SAFETY DATA SHEET

Hydrogen

Section 1. Identification
GHS product identifier

: Hydrogen

Chemical name

: hydrogen

Other means of
identification

: Dihydrogen; o-Hydrogen; p-Hydrogen; Molecular hydrogen; H2; UN 1049

Product use

: Synthetic/Analytical chemistry.

Synonym
SDS #

: Dihydrogen; o-Hydrogen; p-Hydrogen; Molecular hydrogen; H2; UN 1049

: 001026

Supplier's details

: Airgas USA, LLC and its affiliates

259 North Radnor-Chester Road
Suite 100
Radnor, PA 19087-5283
1-610-687-5253

Emergency telephone
number (with hours of
operation)

: 1-866-734-3438

Section 2. Hazards identification

OSHA/HCS status
Classification of the
substance or mixture

: This material is considered hazardous by the OSHA Hazard Communication Standard

(29 CFR 1910.1200).
: FLAMMABLE GASES - Category 1
GASES UNDER PRESSURE - Compressed gas

GHS label elements

Hazard pictograms

Signal word

: Danger

Hazard statements

: Extremely flammable gas.

Contains gas under pressure; may explode if heated.
Burns with invisible flame.
May displace oxygen and cause rapid suffocation.

Precautionary statements
General

Prevention

Response
Storage
Disposal
Date of issue/Date of revision

: Read and follow all Safety Data Sheets (SDSS) before use. Read label before use.
Keep out of reach of children. If medical advice is needed, have product container or
label at hand. Close valve after each use and when empty. Use equipment rated for
cylinder pressure. Do not open valve until connected to equipment prepared for use.
Use a back flow preventative device in the piping. Use only equipment of compatible
materials of construction. Approach suspected leak area with caution.
: Never Put cylinders into unventilated areas of passenger vehicles. Keep away from
heat, sparks, open flames and hot surfaces. - No smoking. Use and store only outdoors
or in a well ventilated place.
: Leaking gas fire: Do not extinguish, unless leak can be stopped safely. Eliminate all
ignition sources if safe to do so.
: Protect from sunlight. Protect from sunlight when ambient temperature exceeds
52C/125F. Store in a well-ventilated place.
: Not applicable.
: 10/15/2014.

Date of previous issue

: 10/2/2014.

Version

: 0.02

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Section 2. Hazards identification

Hazards not otherwise
classified

: In addition to any other important health or physical hazards, this product may displace
oxygen and cause rapid suffocation.

Section 3. Composition/information on ingredients

Substance/mixture

: Substance

Chemical name

: hydrogen

Other means of
identification

: Dihydrogen; o-Hydrogen; p-Hydrogen; Molecular hydrogen; H2; UN 1049

CAS number/other identifiers

CAS number
: 1333-74-0
Product code

: 001026

Ingredient name

CAS number

hydrogen

100

1333-74-0

There are no additional ingredients present which, within the current knowledge of the supplier and in the
concentrations applicable, are classified as hazardous to health or the environment and hence require reporting
in this section.
Occupational exposure limits, if available, are listed in Section 8.

Section 4. First aid measures

Description of necessary first aid measures
Eye contact

Inhalation

Skin contact

Ingestion

: Immediately flush eyes with plenty of water, occasionally lifting the upper and lower
eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10
minutes. Get medical attention if irritation occurs.
: Remove victim to fresh air and keep at rest in a position comfortable for breathing. If
not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial
respiration or oxygen by trained personnel. It may be dangerous to the person providing
aid to give mouth-to-mouth resuscitation. Get medical attention if adverse health effects
persist or are severe. If unconscious, place in recovery position and get medical
attention immediately. Maintain an open airway. Loosen tight clothing such as a collar,
tie, belt or waistband.
: Flush contaminated skin with plenty of water. Remove contaminated clothing and
shoes. To avoid the risk of static discharges and gas ignition, soak contaminated
clothing thoroughly with water before removing it. Get medical attention if symptoms
occur. Wash clothing before reuse. Clean shoes thoroughly before reuse.
: As this product is a gas, refer to the inhalation section.

Most important symptoms/effects, acute and delayed

Potential acute health effects
Eye contact

: Contact with rapidly expanding gas may cause burns or frostbite.

Inhalation

: No known significant effects or critical hazards.

Skin contact

: Contact with rapidly expanding gas may cause burns or frostbite.

Frostbite

: Try to warm up the frozen tissues and seek medical attention.

Ingestion
: As this product is a gas, refer to the inhalation section.
Over-exposure signs/symptoms
Eye contact

: No specific data.

Inhalation

: No specific data.

