Aakash- Some basic concept of Chemistry (.

1 ) 201 amu · ·
(2) 202 amu
(Mole Concept) -
1. A sample of ammonium phosphate (NH4 )3PO 4 (3) 199amu
contains 3. 18 moles of hydrogen atoms. The (4) 200 ·~mu
number of moles of oxygen atoms in the sample Is . . " :.. . - ... - ~ ' . .
(1) 0.265 · ~Stoichiometry·&· S.!oichl'om.~tH.F Calculations)
(2) 0.795 ·
(3) 1.06 ..
(4) 4.00 10. Two metallic oxides · contain ·-27 6% and 30% . ' . \
2. Which has the .maximum number of molecules (.
among the following? oxygen· respectively. If the-for;mμla .of. th~ first oxide
(1) 8gH2 is X3O4
(2) 64 g S02 , that of the second.-wilf:b~ . · . .
(3) 44 g CO2 (1) )0
(4) 48 g 0 3 (2) xo2
3. The total number of electrons in 1.6 g of CH4 to (3) X:Ps
that in 1.8 g of H2O (4) Xi03
(1) Double 11. Haemoglobin contains 0.334% of iron by weight.
(2) Same The molecular weight · of haemoglobin is
(3) Triple approximately 67200. The number of iron atoms
(4) One fourth (Atomic weight of Fe is 56) present in· one
4. When x molecu,es are removed from 200 mg of molecule of haemoglobin is
N20 , 2.89 x 1 o-3 moles of N2O are left. x will be (1) 4
(1) 1020 molecules (2) . 6
(2) 1010 molecules (3) 3
(3) 21 molecules (4) 2
(4) 1021 molecules 12. In the reaction,
. - " . r. " ' - - . , I. ' - .. .: \ . ' 2S02 + 0 2 ➔ 2S03
,. when 1 mole of S02 and 1 mole of 0 2 are made
.. to react to completion
5. . Which has maximum molecules? (1) . All the oxygen will be consumed
6. (2) 1.0 mole of S03 will be produced
(1) 7gN20 (3) 0.5 mole of S02 is remained
(2) 20 g H2 (4) All of these
(3) 16 g N02 13. Consider the following reaction sequence:
(4) 16 g S02 Sa(s) + 802'9) ➔ 8S02'g)
I •• ·•
2S02'g) + 02'9) ➔ 2S03'9)
The number of molecules in 4.25 g .o f . NH3 is
How many grams of S03 are produced from 1 mole
approximately
Sa?
(1) 4 X 1023
(1) 1280 g
(2) 1.5 X 1023
(2) 960 g
(3)' 1 X 1023
(3) 640 g
(4) 6 X 1Q2~ . .
(4) 320 g
7. The maximum number of molecules is present in
14. 4 g of hydrogen reacts with 20 g of oxygen to form
: • •• • ; 1 • ,,. •
water. The mass of. water formed is
(1) 15 L of .H2 gas at STP .
(1) 24 g
'''
(2) 36 g
(2) 5 L of N2 gas at STP \ .
(3) 22.5 g
(3) 0.5 g ~f H2 gas
(4) 40 g
. . ,"\. ~
:)
(4) 10 g of 0 2 ga~
Tl
8. The number of atoms in 0.1. mol of a tetraatomic
(Reactiot1s tn·.solutions)
gas is (NA = 6.02. i~ 1023 ~01- 1) ·. · · , ·
15.". -~C·; loJlat~ the, m.9!~lity of solution containing 3
( 1 ) 2 .4 X 1 022 .
g
(2) 6.026 X 1Q22
. , -,.-"· :glu~se dissglv~Cli Jn 30 g of water. (molar
(3) 2.4 X 1023
mass of
(4) 3.600 X 1023
·;: .. • :i .. .:: glucose,=· 18~)·' I·
9. An element, X · has the following isotopic
•~ ;~ :.l•• ·• .,:~·•~ ,. -, .,<
composition 2~0x: 90% 1_99X : 8% 202x : 2.0%. The
. • .,. (1) •·o.so m
weighted averag~ · atomic ·mass of th~ naturally
.. • (2) 0.56 m , ,
occurring. element x· is closest to , .
(3) 0.091 m (3) Infinite significant figures in both
(4) · 0.05 m (4) Two significant figures in both
16. · H~w m~ny g~am~ of NaOH should be added to 8. Molarity' of 29% ( : ) H2S04 solution whose
water to prepare 250 ml solution of 2 M NaOH? density is 1.22 g m1-1, is [NCERT Pg.-23)
(1) 9.6 X 103 (1) 1.8 M
(2) 2.4 X 103 (2) 3.6 M
(3) 20 (3) 2.4 M
' (4) 1.2 M
(4) , 24 9. In a reaction 3A + B2 ~ ~82 [NCERT Pg. 20)
NCERT Based MCQs If 180 atoms of A and 100 molecules of B react,
1. Number of atoms present in 120 a.m.u. of Ca is , then
2. (1) B is limiting reactant and 100 molecules of
3. ~B2 will be formed
(1) 3 NA (2) A is limiting reactant and 60 molecules of A3B2
(2) 6 NA will be formed
(3) 3 (3) A is limiting reactant and 180 molecules of
(4) 6· A3B2 will be formed
[NCERT Pg. 16] (4) B is limiting reactant and 60 molecules of A3B2
How many moles of aluminium sulphate, Ali(SO will be formed
4h 10. Copper has two naturally occurring isotopes 63Cu
will contain 0.24 mole of oxygen atoms? · and 65Cu. If the average atomic mass of copper is
[NCERT Pg. 20] 63.546 u, then natural abundance of lighter isotope
(1) 2.Q X 102 of Cu will be [NCERT Pg. 17]
(2) 2.0 X 10-2 (1) 46.4%
(3) 3.0 X 1Q3 (2) 27.3%
(4) 1.5 ~ 10-2 (3) 54.2%
Which of the following molecule has highest (4) 72.7%
percentag~ of oxygen by mass? [NCERT Pg. 18] 11. Out of the following statements choose an incorrect
(1) H2O statement regarding compounds [NCERT Pg. 5]
(2) CO2 (1) Constituents of compound can be separated by
(3) CaCO3 physical methods
(4) C2H5OH (2) They can be decomposed by chemical
I methods
,- (3) Properties of a compound are different from
4. How many moles of ethane are required to produce · those of its constituent elements
44 g of CO2(g), after the combustion of ethane? (4) Elements combine in a fixed proportion by
[NCERT Pg. 20] mass in a compound
(1) 2 12. Which of the following are correct statements?
