Analytical Argon

Safety Data Sheet

According To Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules And Regulations And According To The Hazardous
Products Regulation (February 11, 2015).
Date of Issue: 08/10/2020 Version: 1.0

SECTION 1: IDENTIFICATION
1.1. Product Identifier
Product Form: Substance
Product Name: Analytical Argon
CAS-No.: 7440-37-1
Product Code: 601-00192
1.2. Intended Use of the Product
Scientific research and development.
1.3. Name, Address, and Telephone of the Responsible Party
Supplier
Thermo Fisher Scientific
2 Radcliff Road
Tewksbury, MA 01876
978-670-7460
www.thermoscientific.com
1.4. Emergency Telephone Number
Emergency Number : 1-800-424-9300 (CHEMTREC)
SECTION 2: HAZARDS IDENTIFICATION
2.1. Classification of the Substance or Mixture
GHS-US/CA Classification
Simple Asphy
Press. Gas (Comp.) H280
Full text of hazard classes and H-statements : see section 16
2.2. Label Elements
GHS-US/CA Labeling
Hazard Pictograms (GHS-US/CA) :

GHS04

Signal Word (GHS-US/CA) : Warning

Hazard Statements (GHS-US/CA) : H280 - Contains gas under pressure; may explode if heated.
May displace oxygen and cause rapid suffocation.
Precautionary Statements (GHS-US/CA) : P410+P403 - Protect from sunlight. Store in a well-ventilated place.
2.3. Other Hazards
Contact with gas escaping the container can cause frostbite.
2.4. Unknown Acute Toxicity (GHS-US/CA)
No data available
SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS
3.1. Substance
Name : Analytical Argon
CAS-No. : 7440-37-1
Name Synonyms Product Identifier %* GHS Ingredient Classification
Argon Argon, compressed (CAS-No.) 7440-37-1 100 Simple Asphy
Press. Gas (Comp.), H280
Full text of H-phrases: see section 16
*Percentages are listed in weight by weight percentage (w/w%) for liquid and solid ingredients. Gas ingredients are listed in volume
by volume percentage (v/v%).

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Analytical Argon
Safety Data Sheet
According To Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules And Regulations And According To The Hazardous Products Regulation (February 11, 2015).

