Nomenclature of Organic Compound (11th)
Nomenclature of Organic Compound (11th)
Nomenclature of Organic Compound (11th)
NOMENCLATURE
OF
ORGANIC COMPOUNDS
CONTENTS
EXERCISE - I
EXERCISE - II
EXERCISE - III
ANSWER KEY
EXERCISE - I
Q.1 How many 1°carbon atom will be present in a simplest hydrocarbon having two 3° and one 2° carbon
atom?
(A) 3 (B) 4 (C) 5 (D) 6
Q.2 C3H6Br2 can shows:
(A) Two gem dibromide (B) Two vic dibromide
(C) Two tert. dibromo alkane (D) Two sec. dibromo alkane
Q.3 The IUPAC name of the compound CH3CH = CHCH=CHCCCH3 is:
(A) 4,6-octadiene-2-yne (B) 2,4-octadiene-6-yne
(C) 2-octyn-4,6-diene (D) 6-octyn-2,4-diene
Q.4 The correct IUPAC name of the following compound is:
O C CH 2 CH CHO
| |
OH H C O
(A) 3,3-diformyl propanoic acid (B) 3-formyl-4-oxo-butanoic acid
(C) 3,3-dioxo propanoic acid (D) 3,3-dicarbaldehyde propanoic acid
Q.5 The correct IUPAC name of compound:
CH 3 CH 2 C CH CHO
|| | is:
O CN
(A) 2-cyano-3-oxopentanal (B) 2-formyl-3-oxopentanenitrile
(C) 2-cyano-1,3-pentanedione (D) 1,3-dioxo-2-cyanopentane
Q.6 All the following IUPAC names are correct except:
(A) 1-chloro-1-ethoxy propane (B) 1-amino-1-ethoxypropane
(C) 1-ethoxy-2-propanol (D) 1-ethoxy-1-propanamine
Q.7 IUPAC name of:
CH 3 C CH C OCH 3
|| | ||
O C O O
|
CH 3
(A) Methyl-2,2 acetyl ethanoate (B) 2,2 acetyl-1-methoxy ethanone
(C) Methyl-2-acetyl-3-oxobutanoate (D) None
Q.8 The IUPAC name of -ethoxy--hydroxy propionic acid (trivial name) is:
(A) 1,2-dihydroxy-1-oxo-3-ethoxy propane (B) 1-carboxy-2-ethoxy ethanol
(C) 3-Ethoxy-2-hydroxy propanoic acid (D) All above
O CH 3
|| |
Q.9 The IUPAC name of compound CH 3 C CH CH CH CH 3 is:
| |
CH 3 CHO
(A) 3,5-Dimethyl-4-Formyl pentanone (B) 1-Isopropyl-2-methyl-4-oxo butanal
(C) 2-Isopropyl-3-methyl-4-oxo pentanal (D) None of the above
HO C O CH 3
| |
Q.10 The IUPAC name of compound CH 3 C C — C H is:
| |
NH 2 Cl
(A) 2-amino-3-chloro-2-methyl-2-pentenoic acid
(B) 3-amino-4-chloro-2-methyl-2-pentenoic acid
(C) 4-amino-3-chloro-2-methyl-2-pentenoic acid
(D) All of the above
Q.14 How many carbons are in simplest alkyne having two side chains?
(A) 5 (B) 6 (C) 7 (D) 8
CH 3
|
CH 3 C — CH 2 CH CH 3
(D) Iso-octane
| |
CH 3 CH 3
Q.16 Which of the following pairs have absence of carbocyclic ring in both compounds?
(A) Pyridine, Benzene (B) Benzene, Cyclohexane
(C) Cyclohexane, Furane (D) Furane, Pyridine
Q.19 How many secondary carbon atoms does methyl cyclopropane have?
(A) None (B) One (C) Two (D) Three
Q.22 Which of the following is the first member of ester homologous series?
(A) Ethyl ethanoate (B) Methyl ethanoate (C) Methyl methanoate (D) Ethyl methanoate
Ph
|
Q.25 The IUPAC name of the compound is CH 3 CH CH NH 2
|
CH 3
(A) 1-amino-1-phenyl-2-methyl propane (B) 2-methyl-1-phenyl propane-1-amine
(C) 2-methyl-1-amino-1-phenyl propane (D) 1-isopropyl-1-phenyl methyl amine
Q.26 Which of the following compound is wrongly named?
