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    ORGANIC CHEMISTRY-30-07 - 13th Objective

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    Raju Singh
    XIII (XYZ) ORGANIC CHEMISTRY REVIEW TEST-1 PART-A Select the correct alternative. (Only one is correct) [26 × 3 = 78] Q.2 This compound shows: (A) geometrical isomerism (B) optical isomerism (C) both (D*) none [Sol. Cyclohexene do not show geometrical isomerism and the compound given is incapable of showing optical isomerism] %Q.5 Give the correct order of initials T or F for following statements. Use T if statement is true and F if it is false. I. Me–CH=C=C=CH–Br is optically active. II. Al

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    ORGANIC CHEMISTRY-30-07 - 13th Objective

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    Raju Singh
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    XIII (XYZ) ORGANIC CHEMISTRY REVIEW TEST-1 PART-A Select the correct alternative. (Only one is correct) [26 × 3 = 78] Q.2 This compound shows: (A) geometrical isomerism (B) optical isomerism (C) both (D*) none [Sol. Cyclohexene do not show geometrical isomerism and the compound given is incapable of showing optical isomerism] %Q.5 Give the correct order of initials T or F for following statements. Use T if statement is true and F if it is false. I. Me–CH=C=C=CH–Br is optically active. II. Al

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    ORGANIC CHEMISTRY-30-07- 13th Objective

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    XIII (XYZ) ORGANIC CHEMISTRY REVIEW TEST-1 PART-A Select the correct alternative. (Only one is correct) [26 × 3 = 78] Q.2 This compound shows: (A) geometrical isomerism (B) optical isomerism (C) both (D*) none [Sol. Cyclohexene do not show geometrical isomerism and the compound given is incapable of showing optical isomerism] %Q.5 Give the correct order of initials T or F for following statements. Use T if statement is true and F if it is false. I. Me–CH=C=C=CH–Br is optically active. II. Al

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    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    13 views6 pages

    ORGANIC CHEMISTRY-30-07 - 13th Objective

    Uploaded by

    Raju Singh
    XIII (XYZ) ORGANIC CHEMISTRY REVIEW TEST-1 PART-A Select the correct alternative. (Only one is correct) [26 × 3 = 78] Q.2 This compound shows: (A) geometrical isomerism (B) optical isomerism (C) both (D*) none [Sol. Cyclohexene do not show geometrical isomerism and the compound given is incapable of showing optical isomerism] %Q.5 Give the correct order of initials T or F for following statements. Use T if statement is true and F if it is false. I. Me–CH=C=C=CH–Br is optically active. II. Al

    Copyright:

    © All Rights Reserved
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    XIII (XYZ) ORGANIC CHEMISTRY REVIEW TEST-1

    PART-A
    Select the correct alternative. (Only one is correct) [26 × 3 = 78]

    Q.2 This compound shows:

    (A) geometrical isomerism (B) optical isomerism


    (C) both (D*) none
    [Sol. Cyclohexene do not show geometrical isomerism and the compound given is incapable of showing
    optical isomerism]

    %Q.5 Give the correct order of initials T or F for following statements. Use T if statement is true and F if it is
    false.
    I. Me–CH=C=C=CH–Br is optically active.
    II. All optically active compound are chiral.
    III. All chiral pyramidal molecules are optically inactive.
    IV CH3–CH2–CH2–COOH and CH 3  CH  CH 3 are positional isomers.
    |
    COOH
    (A) TTTF (B) FTFT (C*) FTFF (D) TFTT
    [Sol. (II) Cyclic chiral pyramidal molecules are optically active.
    (IV) CH3–CH2–CH2–COOH and CH 3  CH  CH 3 are chain isomers. ]
    |
    COOH

    Q.8goc Which pairs of the salts should have identical solubilities in methanol?

    (I) (II)

    (III) (IV)

    (A*) I & IV (B) I & III (C) I & II (D) II & IV


    [Sol. I & IV are enantiomers, enantiomers have identical solubility]
    Q.14 Ph  CH  CHO
    |
    OH
    (A)
    (A) & (B) are isomer and isomerization is effectively carried out by trace of base. Identify isomer (B).
    O
    ||
    (A) Ph–CH2–CO2H (B) Ph  C  O  CH 3

    O O
    || ||
    (C*) Ph  C  CH 2  OH (D) H  C  CH 2  O  Ph

    [Sol. Ph  CH  CH Ph  C  CH Ph  C  CH 2 ]
    | || | | || |
    OH O OH OH O OH

    Q.1723alkane Sentene ozonolysis


     

