SAFETY DATA SHEET

Version 4.0 SDS Number 300000000004

Revision Date 28.12.2022 Print Date 06.01.2023
Supercedes Version: 3.1

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1. Product identifier : Argon

CAS No. : 7440-37-1

Chemical formula : Ar

Synonyms : Argon, Argon gas, Gaseous Argon, GAR

REACH Registration Number: Listed in Annex IV / V REACH, exempted from registration.

1.2. Relevant identified uses of the substance or mixture and uses advised against
Use of the : Industrial and professional use. Perform risk assessment prior to use.
Substance/Mixture
Restrictions on Use : None.

1.3. Details of the : Air Products Plc

supplier of the safety 2 Millennium Gate
Westmere Drive
data sheet Crewe
Cheshire

Email Address – Technical : [email protected]

Information

Telephone : +44(0)3457 020202

1.4. Emergency : +44(0)8085 020202

telephone number Call NHS, 111 for free from a landline or mobile phone

SECTION 2: Hazards identification

2.1. Classification of the substance or mixture

Gases under pressure - Compressed gas. H280:Contains gas under pressure; may explode if heated.

2.2. Label elements

Hazard pictograms/symbols

Signal Word: Warning

1/13
MSDS_GB Argon
SAFETY DATA SHEET
Version 4.0 SDS Number 300000000004
Revision Date 28.12.2022 Print Date 06.01.2023

Hazard Statements:
H280:Contains gas under pressure; may explode if heated.

Precautionary Statements:
Storage : P403:Store in a well-ventilated place.

2.3. Other hazards

High pressure gas.
Can cause rapid suffocation.
Substance does not meet the criteria for PBT and vPvB according to Regulation (EC) No 1907/2006, Annex XIII.
Environmental Effects
Not harmful.

SECTION 3: Composition/information on ingredients

3.1. Substances
Components EC number CAS Number Concentration
(Volume)
Argon 231-147-0 7440-37-1 100 %

Components Classification (CLP) REACH Reg. No.

Argon Press. Gas (Comp.) ;H280 *1

*1:Listed in Annex IV / V REACH, exempted from registration.

*2:Registration not required: substance manufactured or imported < 1 t/y.
*3:Registration not required: substance manufactured or imported < 1 t/y for non-intermediate uses.

Specific concentration limits, M-factors and ATEs are not applicable for components of this product.

Concentration is nominal. For the exact product composition, please refer to technical specifications.

3.2. Mixtures : Not applicable.

SECTION 4: First aid measures

4.1. Description of first aid measures

General advice : Remove victim to uncontaminated area wearing self-contained breathing
apparatus. Keep victim warm and rested. Call a doctor. Apply artificial
respiration if breathing stopped.

Eye contact : In case of direct contact with eyes, seek medical advice.

Skin contact : Adverse effects not expected from this product.

Ingestion : Ingestion is not considered a potential route of exposure.

Inhalation : Remove to fresh air. If breathing has stopped or is labored, give assisted
respirations. Supplemental oxygen may be indicated. If the heart has stopped,

2/13
MSDS_GB Argon
SAFETY DATA SHEET
Version 4.0 SDS Number 300000000004
Revision Date 28.12.2022 Print Date 06.01.2023

trained personnel should begin cardiopulmonary resuscitation immediately. In

case of shortness of breath, give oxygen.

4.2. Most important symptoms and effects, both acute and delayed
Symptoms : Exposure to oxygen deficient atmosphere may cause the following symptoms:
Dizziness. Salivation. Nausea. Vomiting. Loss of mobility/consciousness.

4.3. Indication of any immediate medical attention and special treatment needed
Treatment : If exposed or concerned: Get medical attention/advice.

SECTION 5: Firefighting measures

5.1. Extinguishing media

Suitable extinguishing media : The product itself does not burn.
Use extinguishing media appropriate for surrounding fire.

Extinguishing media which : Do not use water jet to extinguish.

must not be used for safety
reasons.

