal of spilled material see Section 13 of
this Safety Data Sheet.
7. HANDLING AND STORAGE
General Precautions : Avoid breathing of or direct contact with material. Only use in
well ventilated areas. Wash thoroughly after handling. For
guidance on selection of personal protective equipment see
Section 8 of this Safety Data Sheet.
Use the information in this data sheet as input to a risk
assessment of local circumstances to help determine
appropriate controls for safe handling, storage and disposal of
this material.
Ensure that all local regulations regarding handling and
storage facilities are followed.
Advice on safe handling : Avoid inhaling vapour and/or mists.

Avoid contact with skin, eyes and clothing.
Extinguish any naked flames. Do not smoke. Remove ignition
sources. Avoid sparks.
The vapour is heavier than air. Beware of accumulation in pits
and confined spaces.
Use local exhaust ventilation if there is risk of inhalation of
vapours, mists or aerosols.
Bulk storage tanks should be diked (bunded).
Properly dispose of any contaminated rags or cleaning
materials in order to prevent fires.
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Even with proper grounding and bonding, this material can still
accumulate an electrostatic charge.
If sufficient charge is allowed to accumulate, electrostatic
discharge and ignition of flammable air-vapour mixtures can
occur.
Be aware of handling operations that may give rise to
additional hazards that result from the accumulation of static
charges.
These include but are not limited to pumping (especially
turbulent flow), mixing, filtering, splash filling, cleaning and
filling of tanks and containers, sampling, switch loading,
gauging, vacuum truck operations, and mechanical
movements.
These activities may lead to static discharge e.g. spark
formation.
Restrict line velocity during pumping in order to avoid
generation of electrostatic discharge (≤ 1 m/s until fill pipe
submerged to twice its diameter, then ≤ 7 m/s). Avoid splash
filling.
Do NOT use compressed air for filling, discharging, or
handling operations.
Inhibitor levels should be maintained.
Protect against light.
Avoidance of contact : Strong oxidising agents.

Copper alloys.
Product Transfer : If positive displacement pumps are used, these must be fitted
with a non-integral pressure relief valve. Refer to guidance
under Handling section.
Storage
Conditions for safe storage : Refer to section 15 for any additional specific legislation
covering the packaging and storage of this product.
Other data : Storage Temperature:

25 °C / 77 °F maximum.
Keep away from aerosols, flammables, oxidizing agents,

corrosives and from other flammable products which are not
harmful or toxic to man or to the environment.
Must be stored in a diked (bunded) well- ventilated area, away
from sunlight, ignition sources and other sources of heat.
Must be kept inhibited during storage and shipment as
material can polymerise.
Vapours from tanks should not be released to atmosphere.
Breathing losses during storage should be controlled by a
suitable vapour treatment system.
Electrostatic charges will be generated during pumping.
Electrostatic discharge may cause fire. Ensure electrical
continuity by bonding and grounding (earthing) all equipment
to reduce the risk.
The vapours in the head space of the storage vessel may lie
in the flammable/explosive range and hence may be
flammable.
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Packaging material : Suitable material: For container paints, use epoxy paint, zinc
silicate paint., For containers, or container linings use mild
steel, stainless steel.
Unsuitable material: Copper., Copper alloys.
Container Advice : Containers, even those that have been emptied, can contain
explosive vapours. Do not cut, drill, grind, weld or perform
similar operations on or near containers.
Specific use(s) : Not applicable
Ensure that all local regulations regarding handling and

storage facilities are followed.
See additional references that provide safe handling practices
for liquids that are determined to be static accumulators:
American Petroleum Institute 2003 (Protection Against
Ignitions Arising out of Static, Lightning and Stray Currents) or
National Fire Protection Agency 77 (Recommended Practices
on Static Electricity).
IEC/TS 60079-32-1: Electrostatic hazards, guidance
8. EXPOSURE CONTROLS AND PERSONAL PROTECTION
Components with workplace control parameters

Components CAS-No. Value type Control Basis
(Form of parameters /
exposure) Permissible
concentration
styrene 100-42-5 PEL (long 50 ppm SG OEL
term) 213 mg/m3
styrene PEL (short 100 ppm SG OEL
term) 426 mg/m3
styrene 100-42-5 TWA 20 ppm
85 mg/m3
Further information: The value is provided by the Industry
Association. This value is provided for information only.
styrene 100-42-5 TWA 100 ppm OSHA Z-2
styrene CEIL 200 ppm OSHA Z-2
styrene Peak 600 ppm OSHA Z-2
styrene TWA 20 ppm ACGIH
styrene STEL 40 ppm ACGIH
Biological occupational exposure limits

