SAFETY DATA SHEET

Version 1.16 SDS Number 300000000004

Revision Date 03.08.2016 Print Date 17.03.2018
Supercedes Version: 1.15

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1. Product identifier : Argon

Chemical formula : Ar

Synonyms : Argon, Argon gas, Gaseous Argon, GAR

Refer to Section 3 for REACH information

1.2. Relevant identified uses of the substance or mixture and uses advised against
Use of the : General Industrial
Substance/Mixture

Restrictions on Use : No data available.

1.3. Details of the supplier : Air Products Ireland Ltd

of the safety data sheet Unit 950 Western Industrial Estate
Kileen Road
Dublin 12
Ireland

Email Address – Technical : [email protected]

Information

Telephone : 1-4659650

1.4. Emergency : (01) 463 4200 / +353 1 463 4200

telephone number

SECTION 2: Hazards identification

2.1. Classification of the substance or mixture

Gases under pressure - Compressed gas. H280:Contains gas under pressure; may explode if heated.

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2.2. Label elements

Hazard pictograms/symbols

Signal Word: Warning

Hazard Statements:
H280:Contains gas under pressure; may explode if heated.

Precautionary Statements:
Storage : P403:Store in a well-ventilated place.

2.3. Other hazards

High pressure gas.
Can cause rapid suffocation.

Environmental Effects
Not harmful.

SECTION 3: Composition/information on ingredients

Substance/Mixture : Substance

Components EINECS / ELINCS CAS Number Concentration

Number
(Volume)
Argon 231-147-0 7440-37-1 100 %

Components Classification (CLP) REACH Reg. #

Argon Press. Gas (Comp.) ;H280

If REACH registration numbers do not appear the substance is either exempt from registration, does not meet the
minimum volume threshold for registration, or the registration date has not yet come due.
Concentration is nominal. For the exact product composition, please refer to technical specifications.

SECTION 4: First aid measures

4.1. Description of first aid measures

General advice : Remove victim to uncontaminated area wearing self contained breathing
apparatus. Keep victim warm and rested. Call a doctor. Apply artificial respiration
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if breathing stopped.

Eye contact : In case of direct contact with eyes, seek medical advice.

Skin contact : Adverse effects not expected from this product.

Ingestion : Ingestion is not considered a potential route of exposure.

Inhalation : Remove to fresh air. If breathing has stopped or is labored, give assisted
respirations. Supplemental oxygen may be indicated. If the heart has stopped,
trained personnel should begin cardiopulmonary resuscitation immediately. In
case of shortness of breath, give oxygen.

4.2. Most important symptoms and effects, both acute and delayed
Symptoms : Exposure to oxygen deficient atmosphere may cause the following symptoms:
Dizziness. Salivation. Nausea. Vomiting. Loss of mobility/consciousness.

4.3. Indication of any immediate medical attention and special treatment needed
Treatment : If exposed or concerned: Get medical attention/advice.

SECTION 5: Firefighting measures

5.1. Extinguishing media

Suitable extinguishing media : All known extinguishing media can be used.

Extinguishing media which : No data available.

must not be used for safety
reasons.

5.2. Special hazards : Upon exposure to intense heat or flame, cylinder will vent rapidly and or rupture
arising from the violently. Product is nonflammable and does not support combustion. Move away
from container and cool with water from a protected position. Keep containers
substance or mixture and surroundings cool with water spray.

5.3. Advice for firefighters : Wear self contained breathing apparatus for fire fighting if necessary. Standard
protective clothing and equipment (Self Contained Breathing Apparatus) for fire
fighters. Standard EN 137 - Self-contained open-circuit compressed air breathing
apparatus with full face mask. Standard EN 469 - Protective clothing for
firefighters. Standard - EN 659: Protective gloves for firefighters.

SECTION 6: Accidental release measures

6.1. Personal : Gas/vapor heavier than air. May accumulate in confined spaces, particularly at or
precautions, protective below ground level. Evacuate personnel to safe areas. Wear self-contained
breathing apparatus when entering area unless atmosphere is proved to be safe.
equipment and Monitor oxygen level. Ventilate the area.
emergency procedures

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6.2. Environmental : Do not discharge into any place where its accumulation could be dangerous.
precautions Prevent further leakage or spillage if safe to do so.

6.3. Methods and : Ventilate the area.

material for containment
and cleaning up
Additional advice : If possible, stop flow of product. Increase ventilation to the release area and
monitor oxygen level. If leak is from cylinder or cylinder valve, call the emergency
telephone number. If the leak is in the user's system, close the cylinder valve and
safely vent the pressure before attempting repairs.