5.2. Special hazards : Upon exposure to intense heat or flame, cylinder will vent rapidly and or rupture
arising from the violently. Product is nonflammable and does not support combustion. Move
away from container and cool with water from a protected position. Keep
substance or mixture containers and surroundings cool with water spray.

5.3. Advice for firefighters : Wear self contained breathing apparatus for fire fighting if necessary. Standard
protective clothing and equipment (Self Contained Breathing Apparatus) for fire
fighters. Standard EN 137 - Self-contained open-circuit compressed air
breathing apparatus with full face mask. Standard EN 469 - Protective clothing
for firefighters. Standard - EN 659: Protective gloves for firefighters.

SECTION 6: Accidental release measures

6.1. Personal : Gas/vapor heavier than air. May accumulate in confined spaces, particularly at
precautions, protective or below ground level. Evacuate personnel to safe areas. Wear self-contained
breathing apparatus when entering area unless atmosphere is proved to be
equipment and safe. Monitor oxygen level. Ventilate the area.
emergency procedures

6.2. Environmental : Do not discharge into any place where its accumulation could be dangerous.
precautions Prevent further leakage or spillage if safe to do so.

6.3. Methods and : Ventilate the area.

material for containment
and cleaning up
Additional advice : If possible, stop flow of product. Increase ventilation to the release area and
monitor oxygen level. If leak is from cylinder or cylinder valve, call the
emergency telephone number. If the leak is in the user's system, close the
cylinder valve and safely vent the pressure before attempting repairs.

3/13
MSDS_GB Argon
SAFETY DATA SHEET
Version 4.0 SDS Number 300000000004
Revision Date 28.12.2022 Print Date 06.01.2023

6.4. Reference to other : For more information refer to Sections 8 & 13.
sections

SECTION 7: Handling and storage

7.1. Precautions for safe handling

Protect cylinders from physical damage; do not drag, roll, slide or drop. Do not allow storage area temperature
to exceed 50°C (122°F). Only experienced and properly instructed persons should handle compressed
gases/cryogenic liquids. Before using the product, determine its identity by reading the label. Know and
understand the properties and hazards of the product before use. When doubt exists as to the correct handling
procedure for a particular gas, contact the supplier. Do not remove or deface labels provided by the supplier for
the identification of the cylinder contents. When moving cylinders, even for short distances, use a cart (trolley,
hand truck, etc.) designed to transport cylinders. Leave valve protection caps in place until the container has
been secured against either a wall or bench or placed in a container stand and is ready for use. Use an
adjustable strap wrench to remove over-tight or rusted caps. Before connecting the container, check the
complete gas system for suitability, particularly for pressure rating and materials. Before connecting the
container for use, ensure that back feed from the system into the container is prevented. Ensure the complete
gas system is compatible for pressure rating and materials of construction. Ensure the complete gas system has
been checked for leaks before use. Employ suitable pressure regulating devices on all containers when the gas
is being emitted to systems with lower pressure rating than that of the container. Never insert an object (e.g.
wrench, screwdriver, pry bar, etc.) into valve cap openings. Doing so may damage valve, causing a leak to
occur. Open valve slowly. If user experiences any difficulty operating cylinder valve discontinue use and contact
supplier. Close container valve after each use and when empty, even if still connected to equipment. Never
attempt to repair or modify container valves or safety relief devices. Damaged valves should be reported
immediately to the supplier. Close valve after each use and when empty. Replace outlet caps or plugs and
container caps as soon as container is disconnected from equipment. Do not subject containers to abnormal
mechanical shock. Never attempt to lift a cylinder by its valve protection cap or guard. Do not use containers as
rollers or supports or for any other purpose than to contain the gas as supplied. Never strike an arc on a
compressed gas cylinder or make a cylinder a part of an electrical circuit. Do not smoke while handling product
or cylinders. Never re-compress a gas or a gas mixture without first consulting the supplier. Never attempt to
transfer gases from one cylinder/container to another. Always use backflow protective device in piping. When
returning cylinder install valve outlet cap or plug leak tight. Never use direct flame or electrical heating devices to
raise the pressure of a container. Containers should not be subjected to temperatures above 50°C (122°F).