Skin contact

: No specific data.

Date of issue/Date of revision

: 10/15/2014.

Date of previous issue

: 10/2/2014.

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: 0.02

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Hydrogen

Section 4. First aid measures

Ingestion

: No specific data.

Indication of immediate medical attention and special treatment needed, if necessary

Notes to physician
: Treat symptomatically. Contact poison treatment specialist immediately if large
quantities have been ingested or inhaled.
Specific treatments
: No specific treatment.
Protection of first-aiders

: No action shall be taken involving any personal risk or without suitable training. It may
be dangerous to the person providing aid to give mouth-to-mouth resuscitation.

See toxicological information (Section 11)

Section 5. Fire-fighting measures

Extinguishing media
Suitable extinguishing
media

: Use an extinguishing agent suitable for the surrounding fire.

Unsuitable extinguishing
media

: None known.

Specific hazards arising

from the chemical
Hazardous thermal
decomposition products
Special protective actions
for fire-fighters

Special protective
equipment for fire-fighters

: Contains gas under pressure. Extremely flammable gas. In a fire or if heated, a

pressure increase will occur and the container may burst, with the risk of a subsequent
explosion.
: No specific data.

: Promptly isolate the scene by removing all persons from the vicinity of the incident if
there is a fire. No action shall be taken involving any personal risk or without suitable
training. Contact supplier immediately for specialist advice. Move containers from fire
area if this can be done without risk. Use water spray to keep fire-exposed containers
cool. If involved in fire, shut off flow immediately if it can be done without risk. If this is
impossible, withdraw from area and allow fire to burn. Fight fire from protected location
or maximum possible distance. Eliminate all ignition sources if safe to do so.
: Fire-fighters should wear appropriate protective equipment and self-contained breathing
apparatus (SCBA) with a full face-piece operated in positive pressure mode.

Section 6. Accidental release measures

Personal precautions, protective equipment and emergency procedures
For non-emergency
personnel

: Accidental releases pose a serious fire or explosion hazard. No action shall be taken
involving any personal risk or without suitable training. Evacuate surrounding areas.
Keep unnecessary and unprotected personnel from entering. Shut off all ignition
sources. No flares, smoking or flames in hazard area. Avoid breathing gas. Provide
adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put
on appropriate personal protective equipment.
For emergency responders : If specialised clothing is required to deal with the spillage, take note of any information
in Section 8 on suitable and unsuitable materials. See also the information in "For nonemergency personnel".
Environmental precautions

: Ensure emergency procedures to deal with accidental gas releases are in place to avoid
contamination of the environment. Inform the relevant authorities if the product has
caused environmental pollution (sewers, waterways, soil or air).

Methods and materials for containment and cleaning up

Date of issue/Date of revision

: 10/15/2014.

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: 10/2/2014.

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Section 6. Accidental release measures

Small spill
Large spill

: Immediately contact emergency personnel. Stop leak if without risk. Use spark-proof
tools and explosion-proof equipment.
: Immediately contact emergency personnel. Stop leak if without risk. Use spark-proof
tools and explosion-proof equipment. Note: see Section 1 for emergency contact
information and Section 13 for waste disposal.

Section 7. Handling and storage

Precautions for safe handling
Protective measures

: Put on appropriate personal protective equipment (see Section 8). Contains gas under
pressure. Avoid contact with eyes, skin and clothing. Avoid breathing gas. Use only
with adequate ventilation. Wear appropriate respirator when ventilation is inadequate.
Do not enter storage areas and confined spaces unless adequately ventilated. Store
and use away from heat, sparks, open flame or any other ignition source. Use
explosion-proof electrical (ventilating, lighting and material handling) equipment. Use
only non-sparking tools. Empty containers retain product residue and can be hazardous.
Do not puncture or incinerate container. Use equipment rated for cylinder pressure.
Close valve after each use and when empty. Protect cylinders from physical damage;
do not drag, roll, slide, or drop. Use a suitable hand truck for cylinder movement.

Advice on general
occupational hygiene

: Eating, drinking and smoking should be prohibited in areas where this material is
handled, stored and processed. Workers should wash hands and face before eating,
drinking and smoking. Remove contaminated clothing and protective equipment before
entering eating areas. See also Section 8 for additional information on hygiene
measures.

Conditions for safe storage,

including any
incompatibilities

: Store in accordance with local regulations. Store in a segregated and approved area.
Store away from direct sunlight in a dry, cool and well-ventilated area, away from
incompatible materials (see Section 10). Eliminate all ignition sources. Keep container
tightly closed and sealed until ready for use. Cylinders should be stored upright, with
valve protection cap in place, and firmly secured to prevent falling or being knocked
over. Cylinder temperatures should not exceed 52 C (125 F).