3.2. Mixture
Not applicable
SECTION 4: FIRST AID MEASURES
4.1. Description of First-aid Measures
General: Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice (show the label where
possible).
Inhalation: First, take proper precautions to ensure your own safety before attempting rescue (e.g. wear appropriate respiratory
protective equipment, use the buddy system), then remove the exposed person to fresh air. Keep at rest in a position comfortable for
breathing. Obtain medical attention if breathing difficulty persists.
Skin Contact: Remove contaminated clothing. Drench affected area with water for at least 5 minutes. For brief contact with a small
amount: Rewarm with body heat. Get immediate medical advice/attention. For extensive contact or a large amount: Immediately call
a poison center/doctor and follow their advice. Specific treatment is urgent, incorrect first-aid practices will aggravate the injury.
Protect affected area with a loose cover until proper medical treatment is received.
Eye Contact: Rinse cautiously with water for at least 5 minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
Obtain medical attention if irritation develops or persists.
Ingestion: Rinse mouth. Do NOT induce vomiting. Obtain medical attention.
4.2. Most Important Symptoms and Effects Both Acute and Delayed
General: Contact with gas escaping the container can cause frostbite. Asphyxia by lack of oxygen: risk of death.
Inhalation: In elevated concentrations may cause asphyxiation, central nervous system effects, and increased breathing rate.
Symptoms of asphyxiation include headache, dizziness, rapid breathing, increased pulse, mood changes, tremors, cyanosis, muscular
weakness, narcosis, numbness of the extremities, unconsciousness and death.
Skin Contact: Contact with gas escaping the container can cause frostbite and freeze burns.
Eye Contact: Contact with gas escaping the container can cause frostbite, freeze burns, and permanent eye damage.
Ingestion: Not considered a potential route of exposure, but contact with gas escaping the container can cause freeze burns and
frostbite.
Chronic Symptoms: None expected under normal conditions of use.
4.3. Indication of Any Immediate Medical Attention and Special Treatment Needed
If exposed or concerned, get medical advice and attention. If medical advice is needed, have product container or label at hand.
SECTION 5: FIRE-FIGHTING MEASURES
5.1. Extinguishing Media
Suitable Extinguishing Media: Water spray, fog, carbon dioxide (CO2), alcohol-resistant foam, or dry chemical.
Unsuitable Extinguishing Media: Do not use a heavy water stream. Use of heavy stream of water may spread fire.
5.2. Special Hazards Arising From the Substance or Mixture
Fire Hazard: Not flammable.
Explosion Hazard: Container may explode in heat of fire. Ruptured cylinders may rocket.
Reactivity: Hazardous reactions will not occur under normal conditions.
5.3. Advice for Firefighters
Precautionary Measures Fire: Exercise caution when fighting any chemical fire.
Firefighting Instructions: Use water spray or fog for cooling exposed containers. Fight fire remotely due to the risk of explosion.
Protection During Firefighting: Do not enter fire area without proper protective equipment, including respiratory protection.
Hazardous Combustion Products: None known.
5.4. Reference to Other Sections
Refer to Section 9 for flammability properties.
SECTION 6: ACCIDENTAL RELEASE MEASURES
6.1. Personal Precautions, Protective Equipment and Emergency Procedures
General Measures: Do not get in eyes, on skin, or on clothing. Do not breathe gas.
6.1.1. For Non-Emergency Personnel
Protective Equipment: Use appropriate personal protective equipment (PPE).
Emergency Procedures: Evacuate unnecessary personnel.
6.1.2. For Emergency Personnel
Protective Equipment: Equip cleanup crew with proper protection.
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Analytical Argon
Safety Data Sheet
According To Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules And Regulations And According To The Hazardous Products Regulation (February 11, 2015).

Emergency Procedures: Upon arrival at the scene, a first responder is expected to recognize the presence of dangerous goods,
protect oneself and the public, secure the area, and call for the assistance of trained personnel as soon as conditions permit.
Evacuate unnecessary personnel, isolate, and ventilate area.
6.2. Environmental Precautions
Prevent entry to sewers and public waters.
6.3. Methods and Materials for Containment and Cleaning Up
For Containment: Stop leak, if possible without risk. As an immediate precautionary measure, isolate spill or leak area in all
directions.
Methods for Cleaning Up: Clean up spills immediately and dispose of waste safely. Transfer spilled material to a suitable container
for disposal. Contact competent authorities after a spill. Stop the source of the release, if safe to do so. Consider the use of water
spray to disperse vapors. Isolate the area until gas has dispersed. Ventilate and gas test area before entering.
6.4. Reference to Other Sections
See Section 8 for exposure controls and personal protection and Section 13 for disposal considerations.
SECTION 7: HANDLING AND STORAGE
7.1. Precautions for Safe Handling
Additional Hazards When Processed: Do not pressurize, cut, or weld containers. Ruptured cylinders may rocket. Asphyxiating gas at
high concentrations.
Precautions for Safe Handling: Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking
and when leaving work. Avoid prolonged contact with eyes, skin and clothing. Do not breathe gas.
Hygiene Measures: Handle in accordance with good industrial hygiene and safety procedures.
7.2. Conditions for Safe Storage, Including Any Incompatibilities
Technical Measures: Comply with applicable regulations. Proper grounding procedures to avoid static electricity should be followed.
Storage Conditions: Keep container closed when not in use. Store in a dry, cool place. Keep/Store away from direct sunlight,
extremely high or low temperatures and incompatible materials.
Incompatible Materials: None known.
7.3. Specific End Use(s)
Scientific research and development.
SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
8.1. Control Parameters
For substances listed in section 3 that are not listed here, there are no established exposure limits from the manufacturer, supplier,
importer, or the appropriate advisory agency including: ACGIH (TLV), AIHA (WEEL), NIOSH (REL), OSHA (PEL), or Canadian provincial
governments.
Argon (7440-37-1)
USA ACGIH ACGIH chemical category Simple asphyxiant See Appendix F: Minimal Oxygen
Content
8.2. Exposure Controls
Appropriate Engineering Controls: Suitable eye/body wash equipment should be available in the vicinity of any potential exposure.
Ensure adequate ventilation, especially in confined areas. Ensure all national/local regulations are observed. Use explosion-proof
equipment. Oxygen detectors should be used when asphyxiating gases may be released.
Personal Protective Equipment: Gloves. Protective clothing. Protective goggles. Insufficient ventilation: wear respiratory protection.
Respiratory protection of the dependent type.