No biological limit allocated.
Monitoring Methods
Monitoring of the concentration of substances in the breathing zone of workers or in the general
workplace may be required to confirm compliance with an OEL and adequacy of exposure
controls. For some substances biological monitoring may also be appropriate.
Validated exposure measurement methods should be applied by a competent person and
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samples analysed by an accredited laboratory.
Examples of sources of recommended exposure measurement methods are given below or
contact the supplier. Further national methods may be available.
National Institute of Occupational Safety and Health (NIOSH), USA: Manual of Analytical Methods
http://www.cdc.gov/niosh/
Occupational Safety and Health Administration (OSHA), USA: Sampling and Analytical Methods
http://www.osha.gov/
Health and Safety Executive (HSE), UK: Methods for the Determination of Hazardous Substances
http://www.hse.gov.uk/
Institut für Arbeitsschutz Deutschen Gesetzlichen Unfallversicherung (IFA) , Germany
http://www.dguv.de/inhalt/index.jsp
L'Institut National de Recherche et de Securité, (INRS), France http://www.inrs.fr/accueil
Engineering measures : Use sealed systems as far as possible.

Adequate explosion-proof ventilation to control airborne
concentrations below the exposure guidelines/limits.
Local exhaust ventilation is recommended.
Firewater monitors and deluge systems are recommended.
Eye washes and showers for emergency use.
Where material is heated, sprayed or mist formed, there is
greater potential for airborne concentrations to be generated.
The level of protection and types of controls necessary will
vary depending upon potential exposure conditions. Select
controls based on a risk assessment of local circumstances.
Appropriate measures include:
General Information:
Consider technical advances and process upgrades (including
automation) for the elimination of releases. Minimise exposure
using measures such as closed systems, dedicated facilities
and suitable general/local exhaust ventilation. Drain down
systems and clear transfer lines prior to breaking containment.
Clean/flush equipment, where possible, prior to maintenance.
Where there is potential for exposure: restrict access to
authorised persons; provide specific activity training to
operators to minimise exposures; wear suitable gloves and
coveralls to prevent skin contamination; wear respiratory
protection when there is potential for inhalation; clear up spills
immediately and dispose of wastes safely.Ensure safe
systems of work or equivalent arrangements are in place to
manage risks. Regularly inspect, test and maintain all control
measures. Consider the need for risk based health
surveillance.
Personal protective equipment

Protective measures
Personal protective equipment (PPE) should meet recommended national standards. Check with
PPE suppliers.
Respiratory protection : If engineering controls do not maintain airborne

concentrations to a level which is adequate to protect worker
health, select respiratory protection equipment suitable for the
specific conditions of use and meeting relevant legislation.
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Check with respiratory protective equipment suppliers.
Where air-filtering respirators are unsuitable (e.g. airborne
concentrations are high, risk of oxygen deficiency, confined
space) use appropriate positive pressure breathing apparatus.
Where air-filtering respirators are suitable, select an
appropriate combination of mask and filter.
If air-filtering respirators are suitable for conditions of use:
Select a filter suitable for organic gases and vapours [Type A
boiling point >65°C (149°F)].
Hand protection
Remarks : Where hand contact with the product may occur the use of
gloves approved to relevant standards (e.g. Europe: EN374,
US: F739) made from the following materials may provide
suitable chemical protection. Longer term protection: Viton.
Incidental contact/Splash protection: Nitrile rubber.
For continuous contact we recommend gloves with

