Fosroc Solvent 102 SDS Promain 17 09 2018

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Revision date: 17/09/2018 Revision: 7a Supersedes date: 11/07/2015

SAFETY DATA SHEET


Fosroc Solvent 102

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1. Product identifier


Product name Fosroc Solvent 102

Product number 1565005UK9, 1565006UK9, 1565010UK9

UFI UFI: 7250-60DW-X004-38C6

1.2. Relevant identified uses of the substance or mixture and uses advised against
Identified uses Cleaning agent. Cleaning sealant application equipment.

1.3. Details of the supplier of the safety data sheet


Manufacturer Fosroc International Limited
Drayton Manor Business Park
Coleshill Road
Tamworth
Staffordshire
B78 3XN
England
Tel: +44 (0) 1827 262222
Fax: +44 (0) 1827 262444
[email protected]

1.4. Emergency telephone number


Emergency telephone +44 (0) 1827 265 279 (Monday-Sunday 24 hours a day)

SECTION 2: Hazards identification

2.1. Classification of the substance or mixture


Classification (EC 1272/2008)
Physical hazards Flam. Liq. 3 - H226

Health hazards STOT SE 3 - H335, H336

Environmental hazards Aquatic Chronic 2 - H411

Human health The liquid may be irritating to eyes, respiratory system and skin.

Environmental The product contains a substance which is toxic to aquatic organisms and which may cause
long-term adverse effects in the aquatic environment.

Physicochemical Vapours may form explosive mixtures with air.

2.2. Label elements

Hazard pictograms

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Signal word Warning

Hazard statements H226 Flammable liquid and vapour.


H335 May cause respiratory irritation.
H336 May cause drowsiness or dizziness.
H411 Toxic to aquatic life with long lasting effects.

Precautionary statements P261 Avoid breathing vapour/ spray.


P280 Wear protective gloves/ protective clothing/ eye protection/ face protection.
P303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing.
Rinse skin with water or shower.
P331 Do NOT induce vomiting.
P501 Dispose of contents/ container in accordance with national regulations.

Contains HYDROCARBONS, C9, aromatics, 1-METHOXY-2-PROPANOL

Supplementary precautionary P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No
statements smoking.
P240 Ground and bond container and receiving equipment.
P241 Use explosion-proof electrical equipment.
P242 Use non-sparking tools.
P243 Take action to prevent static discharges.
P271 Use only outdoors or in a well-ventilated area.
P273 Avoid release to the environment.
P301+P310 IF SWALLOWED: Immediately call a POISON CENTER/ doctor.
P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P312 Call a POISON CENTRE/doctor if you feel unwell.
P370+P378 In case of fire: Use foam, carbon dioxide, dry powder or water fog to extinguish.
P391 Collect spillage.
P403+P233 Store in a well-ventilated place. Keep container tightly closed.
P403+P235 Store in a well-ventilated place. Keep cool.
P405 Store locked up.

2.3. Other hazards


This substance is not classified as PBT or vPvB according to current EU criteria.

SECTION 3: Composition/information on ingredients

3.2. Mixtures

HYDROCARBONS, C9, aromatics 60-100%


CAS number: 64742-95-6 EC number: 918-668-5 REACH registration number: 01-
2119455851-35-0000

Classification
Flam. Liq. 3 - H226
STOT SE 3 - H335, H336
Asp. Tox. 1 - H304
Aquatic Chronic 2 - H411

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Fosroc Solvent 102

1-METHOXY-2-PROPANOL 10-30%
CAS number: 107-98-2 EC number: 203-539-1

Classification
Flam. Liq. 3 - H226
STOT SE 3 - H336

The Full Text for all R-Phrases and Hazard Statements are Displayed in Section 16.

SECTION 4: First aid measures

4.1. Description of first aid measures


General information Move affected person to fresh air at once. Get medical attention if any discomfort continues.

Inhalation Get medical attention. Move affected person to fresh air and keep warm and at rest in a
position comfortable for breathing. When breathing is difficult, properly trained personnel may
assist affected person by administering oxygen.

Ingestion Do not induce vomiting. If vomiting occurs, the head should be kept low so that vomit does not
enter the lungs. Never give anything by mouth to an unconscious person. Give plenty of water
to drink. Get medical attention immediately. Move affected person to fresh air and keep warm
and at rest in a position comfortable for breathing.

Skin contact Remove affected person from source of contamination. Remove contaminated clothing. Wash
skin thoroughly with soap and water. Get medical attention promptly if symptoms occur after
washing.

Eye contact Rinse immediately with plenty of water. Remove contact lenses, if present and easy to do.
Continue rinsing. Continue to rinse for at least 15 minutes. Get medical attention if irritation
persists after washing. Show this Safety Data Sheet to the medical personnel.