    Which is the correct structure of Sentene

    (A) (B) (C*) (D)

    [Sol. + O3   ]
    Question No. 19 to 23 (5 questions)
    Alkanes are halogenated in presence of sunlight. The reaction follows free radical mechanism which
    completes in three steps.
    h
    R  H  X 2  RXHX
    (i) Chain initiation (fast)
    h
    X–X  X° + X°
    (ii) Chain propogation (slow)
    R–H+X° RDS  H–X + R°
    R°+X–X  R–X + X°
    (iii) Chain termination (fast)
    R° + X°  R – X
    R°+ R°  R – R
    X° + X°  X – X
    Rate of this reaction increasing with stability of free radical formed and ease of its formation.
    Rate 1° < 2°<3° (for same halogen)
    Rate F2 > Cl2 > Br2 > I2 (for same alkane)
    If excess of halogen is used one by one all H are replaced by X.

    %Q.198alkane Correct order of rate of photochlorination for following compounds is:


    CH 3
    |
    CH3–CH3 CD3–CD3 CH 3  C  CH 3
    |
    CH 3
    (I) (II) (III)
    (A*) II < I < III (B) I < II < III (C) III < I < II (D) II < III < I
    [Sol. C–D bond is stronger than C–H bond. Neo pentane is 1.15 times more reactive than ethane towards
    photochlorination ]
    %Q.209alkane If rate determining step of this reaction is chain initiation not chain propogation what will be the
    order of rate of reaction for same alkane?
    (A*) F2 >Cl2 < Br2 < I2 (B) F2 > Cl2 > Br2 > I2
    (C) F2 < Cl2 < Br2 < I2 (D) F2 = Cl2 = Br2 = I2
    [Sol. If chain initiation is RDS rate will be decided according to X–X bond energy order. ]

    %Q.2110alkane How many possible monochloro products are formed when 2-methoxy propane is treated with
    Cl2 in presence of sunlight?
    (A*) 4 (B) 3 (C) 2 (D) 1
    Cl
    * * |
    [Sol. ClCH 2  C H  CH 3 ; CH 3  C H  ClCH 2 ; CH  C  CH ; CH 3  CH  CH 3 ]
    3 3
    | | | |
    OCH 3 OCH 3 OCH 3 OCH 2Cl
    %Q.2212alkane Total number of chloro derivative possible for ethane is:
    (A) 6 (B) 7 (C) 8 (D*) 9
    Cl
    |
    [Sol. (1) C–C–Cl, C–C , (2) Cl–C–C–Cl, (3) C  C  Cl , (4) Cl–C–C ,
    |
    Cl

    (5) C–C , (6) Cl–C– , (7) C– , (8) Cl3C–CCl3]

    %Q.23alkene Pick the correct statement for monochlorination of R-secbutyl chloride.

    Cl
    
    2
    300C

    (A) There are four possible products ; three are optically active one is optically inactive
    (B) There are five possible products ; three are optically inactive & two are optically active
    (C*) There are five possible products ; two are optically inactive & three are optically active
    (D) There are four possible products ; two are optically active & two are optically inactive

    [Sol. ]

    One or more than one is/are correct


    Q.27more Which of the following is/are a bicyclo compound(s):

    (A) (B) (C*) (D*)

    [Sol. A is cycloalkyl cycloalkane, B is spiro compound, only C and D are bicyclo compounds ]

    %Q.30 Configuration of is

    (A*) R (B) S (C*) D (D) L

    Q.33 Which of the following is primary amine


    (A*) t-butyl amine (B*) aniline (C*) sec. butylamine (D) N-methyl methanamine
    [Sol. D is 2° amine]
    MATCH THE COLUMN

    %Q.1 Match the column-I with column-II, where column I indicates a pair compound and column II indicates
    their relationship. Note that column-I may have more than one matching options in column-II.
    [4 × 1 = 4]
    Column-I Column-II

    (A) & (P) Identical

    (B) & (Q) Geometrical isomers

    (C) & (R) Diastereoisomers

    (D) & (S) Enantiomers

    [Ans. (A): Q, R; (B) R; (C) P; (D): R]


    %Q.2 Match the column-I with column-II, where column I indicates a compound and column II indicates its
    configuration. Note that column-I may have more than one matching options in column-II.
    [4 × 1 = 4]
    Column-I Column-II

    (A) (P) 2R 3S

    (B) (Q) S

    (C) (R) R

    (D) (S) 2S 3R

    [Ans. (A): R; (B): Q; (C): P; (D): S]

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