breakthrough time of more than 240 minutes with preference
for > 480 minutes where suitable gloves can be identified. For
short-term/splash protection we recommend the same but
recognize that suitable gloves offering this level of protection
may not be available and in this case a lower breakthrough
time maybe acceptable so long as appropriate maintenance
and replacement regimes are followed. Glove thickness is not
a good predictor of glove resistance to a chemical as it is
dependent on the exact composition of the glove material.
Glove thickness should be typically greater than 0.35 mm
depending on the glove make and model. Suitability and
durability of a glove is dependent on usage, e.g. frequency
and duration of contact, chemical resistance of glove material,
dexterity. Always seek advice from glove suppliers.
Contaminated gloves should be replaced. Personal hygiene is
a key element of effective hand care. Gloves must only be
worn on clean hands. After using gloves, hands should be
washed and dried thoroughly. Application of a non-perfumed
moisturizer is recommended.
Eye protection : Wear goggles for use against liquids and gas.
Wear full face shield if splashes are likely to occur.
Skin and body protection : Wear chemical resistant gloves/gauntlets and boots. Where
risk of splashing, also wear an apron.
Wear antistatic and flame-retardant clothing, if a local risk
assessment deems it so.
Hygiene measures : Wash hands before eating, drinking, smoking and using the
toilet.
Launder contaminated clothing before re-use.
Environmental exposure controls

General advice : Local guidelines on emission limits for volatile substances
must be observed for the discharge of exhaust air containing
vapour.
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Minimise release to the environment. An environmental
assessment must be made to ensure compliance with local
environmental legislation.
Information on accidental release measures are to be found in
section 6.
9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance : Oily liquid.
Colour : Colourless to yellowish

Odour : Aromatic hydrocarbon
Odour Threshold : 0.1 ppm
pH : Not applicable
Melting / freezing point : -31 °C / -24 °F
Boiling point : 145 °C / 293 °F
Flash point : 32 °C / 90 °F
Evaporation rate : 12.4

Method: ASTM D 3539, nBuAc=1
Flammability (solid, gas) : Data not available
Upper explosion limit : 6.1 %(V)
Lower explosion limit : 1.1 %(V)
Vapour pressure : 670 Pa (20 °C / 68 °F)
Relative vapour density : 3.6

Relative density : Data not available
Density : 906 kg/m3 (20 °C / 68 °F)
Solubility(ies)
Water solubility : 0.29 kg/m3 (20 °C / 68 °F)
Partition coefficient: n- : log Pow: 2.96Method: Literature data.

octanol/water
Auto-ignition temperature : 490 °C / 914 °F
Decomposition temperature : Data not available
Viscosity
Viscosity, dynamic : 0.7 mPa.s (25 °C / 77 °F)
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Viscosity, kinematic : Data not available

Explosive properties : Not applicable
Oxidizing properties : Not applicable
Self-heating substances : At high temperatures, for example fire conditions, exothermic

polymerisation may occur causing possible container rupture.,
Dangerous polymerisation can occur on contact with highly
catalytic surfaces., In case of contact with water the inhibitor
concentration might decrease and cause polymerisation.
Surface tension : 34 mN/m
Conductivity : Low conductivity: < 100 pS/m, The conductivity of this material
makes it a static accumulator., A liquid is typically considered
nonconductive if its conductivity is below 100 pS/m and is
considered semi-conductive if its conductivity is below 10,000
pS/m., Whether a liquid is nonconductive or semiconductive,
the precautions are the same., A number of factors, for
example liquid temperature, presence of contaminants, and
anti-static additives can greatly influence the conductivity of a
liquid
Particle size : Data not available
Molecular weight : 104.15 g/mol
10. STABILITY AND REACTIVITY
Reactivity : Polymerises with risk of fire and explosion., Reacts with strong
oxidising agents.
Chemical stability : Material is stable when properly inhibited and an appropriate

dissolved oxygen level is maintained (see Storage in Chapter
7). Polymerises with risk of fire and explosion. Reacts with
strong oxidising agents.
Possibility of hazardous : Normally stable under ambient conditions and if properly

reactions inhibited.
Conditions to avoid : Heat, flames, and sparks.

Exposure to sunlight.
Exposure to air.
In certain circumstances product can ignite due to static
electricity.
Incompatible materials : Strong oxidising agents.

