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Revision Date December 2014 Revision 9

Revision 9

SAFETY DATA SHEET

CEMENTONE BITUMINOUS MASTIC FOR ROOFS
According to Regulation (EC) No 1907/2006

SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING

1.1. Product identifier

Product name CEMENTONE BITUMINOUS MASTIC FOR ROOFS
Product No. 154025, 15403, 15404x

1.2. Relevant identified uses of the substance or mixture and uses advised against

1.3. Details of the supplier of the safety data sheet

Supplier BOSTIK LIMITED
COMMON ROAD
STAFFORD
STAFFORDSHIRE
ST16 3EH
+44 1785 272625
[email protected]

1.4. Emergency telephone number

+44 1785 272650 (24 Hours)

SECTION 2: HAZARDS IDENTIFICATION

2.1. Classification of the substance or mixture

Classification (EC 1272/2008)
Physical and Chemical Hazards Flam. Liq. 3 - H226
Human health STOT RE 2 - H373
Environment Aquatic Chronic 2 - H411
Classification (1999/45/EEC) N;R51/53. R10.
The Full Text for all R-Phrases and Hazard Statements are Displayed in Section 16.

2.2. Label elements

Label In Accordance With (EC) No. 1272/2008

Signal Word Warning

Hazard Statements
H226 Flammable liquid and vapour.
H373 May cause damage to organs through prolonged or repeated exposure.
H411 Toxic to aquatic life with long lasting effects.
Precautionary Statements
P102 Keep out of reach of children.
P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P305+351+338 IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing.
P403+235 Store in a well-ventilated place. Keep cool.
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P501 Dispose of contents/container in accordance with local regulations.
Supplementary Precautionary Statements
P233 Keep container tightly closed.
P240 Ground/bond container and receiving equipment.
P241 Use explosion-proof electrical equipment.
P242 Use only non-sparking tools.
P243 Take precautionary measures against static discharge.
P273 Avoid release to the environment.
P260 Do not breathe vapour/spray.
P370+378 In case of fire: Use foam, carbon dioxide, dry powder or water fog for
extinction.
P303+361+353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated
clothing. Rinse skin with water/shower.
P314 Get medical advice/attention if you feel unwell.
P391 Collect spillage.

2.3. Other hazards

Vapours are heavier than air and can travel long distances to a source of ignition Pilot lights can ignite the vapour

SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS

3.2. Mixtures

HYDROCARBONS, C16-C20, n-ALKANES, ISOALKANES, CYCLICS, AROMATICS (2-30%) 5-10%

CAS-No.: 64742-80-9 EC No.: 919-006-8

Classification (EC 1272/2008) Classification (67/548/EEC)

EUH066 Xn;R65. R53,R66.
Asp. Tox. 1 - H304
Aquatic Chronic 4 - H413

ISODECYLOXYPROPYLAMINE ACETATE < 1%

CAS-No.: 28701-67-9 EC No.: 249-166-8

Classification (EC 1272/2008) Classification (67/548/EEC)

Acute Tox. 4 - H302 Xn;R22.
Skin Corr. 1B - H314 C;R34.
Aquatic Acute 1 - H400 N;R50/53.
Aquatic Chronic 1 - H410

NAPHTHA (PETROLEUM), HYDROSULFURIZED HEAVY; LOW BOILING* 5-10%

CAS-No.: 64742-82-1 EC No.: 265-185-4

Classification (EC 1272/2008) Classification (67/548/EEC)

Flam. Liq. 3 - H226 Xn;R48/20,R65.
EUH066 N;R51/53.
STOT SE 3 - H336 R10,R66,R67.
STOT RE 1 - H372
Asp. Tox. 1 - H304
Aquatic Chronic 2 - H411
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PHOSPHORIC ACID ...% < 1%

CAS-No.: 7664-38-2 EC No.: 231-633-2 Registration Number: 01-2119485924-24

Classification (EC 1272/2008) Classification (67/548/EEC)

Skin Corr. 1B - H314 C;R34

PROPAN-2-OL < 1%

CAS-No.: 67-63-0 EC No.: 200-661-7 Registration Number: 01-2119457558-25

Classification (EC 1272/2008) Classification (67/548/EEC)

Flam. Liq. 2 - H225 F;R11
Eye Irrit. 2 - H319 Xi;R36
STOT SE 3 - H336 R67

The Full Text for all R-Phrases and Hazard Statements are Displayed in Section 16.

Composition Comments
Product contains silica which in the form the product is supplied is not hazardous, however inhalation of dust generated from dried
material must be avoided.

SECTION 4: FIRST AID MEASURES

4.1. Description of first aid measures

Inhalation
Move the exposed person to fresh air at once. Get medical attention if any discomfort continues.
Ingestion
DO NOT INDUCE VOMITING! NEVER MAKE AN UNCONSCIOUS PERSON VOMIT OR DRINK FLUIDS! If vomiting occurs, keep head
low so that stomach content doesn't get into the lungs. Get medical attention immediately!
Skin contact
Remove affected person from source of contamination. Promptly wash contaminated skin with soap or mild detergent and water. Promptly
remove clothing if soaked through and wash as above.
Eye contact
Make sure to remove any contact lenses from the eyes before rinsing. Promptly wash eyes with plenty of water while lifting the eye lids.
Continue to rinse for at least 15 minutes. Get medical attention promptly if symptoms occur after washing.