6.4. Reference to other : For more information refer to Sections 8 & 13

sections

SECTION 7: Handling and storage

7.1. Precautions for safe handling

Protect cylinders from physical damage; do not drag, roll, slide or drop. Do not allow storage area temperature to
exceed 50°C (122°F). Only experienced and properly instructed persons should handle compressed
gases/cryogenic liquids. Before using the product, determine its identity by reading the label. Know and
understand the properties and hazards of the product before use. When doubt exists as to the correct handling
procedure for a particular gas, contact the supplier. Do not remove or deface labels provided by the supplier for the
identification of the cylinder contents. When moving cylinders, even for short distances, use a cart (trolley, hand
truck, etc.) designed to transport cylinders. Leave valve protection caps in place until the container has been
secured against either a wall or bench or placed in a container stand and is ready for use. Use an adjustable strap
wrench to remove over-tight or rusted caps. Before connecting the container, check the complete gas system for
suitability, particularly for pressure rating and materials. Before connecting the container for use, ensure that back
feed from the system into the container is prevented. Ensure the complete gas system is compatible for pressure
rating and materials of construction. Ensure the complete gas system has been checked for leaks before use.
Employ suitable pressure regulating devices on all containers when the gas is being emitted to systems with lower
pressure rating than that of the container. Never insert an object (e.g. wrench, screwdriver, pry bar, etc.) into valve
cap openings. Doing so may damage valve, causing a leak to occur. Open valve slowly. If user experiences any
difficulty operating cylinder valve discontinue use and contact supplier. Close container valve after each use and
when empty, even if still connected to equipment. Never attempt to repair or modify container valves or safety
relief devices. Damaged valves should be reported immediately to the supplier. Close valve after each use and
when empty. Replace outlet caps or plugs and container caps as soon as container is disconnected from
equipment. Do not subject containers to abnormal mechanical shock. Never attempt to lift a cylinder by its valve
protection cap or guard. Do not use containers as rollers or supports or for any other purpose than to contain the
gas as supplied. Never strike an arc on a compressed gas cylinder or make a cylinder a part of an electrical circuit.
Do not smoke while handling product or cylinders. Never re-compress a gas or a gas mixture without first
consulting the supplier. Never attempt to transfer gases from one cylinder/container to another. Always use
backflow protective device in piping. When returning cylinder install valve outlet cap or plug leak tight. Never use
direct flame or electrical heating devices to raise the pressure of a container. Containers should not be subjected
to temperatures above 50°C (122°F).

7.2. Conditions for safe storage, including any incompatibilities

Full containers should be stored so that oldest stock is used first. Containers should be stored in a purpose build

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compound which should be well ventilated, preferably in the open air. Stored containers should be periodically
checked for general condition and leakage. Observe all regulations and local requirements regarding storage of
containers. Protect containers stored in the open against rusting and extremes of weather. Containers should not
be stored in conditions likely to encourage corrosion. Containers should be stored in the vertical position and
properly secured to prevent toppling. The container valves should be tightly closed and where appropriate valve
outlets should be capped or plugged. Container valve guards or caps should be in place. Keep containers tightly
closed in a cool, well-ventilated place. Store containers in location free from fire risk and away from sources of
heat and ignition. Full and empty cylinders should be segregated. Do not allow storage temperature to exceed
50°C (122°F). Return empty containers in a timely manner.

Technical measures/Precautions
Containers should be segregated in the storage area according to the various categories (e.g. flammable, toxic,
etc.) and in accordance whit local regulations. Keep away from combustible material.

7.3. Specific end use(s)

Refer to section 1 or the extended SDS if applicable.

SECTION 8: Exposure controls/personal protection

8.1. Control parameters

If applicable, refer to the extended section of the SDS for further information on CSA.

8.2. Exposure controls

Engineering measures
Provide natural or mechanical ventilation to prevent oxygen deficient atmospheres below 19.5% oxygen.

Personal protective equipment

Respiratory protection : Self contained breathing apparatus (SCBA) or positive pressure airline with mask
are to be used in oxygen-deficient atmosphere.
Air purifying respirators will not provide protection. Users of breathing apparatus
must be trained.

Hand protection : Wear working gloves when handling gas containers.

Standard EN 388 - Protective gloves against mechanical risk.

Eye/face Protection : Safety glasses recommended when handling cylinders.

Standard EN 166 - Personal eye-protection.

Skin and body protection : Safety shoes are recommended when handling cylinders.
Standard EN ISO 20345 - Personal protective equipment - Safety footwear.

Special instructions for : Ensure adequate ventilation, especially in confined areas.

protection and hygiene

Environmental Exposure : If applicable, refer to the extended section of the SDS for further information on
Controls CSA.
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Remarks : Simple asphyxiant.

SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties

(a/b) Physical state/Colour : Compressed gas. Colorless gas

(c) Odour : No odor warning properties.