Copper alloys.
Hazardous decomposition : Thermal decomposition is highly dependent on conditions. A

products complex mixture of airborne solids, liquids and gases,
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including carbon monoxide, carbon dioxide and other organic
compounds will be evolved when this material undergoes
combustion or thermal or oxidative degradation.
11. TOXICOLOGICAL INFORMATION
Information on likely routes of : Inhalation is the primary route of exposure although

exposure absorption may occur through skin contact or following
accidental ingestion.
Acute toxicity
Product:
Acute oral toxicity : LD 50 Rat, male and female: > 5,000 mg/kg
Method: Based on weight of evidence.
Remarks: Low toxicity:
Acute inhalation toxicity : LC 50 Rat, Unspecified: 11.8 mg/l, 2770 ppm

Exposure time: 4 h
Test atmosphere: vapour
Remarks: Harmful if inhaled.
Acute dermal toxicity : LD 50 Rat, male and female: > 2,000 mg/kg
Method: OECD Test Guideline 402
Remarks: Based on available data, the classification criteria
are not met.
Skin corrosion/irritation
Product:
Species: Rabbit
Remarks: Causes skin irritation.
Serious eye damage/eye irritation

Product:
Species: Rabbit
Remarks: Causes serious eye irritation.
Respiratory or skin sensitisation

Product:
Species: Humans
Method: Based on Human Evidence
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Remarks: Based on available data, the classification criteria are not met.
Germ cell mutagenicity

Product:
Genotoxicity in vitro : Method: Based on weight of evidence.
are not met.
: Method: Based on weight of evidence.
are not met.
Germ cell mutagenicity- : This product does not meet the criteria for classification in
Assessment categories 1A/1B.
Carcinogenicity
Product:
Species: Humans
Application Route: Occupational exposure
Species: Rat
Application Route: Inhalation
Species: Rat
Application Route: Oral
Carcinogenicity - : This product does not meet the criteria for classification in
Material GHS/CLP Carcinogenicity Classification

styrene No carcinogenicity classification.
Material Other Carcinogenicity Classification

styrene IARC: Group 2A: Probably carcinogenic to humans
Reproductive toxicity
Product:
: Species: Rat
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are not met.
Effects on foetal : Species: Rat

development Application Route: Inhalation
Remarks: Causes foetotoxicity in animals at doses which are
maternally toxic.
Reproductive toxicity - : This product does not meet the criteria for classification in
STOT - single exposure

Product:
Exposure routes: Inhalation
Target Organs: Respiratory system
Remarks: Inhalation of vapours or mists may cause irritation to the respiratory system.
STOT - repeated exposure

Product:
Exposure routes: Inhalation
Target Organs: ear
Remarks: Harmful: danger of serious damage to health by prolonged exposure through
inhalation., Can cause liver damage., Respiratory system: repeated exposure affects the
respiratory system. Effects were seen at high doses only., Auditory system: prolonged and
repeated exposures to high concentrations have resulted in hearing loss in rats.
Repeated dose toxicity

Product:
Humans, Unspecified:
Method: Occupational exposure
Target Organs: ear
inhalation.
Can cause liver damage.
Respiratory System: repeated exposure affects the respiratory system.
Auditory system: prolonged and repeated exposures to high concentrations have resulted in
hearing loss in rats. Solvent abuse and noise interaction in the work environment may cause
hearing loss.
Nervous system: repeated exposure affects the nervous system. Effects were seen at high
doses only.
Rat, Unspecified:
Test atmosphere: vapour
Method: Acceptable non-standard method.
Target Organs: ear
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inhalation.
Can cause liver damage.
Respiratory System: repeated exposure affects the respiratory system.
Auditory system: prolonged and repeated exposures to high concentrations have resulted in
hearing loss in rats. Solvent abuse and noise interaction in the work environment may cause
hearing loss.
Nervous system: repeated exposure affects the nervous system. Effects were seen at high
doses only.
Aspiration toxicity
Product:
Aspiration into the lungs when swallowed or vomited may cause chemical pneumonitis which
can be fatal.
Further information
Product:
Remarks: Classifications by other authorities under varying regulatory frameworks may exist.
12. ECOLOGICAL INFORMATION
Basis for assessment : Information given is based on product data.
Ecotoxicity
Product:
Toxicity to fish (Acute : LC50 (Pimephales promelas (fathead minnow)): 4.02 mg/l
toxicity) Exposure time: 96 h
Remarks: Toxic
LC/EC/IC50 >1 - <=10 mg/l
Toxicity to crustacean (Acute : EC50 (Daphnia magna (Water flea)): 4.7 mg/l
toxicity) Exposure time: 48 h
Remarks: Toxic
LC/EC/IC50 >1 - <=10 mg/l
Toxicity to algae/aquatic : ErC50 (Pseudokirchneriella subcapitata (algae)): 4.9 mg/l

plants (Acute toxicity) Exposure time: 96 h
Method: Test(s) equivalent or similar to OECD Guideline 202
Remarks: Toxic
NOEC/NOEL > 1.0 - <= 10 mg/l
Toxicity to fish (Chronic : Remarks: Data not available

toxicity)
Toxicity to crustacean : NOEC: 1.01 mg/l
(Chronic toxicity) Exposure time: 21 d
Species: Daphnia magna (Water flea)
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SAFETY DATA SHEET
Styrene Monomer

