SUBJECT : CHEMISTRY

SECTION-I 8. Law of multiple proportion can be illustreated by

Attempt All 35 questions following pairs of compounds

1. A sample of copper sulphate pentahydrate, (1) CO, CO2 (2) NO, CO

CuSO4. 5H2O contains 1 mole of Cu. How (3) H2O, D2O (4) N2O, N
many moles of oxygen atoms are in this 9. Number of atoms of He in 100 amu of He is:
sample? (Atomic mass of He is 4)
(1) 2 (2) 3 (3) 5 (4) 9 (1) 25 (2) 100
2. A compound contains 3.2 % of oxygen by mass. (3) 50 (4) 100 × 6 × 10 – 23
The minimum mol. wt. of the compound is :-
10. 1 gram of a carbonate (M2CO3) on treatment
(1) 300 (2) 400 (3) 350 (4) 500 with excess HCl produces 0.01186 mole of CO2.
3. The vapour densities of two gases are in the The molar mass of M2CO3 in g mol – 1 is
ratio of 1:3. Their molecular masses are in the (1) 118.6 (2) 11.86 (3) 1186 (4) 84.3
ratio of :
11. The limiting reagent in a chemical reaction is
(1) 1 : 2 (2) 2 : 3 (3) 1 : 3 (4) 3 : 1 one that :
4. An oxide of sulphur contain 80% of sulphur in (1) has the largest molar mass (formula weight)
it. Its empirical formula is
(2) is consumed completely
(1) SO2 (2) S2O (3) S3O (4) SO3
(3) has the smallest molar mass (formula
5. A gas is found to have the formula (NO)x. Its weight)
vapour density is 150. The value of x must be:
(4) has the smallest coefficient
(1) 4 (2) 8 (3) 5 (4) 10
12. Which of the following contains largest number
6. The number of oxygen atoms in 6.4 g of SO2 is: of atoms ?
(1) 6 × 1023 (2) 11 × 1023 (1) 4 g of H2 (2) 16 g of O2
(3) 12 × 1023 (4) 1.2 × 1023 (3) 28 g of N2 (4) 18 g of H2O
7. The weight of a molecule of the compound 13. How many moles of Na+ ions are in 20 mL of
C6H12O6 is : 0.40 M Na3PO4
(1) 1.09 × 10 – 21 g (2) 2.988 × 10 – 22 g (1) 0.0080 (2) 0.024 (3) 0.050 (4) 0.20
(3) 5.025 × 10 – 23 g (4) 16.023 × 10 – 23 g
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14. If 92g of C2H5OH is present in 250 mL of 21. In a gaseous reaction of type :
solution. Then molarity of solution will be :- xA(g) + yB(g) → pC(g) + qD(g)
(1) 8 M (2) 10 M where x, y, p and q are stoichiometric
(3) 4 M (4) None of these coefficients.
Which of the following statements is incorrect :
15. Atomicity of methane will be
(1) At STP, x litre of A combine with y litre of
(1) 2 (2) 3 (3) 4 (4) 5
B to give C and D
16. Which has maximum number of atoms :
(2) x mole of A combine with y mole of B to
(1) 24 g of C (12) (2) 56 g of Fe (56) give C and D
(3) 27 g of Al (27) (4) 108 g of Ag (108) (3) x g of A combine with y g of B to give C
17. 1 Mol CH4 contains :- and D.
(1) 6 × 1023 atoms H (4) x molecules of A combine with y molecules
(2) 4g atom H of B to give C and D.
(3) 1.8 × 1023 molecules 22. 11.2 litre of NH3 at STP has electrons :
CH4 (1) 3.01 × 1021 (2) 3.01 × 1022
(4) 3g carbon
(3) 3.01 × 1025 (4) 3.01 × 1024
18. 1.5 mol of O2 combine with Mg to form MgO.
The mass of Mg that has compound is :- 23. How many grams are contained is 1 g – atom of
2 Mg + O2 → 2MgO Na?
(1) 72 g (2) 36 g (3) 48 g (4) 24 g (1) 13 g (2) 23 g
19. Average atomic weight of boron is 10.10 and (4) 1 g
(3) 1g
boron exists in two isotopic forms B10 and B11. 23
The percentage abundance of B10 is 24. Normality of 0.04 M H2SO4 is:
(1) 10% (2) 90% (3) 50% (4) 20% (1) 0.02 N (2) 0.01 N
20. Which of the following statement is correct : (3) 0.04 N (4) 0.08 N
(1) 5.6 L of oxygen at STP contains 3.01 ×
1023 atoms of oxygen 25. 50 g of calcium carbonate was completely
burnt in air. What is the weight (in grams) of
(2) 5.6 L of oxygen at STP equivalent to 1/2
mole the residue?
(3) vapour density = molar mass × 2 (1) 28 (2) 2.8 (3) 46 (4) 4.8
(4) Mole fraction is temperature dependent