(d) Density : 0.0017 g/cm3 (0.106 lb/ft3) at 21 °C ( 70 °F)

Note: (as vapor)

(e) Relative Density : No data available.

(f) Melting point / freezing point : -309 °F (-189.3 °C)

(g) Boiling point/range : -302 °F (-185.8 °C)

(h) Vapor pressure : Not applicable.

(i) Water solubility : 0.061 g/l

(j) Partition coefficient : Not applicable.

(n-octanol/water)

(k) pH : Not applicable.

(l) Viscosity : Not applicable.

(m) Particle characteristics : No data available.

(n) Lower and upper explosion : No data available.

/ flammability limits

(o) Flash point : Not applicable.

(p) Autoignition temperature : No data available.

(q) Decomposition : No data available.

temperature

9.2. Other information

Explosive properties : No data available.

Oxidizing properties : No data available.

Molecular Weight : 39.95 g/mol

Odor threshold : No data available.

Evaporation rate : Not applicable.

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Flammability (solid, gas) : Refer to product classification in Section 2

Specific Volume : 0.6043 m3/kg (9.68 ft3/lb) at 21 °C ( 70 °F)

Upper flammability limit : Not applicable.

Lower flammability limit : Not applicable.

Relative vapor density : 1.379 (air = 1) Heavier than air.

SECTION 10: Stability and reactivity

10.1. Reactivity : Refer to possibility of hazardous reactions and/or incompatible materials
sections.

10.2. Chemical stability : Stable under normal conditions.

10.3. Possibility of hazardous : No data available.

reactions

10.4. Conditions to avoid : No data available.

10.5. Incompatible materials : No data available.

10.6. Hazardous : Under normal conditions of storage and use, hazardous decomposition products
decomposition products should not be produced.

SECTION 11: Toxicological information

11.1. Information on toxicological effects

Likely routes of exposure
Effects on Eye : In case of direct contact with eyes, seek medical advice.

Effects on Skin : Adverse effects not expected from this product.

Inhalation Effects : In high concentrations may cause asphyxiation. Asphyxiation may bring
about unconsciousness without warning and so rapidly that victim may be
unable to protect themselves.

Ingestion Effects : Ingestion is not considered a potential route of exposure.

Symptoms : Exposure to oxygen deficient atmosphere may cause the following

symptoms: Dizziness. Salivation. Nausea. Vomiting. Loss of
mobility/consciousness.

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Acute toxicity

Acute Oral Toxicity : No data is available on the product itself.

Acute Inhalation Toxicity : No data is available on the product itself.

Acute Dermal Toxicity : No data is available on the product itself.

Skin corrosion/irritation : No data available.

Serious eye damage/eye : No data available.

irritation

Sensitization. : No data available.

Chronic toxicity or effects from long term exposures

Carcinogenicity : No data available.

Reproductive toxicity : No data is available on the product itself.

Germ cell mutagenicity : No data is available on the product itself.

Specific target organ systemic : No data available.

toxicity (single exposure)

Specific target organ systemic : No data available.

toxicity (repeated exposure)

Aspiration hazard : No data available.

SECTION 12: Ecological information

12.1. Toxicity
Aquatic toxicity : No data is available on the product itself.

Toxicity to other : No data is available on the product itself.

organisms

12.2. Persistence and degradability

No data available.

12.3. Bioaccumulative potential

Refer to Section 9 "Partition Coefficient (n-octanol/water)".

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12.4. Mobility in soil

Because of its high volatility, the product is unlikely to cause ground pollution.

12.5. Results of PBT and vPvB assessment

If applicable, refer to the extended section of the SDS for further information on CSA.

12.6. Other adverse effects

This product has no known eco-toxicological effects.

Effect on the ozone layer

Ozone Depleting : No data available.
Potential

Global Warming Potential : No data available.

SECTION 13: Disposal considerations

13.1. Waste treatment : Contact supplier if guidance is required. Return unused product in original
methods cylinder to supplier. Refer to the EIGA code of practice Doc. 30 "Disposal of
Gases", downloadable at http://www.eiga.org for more guidance on suitable
disposal methods. List of hazardous waste codes: 16 05 05: Gases in pressure
containers other than those mentioned in 16 05 04.

Contaminated packaging : Return cylinder to supplier.