Remarks: NOEC/NOEL > 1.0 - <=10 mg/l (based on test data)
Toxicity to microorganisms : LC50 (Activated sludge): 500 mg/l

(Acute toxicity) Exposure time: 3 h
Method: Test(s) equivalent or similar to OECD Guideline 209
Remarks: Practically non toxic:
LL/EL/IL50 > 100 mg/l
Persistence and degradability

Product:
Biodegradability : Biodegradation: 70.9 %
Exposure time: 28 d
Method: Other guideline method.
Remarks: Readily biodegradable.
Bioaccumulative potential
Product:
Bioaccumulation : Remarks: Does not bioaccumulate significantly.
Partition coefficient: n- : log Pow: 2.96Method: Literature data.

octanol/water
Mobility in soil
Product:
Mobility : Remarks: Floats on water., If product enters soil, it will be
highly mobile and may contaminate groundwater.
Other adverse effects
Product:
Results of PBT and vPvB : The substance does not fulfill all screening criteria for
assessment persistence, bioaccumulation and toxicity and hence is not
considered to be PBT or vPvB.
13. DISPOSAL CONSIDERATIONS
Disposal methods
Waste from residues : Recover or recycle if possible.
It is the responsibility of the waste generator to determine the
toxicity and physical properties of the material generated to
determine the proper waste classification and disposal
methods in compliance with applicable regulations.
Do not dispose into the environment, in drains or in water

courses
Waste product should not be allowed to contaminate soil or
water.
Disposal should be in accordance with applicable regional,

national, and local laws and regulations.
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SAFETY DATA SHEET
Styrene Monomer

Local regulations may be more stringent than regional or
national requirements and must be complied with.
Contaminated packaging : Drain container thoroughly.

After draining, vent in a safe place away from sparks and fire.
Residues may cause an explosion hazard.
Do not puncture, cut, or weld uncleaned drums.
Send to drum recoverer or metal reclaimer.
Packing: Emptying: Place the package upside down, and tilt

slightly, circa 10 degrees, to enable drainage in such a way
that the lowest part of the package is at the exit orifice. On
some packing an extra hole must be made. Drainage should
be carried out at room temperature (at least 15 °C). Wait until
the package is drip dry. Do not close package after draining.
Please note the risks connected with emptying package and
containers with flammable liquids. Emptied package should be
ventilated in a safe place away from sparks and fire. Residues
may be an explosion risk. Do not puncture, cut or weld in non-
cleaned package, containers or drums.
14. TRANSPORT INFORMATION
International Regulations
ADR
UN number : 2055
Proper shipping name : STYRENE MONOMER, STABILIZED
Class : 3
Packing group : III
Labels : 3
Hazard Identification Number : 39
Environmentally hazardous : no
IATA-DGR
UN/ID No. : UN 2055
Class : 3
Packing group : III
Labels : 3
IMDG-Code
UN number : UN 2055
Class : 3
Packing group : III
Labels : 3
Marine pollutant : no
Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Pollution category : Y
Ship type : 3; Must be Double Hulled
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SAFETY DATA SHEET
Styrene Monomer

Product name : Styrene monomer
Special precautions for user
Remarks : Special Precautions: Refer to Section 7, Handling & Storage,
for special precautions which a user needs to be aware of or
needs to comply with in connection with transport.
Additional Information : This product may be transported under nitrogen blanketing.