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26. The phosphate of a certain metal M is 32. The eq. wt. of H3PO4 in the reaction will be
M3(PO4)2. The correct formula of metal H3 P O4 + Ca(OH)2 → CaHP O4 + 2H2 O
sulphate would be. (1) 98 (2) 49
(1) M2(SO4)2 (2) MSO4 (3) 32.66 (4) None of these
(3) M3(SO4)2 (4) M2SO4 33. Volume of 2 mole of gas occupied at 2 atm and
273 K is :-
27. Sum of number of proton, electron and neutron
in 1 mol hydrogen gas is - (1) 22.4 Litre (2) 44.8 Litre

(1) 1NA (2) 2NA (3) 4NA (4) 6NA (3) 11.2 Litre (4) 67.2 Litre
34. A hydrocarbon on combustion produces 13.2 g
28. Which of the following contains maximum
CO2 and 2.7 g water then the hydrocarbon is
number of oxygen atoms ?
(1) C2H4 (2) C6H6
(1) 1 g of O
(3) C7H8 (4) C5H12
(2) 1 g of O2
35. The empirical formula of a compound is CH2O.
(3) 1 g of O3
If its VD is 30, its molecular formula is :-
(4) all have the same number of atoms
(1) CH2O (2) C2H4O2
29. Which of the following contains the least
number of molecules ? (3) C3H6O3 (4) CH3OH

(1) 4.4 g CO2 (2) 3.4 g NH3 SECTION-II

This section will have 15 questions. Candidate
(3) 1.6 g CH4 (4) 3.2 g SO2 can choose to attempt any 10 questions out of
30. An oxide of sulphur contains 50% of sulphur in these 15 questions. In case if candidate attempts
it. Its empirical formula is - more than 10 questions, first 10 attempted
questions will be considered for marking.
(1) SO2 (2) SO3 (3) SO (4) S2O
36. Density of at 1 mole NH3 at STP is. (g.L – 1)
31. Weight of oxygen in Fe2O3 and FeO is in the
simple ratio of : (1) 1.517 g.L – 1 (2) 0.379 g.L – 1
(1) 3 : 2 (2) 1 : 2 (3) 2 : 1 (4) 3 : 1 (3) 0.758 g.L – 1 (4) 2.9 g.L – 1

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37. Assertion : Equal moles of C-12 and C-13 will 40. The vapour density of a hydrocarbon CnH2n is 28
have equal number of atoms. then the value of n is :-
Reason : Equal moles of C-12 and C-13 will (1) 2 (2) 4 (3) 3 (4) 5
have equal mass.
41. A sample of ammonium phosphate, (NH4)3PO4,
(1) Both Assertion and Reason are true and
contains 3.18 mol of hydrogen atoms. The
Reason is the correct explanation of
Assertion. number of moles of oxygen atoms in the sample
is:
(2) Both Assertion and Reason are true but
Reason is not the correct explanation of (1) 0.265 (2) 0.795 (3) 1.06 (4) 3.18
Assertion. 42. 16 g of SOx occupies 5.6 litre at STP. Assuming
(3) Assertion is true but Reason is false. ideal gas nature, the value of x is :-
(4) Both Assertion and Reason are false. (1) 1 (2) 2
38. Molality of 40 % by mass of urea (3) 3 (4) None of these
(NH2 CONH2 ) solution is :
43. Which of the following depends upon
(1) 0.167 (2) 0.60 temperature?
(3) 11.11 (4) 0.167 (2) Mass fraction of
(1) Molality
39. Assertion : Molar mass = 2 × vapour density for solute
gaseous substances. (3) Molarity (4) Mole fraction
Reason : Molar mass is the mass of 1 mole of 44. For preparing 0.1 M solution of H2SO4 in one
the substance.
litre, we need H2SO4 :
(1) Both Assertion and Reason are true and
Reason is the correct explanation of (1) 0.98 g (2) 4.9 g
Assertion. (3) 49.0 g (4) 9.8 g
(2) Both Assertion and Reason are true but 45. 3.5 L of 0.01 M NaCl is mixed with 1.5 L of
Reason is not the correct explanation of 0.05 M NaCl. What is the concentration of final
Assertion. solution ?
(3) Assertion is true but Reason is false. (1) 0.022 (2) 0.011
(4) Both Assertion and Reason are false. (3) 0.22 (4) 0.033

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46. 1.520 g of the hydroxide of a metal on ignition
gave 0.995 g of oxide. The equivalent mass of
metal is:
(1) 1.520 (2) 19.00
(3) 9.00 (4) 0.995
47. An aqueous solution of 6.3 g of oxalic acid
dihydrate is made upto 250 mL. The volume of
0.1 N NaOH required completely neutralize 10
mL of this solution is-
(1) 40 mL (2) 20 mL
(3) 10 mL (4) 4 mL
48. In an organic compound C, H and N are present in
9 : 1 : 3.5 by mass. Molecular formula can be :-
(1) C6H8N2 (2) C7H10N
(3) C5H6N2 (4) C4H18N3
49. 4.6 × 1022 atoms of an elements weigh 13.8 g.
The atomic mass of the element is :
(1) 290 (2) 180 (3) 34.4 (4) 10.4
50. Which property of an element is not variable:
(1) Valency (2) Atomic weight
(3) Equivalent mass (4) None of these

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