7.2. Conditions for safe storage, including any incompatibilities

Full containers should be stored so that oldest stock is used first. Containers should be stored in a purpose build
compound which should be well ventilated, preferably in the open air. Stored containers should be periodically
checked for general condition and leakage. Observe all regulations and local requirements regarding storage of
containers. Protect containers stored in the open against rusting and extremes of weather. Containers should
not be stored in conditions likely to encourage corrosion. Containers should be stored in the vertical position and
properly secured to prevent toppling. The container valves should be tightly closed and where appropriate valve
outlets should be capped or plugged. Container valve guards or caps should be in place. Keep containers tightly
closed in a cool, well-ventilated place. Store containers in location free from fire risk and away from sources of
heat and ignition. Full and empty cylinders should be segregated. Do not allow storage temperature to exceed
50°C (122°F). Return empty containers in a timely manner.

Technical measures/Precautions
Containers should be segregated in the storage area according to the various categories (e.g. flammable, toxic,
etc.) and in accordance whit local regulations. Keep away from combustible material.

7.3. Specific end use(s)

Refer to section 1 or the extended SDS if applicable.
4/13
MSDS_GB Argon
SAFETY DATA SHEET
Version 4.0 SDS Number 300000000004
Revision Date 28.12.2022 Print Date 06.01.2023

SECTION 8: Exposure controls/personal protection

8.1. Control parameters

If applicable, refer to the extended section of the SDS for further information on CSA.

DNEL: Derived no effect level (Workers)

None available.

PNEC: predicted no effect concentration

None available.

8.2. Exposure controls

Engineering measures
Provide natural or mechanical ventilation to prevent oxygen deficient atmospheres below 19.5% oxygen.

Personal protective equipment

Respiratory protection : Self contained breathing apparatus (SCBA) or positive pressure airline with
mask are to be used in oxygen-deficient atmosphere.
Air purifying respirators will not provide protection. Users of breathing
apparatus must be trained.

Hand protection : Wear work gloves when handling gas containers.

Standard EN 388 - Protective gloves against mechanical risk.
Eye/face Protection : Safety glasses recommended when handling cylinders.
Standard EN 166 - Personal eye-protection.
Skin and body protection : Safety shoes are recommended when handling cylinders.
Standard EN ISO 20345 - Personal protective equipment - Safety footwear.

Special instructions for : Ensure adequate ventilation, especially in confined areas.

protection and hygiene

Environmental Exposure : If applicable, refer to the extended section of the SDS for further information on
Controls CSA.
Remarks : Simple asphyxiant.

SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties

(a) Physical state : Gaseous.

Compressed gas.

(b) Colour : Colorless gas.

(c) Odour : No odor warning properties.

Odour threshold is subjective and inadequate to warn of overexposure.

(d) Melting point/freezing point : -189.3 °C ( -309 °F )

5/13
MSDS_GB Argon
SAFETY DATA SHEET
Version 4.0 SDS Number 300000000004
Revision Date 28.12.2022 Print Date 06.01.2023

(e) Boiling point/range : -185.8 °C ( -302 °F )

(f) Flammability : Non flammable.

(g) Lower and upper explosion : Lower explosion limit : Not applicable.
limit Upper explosion limit :
Not applicable.

(h) Flash point : Not applicable for gases and gas mixtures.

(i) Auto-ignition temperature : Not applicable.

(j) Decomposition temperature : Not applicable.

(k) pH : Not applicable for gases and gas mixtures.

(l) Kinematic viscosity : Not applicable for gases and gas mixtures.

(m) Water solubility [20°C] : 0.0673 g/l

(n) Partition coefficient n- : Not applicable for inorganic gases.

octanol/water (log value)

(o) Vapour pressure : Not applicable.

(p) Density and/or relative : 0.0017 g/cm3

density at 21 °C

(q) Relative vapour density : 1.38

(air = 1)
Heavier than air.

(r) Particle characteristics : Not applicable for gases and gas mixtures.
Nanoforms are not relevant for gases and gas mixtures.

9.2. Other information

Oxidising properties : No oxidising properties.