4.2. Most important symptoms and effects, both acute and delayed
General information The severity of the symptoms described will vary dependent on the concentration and the
length of exposure.

Inhalation Headache. Drowsiness, dizziness, disorientation, vertigo. Nausea, vomiting. A single


exposure may cause the following adverse effects: Central nervous system depression.
Difficulty in breathing.

Ingestion May cause discomfort if swallowed. Entry into the lungs following ingestion or vomiting may
cause chemical pneumonitis.

Skin contact Prolonged or repeated contact with skin may cause irritation, redness and dermatitis.

Eye contact May cause temporary eye irritation.

4.3. Indication of any immediate medical attention and special treatment needed
Notes for the doctor Treat symptomatically.

SECTION 5: Firefighting measures

5.1. Extinguishing media


Suitable extinguishing media Extinguish with foam, carbon dioxide, dry powder or water fog. Foam. Dry chemicals, sand,
dolomite etc.

Unsuitable extinguishing Do not use water jet as an extinguisher, as this will spread the fire.
media

5.2. Special hazards arising from the substance or mixture

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Specific hazards No unusual fire or explosion hazards noted.

Hazardous combustion Thermal decomposition or combustion may liberate carbon oxides and other toxic gases or
products vapours.

5.3. Advice for firefighters


Protective actions during Avoid breathing fire gases or vapours. Cool containers exposed to heat with water spray and
firefighting remove them from the fire area if it can be done without risk.

Special protective equipment Wear chemical protective suit.


for firefighters

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures


Personal precautions Wear protective clothing as described in Section 8 of this safety data sheet.

6.2. Environmental precautions


Environmental precautions Do not discharge into drains or watercourses or onto the ground.

6.3. Methods and material for containment and cleaning up


Methods for cleaning up Eliminate all sources of ignition. No smoking, sparks, flames or other sources of ignition near
spillage. Provide adequate ventilation. Stop leak if possible without risk. Contain and absorb
spillage with sand, earth or other non-combustible material. Collect spillage with a shovel and
broom, or similar and reuse, if possible. Dispose of waste to licensed waste disposal site in
accordance with the requirements of the local Waste Disposal Authority. Avoid the spillage or
runoff entering drains, sewers or watercourses. Inform authorities if large amounts are
involved.

6.4. Reference to other sections


Reference to other sections For personal protection, see Section 8. For waste disposal, see section 13.

SECTION 7: Handling and storage

7.1. Precautions for safe handling


Usage precautions Avoid spilling. Avoid contact with skin and eyes. Provide adequate ventilation. Avoid inhalation
of vapours. Use approved respirator if air contamination is above an acceptable level. Keep
away from heat, sparks and open flame. Static electricity and formation of sparks must be
prevented. Storage tanks and other containers must be earthed.

7.2. Conditions for safe storage, including any incompatibilities


Storage precautions Store in tightly-closed, original container in a dry, cool and well-ventilated place. Keep only in
the original container.

Storage class Flammable liquid storage.

7.3. Specific end use(s)


Specific end use(s) The identified uses for this product are detailed in Section 1.2.

SECTION 8: Exposure controls/Personal protection

8.1. Control parameters


Occupational exposure limits
HYDROCARBONS, C9, aromatics
Long-term exposure limit (8-hour TWA): WEL 100 mg/m³
1-METHOXY-2-PROPANOL

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Sk
Long-term exposure limit (8-hour TWA): WEL 100 ppm 375 mg/m³
Short-term exposure limit (15-minute): WEL 150 ppm 560 mg/m³
Sk = Can be absorbed through the skin.
WEL = Workplace Exposure Limit.

HYDROCARBONS, C9, aromatics (CAS: 64742-95-6)

DNEL Professional - Dermal; systemic effects: 25 mg/kg/day


Professional - Inhalation; systemic effects: 150 mg/m³
Consumer - Oral; systemic effects: 11 mg/kg/day
Consumer - Inhalation; systemic effects: 32 mg/m³
Consumer - Dermal; systemic effects: 11 mg/kg/day

1-METHOXY-2-PROPANOL (CAS: 107-98-2)

DNEL Industry - Inhalation; Short term local effects: 553.5 mg/m³


Industry - Dermal; Long term systemic effects: 50.6 mg/kg/day
Industry - Inhalation; Long term systemic effects: 369 mg/m³

PNEC - Fresh water; 10 mg/l


- marine water; 1 mg/l
- Intermittent release; 100 mg/l

8.2. Exposure controls

Protective equipment

Appropriate engineering Provide adequate general and local exhaust ventilation.


controls

Eye/face protection The following protection should be worn: Chemical splash goggles.

Hand protection It is recommended that gloves are made of the following material: Nitrile rubber. It should be
noted that liquid may penetrate the gloves. Frequent changes are recommended. The most
suitable glove should be chosen in consultation with the glove supplier/manufacturer, who can
provide information about the breakthrough time of the glove material.