Nitrogen is an odourless and invisible gas. Exposure to
nitrogen enriched atmospheres displaces available oxygen
which may cause asphyxiation or death. Personnel must
observe strict safety precautions when involved with a
confined space entry.
15. REGULATORY INFORMATION
Safety, health and environmental regulations/legislation specific for the substance or

mixture
Local Regulations
Workplace Safety and Health Act & Workplace This product is subject to the SDS, Labelling,
Safety and Health (General Provision) PEL and other requirements in the Act/
Regulations Regulations.
Fire Safety Act and Fire Safety (Petroleum & This product is subject to the requirements in
Flammable Materials) Regulations the Act/ Regulations.
Maritime and Port Authority of Singapore This product is subject to the requirements of
(Dangerous Goods, Petroleum and Explosives) this regulation.
Regulations
Environmental Protection and Management Act This product is not subject to the requirements
and Environmental Protection and in the Act/Regulations.
Management (Hazardous Substances)
Regulations
The regulatory information is not intended to be comprehensive. Other regulations may apply to
this material.
Other international regulations
The components of this product are reported in the following inventories:
AIIC : Listed
DSL : Listed
IECSC : Listed
ENCS : Listed
KECI : Listed
NZIoC : Listed
PICCS : Listed
TSCA : Listed
TCSI : Listed
16. OTHER INFORMATION
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SAFETY DATA SHEET
Styrene Monomer
Full text of H-Statements

H226 Flammable liquid and vapour.
H304 May be fatal if swallowed and enters airways.
H315 Causes skin irritation.
H319 Causes serious eye irritation.
H332 Harmful if inhaled.
H335 May cause respiratory irritation.
H372 Causes damage to organs through prolonged or repeated exposure.
H401 Toxic to aquatic life.
H412 Harmful to aquatic life with long lasting effects.
Full text of other abbreviations
Acute Tox. Acute toxicity
Aquatic Acute Short-term (acute) aquatic hazard
Aquatic Chronic Long-term (chronic) aquatic hazard
Asp. Tox. Aspiration hazard
Eye Irrit. Eye irritation
Flam. Liq. Flammable liquids
Skin Irrit. Skin irritation
STOT RE Specific target organ toxicity - repeated exposure
STOT SE Specific target organ toxicity - single exposure
Abbreviations and Acronyms
AICS - Australian Inventory of Chemical Substances; AIIC - Australian Inventory of Industrial

Chemicals; ANTT - National Agency for Transport by Land of Brazil; ASTM - American Society for
the Testing of Materials; bw - Body weight; CMR - Carcinogen, Mutagen or Reproductive
Toxicant; DIN - Standard of the German Institute for Standardisation; DSL - Domestic Substances
List (Canada); ECx - Concentration associated with x% response; ELx - Loading rate associated
with x% response; EmS - Emergency Schedule; ENCS - Existing and New Chemical Substances
(Japan); ErCx - Concentration associated with x% growth rate response; ERG - Emergency
Response Guide; GHS - Globally Harmonized System; GLP - Good Laboratory Practice; IARC -
International Agency for Research on Cancer; IATA - International Air Transport Association; IBC
- International Code for the Construction and Equipment of Ships carrying Dangerous Chemicals
in Bulk; IC50 - Half maximal inhibitory concentration; ICAO - International Civil Aviation
Organization; IECSC - Inventory of Existing Chemical Substances in China; IMDG - International
Maritime Dangerous Goods; IMO - International Maritime Organization; ISHL - Industrial Safety
and Health Law (Japan); ISO - International Organisation for Standardization; KECI - Korea
Existing Chemicals Inventory; LC50 - Lethal Concentration to 50 % of a test population; LD50 -
Lethal Dose to 50% of a test population (Median Lethal Dose); MARPOL - International
Convention for the Prevention of Pollution from Ships; n.o.s. - Not Otherwise Specified; Nch -
Chilean Norm; NO(A)EC - No Observed (Adverse) Effect Concentration; NO(A)EL - No Observed
(Adverse) Effect Level; NOELR - No Observable Effect Loading Rate; NOM - Official Mexican
Norm; NTP - National Toxicology Program; NZIoC - New Zealand Inventory of Chemicals; OECD
- Organization for Economic Co-operation and Development; OPPTS - Office of Chemical Safety
and Pollution Prevention; PBT - Persistent, Bioaccumulative and Toxic substance; PICCS -
Philippines Inventory of Chemicals and Chemical Substances; (Q)SAR - (Quantitative) Structure
Activity Relationship; REACH - Regulation (EC) No 1907/2006 of the European Parliament and of
the Council concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals;
SADT - Self-Accelerating Decomposition Temperature; SDS - Safety Data Sheet; TCSI - Taiwan
Chemical Substance Inventory; TDG - Transportation of Dangerous Goods; TSCA - Toxic
Substances Control Act (United States); UN - United Nations; UNRTDG - United Nations
Recommendations on the Transport of Dangerous Goods; vPvB - Very Persistent and Very
Bioaccumulative; WHMIS - Workplace Hazardous Materials Information System
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SAFETY DATA SHEET
Styrene Monomer

