MSDS Resin
MSDS Resin
MSDS Resin
1.2. Relevant identified uses of the substance or mixture and uses advised against
Application: Resin.
Uses Advised Against At this moment in time we do not have information on use restrictions. They will be included
in this safety data sheet when available
3.2. Mixtures
DIPHENYLMETHANE-4,4'-DI-ISOCYANATE 80-100%
The Full Text for all R-Phrases and Hazard Statements is Displayed in Section 16.
Composition Comments
Ingredients not listed are classified as non-hazardous or at a concentration below reportable levels Ingredients are
registered on AICS
4.2. Most important symptoms and effects, both acute and delayed
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4.3. Indication of any immediate medical attention and special treatment needed
Treat Symptomatically.
When dealing with a spillage, please consult the section relating to suitable protective measures. Wear necessary
protective equipment. Stop leak if possible without risk. Flush with plenty of water to clean spillage area. Do not
contaminate water sources or sewer.
Wear protective clothing as described in Section 8 of this safety data sheet. See section 11 for additional information on
health hazards. For waste disposal, see section 13.
Persons with impaired lung functions should not handle this preparation. Persons susceptible to allergic reactions should
not handle this product. Avoid forming spray/aerosol mists. Avoid inhalation of vapours/spray and contact with skin and
eyes. Ventilate well, avoid breathing vapours. Use approved respirator if air contamination is above accepted level. Use
mechanical ventilation in case of handling which causes formation of vapours. Spraying is permitted only in closed
systems, spray cabinets or spray boxes with adequate ventilation. Eye wash facilities and emergency shower must be
available when handling this product.
Keep in original container. Store in tightly closed original container in a dry, cool and well-ventilated place. Keep away from
heat, sparks and open flame.
The identified uses for this product are detailed in Section 1.2.
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Ingredient Comments
No exposure limits noted for ingredient(s).
Process Conditions
Use engineering controls to reduce air contamination to permissible exposure level. Provide eyewash station.
Engineering measures
Provide sufficient ventilation during operations which cause vapour formation. Provide adequate ventilation, including
appropriate local extraction, to ensure that the defined occupational exposure limit is not exceeded.
Respiratory equipment
Respiratory protection must be used if air contamination exceeds acceptable level. It is recommended to use respiratory
equipment with combination filter, type A2/Р2. EN14387 When spraying use suitable air-supplied respirator.
Hand protection
Use protective gloves made of: Rubber, neoprene or PVC. The most suitable glove must be chosen in consultation with
the gloves supplier, who can inform about the breakthrough time of the glove material. Gloves should conform to EN374
Eye protection
Wear approved chemical safety goggles where eye exposure is reasonably probable. EN166
Other Protection
Wear appropriate clothing to prevent any possibility of liquid contact and repeated or prolonged vapour contact.
Hygiene measures
DO NOT SMOKE IN WORK AREA! Wash hands at the end of each work shift and before eating, smoking and using the
toilet. Promptly remove any clothing that becomes contaminated. Wash promptly if skin becomes contaminated. When
using do not eat, drink or smoke.
Environmental Exposure Controls
Residues and empty containers should be taken care of as hazardous waste according to local and national provisions.
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Reacts strongly with strong acids, bases, organic chemicals and certain metal combinations.
Avoid heat, flames and other sources of ignition. Reacts strongly with strong acids, bases, organic chemicals and certain
metal combinations.
High temperatures generate: Toxic gases/vapours/fumes of: Carbon dioxide (CO2). Carbon monoxide (CO). Hydrogen
cyanide (HCN).
Toxic Dose 1 - LD 50
>2000 mg/kg (oral rat)
Toxic Conc. - LC 50
490 mg/l/4h (inh-rat)
Other Health Effects
This substance has no evidence of carcinogenic properties.
General information
No specific health warnings noted.
Inhalation
Harmful by inhalation. High concentrations of vapours may irritate respiratory system and lead to headache, fatigue,
nausea and vomiting. May cause sensitisation by inhalation.
Ingestion
May cause stomach pain or vomiting.
Skin contact
Irritating to skin. Prolonged or repeated exposure may cause severe irritation.
Eye contact
Irritating to eyes.
Ecotoxicity
Not regarded as dangerous for the environment. The polymer is expected to be of low toxicity.
12.1. Toxicity
LC 50, 96 Hrs, Fish mg/l >1000
Acute Toxicity - Fish
LC0 96 hours > 1000 mg/l
EC 50, 48 Hrs, Daphnia, mg/l >500
Acute Toxicity Aquatic Invertebrates
EC0 > 500 mg/l Daphnia magna
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No information required.
General information
Waste is classified as hazardous waste. Disposal to licensed waste disposal site in accordance with the local Waste
Disposal Authority.
Residues and empty containers should be taken care of as hazardous waste according to local and national provisions.
General The product is not covered by international regulation on the transport of dangerous goods
(IMDG, IATA, ADG).
Road Transport Notes Not Classified
Sea Transport Notes Not classified.
Air Transport Notes Not classified.
14.1. UN number
Transport Labels
No transport warning sign required.
14.7. Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code
Not applicable.
UDF Phrase 1 Not classified for transportation
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15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
Health And Environmental Listings
None of the ingredients are listed.