Other skin and body Wear appropriate clothing to prevent any possibility of liquid contact and repeated or
protection prolonged vapour contact.

Hygiene measures Use engineering controls to reduce air contamination to permissible exposure level. Provide
eyewash station. Do not smoke in work area. Wash at the end of each work shift and before
eating, smoking and using the toilet. Promptly remove any clothing that becomes
contaminated. Wash promptly with soap and water if skin becomes contaminated. Use
appropriate skin cream to prevent drying of skin. When using do not eat, drink or smoke.

Respiratory protection If ventilation is inadequate, suitable respiratory protection must be worn. Wear a respirator
fitted with the following cartridge: Gas filter, type AX.

SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties


Appearance Liquid.

Colour Colourless.

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Odour Aromatic.

Odour threshold Not determined.

pH Not applicable.

Melting point Not applicable.

Initial boiling point and range 117 - 160°C @ 101 kPa

Flash point 38°C

Evaporation rate Not determined.

Evaporation factor Not determined.

Flammability (solid, gas) Not applicable.

Upper/lower flammability or Lower flammable/explosive limit: 1 % Upper flammable/explosive limit: 11.5 %


explosive limits

Other flammability Not determined.

Vapour pressure 0.26 kPa @ 20°C

Vapour density Not determined.

Relative density 0.9 @ at 20°C

Bulk density Not applicable.

Solubility(ies) Insoluble in water.

Partition coefficient Not determined.

Auto-ignition temperature >500°C

Decomposition Temperature Not determined.

Viscosity Not determined.

Explosive properties Not considered to be explosive.

Explosive under the influence Not considered to be explosive.


of a flame

Oxidising properties Does not meet the criteria for classification as oxidising.

9.2. Other information


Other information No data available.

SECTION 10: Stability and reactivity

10.1. Reactivity
Reactivity There are no known reactivity hazards associated with this product.

10.2. Chemical stability


Stability Stable at normal ambient temperatures. Contains volatile solvent.

10.3. Possibility of hazardous reactions


Possibility of hazardous None known. Will not polymerise.
reactions

10.4. Conditions to avoid


Conditions to avoid Avoid heat, flames and other sources of ignition.

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10.5. Incompatible materials


Materials to avoid Strong oxidising agents. Strong acids.

10.6. Hazardous decomposition products


Hazardous decomposition Oxides of carbon.
products

SECTION 11: Toxicological information

11.1. Information on toxicological effects

Inhalation Gas or vapour in high concentrations may irritate the respiratory system. Symptoms following
overexposure may include the following: Coughing. Vapours in high concentrations are
anaesthetic. Headache. Fatigue. Dizziness. Central nervous system depression.

Ingestion Aspiration hazard if swallowed. Entry into the lungs following ingestion or vomiting may cause
chemical pneumonitis. May cause discomfort if swallowed.

Skin contact Product has a defatting effect on skin. Prolonged or repeated exposure may cause severe
irritation. Repeated and/or prolonged contact may lead to dermatitis.

Eye contact May cause temporary eye irritation.

Toxicological information on ingredients.

HYDROCARBONS, C9, aromatics

Acute toxicity - oral

Acute toxicity oral (LD₅₀ 3,592.0


mg/kg)

Species Rat

Acute toxicity - dermal

Acute toxicity dermal (LD₅₀ 3,160.0


mg/kg)

Species Rabbit

Acute toxicity - inhalation

Acute toxicity inhalation 6.2


(LC₅₀ vapours mg/l)

Species Rat

ATE inhalation (vapours 6.2


mg/l)

1-METHOXY-2-PROPANOL

Acute toxicity - oral

Notes (oral LD₅₀) LD₅₀ 11700 mg/kg, Oral, Rat

Acute toxicity - dermal

Notes (dermal LD₅₀) LD₅₀ 13000 mg/kg, Dermal, Rabbit

Acute toxicity - inhalation

Notes (inhalation LC₅₀) LC50 10000 ppm, Inhalation, Rat

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SECTION 12: Ecological information

Ecotoxicity The product contains substances which are toxic to aquatic organisms and which may cause
long-term adverse effects in the aquatic environment.

12.1. Toxicity
Toxicity No data available.

Ecological information on ingredients.

HYDROCARBONS, C9, aromatics

Acute aquatic toxicity

Acute toxicity - fish LC₅₀, : 9.2 mg/l, Oncorhynchus mykiss (Rainbow trout)

Acute toxicity - aquatic EC₅₀, : 3.2 mg/l, Daphnia magna


invertebrates

Acute toxicity - aquatic EC₅₀, : 2.6 mg/l, Pseudokirchneriella subcapitata


plants

1-METHOXY-2-PROPANOL

Acute aquatic toxicity

Acute toxicity - fish LC₅₀, 96 hours: 6812 mg/l, Leuciscus idus (Golden orfe)

Acute toxicity - aquatic EC₅₀, 48 hours: >21000 mg/l, Daphnia magna


invertebrates

12.2. Persistence and degradability


Persistence and degradability The product is expected to be biodegradable.