4.2. Most important symptoms and effects, both acute and delayed

4.3. Indication of any immediate medical attention and special treatment needed

SECTION 5: FIREFIGHTING MEASURES

5.1. Extinguishing media

Extinguishing media
Water spray, fog or mist. Foam. Carbon dioxide (CO2). Dry chemicals, sand, dolomite etc.

5.2. Special hazards arising from the substance or mixture

Unusual Fire & Explosion Hazards
May explode when heated or when exposed to flames or sparks. May travel considerable distance to source of ignition and flash back.
Vapour explosion and poison hazard indoors, outdoors and in sewers.

5.3. Advice for firefighters

Special Fire Fighting Procedures
Keep run-off water out of sewers and water sources. Dike for water control. Cool containers exposed to flames with water until well after the
fire is out. Move container from fire area if it can be done without risk. Use water spray to reduce vapours. If risk of water pollution occurs,
notify appropriate authorities.

SECTION 6: ACCIDENTAL RELEASE MEASURES

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6.1. Personal precautions, protective equipment and emergency procedures
Avoid skin and eye contact. Ensure adequate ventilation. Wear personal protective equipment. Wear self contained breathing apparatus.

6.2. Environmental precautions

6.3. Methods and material for containment and cleaning up

Wear necessary protective equipment. Extinguish all ignition sources. Avoid sparks, flames, heat and smoking. Ventilate. Runoff or
release to sewer, waterway or ground is forbidden. Absorb in vermiculite, dry sand or earth and place into containers. Do not let washing
down water contaminate ponds or waterways. Collect in containers and seal securely. Containers with collected spillage must be properly
labelled with correct contents and hazard symbol.

6.4. Reference to other sections

Wear protective clothing as described in Section 8 of this safety data sheet.

SECTION 7: HANDLING AND STORAGE

7.1. Precautions for safe handling

Keep away from heat, sparks and open flame. Provide good ventilation. Avoid spilling, skin and eye contact. Avoid acids, moisture,
and combustible materials.

7.2. Conditions for safe storage, including any incompatibilities

Flammable/combustible - Keep away from oxidisers, heat and flames. Isolate from other materials. Store in tightly closed original
container in a dry, cool and well-ventilated place. Ground container and transfer equipment to eliminate static electric sparks.
Storage Class
Flammable liquid storage.

7.3. Specific end use(s)

The identified uses for this product are detailed in Section 1.2.

SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION

8.1. Control parameters

Name STD TWA - 8 Hrs STEL - 15 Min Notes

PHOSPHORIC ACID ...% WEL 1 mg/m3 2 mg/m3

PROPAN-2-OL WEL 400 ppm 999 mg/m3 500 ppm 1250 mg/m3

WEL = Workplace Exposure Limit.

Ingredient Comments
WEL = Workplace Exposure Limits

8.2. Exposure controls

Protective equipment

Process conditions
Use engineering controls to reduce air contamination to permissible exposure level.
Engineering measures
Provide adequate general and local exhaust ventilation. Explosion-proof general and local exhaust ventilation.
Respiratory equipment
No specific recommendation made, but respiratory protection must be used if the general level exceeds the recommended occupational
exposure limit.
Hand protection
For prolonged or repeated skin contact use suitable protective gloves. Use protective gloves made of: Nitrile.
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Eye protection
Use approved safety goggles or face shield.
Other Protection
Provide eyewash station. Wear suitable protective clothing as protection against splashing or contamination.
Hygiene measures
DO NOT SMOKE IN WORK AREA! Wash hands at the end of each work shift and before eating, smoking and using the toilet. Promptly
remove any clothing that becomes contaminated. Wash promptly with soap & water if skin becomes contaminated. When using do not
eat, drink or smoke. Use appropriate skin cream to prevent drying of skin.

SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES

9.1. Information on basic physical and chemical properties

Appearance Fibrous Paste
Colour Black.
Odour Solvent.
Solubility Insoluble in water
Relative density 1.45
Flash point (°C) 50 CC (Closed cup).

9.2. Other information

SECTION 10: STABILITY AND REACTIVITY

10.1. Reactivity

10.2. Chemical stability

Stable under normal temperature conditions.

10.3. Possibility of hazardous reactions

10.4. Conditions to avoid

Avoid heat, flames and other sources of ignition. Avoid contact with strong oxidisers.

10.5. Incompatible materials

10.6. Hazardous decomposition products

SECTION 11: TOXICOLOGICAL INFORMATION

11.1. Information on toxicological effects

Inhalation
May cause irritation to the respiratory system.

Ingestion
Pneumonia may be the result if vomited material containing solvents reaches the lungs.

Skin contact
Liquid may irritate skin.

Eye contact
Irritation, burning, lachrymation, blurred vision after liquid splash.
Medical Considerations
Chronic respiratory and obstructive airway diseases. Skin disorders and allergies. History of smoking.

