Date Printed: 05/04/2020 Product: IIN-DECKPUTTY-AC

Safety Data Sheet

according to Regulation (EC)
No. 2015/830

SECTION 1: Identification of the Substance/Mixture and the Company/Undertaking

1.1 Product Identifier IIN-DECKPUTTY-AC Revision Date: 05/04/2020

Product Name: DECKSHIELD PUTTY Supersedes Date: New SDS

HARDENER B

1.2 Relevant identified uses of the Hardener for 2 components coatings - Industrial use.
substance or mixture and
uses advised against

1.3 Details of the supplier of the safety data sheet

Importer: None

Manufacturer: StonCor Middle East L.L.C.

Plot # B518, Al Quoz Industrial Area 3
P.O. Box: 3034
Dubai, U.A.E.

Regulatory / Technical Information:

+971 4 347 0460
+971 4 347 0242 (fax)

Datasheet Produced by: Rivero, Melody - [email protected]

1.4 Emergency telephone number: CHEMTREC +1 703 5273887 (Outside US)

+ 971 55 781 7362(Sarvar Ansari- Regional
Technical Manager)
+ 971 50 656 0453(Kevin McCarthy - Regional
Operations Manager)

SECTION 2: Hazard Identification

2.1 Classification of the substance or mixture

Classification according to Classification, Labeling & Packaging Regulation (EC) 1272/2008

HAZARD STATEMENTS

Skin Corrosion, category 1 H314-1

Skin Sensitizer, category 1 H317

Page 1 / 10
Date Printed: 05/04/2020 Product: IIN-DECKPUTTY-AC

Acute Toxicity, Inhalation, category 2 H330-2

Carcinogenicity, category 1A H350-1A
Reproductive Toxicity, category 2 H361
STOT, single exposure, category 1 H370
Hazardous to the aquatic environment, Chronic, category 2 H411
2.2 Label elements

Symbol(s) of Product

Signal Word
Danger

Named Chemicals on Label

Diethylenetriamine, quartz (silicon dioxide), 4-nonylphenol, branched
HAZARD STATEMENTS

Skin Corrosion, category 1 H314-1 Causes severe skin burns and eye damage.
Skin Sensitizer, category 1 H317 May cause an allergic skin reaction.
Acute Toxicity, Inhalation, category 2 H330-2 Fatal if inhaled.
Carcinogenicity, category 1A H350-1A May cause cancer.
Reproductive Toxicity, category 2 H361 Suspected of damaging fertility or the unborn child.
STOT, single exposure, category 1 H370 Causes damage to organs.
Hazardous to the aquatic environment, H411 Toxic to aquatic life with long lasting effects.
Chronic, category 2
PRECAUTION PHRASES
P201 Obtain special instructions before use.
P202 Do not handle until all safety precautions have been read
and understood.
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P264 Wash hands thoroughly after handling.
P273 Avoid release to the environment.
P280 Wear protective gloves/protective clothing/eye protection/
face protection.
P284 Wear respiratory protection.
P301+310 IF SWALLOWED: Immediately call a POISON CENTER or
doctor/physician.
P301+330+331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P302+352 IF ON SKIN: Wash with plenty of soap and water.
P304+340 IF INHALED: Remove victim to fresh air and keep at rest in
a position comfortable for breathing.
P305+P351+P33 IF IN EYES: Rinse cautiously with water for several minutes.
8 Remove contact lenses, if present and easy to do so.
Continue rinsing.
P307+311 IF exposed, call a POISON CENTER or doctor/physician.
P308+313 IF exposed or concerned: Get medical advice/attention.
P314 Get medical advice/attention if you feel unwell.
P333+313 If skin irritation or rash occurs: Get medical advice/attention.
P363 Wash contaminated clothing before reuse.
P391 Collect spillage.
P403+233 Store in a well-ventilated place. Keep container tightly
closed.

Page 2 / 10
Date Printed: 05/04/2020 Product: IIN-DECKPUTTY-AC

2.3 Other hazards

No Information

Results of PBT and vPvB assessment:

The product does not meet the criteria for PBT/VPvB in accordance with Annex XIII.

SECTION 3: Composition/Information On Ingredients

3.2 Mixtures
Hazardous Ingredients
CAS-No. EINEC No. Name According to EEC %
14808-60-7 238-878-4 quartz (silicon dioxide) 50 - <75
84852-15-3 284-325-5 4-nonylphenol, branched 10 - <25
111-40-0 203-865-4 Diethylenetriamine 1.0 - <2.5

CAS-No. REACH Reg No. CLP Symbols CLP Hazard Statements M-Factors
14808-60-7 GHS08 H350-370
84852-15-3 GHS05-GHS07-GHS08-GHS09 H302-314-361-400-410
111-40-0 GHS05-GHS06 H302-312-314-317-330-335

Additional Information: The text for CLP Hazard Statements shown above (if any) is given in Section 16.