Critical temperature : -122.4 °C ( -188 °F )

Molar mass : 40 g/mol

SECTION 10: Stability and reactivity

10.1. Reactivity : No reactivity hazard other than the effects described in sub-sections below.

10.2. Chemical stability : Stable under normal conditions.

6/13
MSDS_GB Argon
SAFETY DATA SHEET
Version 4.0 SDS Number 300000000004
Revision Date 28.12.2022 Print Date 06.01.2023

10.3. Possibility of hazardous : No data available.

reactions

10.4. Conditions to avoid : None under recommended storage and handling conditions (see section 7).

10.5. Incompatible materials : No data available.

10.6. Hazardous : Under normal conditions of storage and use, hazardous decomposition
decomposition products products should not be produced.

SECTION 11: Toxicological information

11.1. Information on hazard classes as defined in Regulation (EC) No 1272/2008

Likely routes of exposure
Effects on Eye : In case of direct contact with eyes, seek medical advice.

Effects on Skin : Adverse effects not expected from this product.

Inhalation Effects : In high concentrations may cause asphyxiation. Asphyxiation may bring
about unconsciousness without warning and so rapidly that victim may be
unable to protect themselves.

Ingestion Effects : Ingestion is not considered a potential route of exposure.

Symptoms : Exposure to oxygen deficient atmosphere may cause the following

symptoms: Dizziness. Salivation. Nausea. Vomiting. Loss of
mobility/consciousness.

Acute toxicity

Acute Oral Toxicity : No data is available on the product itself.

Acute Inhalation Toxicity : No data is available on the product itself.

Acute Dermal Toxicity : No data is available on the product itself.

Skin corrosion/irritation : No data available.

Serious eye damage/eye : No data available.

irritation

Sensitization. : No data available.

Chronic toxicity or effects from long term exposures

Carcinogenicity : No data available.

Reproductive toxicity : No data is available on the product itself.

Germ cell mutagenicity : No data is available on the product itself.

Specific target organ systemic : No data available.

toxicity (single exposure)
7/13
MSDS_GB Argon
SAFETY DATA SHEET
Version 4.0 SDS Number 300000000004
Revision Date 28.12.2022 Print Date 06.01.2023

Specific target organ systemic : No data available.

toxicity (repeated exposure)

Aspiration hazard : No data available.

11.2. Information on other hazards

The substance/mixture has no endocrine disrupting properties.

SECTION 12: Ecological information

12.1. Toxicity
Aquatic toxicity : No data is available on the product itself.

Toxicity to other : No data is available on the product itself.

organisms

12.2. Persistence and degradability

No data available.

12.3. Bioaccumulative potential

Refer to Section 9 "Partition Coefficient (n-octanol/water)".

12.4. Mobility in soil

Because of its high volatility, the product is unlikely to cause ground pollution.

12.5. Results of PBT and vPvB assessment

If applicable, refer to the extended section of the SDS for further information on CSA.

12.6. Endocrine disrupting properties

The substance/mixture has no endocrine disrupting properties.

12.7. Other adverse effects

This product has no known eco-toxicological effects.

Effect on the ozone layer : No known effects from this product.

Ozone Depleting Potential : None

Effect on global warming : No known effects from this product.

8/13
MSDS_GB Argon
SAFETY DATA SHEET
Version 4.0 SDS Number 300000000004
Revision Date 28.12.2022 Print Date 06.01.2023

Global Warming Potential : None

SECTION 13: Disposal considerations

13.1. Waste treatment : Contact supplier if guidance is required. Return unused product in original
methods cylinder to supplier. Refer to the EIGA code of practice Doc. 30 "Disposal of
Gases", downloadable at http://www.eiga.org for more guidance on suitable
disposal methods. List of hazardous waste codes: 16 05 05: Gases in pressure
containers other than those mentioned in 16 05 04.

Contaminated packaging : Return cylinder to supplier.