SECTION 12: ECOLOGICAL INFORMATION

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Ecotoxicity
Dangerous for the environment: May cause long-term adverse effects in the aquatic environment. Contamination of the terrestrial and
aquatic environments should be avoided

12.1. Toxicity
No data available

12.2. Persistence and degradability

Degradability
No data available.

12.3. Bioaccumulative potential

Bioaccumulative potential
No data available on bioaccumulation.

12.4. Mobility in soil

12.5. Results of PBT and vPvB assessment

No data available

12.6. Other adverse effects

Not available.

SECTION 13: DISPOSAL CONSIDERATIONS

General information
This material is classified as special waste as defined by Special Waste Regulations 1996 and must be disposed of by an authorised
contractor

13.1. Waste treatment methods

Dispose of waste and residues in accordance with local authority requirements.

SECTION 14: TRANSPORT INFORMATION

14.1. UN number

UN No. (ADR/RID/ADN) 1133

UN No. (IMDG) 1133

UN No. (ICAO) 1133

14.2. UN proper shipping name

Proper Shipping Name ADHESIVES (NAPHTHA (PETROLEUM), HYDROSULFURIZED HEAVY; LOW BOILING*)

14.3. Transport hazard class(es)

ADR/RID/ADN Class 3

ADR/RID/ADN Class Class 3: Flammable liquids.

ADR Label No. 3

IMDG Class 3

ICAO Class/Division 3

Transport Labels

FLAMMABLE
LIQUID
3

14.4. Packing group

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ADR/RID/ADN Packing group III

IMDG Packing group III

ICAO Packing group III

14.5. Environmental hazards

Environmentally Hazardous Substance/Marine Pollutant

14.6. Special precautions for user

EMS F-E, S-D

Emergency Action Code •3Y

Hazard No. (ADR) 30

Tunnel Restriction Code (D/E)

14.7. Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code

SECTION 15: REGULATORY INFORMATION

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
Statutory Instruments
The Chemicals (Hazard Information and Packaging for Supply) Regulations 2009 (S.I 2009 No. 716). Control of Substances Hazardous to
Health.
Approved Code Of Practice
Classification and Labelling of Substances and Preparations Dangerous for Supply. Safety Data Sheets for Substances and Preparations.
Guidance Notes
Workplace Exposure Limits EH40. CHIP for everyone HSG(108).
EU Legislation
Dangerous Substance Directive 67/548/EEC. Dangerous Preparations Directive 1999/45/EC. Regulation (EC) No 1907/2006 of the
European Parliament and of the Council of 18 December 2006 concerning the Registration, Evaluation, Authorisation and Restriction of
Chemicals (REACH), establishing a European Chemicals Agency, amending Directive 1999/45/EC and repealing Council Regulation
(EEC) No 793/93 and Commission Regulation (EC) No 1488/94 as well as Council Directive 76/769/EEC and Commission Directives
91/155/EEC, 93/67/EEC, 93/105/EC and 2000/21/EC, including amendments. Regulation (EC) No 1272/2008 of the European Parliament
and of the Council of 16 December 2008 on classification, labelling and packaging of substances and mixtures, amending and repealing
Directives 67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006 with amendments.

15.2. Chemical Safety Assessment

SECTION 16: OTHER INFORMATION

General information
This product should be used as directed by Bostik Ltd. For further information consult the product data sheet or contact Technical Services.
Information Sources
This safety data sheet was compiled using current safety information supplied by distributor of raw materials.
Revision Comments
NOTE: Lines within the margin indicate significant changes from the previous revision. This safety data sheet supersedes all previous
issues and users are cautioned to ensure that it is current. Destroy all previous data sheets and if in doubt contact Bostik Limited.
Issued By Approved LJ
Revision Date December 2014
Revision 9
Date March 2007
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Risk Phrases In Full
R34 Causes burns.
R10 Flammable.
R22 Harmful if swallowed.
R48/20 Harmful: danger of serious damage to health by prolonged exposure through inhalation.
R65 Harmful: may cause lung damage if swallowed.
R11 Highly flammable
R36 Irritating to eyes.
R53 May cause long-term adverse effects in the aquatic environment.
R66 Repeated exposure may cause skin dryness or cracking.
R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
R67 Vapours may cause drowsiness and dizziness.
R50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
Hazard Statements In Full
EUH066 Repeated exposure may cause skin dryness or cracking.
H225 Highly flammable liquid and vapour.
H226 Flammable liquid and vapour.
H302 Harmful if swallowed.
H304 May be fatal if swallowed and enters airways.
H314 Causes severe skin burns and eye damage.
H319 Causes serious eye irritation.
H336 May cause drowsiness or dizziness.
H372 Causes damage to organs <<Organs>> through prolonged or repeated exposure.
H373 May cause damage to organs <<Organs>> through prolonged or repeated exposure.
H400 Very toxic to aquatic life.
H410 Very toxic to aquatic life with long lasting effects.
H411 Toxic to aquatic life with long lasting effects.
H413 May cause long lasting harmful effects to aquatic life.