SECTION 4: First-aid Measures

4.1 Description of First Aid Measures
GENERAL NOTES: When symptoms persist or in all cases of doubt seek medical advice.
AFTER INHALATION: Move to fresh air. Consult a physician after significant exposure.
AFTER SKIN CONTACT: Use a mild soap if available. Wash off immediately with soap and plenty of water while removing
all contaminated clothes and shoes.
AFTER EYE CONTACT: Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Remove
contact lenses.
AFTER INGESTION: Do NOT induce vomiting. Never give anything by mouth to an unconscious person.
Self protection of the first aider:
No action shall be taken involving any personal risk or without suitable training. It may be dangerous to the person providing
aid to give mouth-to-mouth resuscitation. Wash contaminated clothing thoroughly with water before removing it, or wear
gloves.

4.2 Most important symptoms and effects, both acute and delayed

No Information
4.3 Indication of any immediate medical attention and special treatment needed

No information available on clinical testing and medical monitoring. Specific toxicological information on substances, if
available, can be found in section 11.

SECTION 5: Fire-fighting Measures

5.1 Extinguishing Media:
Carbon Dioxide, Dry Chemical, Foam
FOR SAFETY REASONS NOT TO BE USED: Alcohol, Alcohol based solutions, any other media not listed above.

5.2 Special hazards arising from the substance or mixture

No Information

5.3 Advice for firefighters

In the event of fire, wear self-contained breathing apparatus. High volume water jet. Hazardous decomposition products
formed under fire conditions. Collect contaminated fire extinguishing water separately. This must not be discharged into

Page 3 / 10
Date Printed: 05/04/2020 Product: IIN-DECKPUTTY-AC

drains. Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.

SECTION 6: Accidental Release Measures

6.1 Personal precautions, protective equipment and emergency procedures
Ensure adequate ventilation. Use personal protective equipment.
6.2 Environmental precautions
Do not allow material to contaminate ground water system. Prevent product from entering drains. Keep the container open.
6.3 Methods and material for containment and cleaning up
Prevent further leakage or spillage if safe to do so. Contain spillage, soak up with non-combustible absorbent material, (e.g.
sand, earth, diatomaceous earth, vermiculite) and transfer to a container for disposal according to local / national regulations
(see section 13).
6.4 Reference to other sections

FURTHER INSTRUCTIONS: Please refer to EU disposal requirements or country specific disposal requirements for this
material. See Section 13 for further information.

SECTION 7: Handling and Storage

7.1 Precautions for safe handling

Use only in area provided with appropriate exhaust ventilation. Wear personal protective equipment. Do not breathe
vapours or spray mist. Persons with a history of skin sensitisation problems or asthma, allergies, chronic or recurrent
respiratory disease should not be employed in any process in which this preparation is being used.
Wash hands before breaks and at the end of workday. When using, do not eat, drink or smoke.

7.2 Conditions for safe storage, including any incompatibilities

CONDITIONS TO AVOID: Avoid dust accumulation in enclosed space.
STORAGE CONDITIONS: Store in original container. Keep container tightly closed in a dry and well-ventilated place. Keep
locked up or in an area accessible only to qualified or authorised persons.
7.3 Specific end use(s)

No specific advice for end use available.

SECTION 8: Exposure Controls/Personal Protection

8.1 Control parameters

Ingredients with Occupational Exposure Limits
(EU)

Name CAS-No. LTEL ppm STEL ppm STEL mg/m3 LTEL mg/m3
quartz (silicon dioxide) 14808-60-7
4-nonylphenol, branched 84852-15-3
Diethylenetriamine 111-40-0

Name CAS-No. OEL Note

quartz (silicon dioxide) 14808-60-7

4-nonylphenol, branched 84852-15-3

Diethylenetriamine 111-40-0

FURTHER ADVICE: Refer to the regulatory exposure limits for the workforce enforced in each country. Some components may
not have been classified under the EU CLP Regulation.

Page 4 / 10
Date Printed: 05/04/2020 Product: IIN-DECKPUTTY-AC

8.2 Exposure controls

Personal Protection
RESPIRATORY PROTECTION: Respirator with a vapor filter.
EYE PROTECTION: Tightly fitting safety goggles.
HAND PROTECTION: Impervious gloves. Long sleeved clothing. Remove and wash contaminated clothing before re-use.
OTHER PROTECTIVE EQUIPMENT: No Information
ENGINEERING CONTROLS: Avoid contact with skin, eyes and clothing. Ensure adequate ventilation, especially in
confined areas.