(2) 1 [NCERT Pg. 13]
(3) 0.5 (a) Precision refers to closeness of various
(4) 0.25 measurements for the same quantity.
5. What is mass of sodium acetate (CH3COONa) (b) Accuracy is the agreement of particular value
required to make 200 ml of 0.245 molar aqueous to the true value of the result.
solution? (Molar mass of CH3COONa = 82 g mol-1) (c) Accuracy is closeness of various
[NCERT Pg. 23] measurements for the same quantity.
(1) 3 g (1) (a) & (b) only
(2) 4 g (2) (b) & (c) only
(3) 5 g (3) (a) & (c) only
(4) 6 g (4) (a), (b) & (c)
6. Which of the following is not related to Dalton's 13. Numerical prefix used for 1012 is [NCERT Pg. 9]
atomic theory? [NCERT Pg. 16] (1) Giga (2) Tera
(1) Matter consists of indivisible atoms (3) Peta (4) Exa
(2) All the atoms of a given element have identical, 14. The number, 0.00001465 can be correctly
chemical properties expressed in scientific notation as
(3) Matter can be classified into elements and (1) 146.5 x 10-6
compounds (3) 1.465 X 1 o-5
(4) Compounds are formed when atoms of different [NCERT Pg. 11)
elements combine in fixed ratio (2) 146.5 x 1 Q-3
7. Counting numbers of objects, for example 4 balls (4) 1.465 x 1 Q-4
and 10 eggs have [NCERT Pg. 12] 15. 28 g of N2 and 6 g of H2 react to give 34 g of NH3 .
(1) One and two significant figures respectively This statement illustrates the law of
(Z) One significant figures in both (1) Conservation of mass
(2) Definite proportion (3) 1.5
(3) Multiple proportion (2) 2
(4) Reciprocal proportion (4) 3
[NCERT Pg. 14] 10. The amount of zinc required to produce 1.12 ml of
Objective Type Questions H2 at STP on treatment with dilute HCI will be
(Mole Concept) (1) 65 g (2) 0.065 g
1. The total number of electrons in 4.2 g of N3- ion ls (3) 32.5 X 10-4 Q (4) 6.5 Q
(NA is the Avogadro's number) 11. Volume of CO2 obtained at STP by the complete
2. decomposition of 9.85 g Na2CO~ is
(1) 2.1 NA (2) 4.2NA (1) 2.24 litre (2) Zero
(3) 3 NA (4) 3.2 NA (3) 0.85 litre (4) 0.56 litre
Suppose that A and B f6nn the compounds B 12. One litre of CO2 is passed through red hot coke.
2 The volume becomes 1.4 litres at same
A temperature and pressure: The composition of
3 products is
and B2A. If 0.05 mole of B/\3 weighs 9 g and (1) 0.8 litre of CO2 and 0.6 litre of CO
0.1 mole of BiA weighs 10 g, the atomic weight of (2) 0.7 litre of CO2 and 0.7 litre of CO
A and B respectively are (3) 0.6 litre of CO2 and 0.8 litre of CO
(1) 30 and 40 (4) 0.4 litre of CO2 and 1.0 litre of CO
(3) 20 and 5 13. An organic compound containing C and H gave the
(2) 40 and 30 following analysis C = 40%, H = 6.7%. Its
(4) 15 and 20 empirical formula would be
3. Number of Fe atoms in 100 g Haemoglobin if it 14. How many litre of oxygen at STP is required to burn
contains 0.33% Fe. (Atomic mass of Fe= 56) 60 g C2H6? ·
(1) 0.035 X 1023 (2) 35 (1) 22.4 L (2) 11 .2 L
(3) 3.5 X 1Q2J (4) 7 X 1Q8 (3) 22.4 >< 7 L (4) 8.5 L
4. The number of electrons in 1.6 g of CH4 is 15: For the formation of 3.65 g of HCI gas, what v~lume
approximately of hydrogen gas and chlorine gas are required at
(1 ) 25 X 1024 NTP conditions? ·
(3) 6 X 1Q23 (1) 1 L, 1 L (2) 1.12 L, 2.24 L -
(2) 1.5 X 1024 . (3) 3.65 L, 1.83 L (4) 1.12 L, 1.12 L
(4) 3.0 )( 1024 16. The crystalline salt Na2SO4.xH2O on_ heating loses
5. Specific volume of cylindrical virus particle is 55.9% of its mass and becomes anhydrous. The
6.02 x 10-2 cc/gm whose radius and length are formula of crystalline salt is
7 A and 10 A respectively. If NA = 6.02 x 1023, (1) Na2SO4.5H2O (2) Na2SO4.7H2O
find molecular weight of virus. (3) Na2SO4.2H2O (4) Na2SO4. 10H20
(1) 15.4 kg/mol (2) 1.54 x 104 kg/mol 17. A certain amount of a metal whose equivalent.mass
(3) 3.08 x 104 kg/mol (4) 3.08 x 103 kg/mol is 28 displaces 0.7 L of H2 at S.T.P. from an acid
6. The number of mole of nitrogen in one litre of air hence mass of the element is
containing 10% nitrogen by volume, under standard (1) 1.75 g
conditions, is (3) 3.50 g
(1) 0.03 mole (2) 0.875 g
(3) 0.186 mole (4) 7.00 g
(2) 2.10 moles (Reactions in Solutions)
(4) 4.46 x 10-3 mole M ..