SECTION 14: Transport information

ADR
UN/ID No. : UN1006
Proper shipping name : ARGON, COMPRESSED
Class or Division : 2
Tunnel Code : (E)
Label(s) : 2.2
ADR/RID Hazard ID no. : 20
Marine Pollutant : No

IATA
UN/ID No. : UN1006
Proper shipping name : Argon, compressed
Class or Division : 2.2
Label(s) : 2.2
Marine Pollutant : No
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IMDG
UN/ID No. : UN1006
Proper shipping name : ARGON, COMPRESSED
Class or Division : 2.2
Label(s) : 2.2
Marine Pollutant : No
Segregation Group: : None

RID
UN/ID No. : UN1006
Proper shipping name : ARGON, COMPRESSED
Class or Division : 2
Label(s) : 2.2
Marine Pollutant : No

Further Information
Avoid transport on vehicles where the load space is not separated from the driver's compartment. Ensure vehicle
driver is aware of the potential hazards of the load and knows what to do in the event of an accident or an
emergency. The transportation information is not intended to convey all specific regulatory data relating to this
material. For complete transportation information, contact customer service.

SECTION 15: Regulatory information

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
Country Regulatory list Notification
USA TSCA Included on Inventory.
EU EINECS Included on Inventory.
Canada DSL Included on Inventory.
Australia AICS Included on Inventory.
Japan ENCS Included on Inventory.
South Korea ECL Included on Inventory.
China SEPA Included on Inventory.
Philippines PICCS Included on Inventory.

Other Regulations
REGULATION (EC) No 1907/2006 OF THE EUROPEAN PARLIAMENT
AND OF THE COUNCIL of 18 December 2006 concerning the Registration,
Evaluation, Authorisation and Restriction of Chemicals (REACH),
establishing a European Chemicals Agency, amending Directive 1999/45/EC
and repealing Council Regulation (EEC) No 793/93 and Commission
Regulation (EC) No 1488/94 as well as Council Directive 76/769/EEC and
Commission Directives 91/155/EEC, 93/67/EEC, 93/105/EC and 2000/21/EC.

COMMISSION REGULATION (EU) 2015/830 of 28 May 2015 amending Regulation

(EC) No 1907/2006 of the European Parliament and of the Council on the

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Registration, Evaluation, Authorisation and Restriction of Chemicals

(REACH).

Regulation (EC) No 1272/2008 the European Parliament and of the Council

of 16 December 2008 on classification, labelling and packaging of
substances and mixtures, amending and repealing Directives 67/548/EEC
and 1999/45/EC, and amending Regulation (EC) No 1907/2006.

15.2. Chemical safety assessment

If this product does not contain exposure scenarios, the components in this product are either exempt from REACH, do not
meet the minimum volume threshold for a CSA, or the CSA has not yet been completed.

SECTION 16: Other information

Ensure all national/local regulations are observed.

Hazard Statements:
H280 Contains gas under pressure; may explode if heated.

Indication of Method:
Gases under pressure Compressed gas. Contains gas under pressure; may explode if heated. Calculation method

Abbreviations and acronyms:

ATE - Acute Toxicity Estimate
CLP - Classification Labelling Packaging Regulation; Regulation (EC) No 1272/2008
REACH - Registration, Evaluation, Authorisation and Restriction of Chemicals Regulation (EC) No 1907/2006
EINECS - European Inventory of Existing Commercial Chemical Substances
ELINCS - European List of Notified Chemical Substances
CAS# - Chemical Abstract Service number
PPE - Personal Protection Equipment
Kow - octanol-water partition coefficient
DNEL - Derived No Effect Level
LC50 - Lethal Concentration to 50 % of a test population
LD50 - Lethal Dose to 50% of a test population (Median Lethal Dose)
NOEC - No Observed Effect Concentration
PNEC - Predicted No Effect Concentration
RMM - Risk Management Measure
OEL - Occupational Exposure Limit
PBT - Persistent, Bioaccumulative and Toxic
vPvB - Very Persistent and Very Bioaccumulative
STOT - Specific Target Organ Toxicity
CSA - Chemical Safety Assessment
EN - European Standard
UN - United Nations
ADR - European Agreement concerning the International Carriage of Dangerous Goods by Road
IATA - International Air Transport Association
IMDG - International Maritime Dangerous Goods
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RID - Regulations concerning the International Carriage of Dangerous Goods by Rail

WGK - Water Hazard Class

Key literature references and sources for data:

ECHA - Guidance on the compilation of safety data sheets
ECHA - Guidance on the application of the CLP Criteria
ARIEL database

Prepared by : Air Products and Chemicals, Inc. Global EH&S Product Safety Department

For additional information, please visit our Product Stewardship web site at
http://www.airproducts.com/productstewardship/

This Safety Data Sheet has been established in accordance with the applicable European Directives and applies to
all countries that have translated the Directives in their national laws. COMMISSION REGULATION (EU) 2015/830 of
28 May 2015 amending Regulation (EC) No 1907/2006 of the European Parliament and of the Council on the
Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH).

Details given in this document are believed to be correct at the time of going to press. Whilst proper care has been
taken in the preparation of this document, no liability for injury or damage resulting from its use can be accepted.

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