Some - Basic - Concepts - of - Chemistry 1-7 DPP
Some - Basic - Concepts - of - Chemistry 1-7 DPP
Some - Basic - Concepts - of - Chemistry 1-7 DPP
04. The weight of one molecule of a compound 2) One fourth of the gram atomic mass of oxy-
C60H122 is : gen
1) 1.30 × 10–20 g 2) 5.01 × 10–21 g 3) Double the gram atomic mass of oxygen
3) 3.72 × 10–23 g 4) 1.4 × 10–21 g 4) Half of the gram atomic mass of oxygen
05. If 224 mL of a triatomic gas has a mass of 1 g at 11. What is the mass of one molecule of yellow
273 K and 1 atm pressure, then the mass of one phosphorus ? (Atomic mass of phosphorus =
atom is : 30)
Page No. 1
12. Which one of the following will have largest 19. The number of sodium atoms in 2 moles of so-
number of atoms ? dium ferrocyanide Na4[Fe(CN)6] is :
1) 1 g Au (s) 2) 1 g Na (s) 1) 12 × 1023 2) 26 × 1023
3) 1 g Li (s) 4) 1 g of Cl2 (g) 3) 34 × 1023 4) 48 × 1023
13. The maximum number of molecules is present 20. Which of the following has maximum number
in : of molecules ?
1) 15 L of H2 gas S.T.P. 1) 16 g of O2 2) 16 g of NO2
2) 5 L of N2 gas at S.T.P. 3) 4 g of N2 4) 32 g of N2
3) 0.5 g of H2 gas
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4) 10 g of O2 gas
14. A gaseous mixture contains oxygen and nitro- DPP - 02
gen in the ratio of 1 : 4 by weight. Therefore,
the ratio of their number of molecules is :
01. The number of water molecules is maximum in
1) 1 : 4 2) 1 : 8
1) 18 gram of water
3) 7 : 32 4) 3 : 16
2) 18 moles of water
15. Four one–litre flasks are separately filled with
3) 18 molecules of water
the gases hydrogen, helium, oxygen and ozone
at the same room temperature and pressure. The 4) 1.8 gram of water
ratio of total number of atoms of these gases
02. A person adds 1.71 gram of sugar (C12H22O11)
present in the different flasks would be
in order to sweeten his tea. The number of car-
1) 1 : 1 : 1 : 1 2) 1 : 2 : 2 : 3 bon atoms added are (mol. mass of sugar = 342)
3) 2 : 1 : 2 : 3 4) 3 : 2 : 2 : 1 1) 3.6 × 1022 2) 7.2 × 1021
16. How many molecules of an ideal gas are there 3) 0.05 4) 6.6 × 1022
in 1 mL of the gas if temperature is 27oC and
03. If isotopic distribution of C–12 and C–14 is 98%
pressure is 3 atm ?
and 2% respectively, then the number of C–14
1) 8.15 × 1023 2) 8.15 × 1020 atoms in 12 g of carbon is
3) 7.34 × 1019 4) 7.34 × 1022 1) 1.032 × 1022 2) 3.01 × 1022
17. The total number of protons in 10 g of calcium 3) 5.88 × 1023 4) 6.023 × 1023
carbonate is (N0 = 6.023 × 1023 )
04. Which has maximum number of atoms ?
1) 1.5057 × 1024 2) 2.0478 × 1024
1) 24 g of C (12) 2) 56 g of Fe (56)
3) 3.0115 × 1024 4) 4.0956 × 1024
3) 27 g of Al (27) 4) 108 g of Ag (108)
18. Number of water molecules in the drop of wa-
05. The number of atoms of oxygen present in 10.6
ter, if 1 ml of water has 20 drops and A is
g of Na2CO3 will be
Avogadro’s number, is :
1) 6.02 × 1022 2) 12.04 × 1023
1) 0.5 A/18 2) 0.05 A
3) 1.806 × 1023 4) 31.8
3) 0.5 A 4) 0.05 A/18
Page No. 2
06. Which of the following has the largest number 3) 28 g of N2 and 22 g of CO2
of atoms ?