SECTION 14: Transport information

14.1. UN number or ID number

UN/ID No. : UN1006

14.2. UN proper shipping name

Transport by road/rail (ADR/RID) : ARGON, COMPRESSED
Transport by air (ICAO-TI / IATA-DGR) : Argon, compressed
Transport by sea (IMDG) : ARGON, COMPRESSED

14.3. Transport hazard class(es)

Label(s) : 2.2
Transport by road/rail (ADR/RID)
Class or Division : 2
ADR/RID Hazard ID no. : 20
Tunnel Code : (E)

Transport by air (ICAO-TI / IATA-DGR)

Class or Division : 2.2

Transport by sea (IMDG)

Class or Division : 2.2

14.4. Packing group

Transport by road/rail (ADR/RID) : Not applicable.

Transport by air (ICAO-TI / IATA-DGR) : Not applicable.

Transport by sea (IMDG) : Not applicable.

14.5. Environmental hazards

Transport by road/rail (ADR/RID)
Marine Pollutant : No

Transport by air (ICAO-TI / IATA-DGR)

9/13
MSDS_GB Argon
SAFETY DATA SHEET
Version 4.0 SDS Number 300000000004
Revision Date 28.12.2022 Print Date 06.01.2023

Marine Pollutant : No

Transport by sea (IMDG)

Marine Pollutant : No
Segregation Group : None

14.6. Special precautions for user

Transport by air (ICAO-TI / IATA-DGR)
Passenger and Cargo Aircraft : Transport allowed
Cargo Aircraft only : Transport allowed

Further Information
Avoid transport on vehicles where the load space is not separated from the driver's compartment. Ensure vehicle
driver is aware of the potential hazards of the load and knows what to do in the event of an accident or an
emergency. The transportation information is not intended to convey all specific regulatory data relating to this
material. For complete transportation information, contact customer service.

14.7. Maritime transport in bulk according to IMO instruments

Not applicable.

SECTION 15: Regulatory information

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
Country/Region Regulatory list Notification
USA TSCA Included on Inventory
Australia AU AIICL Included on Inventory
Canada DSL Included on Inventory
Japan ENCS (JP) Included on Inventory
Korea KECI (KR) Included on Inventory
China IECSC Included on Inventory
Switzerland CH INV Included on Inventory
Taiwan TCSI Included on Inventory
Other Regulations

The REACH etc. (Amendment etc.) (EU Exit) Regulations 2019 No. 2019/758

The REACH etc. (Amendment etc.) (EU Exit) (No. 2) Regulations 2019 No.
2019/858

The REACH etc. (Amendment etc.) (EU Exit) (No. 3) Regulations 2019 No.
2019/1144

The REACH etc. (Amendment etc.) (EU Exit) Regulations 2020 No. 2020/1577

The REACH etc. (Amendment) Regulations 2021 No. 2021/904

Control of Substances Hazardous to Health Regulations 2002 (as amended)

Health and Safety at Work etc. Act 1974

Management of Health and Safety at Work Regulations (Northern Ireland)

2000 c.388, and as amended

10/13
MSDS_GB Argon
SAFETY DATA SHEET
Version 4.0 SDS Number 300000000004
Revision Date 28.12.2022 Print Date 06.01.2023

Management of Health and Safety at Work Regulations 1999 (S.I. number

3242)

The Health and Safety at Work etc. Act 1974 (Application to

Environmentally Hazardous Substances) Regulations 2002 (England and
Wales and Scotland) 11 March 2002 c.282, and as amended

Health and Safety at Work Order (Application to Environmentally

Hazardous Substances) Regulations (Northern Ireland) 2003 (Northern
Ireland) 14 March 2003 c52, and as amended

The Control of Major Accident Hazards Regulations 2015 c483

The Control of Major Accident Hazards Regulations (Northern Ireland)

2015 c325

The Pressure Systems Safety Regulations 2000 (S.I. number 128) link to
Pressure Equipment Directive (97/23/EC)

The Carriage of Dangerous Goods and Use of Transportable Pressure

Equipment Regulations 2011 c1885, and as amended

The Carriage of Dangerous Goods and Use of Transportable Pressure

Equipment Regulations with amendments (Northern Ireland) 2011 c365

The Water Environment (Water Framework Directive) (England and Wales)