7. Number of significant figures in 6.62 x 10-34. 18. When 100 ml of 10 H2SO 4 is mixed with 500 ml of
(1) Too M
(3) Four 10 NaOH then nature of resulting solution and
(2) Three normality of excess of reactant left is
(4) One NN
• - • e t _ I• ~ J ,., - - J ""~f - ..ta • • • I (1) Acidic, 5 (2) Basic, 5
(Stoichiometry & Stoichiometric Calculations) NN
8. Liquid benzene (C6H6) burns in oxygen according (3) Basic,
to 2C6H6 (I)+ 15Oi(g)~ 12CO2(g) + 6H2O(g) 20
How many litres of 0 2 at STP are needed to (4) Acidic, 10
complete the combustion of 39 g of liquid benzene? 19. Mole fraction of solvent in aqueous solution of
(1) 74L (2) 11.2L . NaOH having molality of 3 is
(3) 22.4 L (4) 84 L (1) 0.3 (2) 0.05
9. 1 mol of KCIO3 is thermally decomposed and (3) 0.7 (4) 0.95
excess of aluminium is burnt in the gaseous 20. Concentrated aqueous sulphuric acid is 98% H2SO 4
product. How many moles of Al2O3 are formed? by mass and has a density of 1.80 gml-1. Volume
(1) 1 of acid required to make one litre of 0.1 M H2SO4
solution is molecular mass of NaOH = 40 g moI-1]
(1) 16.65 ml (2) 22.20 ml (1) 1.32 m
(3) 5.55 ml (4) 11.10ml (3) 1.56 m
21. Ammonia gas is passe_d into water, yielding a [NEET-2019 (Odisha)]
solution . of density 0.93 g/cm3 and containing (2) 1.20 m
1 (4) 1.67 m
18.6% NH3 by weight. The mass of NH3 per cc of 4. The number of moles of hydrogen molecules
the solution is 2. required to produce 20 moles of ammonia through
(1) 0.17 g/cm3 (2) 0.34 g/cm3 Haber's process is : [NEET-2019]
(3) 0.51 g/cm3 (4) 0.68 g/cm3 (1) 10
22. 6.025 x 102° molecules of acetic acid are present in (3) 30
500 ml of its solution. The concentration of solution is (2) 20
(1) 0.002 M (2) 10.2 M (4) 40
(3) 0.012 M (4) 0.001 M 5. A mixture of 2.3 g formic acid and 4.5 g oxalic
(Equi~alent Mass) acid ·is treated with cone. H2SO4. The evolved
23. 7 4.5 _g of metal chloride contains 35.5 g of gaseous mixture is passed through KOH pellets.
chlorine. Weight (in g) of the remaining product at STP will
The equivalent weight of metal is be · [NEET-2018]
(1) 74.5 · (2) 39 (1) 1.4
(3) 35.5 (4) 7.45 (3) 4.4
24. Equivalent wejght of crystalline oxalic acid is (2) 3.0
(1) 90 (2) 63 (4) 2.8
(3) 53 (4) 45 6. In which case is nur:nber of molecules of water
25. Equivalent mass of H3PO 4 (Molar mass = M) for maximum? [NEET-2018]
the given reaction, H3PO 4 + Ca(OH)i ➔ CaHPO 4 + (1) 18 ml of water
2H20 is (2) 0.18 g of water:
(1) M (3) 10-3 mol of water
1 (4) 0.00224 L of water vapours at 1 atm and 273 K
(3) 2 M 7. Suppose the elements X and Y combine to form
M two compounds XY 2 and X3 Y 2. When 0.1 mole of
(2) 2 XY 2 weighs 10 g and 0.05 mole of X3 Y 2 weighs
M 9 g, the atomic weights of X and Y are
(4) 4 (1) 40, 30
26. Equivalent mass of a metal is 12. Hence, equivalent (3) 20, 30
mass of its oxide is [NEET-Phase-2-2016]
(1) 24 (2) 60, 40
(3) 20 (4) 30, 20
(2) 28 8. What is the mass of the precipitate formed when
(4) 34 50 ml of 16.9% (w/v) solution of AgNO3 is mixed
27. 4 g of a metal oxide contains 1.6 g oxygen, then with 50 ml of 5.8% (w/v) NaCl solution?
