DPP-04 5

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M.M. : 33 DPP # 04 TIME : 30 Min.

1. C5H12 has a symmetrical


(i)HNO /0 C structure with one quaternary carbon. Its IUPAC name is : [3]

(ii)Cu Cl / HC

(A) n-pentane(iii) (B)
NaOH/600
(iv) HNO / H S
 2-methylbutane (C) 2,2-dimethylpropane (D) 3-methylbutane
3 2
(v) H / Pd/ EtO
2. Which of the following compound
(vi) Ac O/ Pyri
e(1eq.) has all four type (1°,2°,3°, 4°) of carbon atoms : [3]
(A) 2,3,4-Trimethylpentane
(i) Ag,  (B) 2,2,3-Trimethylpentane
(ii)Fetu

(C) neo-pentane (iii)CH 3 Cl/AlCl3
(iv) Zn  /HCl
(D) none of the three
(v)KMn , NaOH/
3. In following compound [3]

CH3 
CH3
CH3 –CH2–C–—CH–CH–CH2–CH3
CH3 CH3 Carbocation involve n any step of
The correct lowest set of locant is :
(A) 3,3,4,5 (B) 3,4,5,5 (C) 4,5,3,3 (D) 5,5,4,3
4. The IUPAC name of [3]
CH3 – C = C — CH – CH2 – C º CH
Cl CH3 C2H5
(A) 2-Chloro-4-ethyl-3-methyl-6-heptyn-2 ene
(B) 2-Chloro-4-ethyl-3-methyl-2-heptyn-6 yne
(C) 6-Chloro-4-ethyl-5-methyl-1-heptyn-5 ene
(D) 6-Chloro-4-ethyl-5-methyl-5-hepten-1 yne
H C4H9

5. IUPAC name of CH3 – C — C — CH2 – CH3 is: [3]

CH3 CH3
(A) 3,4,4- Trimethylheptane (B) 4-Ethyl-3,4-dimethyl octane
(C) 2-Butyl-2-methyl-3-ethylbutane (D) None of these
6. Match the column: [3]
Column I Column II
(Compounds) (Property)

(A) (P) Homocyclic compound


N

(B) (Q) Homocyclic hydrocarbon

NH2
(C) (R) Heterocyclic

(D) (S) Even number of p-bond

H.O. 92, Rajeev Gandhi Nagar, Kota (R .) Mob. 97831 (T) Odd number of s-bond
w.nucleuseducation.in

C.O.: NAIVEDHYAM, Plot No. SP-11, Old INOX, Indira Vihar, Kota (Raj.) 324005 Ph. 0744-2799900 1
ONLINE PARTNER UNACADEMY
CH2 – CH3
(i)HNO /0 C
7. CH3 – CH2 – 
CH 2 – CH2 –
(ii)Cu Cl / HC CH – CH – CH – CH – CH – CH
2 2 2 3 [3]
(iii) NaOH/600
(iv) HNO3 / H 2S
CH – C – CH3
(v) H / Pd/ EtO
3
(vi) Ac O/ Pyri e(1eq.)

(i) Ag,  CH
3
 (ii)Fetu
(iii)CH3

Cl/AlCl3
(A) 5-(1, 1-Dimethyl(iv)Ethyl)-6-Ethyl
Zn  /HCl decane (B) 5-Ethyl-6-(1, 1-Dimethyl Ethyl) decane
(v)KMn , NaOH/
(C) 6-Ethyl-5-(1, 1-Dimethyl Ethyl) decane (D) 6-(1, 1-Dimethyl Ethyl)-5 Ethyl decane
 
8. IUPAC name of CH3 – CH = CH – C º CH is: [3]
(A) 2-Penten-4-yne (B) 1-Pentyn-3-ene (C) 3-Penten-1-yne (D) None of these
Carbocation involve n any step of

9. Provide IUAPC name of the following compounds : [3]


O
O
O-Et OH
(A) NH2 (B) (C) Cl (D) N
O Cl
O
Cl

10. Write correct IUPAC names of following compounds [3]


(i) 2-Ethyl-5-hexyne (ii) 1-amino-3-isopropylpentan-1-one
(iii) 1-methyl-2-vinyl cyclohex-1(6)-ene

The IUPAC name of the crotonaldehyde is: (CH3–CH = CH–CHO) is - [3]


11.
(A) 2-Propenal (B) Propenal (C) 2-Butenal (D) Butenals

H.O. 92, Rajeev Gandhi Nagar, Kota (R .) Mob. 97831 w.nucleuseducation.in

C.O.: NAIVEDHYAM, Plot No. SP-11, Old INOX, Indira Vihar, Kota (Raj.) 324005 Ph. 0744-2799900 2
ONLINE PARTNER UNACADEMY

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