Materials for Protective Clothing: Chemically resistant materials and fabrics.

Hand Protection: Wear protective gloves. If material is cold, wear thermally resistant protective gloves.
Eye and Face Protection: Chemical safety goggles.
Skin and Body Protection: Wear suitable protective clothing.
Respiratory Protection: Use a NIOSH-approved self-contained breathing apparatus whenever exposure may exceed established
Occupational Exposure Limits.

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Analytical Argon
Safety Data Sheet
According To Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules And Regulations And According To The Hazardous Products Regulation (February 11, 2015).

Thermal Hazard Protection: Wear thermally resistant protective clothing.

Other Information: When using, do not eat, drink or smoke.
SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES
9.1. Information on Basic Physical and Chemical Properties
Physical State : Gas
Appearance : Not available
Odor : Not available
Odor Threshold : Not available
pH : Not available
Evaporation Rate : Not available
Melting Point : Not available
Freezing Point : Not available
Boiling Point : Not available
Flash Point : Not available
Auto-ignition Temperature : Not available
Decomposition Temperature : Not available
Flammability (solid, gas) : Not available
Lower Flammable Limit : Not available
Upper Flammable Limit : Not available
Vapor Pressure : Not available
Relative Vapor Density at 20°C : Not available
Relative Density : Not available
Specific Gravity : Not available
Solubility : Not available
Partition Coefficient: N-Octanol/Water : Not available
Viscosity : Not available
Explosive Properties : Contains gas under pressure; may explode if heated
SECTION 10: STABILITY AND REACTIVITY
10.1. Reactivity: Hazardous reactions will not occur under normal conditions.
10.2. Chemical Stability: Contains gas under pressure; may explode if heated.
10.3. Possibility of Hazardous Reactions: Hazardous polymerization will not occur.
10.4. Conditions to Avoid: Direct sunlight, extremely high or low temperatures, open flames, sources of ignition and
incompatible materials.
10.5. Incompatible Materials: None known.
10.6. Hazardous Decomposition Products: None known.
SECTION 11: TOXICOLOGICAL INFORMATION
11.1. Information on Toxicological Effects - Product
Acute Toxicity (Oral): Not classified
Acute Toxicity (Dermal): Not classified
Acute Toxicity (Inhalation): Not classified
LD50 and LC50 Data: Not available
Skin Corrosion/Irritation: Not classified
Eye Damage/Irritation: Not classified
Respiratory or Skin Sensitization: Not classified
Germ Cell Mutagenicity: Not classified
Carcinogenicity: Not classified
Specific Target Organ Toxicity (Repeated Exposure): Not classified
Reproductive Toxicity: Not classified
Specific Target Organ Toxicity (Single Exposure): Not classified
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Analytical Argon
Safety Data Sheet
According To Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules And Regulations And According To The Hazardous Products Regulation (February 11, 2015).