equivalent mass of the metal is (Ag= 107.8, N = 14, 0 = 16, Na= 23, Cl= 35.5)
(1) 3.2 (1) 7 g
(3) 12 (2) 14 g
(2) 24 (3) 28 g
(4) 20 (4) 3.5 g
Previous Years Questions ''
1. Which one of the followings has maximum number [Re-AIPMT-2015]
· of atoms? [NEET-2020 (Phase-1)] _____________ .. •·~-.,(: . .,;
(1) 1 g of Mg(s) [Atomic mass of Mg = 24] 9. If Avogadro number NA, is changed from
(2) 1 g of Oz(g) [Atomic mass of O = ·16] 6.022 x 1023 mol-1 to -6.022 x 1020 moI-1, this
(3) 1 g of Li(s) [Atomic mass of Li = 7] would change [Re-AIPMT-2015]
(4) . 1 g of Ag(s) [Atomic mass of Ag= 108] (1) The ratio of chemical species to each other in
2. One mole of carbon atom weighs 12 g, the number a balanced equation
of atoms in it is equal to, (Mass of carbon-12 is (2) The ratio of elements to each other in a
· 1.9926 x 10-2~ g) [NEET-2020 (Phase-2)] compound
(1) 6.022 X 1023 (3) The definition of mass in units of grams
(2) 1.2 X 1023 (4) The mass of one mole of carbon
(3) 6.022 X 1022 10. 20.0 g of a magnesium carbonate sample
(4) 12 X 1022 decomposes on heating to give carbon dioxide and
3. The density of 2 M aqueous solution of NaOH is 1.28 8.0 g magnesium oxide. What will be the
g/cm3. The molality of the solution is [Given th~t percentage purity of magnesium carbonate in the
sample? (At. wt. : Mg = 24) [Re-AIPMT-2015]
(1) 60 (2) 84 Na2C03 = 106 g mol-1) [AIPMT (Prelims)-2010]
.(3) 75 (4) 96 (1) 0.955 Mand 1.910 M
11 . A mixture of gases contains H2 and 0 2 gases in (2) 1.910 M and 0.955 M
the ratio of 1 : 4 (w/w). What is the molar ratio of (3) 1.90Mand1.910M
the two gases in the mixture? [AIPMT-2015] (4) 0.477 Mand 0.477 M
(1) 2 : 1 20. 10 g of hydrogen and 64 g of oxygen were filled in
(3) 4 : 1 a steel vessel and exploded. Amount of water
(2) 1 : 4 produced in this reaction will be .
(4) 16: 1 (1) 3 mol
12. 1.0 g of magnesium is burnt with 0.56 g 0 (3) 1 mol
2 [AIPMT (Prelims)-2009]
in a (2) 4 mol
closed vessel. Which reactant is left in excess (4) 2 mol ·
and how much? (At. wt. Mg= 24; 0 = 16) 21 , How many moles of lead (II) chloride will be
(1) Mg, 0.16 g formed
(3) Mg, 0.44 g from a reaction between 6.5g of PbO and 3.2 g of
[AIPMT-2014] HCI? [AIPMT (Prelims)-2008]
(2) 0 2, 0.169 (1) 0.029 · (2) 0.044
(4) 0 2, 0.28 g (3) 0.333 (4) 0.011
13. When 22.4 litres of H2 (g) is mixed with 11 .2 litres 22. ◄ Volume,; qccupied by one molecule ~f water
of Cli(g), each at S.T.P, the moles of HCl(g) (den.sity' = ,1 g c_m-3) ·is [AiPMT (Prelims)-2008]
formed is equal to [AIPMT-2014] I
(1) 1 mol of HCI (g) (1) 5.5 x 10-23 cm3
(2) 2 mol of HCI (g) (2) 'g:o · x 10-23 cm3
(3) 0.5 mol of HCI (g) (3) 6.023 x 10-23 .cm3
(4) 1.5 mol of HCI (g) I
14. 6.02 x 1020 molecules of urea are present in (4) 3.0 x 10-23 cm3
100 ml of its solution. The concentration of solution 23. What volume of oxygen gas (02) measured at 0°C
is [NEET-2013] and .1 atm, is needed to burn completely 1 l of
(1) 0.01 M propane gas (C3H8) measured under the same
(2) 0.001 M conditions? [AIPMT ((Prelims)-2008]
(3) 0.1 M (1) 10-l . (2) 7 l
(4) 0.02 M (3) 6 l (4) 5 l
15. -How many grams of concentrated .. nitric1 acid 24. An organic compound contains carbon, hydrogen
solution should be used to prepare 250 ml, of 2 M and oxygen. Its elemental analysis gave C, 38.71 %
HNO3? The concentrated add is 70% (w/w) HNO3 and H, 9.67%. The empirical formula of the
. compound would be [AIPMT (Prelims)-2008)
[NEET-2013] · (1) CH4O (2) CH3O
(1) 90.0 g cone. HNO3 (2) 70.0 g cone. HNO (3) CH2O (4) CHO
3 25. An element, X has the follqwing isotopic
(3) 54.0 g cone. HNO3 (4) 45.0 g cone. HNO3 composition; 200X:90%; 199X:8.0%; 202X:2.0%. ·
16. Mole fraction of the solute in a 1.00 molal aqueous The weighted average atomic mass of the naturally
solution is [AIPMT (Prelims)-2011] · occurring element X is closest to :
(1) 1.7700' [AIPMT (Prelims)-2007]
(3) 0.0177 (1) 199 amu ·
(2) 0.1770 (2) 200 amu
(4) 0.0344 (3) 201 amu
17. Which has the maximum number of molecules (4) 202 amu •
among the following? [AIPMT (Mains)-2011) 26. Concentrated aqueous sulphuric acid is 98% H SO
(1) 8 g H2 (2) 64 g S02 ,24
(4) 48 g 03 by mass and has a density of 1.80 g ml-1. Volume