Further information
Training advice : Provide adequate information, instruction and training for
operators.
Other information : A vertical bar (|) in the left margin indicates an amendment
from the previous version.
Sources of key data used to : The quoted data are from, but not limited to, one or more
compile the Safety Data sources of information (e.g. toxicological data from Shell
Sheet Health Services, material suppliers’ data, CONCAWE, EU
IUCLID date base, EC 1272 regulation, etc).
The information provided in this Safety Data Sheet is correct to the best of our knowledge,
information and belief at the date of its publication. The information given is designed only as a
guidance for safe handling, use, processing, storage, transportation, disposal and release and is
not to be considered a warranty or quality specification. The information relates only to the
specific material designated and may not be valid for such material used in combination with any
other materials or in any process, unless specified in the text.
SG / EN
21 / 21 800001004869
SG

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SAFETY DATA SHEET

Version 5.7 Revision Date 01.10.2020 Print Date 03.09.2022

1. PRODUCT AND COMPANY IDENTIFICATION

Product name : Styrene Monomer

Product code : Q9211, Q9215, Q9257

Synonyms : Phenyl ethene, Phenyl ethylene, Vinyl benzene

Recommended use of the chemical and restrictions on use

Restrictions on use : Restricted to professional users., This product must not be

Version 5.7 Revision Date 01.10.2020 Print Date 03.09.2022

Signal word : Danger

Hazard statements : PHYSICAL HAZARDS:

Version 5.7 Revision Date 01.10.2020 Print Date 03.09.2022

Other hazards which do not result in classification

Substance / Mixture : Substance

If inhaled : Call emergency number for your location / facility.

Version 5.7 Revision Date 01.10.2020 Print Date 03.09.2022

In case of eye contact : Immediately flush eye(s) with plenty of water.

If swallowed : Call emergency number for your location / facility.

Skin irritation signs and symptoms may include a burning

Eye irritation signs and symptoms may include a burning

If material enters lungs, signs and symptoms may include

Defatting dermatitis signs and symptoms may include a

Version 5.7 Revision Date 01.10.2020 Print Date 03.09.2022

Notes to physician : IMMEDIATE TREATMENT IS EXTREMELY IMPORTANT!

Unsuitable extinguishing : Do not use water in a jet.

Specific hazards during : Flammable vapours may be present even at temperatures

Specific extinguishing : Standard procedure for chemical fires.

Special protective equipment : Proper protective equipment including chemical resistant

6. ACCIDENTAL RELEASE MEASURES

Personal precautions, : Observe all relevant local and international regulations.

: Isolate hazard area and deny entry to unnecessary or

Version 5.7 Revision Date 01.10.2020 Print Date 03.09.2022

Additional advice : For guidance on selection of personal protective equipment

7. HANDLING AND STORAGE

Advice on safe handling : Avoid inhaling vapour and/or mists.

Version 5.7 Revision Date 01.10.2020 Print Date 03.09.2022

Avoidance of contact : Strong oxidising agents.

Other data : Storage Temperature:

Keep away from aerosols, flammables, oxidizing agents,

Version 5.7 Revision Date 01.10.2020 Print Date 03.09.2022

Specific use(s) : Not applicable

Ensure that all local regulations regarding handling and

8. EXPOSURE CONTROLS AND PERSONAL PROTECTION

Components with workplace control parameters

Biological occupational exposure limits

Version 5.7 Revision Date 01.10.2020 Print Date 03.09.2022

Engineering measures : Use sealed systems as far as possible.

Personal protective equipment

Respiratory protection : If engineering controls do not maintain airborne

Version 5.7 Revision Date 01.10.2020 Print Date 03.09.2022

For continuous contact we recommend gloves with

Environmental exposure controls

Version 5.7 Revision Date 01.10.2020 Print Date 03.09.2022

9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance : Oily liquid.

Colour : Colourless to yellowish

Evaporation rate : 12.4

Flammability (solid, gas) : Data not available

Upper explosion limit : 6.1 %(V)

Lower explosion limit : 1.1 %(V)