4) 32 g of O2 and 32 g of N2
1) 0.5 g atom of Cu
14. The number of water molecules in 1 litre of
2) 0.635 g of Cu water is :
3) 0.25 mole of Cu 1) 18 2) 18 × 1000
4) 6.35 × 1020 amu of Cu
3) NA 4) 55.55 NA
07. The number of molecules present in drop of
water weighing 0.06 g is approximately 15. The number of oxygen atoms in 4.4 g of CO2 is
approx
21 21
1) 10 2) 2 × 10
1) 1.2 × 1023 2) 6 × 1022
3) 3 × 1021 4) 4 × 1021
3) 6 × 1023 4) 12 × 1023
08. How many atoms are present in a mole of H2 SO4
16. Two containers P and Q equal volume (1 litre
1) 3 × 6.02 × 1023 2) 5 × 6.02 × 1023 each) contain 6 g of O2 and SO2 respectively at
300 K. Then
3) 6 × 6.02 × 1023 4) 7 × 6.02 × 1023
1) Number of molecules in P is less than that in
09. The number of potassium atoms in 2 moles of
Q
potassium ferrocyanide is :
2) Number of molecules in Q is less than that
1) 2 2) 6.02 × 10 23
in P
3) 8 × 6.02 × 1023 4) 4 × 6.02 × 1023
3) Number of molecules in P and Q are same
10. The number of atoms is greatest in
4) Either (a) or (b)
1) 71 g of chlorine 2) 48 g of magnesium
17. Which has maximum number of atoms ?
3) 127 g of iodine 4) 4 g of hydrogen
1) 24 g of C (12) 2) 56 g of Fe (56)
11. Number of molecules in 100 mL of each of O2 ,
NH3 and CO 2 at STP are 3) 27 g of Al (27) 4) 108 g of Ag (108)
1) In the order CO2 < O2 < NH3 18. Which of the following contains maximum
number of molecules ?
2) In the order NH3 < O2 < CO2
1) 100 cc of CO2 at STP
3) The same
2) 1500 cc of N2 at STP
4) NH3 = CO2 < O2
3) 50 cc of SO2 at STP
12. 19.7 kg of gold was recovered from a smug-
gler. How many atoms of gold were recovered 4) 200 cc of NH3 at STP
? (Au = 197)
19. Number of atoms of He in 100 amu of He
1) 100 2) 6.02 × 10 23 (atomic weight of He is 4) is
III. 1 × 10–10 mole of oxygen 08. How many moles of helium gas occupy 22.4
litres at 30oC and 1 atmosphere ?
IV. 1 × 10–10 mole of copper
a) 0.11 b) 0.90
a) II < I < III < IV
c) 1.0 d) 1.11
b) I < II < III < IV
09. The number of moles of oxygen in one litre of
c) III < II < IV < I air containing 21% oxygen by volume, in stan-
dard conditions, is :
d) IV < II < III < I
a) 0.186 mole
02. Which one of the following is the lightest ?
b) 0.21 mole
a) 0.2 mole of hydrogen gas
c) 2.10 mole
b) 6.02 × 10 22 molecules of nitrogen
c) 0.1 g of silver d) 0.0093 mole
10. The number of gram atoms of oxygen in 0.3
d) 0.1 mole of oxygen gas
gram mole of (COOH)2.2H2O is :
03. Which of the following has maximum mass ?
a) 0.6 b) 1.8
a) 0.1 g atom of carbon
c) 1.2 d) 3.6
b) 0.1 mol of ammonia 11. The number of g-atom of oxygen in 6.02 × 1024
c) 6.02 × 1022 molecules of hydrogen gas CO molecules is :
04. Which has the highest mass ? 12. Number of grams of oxygen in 32.2 g Na2SO 4.10
H 2O is
a) 50 g of iron
a) 20.8 b) 22.4
b) 5 moles of N2
c) 2.24 d) 2.08
c) 0.1 g atom of Ag 23
d) 10 atoms of carbon
Page No. 4
13. If the density of water is 1 g cm–3 then the vol- 18. If NA is Avogadro’s number, then number of
ume occupied by one molecule of water is ap- valence electrons in 4.2 g of nitride ions (N3–)
proximately is :
a) 18 cm3 a) 2.4 NA b) 4.2 NA
b) 22400 cm3 c) 1.6 NA d) 3.2 NA
c) 6.02 × 10–23 cm3 19. Mass of a mole of electrons is :
d) 3.0 × 10–23 cm3 a) 0.20 mg b) 0.02 mg
14. What amount of dioxygen (in gram) contains c) 0.55 mg d) 1.00 mg
1.8 × 1022 molecules ?