Aspiration Hazard: Not classified

Symptoms/Injuries After Inhalation: In elevated concentrations may cause asphyxiation, central nervous system effects, and
increased breathing rate. Symptoms of asphyxiation include headache, dizziness, rapid breathing, increased pulse, mood changes,
tremors, cyanosis, muscular weakness, narcosis, numbness of the extremities, unconsciousness and death.
Symptoms/Injuries After Skin Contact: Contact with gas escaping the container can cause frostbite and freeze burns.
Symptoms/Injuries After Eye Contact: Contact with gas escaping the container can cause frostbite, freeze burns, and permanent eye
damage.
Symptoms/Injuries After Ingestion: Not considered a potential route of exposure, but contact with gas escaping the container can
cause freeze burns and frostbite.
Chronic Symptoms: None expected under normal conditions of use.
11.2. Information on Toxicological Effects - Ingredient(s)
LD50 and LC50 Data: Not available

SECTION 12: ECOLOGICAL INFORMATION

12.1. Toxicity
Ecology - General: Not classified.
12.2. Persistence and Degradability
Analytical Argon (7440-37-1)
Persistence and Degradability Not established.
12.3. Bioaccumulative Potential
Analytical Argon (7440-37-1)
Bioaccumulative Potential Not established.
12.4. Mobility in Soil Not available
12.5. Other Adverse Effects
Other Information: Avoid release to the environment.
SECTION 13: DISPOSAL CONSIDERATIONS
13.1. Waste treatment methods
Waste Disposal Recommendations: Dispose of contents/container in accordance with local, regional, national, territorial, provincial,
and international regulations.
Additional Information: Empty gas cylinders should be returned to the vendor for recycling or refilling. Do not puncture or incinerate
container.
Ecology - Waste Materials: Avoid release to the environment.
SECTION 14: TRANSPORT INFORMATION
The shipping description(s) stated herein were prepared in accordance with certain assumptions at the time the SDS was authored,
and can vary based on a number of variables that may or may not have been known at the time the SDS was issued.
14.1. In Accordance with DOT
Proper Shipping Name : ARGON, COMPRESSED
Hazard Class : 2.2
Identification Number : UN1006
Label Codes : 2.2
ERG Number : 121
14.2. In Accordance with IMDG
Proper Shipping Name : ARGON, COMPRESSED
Hazard Class : 2.2
Identification Number : UN1006
Label Codes : 2.2
EmS-No. (Fire) : F-C
EmS-No. (Spillage) : S-V
14.3. In Accordance with IATA
Proper Shipping Name : ARGON, COMPRESSED
Hazard Class : 2.2
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Analytical Argon
Safety Data Sheet
According To Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules And Regulations And According To The Hazardous Products Regulation (February 11, 2015).

Identification Number : UN1006

Label Codes : 2.2
ERG Code (IATA) : 2L
14.4. In Accordance with TDG
Proper Shipping Name : ARGON, COMPRESSED
Hazard Class : 2.2
Identification Number : UN1006
Label Codes : 2.2
SECTION 15: REGULATORY INFORMATION
15.1. US Federal Regulations
Analytical Argon (7440-37-1)
SARA Section 311/312 Hazard Classes Physical hazard - Gas under pressure
Health hazard - Simple asphyxiant
Argon (7440-37-1)
Listed on the United States TSCA (Toxic Substances Control Act) inventory
15.2. US State Regulations
Argon (7440-37-1)
U.S. - Massachusetts - Right To Know List
U.S. - New Jersey - Right to Know Hazardous Substance List
U.S. - Pennsylvania - RTK (Right to Know) List
15.3. Canadian Regulations
Argon (7440-37-1)
Listed on the Canadian DSL (Domestic Substances List)
SECTION 16: OTHER INFORMATION, INCLUDING DATE OF PREPARATION OR LAST REVISION
Date of Preparation or Latest : 08/10/2020
Revision
Other Information : This document has been prepared in accordance with the SDS requirements of the OSHA
Hazard Communication Standard 29 CFR 1910.1200 and Canada’s Hazardous Products
Regulations (HPR) SOR/2015-17.
GHS Full Text Phrases:
------ Press. Gas (Comp.) Gases under pressure Compressed gas
------ Simple Asphy Simple Asphyxiant
------ H280 Contains gas under pressure; may explode if heated

This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and
environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product.

NA GHS SDS 2015 (Can, US)

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