Authorisations (Title VII Regulation 1907/2006)
No specific authorisations are noted for this product.
Restrictions (Title VIII Regulation 1907/2006)
No specific restrictions of use are noted for this product.
Disclaimer
This information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in
any process. Such information is, to the best of the company's knowledge and belief, accurate and reliable as of the date indicated. However, no
warranty guarantee or representation is made to its accuracy, reliability or completeness. It is the user's responsibility to satisfy himself as to the
suitability of such information for his own particular use.
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1.2. Relevant identified uses of the substance or mixture and uses advised against
Application Resin.
Uses advised against At this moment in time we do not have information on use restrictions. They will be included in
this safety data sheet when available
Health hazards Skin Irrit. 2 - H315 Eye Dam. 1 - H318 STOT SE 3 - H335
Pictogram
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Precautionary statements P280 Wear protective gloves, eye and face protection.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing.
3.2. Mixtures
ETHOEXADIOL 10-30%
CAS number: 94-96-2 EC number: 202-377-9
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1,3-BUTADIENE <1%
CAS number: 106-99-0 EC number: 203-450-8
The Full Text for all R-Phrases and Hazard Statements is Displayed in Section 16.
Composition comments Ingredients not listed are classified as non-hazardous or at a concentration below reportable
levels
Inhalation Move affected person to fresh air at once. Keep affected person warm and at rest. Get
medical attention immediately.
Ingestion Do not induce vomiting. Rinse mouth thoroughly with water. Get medical attention
immediately.
Skin Contact Remove affected person from source of contamination. Remove contaminated clothing. Wash
skin thoroughly with soap and water. Get medical attention if any discomfort continues.
Eye contact Remove any contact lenses and open eyelids wide apart. Continue to rinse for at least 15
minutes. Continue to rinse for at least 15 minutes. Get medical attention if any discomfort
continues.
4.2. Most important symptoms and effects, both acute and delayed
4.3. Indication of any immediate medical attention and special treatment needed
Notes for the doctor Treat symptomatically.
Hazardous combustion Oxides of carbon. Thermal decomposition or combustion may liberate carbon oxides and
products other toxic gases or vapours.
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Special protective equipment Wear positive-pressure self-contained breathing apparatus (SCBA) and appropriate protective
for firefighters clothing.
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Protective equipment
Appropriate engineering Provide adequate general and local exhaust ventilation. Observe any occupational exposure
controls limits for the product or ingredients.
Eye/face protection Eyewear complying with an approved standard should be worn if a risk assessment indicates
eye contact is possible. The following protection should be worn: Chemical splash goggles.
EN166
Hand protection Wear protective gloves made of the following material: Rubber (natural, latex). Neoprene.
Polyvinyl chloride (PVC). The most suitable glove should be chosen in consultation with the
glove supplier/manufacturer, who can provide information about the breakthrough time of the
glove material. Gloves should conform to EN374
Other skin and body Wear appropriate clothing to prevent any possibility of liquid contact and repeated or
protection prolonged vapour contact.
Hygiene measures Use engineering controls to reduce air contamination to permissible exposure level. Provide
eyewash station. Do not smoke in work area. Wash hands at the end of each work shift and
before eating, smoking and using the toilet. Wash promptly with soap and water if skin
becomes contaminated. Promptly remove any clothing that becomes contaminated. When
using do not eat, drink or smoke.
Respiratory protection Respiratory protection must be used if the airborne contamination exceeds the recommended
occupational exposure limit. It is recommended to use respiratory equipment with combination
filter, type A2/Р2. EN14387 When spraying, wear a suitable supplied-air respirator.
Colour Black.
Odour Aromatic.
Viscosity @ °C
10.1. Reactivity
Reactivity There are no known reactivity hazards associated with this product.
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Other health effects There is no evidence that the product can cause cancer.
Acute and chronic health No specific acute or chronic health impact noted, but this chemical may still have adverse
hazards impact on human health, either in general or on certain individuals with pre-existing or latent
health problems.
12.1. Toxicity
12.2. Persistence and degradability
Persistence and degradability There are no data on the degradability of this product.
General The product is not covered by international regulations on the transport of dangerous goods
(IMDG, IATA, ADR/RID).
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14.1. UN number
Transport labels
14.7. Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code
Transport in bulk according to Not applicable.
Annex II of MARPOL 73/78
and the IBC Code
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
National regulations The Chemicals (Hazard Information and Packaging for Supply) Regulations 2009 (SI 2009
No. 716).
Control of Substances Hazardous to Health Regulations 2002 (as amended).
Guidance
Authorisations (Title VII No specific authorisations are known for this product.
Regulation 1907/2006)
Restrictions (Title VIII No specific restrictions on use are known for this product.
Regulation 1907/2006)
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Risk phrases in full R36/37/38 Irritating to eyes, respiratory system and skin.
R37/38 Irritating to respiratory system and skin.
R41 Risk of serious damage to eyes.
R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic
environment.
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This information relates only to the specific material designated and may not be valid for such material used in combination
with any other materials or in any process. Such information is, to the best of the company's knowledge and belief, accurate
and reliable as of the date indicated. However, no warranty, guarantee or representation is made to its accuracy, reliability or
completeness. It is the user's responsibility to satisfy himself as to the suitability of such information for his own particular use.
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