Regulations 2017 c.407

The Water Environment Regulations (Northern Ireland) 2017 c.81

Pollution Prevention and Control Act 1999 c.24

The Fluorinated Greenhouse Gases Regulations 2015 c.310

The Fluorinated Greenhouse Gases Regulations (Northern Ireland) 2015

c.425

The Acetylene Safety (England and Wales and Scotland) Regulations 2014
c.1639

The Highly Flammable Liquids and Liquefied Petroleum Gases Regulations

1972 c.917

The Highly Flammable Liquids and Liquefied Petroleum Gases Regulations

(Northern Ireland) 1975 c.256

Dangerous Substances and Explosive Atmospheres Regulations (Northern

Ireland) 2003 c.152

The Dangerous Substances and Explosive Atmospheres Regulations 2002

c.2776

Pollution Prevention and Control Act 1999

The Environmental Permitting (England and Wales) Regulations 2016

11/13
MSDS_GB Argon
SAFETY DATA SHEET
Version 4.0 SDS Number 300000000004
Revision Date 28.12.2022 Print Date 06.01.2023

Ozone Depleting Substances Regulations 2015

SEVESO III: EU. Directive 2012/18/EU (SEVESO III) on major : Not covered.
accident hazards involving dangerous substances, Annex I

15.2. Chemical safety assessment

A CSA does not need to be carried out for this product.

SECTION 16: Other information

Ensure all national/local regulations are observed.

Hazard Statements:
H280 Contains gas under pressure; may explode if heated.

Indication of Method:
Gases under pressure Compressed gas. Contains gas under pressure; may explode if heated. Calculation method

Abbreviations and acronyms:

ATE - Acute Toxicity Estimate
CLP - Classification Labelling Packaging Regulation; Regulation (EC) No 1272/2008
REACH - Registration, Evaluation, Authorisation and Restriction of Chemicals Regulation (EC) No 1907/2006
EINECS - European Inventory of Existing Commercial Chemical Substances
ELINCS - European List of Notified Chemical Substances
CAS# - Chemical Abstract Service number
PPE - Personal Protection Equipment
Kow - octanol-water partition coefficient
DNEL - Derived No Effect Level
LC50 - Lethal Concentration to 50 % of a test population
LD50 - Lethal Dose to 50% of a test population (Median Lethal Dose)
NOEC - No Observed Effect Concentration
PNEC - Predicted No Effect Concentration
RMM - Risk Management Measure
OEL - Occupational Exposure Limit
PBT - Persistent, Bioaccumulative and Toxic
vPvB - Very Persistent and Very Bioaccumulative
STOT - Specific Target Organ Toxicity
CSA - Chemical Safety Assessment
EN - European Standard
UN - United Nations
ADR - European Agreement concerning the International Carriage of Dangerous Goods by Road
IATA - International Air Transport Association
IMDG - International Maritime Dangerous Goods
RID - Regulations concerning the International Carriage of Dangerous Goods by Rail
WGK - Water Hazard Class

Key literature references and sources for data:

ECHA - Guidance on the compilation of safety data sheets
ECHA - Guidance on the application of the CLP Criteria
ECHA - Database of registered substances https://echa.europa.eu
3E database

12/13
MSDS_GB Argon
SAFETY DATA SHEET
Version 4.0 SDS Number 300000000004
Revision Date 28.12.2022 Print Date 06.01.2023

Prepared by : Air Products and Chemicals, Inc. Global EH&S Department

For additional information, please visit our web site at http://www.airproducts.com

This Safety Data Sheet has been established in accordance with the applicable European Directives and applies to
all countries that have translated the Directives in their national laws. COMMISSION REGULATION (EU) 2020/878
of 18 June 2020 amending Annex II to Regulation (EC) No 1907/2006 of the European Parliament and of the
Council concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH).

Details given in this document are believed to be correct at the time of going to press. Whilst proper care has been
taken in the preparation of this document, no liability for injury or damage resulting from its use can be accepted.

13/13
MSDS_GB Argon