(A) CH 3CH 2CH 2CHCOOH ; 2-Chloro pentanoic acid
|
Cl
Q.29 The IUPAC name of the compound Br(Cl) CI. CF3 is:
(A) 2-bromo-2-chloro-2-iodo1,1,1-trifluoroethane
(B) 1,1,1-trifluoro-2-bromo-2-chloro-2-iodo ethane
(C) 2-bromo-2-chloro-1,1,1-trifluoro-2-iodo ethane
(D) 1-bromo-1-chloro-1-iodo-2,2,2-trifloro ethane
Q.33 The IUPAC name of the following structure is [CH3CH(CH3)]2 C(CH2CH3)C(CH3) C(CH2CH3)2
(A) 3,5-diethyl-4,6-dimethyl-5-[1-methylethyl]-3-heptene
(B) 3,5-diethyl-5-isopropyl-4,6-dimethyl-2-heptene
(C) 3,5-diethyl-5-propyl-4,6-dimethyl-3-heptene
(D) None of these
Q.34 and
Number of secondary carbon atoms present in the above compounds are respectively:
(A) 6,4,5 (B) 4,5,6 (C) 5,4,6 (D) 6,2,1
Q.36 When vinyl & allyl are joined each other, we get
(A) Conjugated alkadiene (B) comulative alkadiene
(C) Isolated alkadiene (D) Allenes
Q.37 Glycerine is:
(A) Propane triol-1,2,3 (B) Propylene trialcohol
(C) Propyl glycol (D) Hydroxy methyl glycol
Q.40 A substance containing an equal number of primary, secondary and tertiary carbon atoms is:
(A) Mesityl Oxide (B) Mesitylene (C) Maleic acid (D) Malonic acid
Q.45 The molecular formula of the first member of the family of alkenynes and its name is given by the set
(A) C3H2, alkene (B) C5H6, 1-penten-3-yne
(C) C6H8, 1-hexen-5-yne (D) C4H4, butenyne
Q.46 The IUPAC name of compound
Q.48 One among the following is the correct IUPAC name of the compound
H
|
CH 3CH 2 N CHO
(A) N-Formyl aminoethane (B) N-Ethyl formyl amine
(C) N-Ethyl methanamide (D) Ethylamino methanal
Q.49 Which among the following is the correct IUPAC name of isoamylene:
(A) 1-Pentene (B) 2-Methyl-2-butene (C) 3-Methyl-1-butene (D) 2-Methyl-1-butene
O
||
Q.57 The IUPAC name of C CH 3 is:
(A) phenyl ethanone (B) methyl phenyl ketone
(C) acetophenone (D) phenyl emethyl ketone
Q.59 The suffix of the principal group, the prefixes for the other groups and the name of the parent in the
structure
HO CH 2 CH CH C CH 2 C C OH
| | || | |
CH 3 Cl O O
(A) -oic acid, chloro, hydroxy, oxo, methyl, 4-heptene
(B) -oic acid, chloro, hydroxy, methyl, oxo, 4-heptene
(C) -one, carboxy, chloro. methyl, hydroxy, 4-heptene
(D) -one, carboxy, chloro, methyl, hydroxy, 4-heptene
(C) CH 3 C O CH 2 CH 2 (D) H C O CH CH 3
|| | || |
O CH 3 O CH 3
CH 3 CH 3
| |
Q.67 The correct IUPAC name of the compound CH 3 CH 2 C C CH C CH 2 CH 2 CH 3 :
|
C2 H 5
(A) 5-ethyl-3, 6-dimethyl non-3-ene (B) 5-ethyl-4, 7-dimethyl non-3-ene
(C) 4-methyl-5, 7-diethyl oct-2-ene (D) 2,4-ethyl-5-methyl oct-2-ene
EXERCISE - II
Give the IUPAC names for each of the following :
Q.11
Q.1
Q.12
Q.2
Q.13
Q.14
Q.3 O2N OH
Q.15
Q.4
Q.16
Q.5
Q.17
Q.6
Q.18
Q.7 Q.19
Q.20
Q.8
Q.21
Q.9