20. The number of water molecules present in a
a) 0.960 b) 96.0 drop of water (volume 0.0018 mL) at room tem-
c) 0.0960 d) 9.60 perature is :
15. Which one of the following statements is in- a) 6.023 × 1019 b) 1.084 × 1018
correct ? c) 4.84 × 10 17 d) 6.023 × 1023
a) One gram atom of carbon contains
Avogadro’s number of atoms
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b) One mole of oxygen gas contains Avogadro’s
DPP - 04
number of molecules 01. The percentage of nitrogen in urea is about
c) One mole of hydrogen contains Avogadro’s a) 46 b) 85 c) 18 d) 28
number of atoms 02. Caffeine has a molecular weight of 194. If it
d) One mole of electrons stands for 6.02 × 10 23 contains 28.9% by mass of nitrogen, num-
electrons ber of atoms of nitrogen in one molecule of
16. The total number of electrons present in 18 mL caffeine is :
of water (density of water is 1 g mL–1) is : a) 4 b) 6 c) 2 d) 3
a) 6.02 × 1023
03. Which of the following represents the for-
22
b) 6.02 × 10 mula of a substance which contains about
c) 6.02 × 1024 26% nitrogen and 74% oxygen.
17. The number of gram molecules of oxygen in 04. Harmoglobin contains 0.33% of iron by
6.02 × 10 24 CO molecules is : weight. The molecular weight of haemoglo-
bin is approximately 67200. The number of
a) 10 gm molecules
iron atoms (at. wt. of Fe = 56) present in one
b) 5 gram molecules molecule of haemoglobin is
c) 1 gm molecules a) 6 b) 1 c) 4 d) 2
d) 0.5 molecules 05. The percentage of nitrogen by mass in am-
monium sulphate is closest to (atomic masses
: H = 1, N = 14, O = 16, S = 32)
a) 21% b) 24% c) 36% d) 16%
Page No. 5
06. In a hydrocarbon, the mass ratio of hydro- 13. An organic compound contains carbon, hy-
gen to carbon in 1 : 3. The empirical formula drogen and oxygen. Its chemical analysis
of the hydrocarbon is : gave C, 38.71% and H, 9.67%. The empiri-
a) CH b)CH c) CH d) CH cal formula of the compound would be :
2 2 3 4
a) CH 3O b) CH2O
07. An organic compound contains carbon, hy-
drogen and oxygen. Its chemical analysis c) CHO d) CH4O
gives C, 38.71% and H, 9.67%. The empiri-
cal formula of the compound would be : 14. 0.1 mole of a carbohydrate with empirical
a) CH 3O b) CH2O formula CH2O contains 1 g of hydrogen.
What is its molecular formula ?
c) CHO d) CH4O
a) C 5 H10O 5 b) C6H12O6
08. The empirical formula of an oxide of iron
which has 68.9% iron and 30.1% oxygen by c) C 4H 8O4 d) C3H6O3
mass is (Atomic mass of Fe = 56, O = 16) 15. 10 g of hydrofluoric acid gas occupies 5.6
a) FeO b) Fe 2 O3 litres of volume at STP. If the empirical for-
mula of the gas is HF, then its molecular for-
c) Fe3O4 d) None of these mula in the gaseous state will be
09. A compound (60 g) on analysis gave C = 24 a) HF b) H 2 F 2
g, H and 4 g, O = 32 g. Its empirical formula
is : c) H3 F3 d) H 4F4
a) C 2H2 O2 b) C2H2 O2 16. A gas is found to have the formula (CO)x. Its
V.D. is 70. The value of x must be :
c) CH2 O2 d) CH 2 O
a) 7 b) 4
10. A compound contains 38.8% C, 16.0% and
45.2% N. The formula of the compound c) 5 d) 6
would be :
****************************************
a) CH 3NH 2 b) CH3CN DPP - 05
c) C 2H5CN d) CH2(NH)2
11. An oxide of a metal (M) contains 40% by 01. 30 g of Magnesium and 30 g of oxygen are reacted,
then the residual mixture contains :
mass of oxygen. Metal (M) has relative mass
of 24. The empirical formula of the oxide is a) 60 g of Magnesium oxide only
a) 24 g b) 8 g
c) 40 g d) 10 g
Page No. 7
18. The amount of zinc required to produce 224 ml of 04. In Haber’s process, 30 litres of dihydrogen and 30
H 2 at STP on treatment with dil. H2SO4 will be litres of dinitrogen were taken for reaction which
yielded only 50% of the expected product. What
a) 0.65 g b) 6.5 g
will be the composition of the gaseous mixture un-
c) 65 g d) 0.065 g der the aforesaid conditions in the end ?