Chemical Name:
EC No.: CAS-No.:

DNELs - Derived no effect level

Workers Consumers
Route of Acute effect Acute effects Chronic effects Chronic effects Acute effect Acute effects Chronic effects Chronic effects
Exposure local systemic local systemic local systemic local systemic
Oral Not required
Inhalation
Dermal
PNEC's - Predicted no effect concentration
Environmental protection target PNEC
Fresh water
Fresh water sediments
Marine water
Marine sediments
Food chain
Microorganisms in sewage treatment
soil (agricultural)
Air

SECTION 9: Physical and Chemical Properties

9.1 Information on basic physical and chemical properties
Appearance: Grey Thick Paste
Physical State Liquid
Odor Slight Amine
Odor threshold Not determined
pH Not determined
Melting point / freezing point (°C) Not determined
Boiling point/range (°C) 130 - 277
Flash Point, (°C) 93
Evaporation rate Not determined
Flammability (solid, gas) Not determined

Upper/lower flammability or explosive Not determined

limits
Vapour Pressure Not determined
Vapour density Not determined
Relative density Not determined
Solubility in / Miscibility with water

Page 5 / 10
Date Printed: 05/04/2020 Product: IIN-DECKPUTTY-AC

Insoluble
Partition coefficient: n-octanol/water Not determined
Auto-ignition temperature (°C) Not determined
Decomposition temperature (°C) Not determined
Viscosity Unknown
Explosive properties Not determined
Oxidising properties Not determined

9.2 Other information

VOC Content g/l: N/A

Specific Gravity (g/cm3) 1.690

SECTION 10: Stability and Reactivity

10.1 Reactivity
No reactivity hazards known under normal storage and use conditions.
10.2 Chemical stability
Container can be pressurized by carbon dioxide due to reaction with humid air and/or water. Stable under normal conditions.

10.3 Possibility of hazardous reactions

Hazardous polymerisation does not occur.
10.4 Conditions to avoid
Avoid dust accumulation in enclosed space.
10.5 Incompatible materials
No Information

10.6 Hazardous decomposition products

Carbon dioxide (CO2), carbon monoxide (CO), oxides of nitrogen (NOx), dense black smoke.

SECTION 11: Toxicological Information

11.1 Information on toxicological effects
Acute Toxicity:
Oral LD50: No information available.
Inhalation LC50: No information available.

Irritation: No information available.

Corrosivity: No information available.

Sensitization: No information available.

Repeated dose toxicity: No information available.

Carcinogenicity: No information available.

Mutagenicity: No information available.

Toxicity for reproduction: No information available.

Page 6 / 10
Date Printed: 05/04/2020 Product: IIN-DECKPUTTY-AC

STOT-single exposure: No information available.

STOT-repeated exposure: No information available.

Aspiration hazard: No information available.

If no information is available above under Acute Toxicity then the acute effects of this product have not been tested.
Data on individual components are tabulated below:

CAS-No. Name According to EEC Oral LD50 Dermal LD50 Vapor LC50 Gas LC50 Dust/Mist LC50

84852-15-3 4-nonylphenol, branched 1620 mg/kg oral 0.000 0.000

1080 mg/kg, oral, 10 mg/L / 1 hour,
111-40-0 Diethylenetriamine rat
1090 mg/kg
inh, rat
0.000 0.000

Additional Information:
Persons allergic to isocyanates, and particularly those suffering from asthma or other respiratory conditions, should not work with
isocyanates.

SECTION 12: Ecological Information

12.1 Toxicity:

EC50 48hr (Daphnia): No information

IC50 72hr (Algae): No information
LC50 96hr (fish): No information

12.2 Persistence and degradability: No information

12.3 Bioaccumulative potential: No information

12.4 Mobility in soil: No information

12.5 Results of PBT and vPvB The product does not meet the criteria for PBT/VPvB in accordance with Annex XIII.
assessment:

12.6 Other adverse effects: No information

CAS-No. Name According to EEC EC50 48hr IC50 72hr LC50 96hr

14808-60-7 quartz (silicon dioxide) No information No information

84852-15-3 4-nonylphenol, branched No information No information
111-40-0 Diethylenetriamine 780 mg/l No information 430 mg/l

SECTION 13: Disposal Considerations

13.1 WASTE TREATMENT METHODS: If recycling is not practicable, dispose of in compliance with local regulations. Empty
containers should be taken to an approved waste handling site for recycling or disposal.
European Waste Code: 080111
Packaging Waste Code: 150110