18. The number of atoms in 0.1 mol of a triatomic gas of acid required to make one litre of 0.1 M H
is (NA=6.02 x 1023 mol-1) [AIPMT (Prelims)-2010] · 2
(1) 6.026 X 1022 SO
(3) 3.600 X 1023 4
(2) 1.806 X 1023 is [AIPMT (Prelims)-2007]
(4) 1.800 X 1022 (1) 5.55 ml
19. 25.3 g of sodium carbonate, Na2C03 is dissolved (2) 11.10 ml
in enough water to make. 250 ml of solution. If (3) ·16.65 ml
sodium carbonate dissociates completely, molar (4) · 22.20 ml
concentration of sodium ion, Na+ and carbonate Questions asked prior to Medical Ent. Exams. 2005
ions, co~- are respectively (Mol~r mass of 27. How many grams of CH3OH should be added to
water to prepare 150 ml solution of 2 M CH3OH? (3) 0.85 litre
(1) 9.6 x 103 (2) 1.12 litre
(2) 2.4 X 103 (4) 0.56 litre
(3) 9.6 38. Percentage of Se in peroxidase anhydrous enzyme
(4) 2.4 is 0.5% by weight (at. wt. = 78.4) then minimum
28. The total number of valence electrons in 4.2 g of molecular weight of peroxidase anhydrous enzyme
N3- Ion is (NA is the Avogadro's number) is
(1) 2.1 NA (2) 4.2NA (1) 1.568 x 1 Q4
(3) 1.6 NA (3) 15.68
29. The number of mole of oxygen in one litre of air (2) 1.568 X 103
containing 21 % oxygen by volume, under standard (4) 2.136 X 104
conditions, is 39. 2.5 litre of 1 M NaOH solution mixed with another
(1) 0.0093 mole 3 litre of 0.5 M NaOH solution. Then find out
(3) 0.186 mole molarity of resultant solution.
· (2) 2.10 moles (1) 0.80 M
(4) 0.21 mole (3) 0.73 M
30. The amount of zinc required to produce 224 ml of (2) 1.0 M
H2 at STP on treatment with dilute H2SO 4 will be (4) 0.50 M
(Zn= 65) 40. Which has maximum molecules?
(1) 65 g (1) 7 gm N2
(3) 0.65 g (3) 16 gm N02
(2) 0.065 g (2) 2 gm H2
(4) 6.5 g (4) 16 gm 0 2
31. Given the numbers: 161 cm, 0.161 cm, 0.0161 cm. 41 . In Haber process 30 litres of dihydrogen and
The number of significant figures for the three 30 litres of dinitrogen were taken for reaction which
numbers is yielded only 50% of the expected product. What
(1) 3, 3 and 4 respectively will be the composition of gaseous mixture under
(2) 3, 4 and 4 respectively the aforesaid condition in the end?
(3) 3, 4 and 5 respectively (1) 20 litres ammonia, 20 litres nitrogen, 20 litres
(4) 3, 3 and 3 respectively hydrogen
32. Change in volume when 100 ml PH3 decomposed (2) 10 litres ammonia, 25 litres nitrogen, 15 litres
to solid phosphorus and H2 gas. hydrogen
(1 ) Increase in 50 ml (2) Decrease in 50 ml (3) 20 litres ammonia, 10 litres nitrogen, 30 litres
(3) Increase in 150 ml (4) Decrease in 200 ml hydrogen
33. In the reaction, (4) 20 litres ammonia, 25 litres nitrogen, 15 litres
4NHig) + 5Oig) ➔ 4NO(g) + 6H2O(/) hydrogen
when 1 mole · of ammonia and 1 mole of 0 2 are 42. The maximum number of molecules is present in
made to react to completion (1) 15 L of water at STP
(1 ) All the oxygen will be consumed (2) 15 L of H20 gas at STP
(2) 1.0 mole of NO will be produced (3) 15 g of ice
(3) 1.0 mole of H2O is produced (4) Same in all
(4) All the ammonia will be consumed . u,-.r vv1r1v -uv,v _..,,,..,-,-.- - · · · - ,
34. An organic compound q_ontaining C, H and N gave 43. Concentrated aqueous sulphuric acid is 98% H2SO 4
the following analysis C = 40%, H = 13.33%, . (w/v) and has a density of 1.80 gmL-1• Molarity of
N = 46.67%. Its empirical formula would be solution
(1) CH4N (2) CH5N (1) 1 M .
35. How many g of dibasic acid (mol. weight 200) (3) 10 M.
should be present in 100 ml. of .the aqueous (2) 1.8 M
solution to give strength of 0.1 N? (4) 1.5 M
(1) 10 g 44. · An. ·element, X has the following isotopic
(3) 1 g composition 56X : 90% 57X : 8% 59X· : 2.0%. The
(2) 2 g weighted average atomic mass of the naturally
(4) 20 g occ1:1rrin·g element X is closest to
36. The number of atoms in 4.25 g of NH3 is (1) 56.14 amu
approximately · (3) 60 amu
(1) 4 X 1023 (2) 2 >< 2023 (2) 56.8 amu
(3) 1 )( 1023 (4) 6 )( 1023 (4) 55 amu
37. Volume of CO2 obtained at STP by the complete 45. 10 g of hydrogen and 64 g of oxygen were filled in
decomposition of 9.85 gm BaC03 is (Mol. wt. of a steel vessel and exploded. Volume of gaseous
BaCO3 = 197) product after reaction
(1) 2.24 litre (1) 1 x 22.4 L .