Q.22
Q.10 Q.23
Q.24
Q.35
Q.25
Q.36
Q.26
Q.37
Q.27
Q.38
Q.28
Q.39
Q.40
Q.29
Q.41
Q.30
Q.42
Q.31
Q.43
Q.32
Q.44
Q.33
Q.45
Q.46
Q.34
Q.47
Q.48
O Cl
|| |
Q.49 CH 2 C CH 2 CH CH 3
Q.50
Q.51
Q.52
Q.53
Q.54
EXERCISE - III
Q.1 The IUPAC name of the compound having the formula is:
CH 3
|
H 3C C CH CH 2
|
CH 3
(A) 3,3,3-trimethyl-1-propene (B) 1,1,1-trimethyl-2-propene
(C) 3,3-dimethyl-1-butene (D) 2,2-dimethyl-3-butene [JEE 1984]
Q.4 The number of sigma and pi-bonds in 1-butene 3-yne are: [JEE 1989]
(A) 5 sigma and 5 pi (B) 7 sigma and 3 pi (C) 8 sigma and 2 pi (D) 6 sigma and 4 pi
CH 3
|
(b) H 3C N — CH CH 2CH 3 [JEE 1991]
| |
CH 3 C 2 H 5
EXERCISE - II
5 4 3 2
Q.1 CH 3 CH C CH 2 OH Q.5 CH 3 CH 2 CH 2 CH CHO
| |
CH 2 CH 3 CN
1
2-ethyl-2-buten-1-ol 2-Formyl pentane nitrile
1 2 3
4 5 6 7 8
Q.6 CH 2 CH CH 2 OCH3
Q.2 CH 3 CH 2 CH CH 2 CH 2 CH 2 CH 3
3-Methoxy-1-propene
|
CH 2 CH 2 CH 3
Q.7 5-methyl hepta-1,3,6-triene
4-Ethyl octane
3 2 1 4 3 2 1
Q.3 CH CH CH 2 Q.8 CH 2 CH C CH 2
| | || |
NO 2 OH O OH
3-nitro-2-propen-1-ol 1-Hydroxy-3-Butene-2-one
OH O 5 4
| || CH 3 CH CH 3
Q.4 CH 2 CH CH C C CH 3| 2 1
6 5 4 3 2 1
Q.9 CH 3 CH 2 CH CH CH 3
|
4-hydroxy-5-hexen-1yn-3-one CH 3
3-Ethyl-2,4-dimethyl pentane
1 2 3 4 5 Q.28 1-cyclohexyl-1-propanone
Q.10 CH 2 C CH 2 CH CH 3
| | Q.29 Ethyl cyclohexanecarboxylate
CH 3 CH CH 3 CH 3
2-isopropyl-4-methyl-1-pentene Q.30 4-Bromo-2-ethyl cyclopentanone
or 4-methyl-2-(methyl ethyl)-1- pentene
Q.31 3-(hydroxymethyl)-5-methylheptanal
Q.11 CH 3 CH 2 CH 2
| || Q.32 2-Bromo-6-oxocyclohexanecarbaldehyde
C C CH
Q.33 5-amino-6(1-methyl propyl) cyclo-hex-2-enol
1-Hexen-3-yne
Q.34 2-bromo-2-methyl cyclopentanone
Q.12 CH 3 C CH 2 C CH 3
|| || Q.35 Methyl-2-methoxy-6-methyl-3- cyclohexene
O O carboxylate
2-4, pentane dione
Q.36 Bicylo(2.2.1)heptane
Q.13 Cyclopropanecarboxylic acid
Q.37 9-methyl bicyclo(4.2.1) nonane
Q.14 Cyclopent-2-en-1-one
Q.38 spiro (2.5) octane
Q.15 5 Methyl cyclohexa-1,3-diene
Q.39 spiro(4.5) decane
Q.16 1,3-cyclobutadiene
Q.40 Bicyclo (1.1.0) butane
Q.17 1,2-epoxy propane
Q.41 Bicyclo(4.4.0) decane
Q.18 2,2,6,7-tetramethylocatane
Q.42 Bicyclo(2.2.1) heptane
Q.19 3-ethyl-4,6-dimethyloctane
Q.43 8-chloro bicyclo(4.2.0) oct-2-ene
Q.20 Butyl cyclohexane
Q.44 2-cyclopenten-1-ol
Q.21 1-methyl-3-(methyl ethyl cyclohexane)
or 3-isopropyl-1-methylcyclohexane Q.45 Ethyl-2-oxo-cyclo pentane carboxylate
Q.53 3-ethoxy-1(1-nitrocyclohexyl)-hex-4-en-1-one
Q.54 1,3-diphenyl-1,4-pentadiene
EXERCISE - III
Q.1 C
Q.2 CH 3 CH 2 CH CH COOH
5 4 3 2 1
2-pentene, 1-oic acid and or 2-pentenoic acid
Q.3 B
Q.4 B
Q.5 A
Q.6 (a) 5,6-diethyl-3-methyl-dec-4-ene
(b) N,N, 3-trimethyl-3-pentanamine
Q.7 Butane-1,4-dioic acid
Q.8 C