Page 7 / 10
Date Printed: 05/04/2020 Product: IIN-DECKPUTTY-AC

SECTION 14: Transport Information

14.1 UN number None
14.2 UN proper shipping name Not Regulated
Technical name Not applicable
14.3 Transport hazard class(es) None
Subsidiary shipping hazard Not applicable
14.4 Packing group Not applicable
14.5 Environmental hazards Unknown
14.6 Special precautions for user Unknown
EmS-No.: NONE

14.7 Transport in bulk according to Annex Unknown

II of MARPOL 73/78 and the IBC code

SECTION 15: Regulatory Information

15.1 Safety, health and environmental regulations/legislation for the substance or mixture:

National Regulations:

Denmark Product Registration Number: Not available

Danish MAL Code: Not available

Danish MAL Code - Mixture: Not available

Sweden Product Registration Number: Not available

Norway Product Registration Number: Not available

Germany WGK Class: Not available

Covered by Directive 2012/18/EC (Seveso III): Not applicable

Restrictions to product or to substances according

to Annex XVII, Regulation (CE) 1907/2006: Not applicable

Annex XIV - Authorisation List:

CAS-No. Name According to EEC

Not Applicable

SVHC - Substances of very high concern (Candidate List):

CAS-No. Name According to EEC

Not Applicable

15.2 Chemical Safety Assessment:

No Chemical Safety Assessment has been carried out for this substance/mixture by the supplier.

Page 8 / 10
Date Printed: 05/04/2020 Product: IIN-DECKPUTTY-AC

SECTION 16: Other Information

Text for CLP Hazard Statements shown in Section 3 describing each ingredient:

H302 Harmful if swallowed.

H312 Harmful in contact with skin.
H314 Causes severe skin burns and eye damage.
H317 May cause an allergic skin reaction.
H330 Fatal if inhaled.
H335 May cause respiratory irritation.
H350 May cause cancer.
H361 Suspected of damaging fertility or the unborn child.
H370 Causes damage to organs.
H400 Very toxic to aquatic life.
H410 Very toxic to aquatic life with long lasting effects.
Reasons for revision
No Information

List of References:

This Safety Data Sheet was compiled with data and information from the following sources:

The Ariel Regulatory Database provided by the 3E Corporation in Copenhagen, Denmark;

European Union Commission Regulation No. 1907/2006 on REACH as amended within Commission
Regulation (EU) 2015/830;
European Union (EC) Regulation No. 1272/2008 on the classification, labelling and packaging of
substances and mixtures (CLP Regulation) and subsequent technical progress adaptations (ATP);
EU Council Decision 2000/532/EC and its Annex entitled "List of Wastes".

Acronym & Abbreviation Key:

CLP Classification, Labeling & Packaging Regulation

EC European Commission
EU European Union
US United States
CAS Chemical Abstract Service
EINECS European Inventory of Existing Chemical Substances
REACH Registration, Evaluation, Authorization of Chemicals Regulation
GHS Globally Harmonized System of Classification and Labeling of Chemicals
LTEL Long term exposure limit
STEL Short term exposure limit
OEL Occupational exposure limit
ppm Parts per million
mg/m3 Milligrams per cubic meter
TLV Threshold Limit Value
ACGIH American Conference of Governmental Industrial Hygienists
OSHA Occupational Safety & Health Administration
PEL Permissible Exposure Limits
VOC Volatile organic compounds
g/l Grams per liter
mg/kg Milligrams per kilogram
N/A Not applicable
LD50 Lethal dose at 50%
LC50 Lethal concentration at 50%
EC50 Half maximal effective concentration
IC50 Half maximal inhibitory concentration
PBT Persistent bioaccumulative toxic chemical

Page 9 / 10
Date Printed: 05/04/2020 Product: IIN-DECKPUTTY-AC
vPvB Very persistent and very bioaccumulative
EEC European Economic Community
ADR International Transport of Dangerous Goods by Road
RID International Transport of Dangerous Goods by Rail
UN United Nations
IMDG International Maritime Dangerous Goods Code
IATA International Air Transport Association
MARPOL International Convention for the Prevention of Pollution From Ships, 1973 as
modified by the Protocol of 1978
IBC International Bulk Container
RTI Respiratory Tract Irritation
NE Narcotic Effects

For further information, please contact: Technical Services Department

The information on this sheet corresponds to our present knowledge. It is not a specification
and it does not guarantee specific properties. The information is intended to provide general
guidance as to health and safety based upon our knowledge of the handling, storage, and use of
the product. It is not applicable to unusual or non-standard uses of the product or where
instructions and recommendations are not followed.

Page 10 / 10