(3) 3 x 22.4 L
. \ .,
(2) 2 x 22.4 L (1) 1
(4) 4 x 22.4 L (3) 4
46. What is the [QH-J in the final solution prepared by (2) kg
mixing 20.0 ml of 0.050. M HCI with 30.0 ml of (4) ampere
0.10 M Ba(OH)2? (2) second-1
(1) 0.12 M (2) 0.10 M ( 4) All of these
(3) 0.40 M (4) 0.0050 M (2) 2
47. The number of atoms in 0.1 mol of a triatomic gas (4) 4
is•(NA = 6.02 x 1023 mol-1) (2) 2
(1) 1.800 X 1022 (2) 6.026· X 1022 (4) 5
(3) 1.806 X 1023 (4) 3.600 X 1023 6. Add (0.001 + 0.02) upto correct number of significant
48.,. The total number of electrons in 2.0 g of D figures
2 (1) 0.021
0 to that (3) 0.003
in 1. 8 g of H2O - 7. The multiple 5 x 0.2 after rounding off will be
( 1) Double (2) Same (1) 1
(3) Triple (4) One fourth (3) 1.00
49. From 200 mg of CO2 when x molecules are 8. Round off 0.1525 upto three significant figures
removed, (1) 0.153
2.89 x 1 o-3 moles of CO2 are left. x will be (3) 0.16
(1) 1020 molecules 9. Round off 0.1576 upto one digit after decimal
I (1} 0.1
(2) 1010 molecules (3) 0.2
(3) . 21 molecules 10 Th I 5.86x3.96
(4) 1021 molecules . e va ue of --will be equal to
50. If the weight of metal oxide is x g containing y g of 2.86
oxygen, the equivalent weight of metal will be (1} 8
(1) E=~ (3) 8.11
y (2) 0.02
(3) E = f (4) 0.001
8 (2) 1.0
(2) E = 8( y - X) (4)· 1.000
X (2) 0.152
(4) E = 8(x-y) (4) 0.15
y (2) 1.6 X 10-1
51. The .number of significant figures in 2.653 x 104 is (4) 1.6
(1) 8 (2) 8.1
(3) 7 (4) 8.113
(2) 4 I CA~""' I~&;;, I
(4) 1 11. The percentage of hydrogen in water and hydrogen
52. Mole fraction of solute in aqueous solution of 30% peroxide is 11.1 and 5.9 respectively. These figures
NaOH is illustrate
(1) 0.16 (1) Law of multiple proportions (2) Law of conservation
(3) 0.25 of mass
(2) 0.05 (3) Law of constant proportions (4) Law of combining
(4) 0.95 volumes
1. One day -is equal to 12. Element X forms five stable oxides with oxygen of
(1) 24 X 60 X 60 S formula X20, XO, X20 3, X20 4, ~05. The formation of
(2) 24 X 6Q S these
(3) 24 X 50 X 6Q S oxides explains
(4) 24 x 100 x 60 s (1) Law of definite proportions (2) Law of partial
2. The unit of intensity is pressures
(1) mole . (3) Law of multiple proportions (4) Law of reciprocal
(3) candela proportions
3. The unit of frequency is 13. Which of the following represents Avogadro's
(1) hertz hypothesis?
(3) min-1 (1) Gases react together in volumes which bear a simple
4. How many signific~nt figures are in 0.000p? . ratio to one another
(1) -1 . . (2) Equal volumes of all gases under same conditions of
(3) 3 temperature and pressure contain equal number of
5. The number of significant figures in 1.0001 are molecules
(3) Equal volumes of all gases under same conditions of 24. What weight in gr~ms is .represented by 1.5 moles
temperature and pressure contain equal number of of sulphur dioxide?.
atoms (1) 60g . (2) 74g
(4) The rates of diffusion of gases are inversely (3) 96 g (4) 91 g
proportional to the square root of their densities 25. The number of atoms in 20 g of S03 is
14. When 200 g' of lime stone 'is•strongly heated, It approximately
undergoes thermal decomposition to form 112 g of lime (1) 1 X 1023 (2) 1.5 X 1023
and (3) 2 X 1023 (4) 6 X 1023
· unknown mass of carboh dioxide ·gas ias · · 26. The number of particles·present in 1 mol of nitrogen
What wilf be the mass of CO2 formed? atom are
(1) 88 g (1) 6.022 X 1025 (2) 6.022 X 1024
(3) 64 g (3) 6.022 X 1023 (4) 6:022 X 1022
caqO3 --Cao.+ CO2 27. B has two isotopes 108 (19%) and 118 (81%).