Ecological information on ingredients.

HYDROCARBONS, C9, aromatics

Biodegradation Water - Degradation (%) 78: 28 days


The substance is readily biodegradable.

1-METHOXY-2-PROPANOL

Persistence and The product is biodegradable.


degradability

12.3. Bioaccumulative potential


Bioaccumulative potential Bioaccumulative, however with short retention period of the order of one week or less.

Partition coefficient Not determined.

Ecological information on ingredients.

1-METHOXY-2-PROPANOL

Bioaccumulative potential The product does not contain any substances expected to be bioaccumulating.

12.4. Mobility in soil


Mobility Mobile. The product contains volatile organic compounds (VOCs) which will evaporate easily
from all surfaces. The product is insoluble in water and will spread on the water surface.

12.5. Results of PBT and vPvB assessment

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Results of PBT and vPvB This product does not contain any substances classified as PBT or vPvB.
assessment

12.6. Other adverse effects


Other adverse effects None known.

SECTION 13: Disposal considerations

13.1. Waste treatment methods


General information Waste is suitable for incineration. Waste is classified as hazardous waste.

Disposal methods Dispose of waste to licensed waste disposal site in accordance with the requirements of the
local Waste Disposal Authority.

SECTION 14: Transport information

14.1. UN number
UN No. (ADR/RID) 1993

UN No. (IMDG) 1993

UN No. (ICAO) 1993

UN No. (ADN) 1993

14.2. UN proper shipping name


Proper shipping name FLAMMABLE LIQUID, N.O.S. (CONTAINS SOLVENT NAPHTHA)
(ADR/RID)

Proper shipping name (IMDG) FLAMMABLE LIQUID, N.O.S. (CONTAINS SOLVENT NAPHTHA)

Proper shipping name (ICAO) FLAMMABLE LIQUID, N.O.S. (CONTAINS SOLVENT NAPHTHA)

Proper shipping name (ADN) FLAMMABLE LIQUID, N.O.S. (CONTAINS SOLVENT NAPHTHA)

14.3. Transport hazard class(es)


ADR/RID class 3

ADR/RID classification code F1

ADR/RID label 3

IMDG class 3

ICAO class/division 3

ADN class 3

Transport labels

14.4. Packing group


ADR/RID packing group III

IMDG packing group III

ICAO packing group III

ADN packing group III

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14.5. Environmental hazards

Environmentally hazardous substance/marine pollutant

14.6. Special precautions for user


EmS F-E, S-E

ADR transport category 3

Emergency Action Code •3Y

Hazard Identification Number 30


(ADR/RID)

Tunnel restriction code (D/E)

14.7. Transport in bulk according to Annex II of MARPOL and the IBC Code
Transport in bulk according to Not applicable.
Annex II of MARPOL 73/78
and the IBC Code

SECTION 15: Regulatory information

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
National regulations Control of Substances Hazardous to Health Regulations 2002 (as amended).

EU legislation Regulation (EC) No 1272/2008 of the European Parliament and of the Council of 16
December 2008 on classification, labelling and packaging of substances and mixtures (as
amended).
Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18
December 2006 concerning the Registration, Evaluation, Authorisation and Restriction of
Chemicals (REACH) (as amended).
Commission Regulation (EU) No 2015/830 of 28 May 2015.

Guidance Respiratory protective equipment at work (HSG53).


Introduction to Local Exhaust Ventilation HS(G)37.
Workplace Exposure Limits EH40.
Approved Classification and Labelling Guide (Sixth edition) L131.

15.2. Chemical safety assessment


No chemical safety assessment has been carried out.

SECTION 16: Other information

General information For professional users only.

Revision comments NOTE: Lines within the margin indicate significant changes from the previous revision.

Revision date 17/09/2018

Revision 7a

Supersedes date 11/07/2015

SDS number 12405

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Hazard statements in full H226 Flammable liquid and vapour.


H335 May cause respiratory irritation.
H336 May cause drowsiness or dizziness.
H411 Toxic to aquatic life with long lasting effects.

This Information and our technical advice - whether verbal, in writing or by way of trials - are given without warranty, this also
applies where proprietary rights of third parties are involved. Our advice does not release you from the obligation to verify the
information currently provided - especially that contained in our safety data and technical information sheets - and to test our
products as to their suitability for the intended processes and uses. The application, use and processing of our products and
the products manufactured by you on the basis of our technical advice are beyond our control and, therefore, entirely your
own responsibility.

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