19. Assuming fully decomposed, the volume of CO2 a) 20 litres ammonia, 20 litres nitrogen, 20 litres
released at STP on heating 9.85 g of BaCO3 (Atomic hydrogen
mass, Ba = 137) will be b) 10 litres ammonia, 25 litres nitrogen, 15 litres
a) 0.84 L b) 2.24 L hydrogen
c) 20 litres ammonia, 10 litres nitrogen, 30 litres
c) 4.06 L d) 1.12 L
hydrogen
20. The volume of oxygen at STP required to burn 2.4 d) 20 litres ammonia, 25 litres nitrogen, 15 litres
g of carbon completely is : hydrogen
a) 1.12 L b) 8.96 L 05. What will be the volume of the mixture after the
c) 2.24 L d) 4.48 L reaction
d) O2 = 10 litres, CO2 = 20 litres 07. If 0.5 mol of BaCl2 is mixed with 0.2 mol of Na3PO 4,
the maximum number of moles of Ba3(PO4)2 that
02. What volume of oxygen gas (O2) measured at 0oC can be formed is :
and 1 atm is needed to burn completely 1 L of pro-
pane gas (C3H8) measured under the same condi- a) 0.7 b) 0.5
tions ?
c) 0.30 d) 0.10
a) 7 L b) 6 L c) 5 L d) 10 L 08. For the reaction A + 2 B C, the amount of C
03. 100 ml of PH3 on heating forms P and H2. The vol- formed by starting the reaction with 5 moles of A
ume change in the reaction is : and 8 moles of B is :
a) an increase of 50 ml a) 5 moles b) 8 moles
d) 2 moles of ammonia
Page No. 8
10. In the reaction, 4 NH3 + 5 O 2
4 NO + 6 H2O, 17. When 22.4 litres of H (g) is mixed with 11.2 litres
2
when one mole of ammonia and one mole of oxy- of Cl2 (g) each at S.T.P. the moles of HCl (g) formed
gen are made to react to completion, then : is equal to :
b) all the oxygen is consumed c) 0.5 mol of HCl (g) d) 1.5 mol of HCl (g)
12. The maximum amount of BaSO4 precipitated on c) 6.02 × 1020 d) 6.02 × 1018
mixing equal volumes of BaCl2 (0.5 M) with H2SO 4
(1 M) will correspond to 02. The density of 3 M solution of NaCl is 1.25 g
mL–1. Calculate the molality of the solution.
a) 0.25 M b) 0.50 M
c) 1.0 M d) 1.5 M a) 2.8 m b) 2.6 m
a) 3.01 × 1020 c) 6 g d) 60 g
a) 1 N b) 0.1 N
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c) 5 N d) 0.5 N
12. 100 cm3 of 0.1 N HCl is mixed with 100 cm3 of
0.2 N NaOH solution. The resulting solution is :
a) 0.1 N and the solution is basic
b) 0.05 N and the solution is basic
Page No. 10
DPP - 01 ANSWER KEY
01. 3 02. 4 03. 3 04. 4 05. 3 06. 3 07. 1 08. 3 09. 4 10. 4
11. 2 12. 3 13. 1 14. 3 15. 3 16. 3 17. 3 18. 4 19. 4 20. 4