200 g .112 g . ? The.atomic mass of 8 is
(2) 24 ·g· (1) 10.81 (2) 105
(4) 40 g (3) 11 (4) 10.5
15. Carbon and oxygen .react in ratio of 3 : 8 by· mass to 28. Mass of 1 amu ih g
form CO2. What. weight of carbon should be used to (1) 1.66 X 1024
react completely with 32 g of oxygen? (3) 1.008
(1) 10 g 29. Orie 'u' stands for the mass of
(3) 12 g · (1) An atom of carbon-12
(2) 15 g (3) 1112th of hydrogen atom
(4) 7 g C (2) 1.66 X 10-24
16. Cu forms two oxides cuprous and cupric oxides, (4) 9.1 X 10-28 ·
which law can be proved by the weights of Cu and O? (2)
(1) Con~ta'rit compositi~n (2) Mult.ipfe proporti~ns . (4)
(3) Reciprocal proportions (4) Definite proportions 1/121h of the carbon-12
17. The law of conservation of mass is valid for all the One atom of any of the elements
following, except 30. The mass of one molecule of water is approximately
(1) All chemical reactions (2) Nuclear reactions (1) 3 X 10-23 Q
(3) Endothermic reactions (4) Exothermic reaction (3) 1.5 X 10-23 Q
18. Equal volume of different gases at any definite (2) 18 g
temperature· ·and pressure have (4) 4,5 X 10-23
(1) Equal atoms · · (2) Equal masses -I
(3) Equal densities (4) Equal molecules· I:
19. Which of the following pairs of compound illustrate \'
law of multiple proportions? 31. Two elements X and Y (atomic mass of X = 75, Y =
(1) KOH, CsOH (2) H20, D20 16) combine to give a compound having 76% -of X. The
(3) Ethane, ·benzene (4) KCI, KBr formula of the compound is
20. Gay Lussac's law is not valid in the chemical -
reaction: · 32. The percentage of nitrogen in HNO3 is
(1) Hi(g) + Cl2 (g) ~ 2HCI (g) (1) 22.22%
(3) 2S02(g) + Oi(g)--> 2S0ig) (3) 28.57%
(2) 3H2 (g) + N2 (g) ~ 2NHig) (2) 35°/c,
(4) CaCOis) 6 CaO(s) + C02'g) (4) 45%
I 1:)U:K\ll~C , . 33. What is the ratio of empirical formula mass to
21 .. Atomic weight of chlorine is 35.5. It has two molecular formula mass of benzene?
isotopes of atomic weight 35 and 37. What is the (1) 1 : 6 (2) 2 : 3
percentage of (3) 6 : 1 (4) 3 : 2
the heavier isotope in the sample? 34. The ·compound in •which mass percentage of carbon
(1) 5 is 75% and that of hydrogen is 25% is
(3) 25 (1) C2H6 (2) C2H2 .
(2) 10 ~) c~ ~)~~
(4) 20 I,••
22. The number of rrioles of nitrogen atom in 56 g 35. Identify the molecule having empirical formula
nitrogen gas is CH2O
(1) 2 mol (2) 4 mol (1) CH3CHO (2) HO - CH2 - CH2 - OH
(3) 8 mol (4) 10 mot yOOH
23. The number of mole of N-atom in 18.066 x 1023 (3) COOH (4) CH3COOH
nitrogen atoms is · ' .. .,
(1) 1 mol (2) 2 mol
(3) 3 mol (4) 4 mol •
- •. ___ ....,_, C,,.....b O t ~. . ~ ~4 .-~ ,,,,_ •---·. .... + 2H
W:l&,,,, ..............., :.1. ......-.,fll, ,._, ~.,l\ 2
L.~. ...... ..-.~w........ ~ ......... O
., (1 ) 87% (2) 25%
t (3) 33.3%
• (4) ·13%
36. 8 g H2 and 32 g 0 2 is allowed to -react to form 46. Molality is expressed in units of
water then which of the· following ·statement is (1) mol kg-1
ccfrrect? (3) mol L-1 s-1
(1) 02 is limiting reagent 47. Which of the following is correct?
(3) H2 is limiting reagent '..
(2) . 02 is reagent in excess (2) mol L-1
(4) 40· g water is forrried (4) mol g-1 s-1
37. Equal volume of N2 and H2 react to form ammonia ..
under suitable condition then the limiting reagent is (1) The sum of mole fractions of all the components in a
(1) Hz (2) N2 solution is always unity
(3) NH3 .(4) No one reactant is limiting reagent (2) Mole fraction depends upon temperature I
38. How many grams of calcium oxide is obtained on (3) Mole fraction_is always negative
heating 100 g of ·caCOis)? (4) Mole.fraction is independent of content of solute in
(1) 50 g (2) 40 g solution
(3) 56 g (4) 44 g 48. Which of the following methoqs of expressing
39. The volume of 0 2 at STP required for the complete concentration varies with temperature?
combustion of 4 g CH4 is (1) Molality
(1) 5.6 litre (2) 2.88 _litre (3) Molarity
(3) 22.4 litre (4) 11 .2 litre '
40. 0.9 g Al reacts with dil. HCI to give H2. The volume . . .(2) Weight percent
of H2 evolved at STP is (Atomic weight of Al = 27) (4) Mole fraction
(1) 1.12 litre (2) 2.24 litre 49. What is the molarity of NaOH solution if 250 ml of
(3) 3.33 litre (4) 4.44 litre it contains 1 mg of NaOH?
41 . Which of the following statement is correct? (1) 10-1 M (2) 10-2 M
(1) 28 _g CO contains 12 g carbon and 16 g oxygen (3) 1o-4 M (4) 10-3 M
(2) One mole of CO reacts completely with half mole of 50. How many mole of sodium chloride present in 250
0 2 to form CO2 ml of a 0.50 M NaCl solution?
(3) N2 and CO have same molar mass (1) 0:1'25 mol ·
(4) All of these (3) 0 . .075 moi
42. The volume of CO2 evolved at STP on heating 50 g (2) 0.150 mol
CaCO3 (4) 0.02 mol
(1) 11.2 titre (2) 22.4 litre 51. · 27 g Al (at. 'h1assl = 27) will· read ·completely
(3) 5.6 titre (4) 24.4 litre with oxygen equals to
43. Limiting reagent in a chemical reaction is that . (1) 24 g (2) 8 g
reactant which (3) .40 g (4) 10 g
(1) Left some amount unreacted after the completion of .~.
reaction 52. 12 g Mg (at. mass= 24) react with dilute mineral acid
(2) Reacts completely in the reaction to produce maximum hydrogen equal to
(3) Does not react in the reaction (1) 0.5 mol (2) 1.5 mol
(4) All of these (3) 1.5g (4)_0.Sg
_...,_v~Q;.::'U:.._Ol=-.:\.,:.::0::::_m,:_:;p~e:::.:c~n~I 53. Volume at NTP of oxygen required to completely
V_:::e_!t:.~x~a~m~S~{L:::e:.!v~e-~,1'.l.J_ burn. 1 kg of coal ( 100% carbon)
______________ ;'-.l:.;-:..:'..:..;"..:.-...;-:::.-.::.-.::.;'..:.- (1) 22000 L (2) 22.4 x 103 L
-~--··-- --=r;.___ ______ -· (3) 1.86 x 103 L (4) 1000 L
44. What is the mass of glucose required to produce 44 g
of CO2
, on complete combustion?
(1) 30g (2) 45g
(3) 60 g (4} 22 g
45.
1 O 9 of Mn02 on reaction with HCI forms 2.24 L of
CI2(g) at NTP. the percentage impurity of Mn0
2
is
Mn02 + 4HCI > MnCl2 + Cl
2 Allen- Some basic concepts of chemistry
BEGINNER'S BOX-1 BEGINNER'S BOX-4
1. 1.5 mol of O2 combine with Mg to form oxide MgO.
1. The modern atomic weight scale is based on. The mass of Mg (At. mass 24) that has combined is :
(1) C12 (2) O16 (3) H1 (4) C13 (1) 72 g (2) 36 g (3) 24 g (4) 94 g
2. Gram atomic weight of oxygen is 2. What quantity of lime stone on heating will give 56
(1) 16 amu (2) 16 g (3) 32 amu (4) 32 g kg of CaO :-
3. Molecular weight of SO2 is : (1) 1000 kg (2) 56 kg (3) 44 kg (4) 100 kg
(1) 64 g (2) 64 amu (3) 32 g (4) 32 amu 3. For reaction A + 2 B C. The amount of product
4. 1 amu is equal to :- formed by starting the reaction with 5 mol of A and
(1) 1 8 mol of B is :
12 (1) 5 mol (2) 8 mol (3) 16 mol (4) 4 mol
of C12 (2) 1
14
of O16 (3) 1 g of H2 (4) 1.66 × 10–24 kg
5. The actual molecular mass of chlorine is : BEGINNER'S BOX-5
(1) 58.93 × 10–24 g (2) 117.86 × 10–24 g (3) 58.93 × 1. Molecular weight of dibasic acid is W. Its equivalent
10–24 kg (4) 117.86 × 10–24 kg weight will be :
(1)
W
2
BEGINNER'S BOX-2 (2)
1. Calculate the number of atoms in 11.2 L of SO2 gas at W
STP : 3
(1) A N (3) W (4) 3W
2 2. 0.126 g of an acid requires 20 ml of 0.1 N NaOH for
(2) A 3N complete neutralization. Eq. wt. of the acid is:
2 (1) 45 (2) 53
(3) 3NA (4) NA (3) 40 (4) 63
2. Which of the following has maximum mass : 3. 1 mol O2 will be equal to :
(1) 0.1 gram atom of carbon (2) 0.1 mol of ammonia (1) 4 g equivalent oxygen (2) 2 g equivalent oxygen
(3) 6.02 × 1022 molecules of hydrogen (4) 1120 cc of (3) 32 g equivalent oxygen (4) 8 g equivalent oxygen
carbon dioxide at STP 4. Volume of one gram equivalent of H2 at NTP is :
3. The total number of electrons present in 18 mL of (1) 5.6 L (2) 11.2 L
water :- (3) 22.4 L (4) 44.8 L
(1) 6.02 × 1022 (2) 6.02 × 1023 (3) 6.02 × 1024 (4) 6.02
× 1025
4. The volume of 1.0 g of hydrogen at NTP is :
(1) 2.24 L (2) 22.4 L (3) 1.12 L (4) 11.2 L
5. 11 grams of a gas occupy 5.6 litres of volume at STP.
The gas is :-
(1) NO (2) N2O4 (3) CO (4) CO2
6. At NTP, 5.6 L of a gas weight 8 grams. The vapour
density of gas is :-
(1) 32 (2) 40 (3) 16 (4) 8
7. The vapour densities of two gases are in the ratio of
1 : 3. Their molecular masses are in the ratio of :-
(1) 1 : 3 (2) 1 : 2 (3) 2 : 3 (4) 3 : 1
BEGINNER'S BOX-3
1. A hydrocarbon contain 80% C. The vapour density of
compound is 30. Empirical formula of compound is :-
(1) CH3 (2) C2H6 (3) C4H12 (4) C4H8
2. Two elements X (Atomic weight = 75) and Y (Atomic
weight = 16) combine to give a compound having
75.8% of X. The empirical formula of compound is :
(1) XY (2) X2Y (3) X2Y2 (4) X2Y3
3. In a compound element A (Atomic weight = 12.5) is
25% and element B (Atomic weight = 37.5) is 75% by
weight. The Empirical formula of the compound is :
(1) AB (2) A2B (3) A2B2 (4) A2B3