Section 8. Exposure controls/personal protection

Control parameters
Occupational exposure limits
Ingredient name

Exposure limits

hydrogen

Oxygen Depletion [Asphyxiant]

Appropriate engineering
controls

Environmental exposure
controls

: Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or
other engineering controls to keep worker exposure to airborne contaminants below any
recommended or statutory limits. The engineering controls also need to keep gas,
vapor or dust concentrations below any lower explosive limits. Use explosion-proof
ventilation equipment.
: Emissions from ventilation or work process equipment should be checked to ensure
they comply with the requirements of environmental protection legislation. In some
cases, fume scrubbers, filters or engineering modifications to the process equipment
will be necessary to reduce emissions to acceptable levels.

Individual protection measures

Date of issue/Date of revision

: 10/15/2014.

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: 10/2/2014.

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Section 8. Exposure controls/personal protection

Hygiene measures

Eye/face protection

: Wash hands, forearms and face thoroughly after handling chemical products, before
eating, smoking and using the lavatory and at the end of the working period.
Appropriate techniques should be used to remove potentially contaminated clothing.
Wash contaminated clothing before reusing. Ensure that eyewash stations and safety
showers are close to the workstation location.
: Safety eyewear complying with an approved standard should be used when a risk
assessment indicates this is necessary to avoid exposure to liquid splashes, mists,
gases or dusts. If contact is possible, the following protection should be worn, unless
the assessment indicates a higher degree of protection: safety glasses with sideshields.

Skin protection
Hand protection

Body protection

Other skin protection

Respiratory protection

: Chemical-resistant, impervious gloves complying with an approved standard should be

worn at all times when handling chemical products if a risk assessment indicates this is
necessary. Considering the parameters specified by the glove manufacturer, check
during use that the gloves are still retaining their protective properties. It should be
noted that the time to breakthrough for any glove material may be different for different
glove manufacturers. In the case of mixtures, consisting of several substances, the
protection time of the gloves cannot be accurately estimated.
: Personal protective equipment for the body should be selected based on the task being
performed and the risks involved and should be approved by a specialist before
handling this product. When there is a risk of ignition from static electricity, wear antistatic protective clothing. For the greatest protection from static discharges, clothing
should include anti-static overalls, boots and gloves.
: Appropriate footwear and any additional skin protection measures should be selected
based on the task being performed and the risks involved and should be approved by a
specialist before handling this product.
: Use a properly fitted, air-purifying or air-fed respirator complying with an approved
standard if a risk assessment indicates this is necessary. Respirator selection must be
based on known or anticipated exposure levels, the hazards of the product and the safe
working limits of the selected respirator.

Section 9. Physical and chemical properties

Appearance
Physical state

: Gas

Color

: Colorless.

Molecular weight

: 2.02 g/mole

Molecular formula
Boiling/condensation point
Melting/freezing point

: H2
: -253C (-423.4F)
: -259.15C (-434.5F)

Critical temperature

: -240.15C (-400.3F)

Odor

: Odorless.
: Not available.

Odor threshold
pH
Flash point

: Not available.
: Not available.

Burning time

: Not applicable.

Burning rate

: Not applicable.

Evaporation rate

: Not available.

Flammability (solid, gas)

: Extremely flammable in the presence of the following materials or conditions: oxidizing

materials.
: Lower: 4%
Upper: 76%

Lower and upper explosive

(flammable) limits
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: 10/15/2014.

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: 10/2/2014.

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Section 9. Physical and chemical properties

Vapor pressure

: Not available.

Vapor density

: 0.07 (Air = 1)
3

Specific Volume (ft /lb)

: 191.9386

Gas Density (lb/ft 3)

: 0.00521

Relative density

: Not applicable.

Solubility

: Not available.

Solubility in water

: Not available.

Partition coefficient: noctanol/water

Auto-ignition temperature

: Not available.

Decomposition temperature

: Not available.

SADT

: Not available.

Viscosity

: Not applicable.

Liquid Density@BP: 4.43 lb/ft3 (70.96 kg/m3)

: 500 to 571C (932 to 1059.8F)

Section 10. Stability and reactivity

Reactivity

: No specific test data related to reactivity available for this product or its ingredients.

Chemical stability

: The product is stable.

Possibility of hazardous
reactions

: Under normal conditions of storage and use, hazardous reactions will not occur.

Conditions to avoid

: Avoid all possible sources of ignition (spark or flame). Do not pressurize, cut, weld,
braze, solder, drill, grind or expose containers to heat or sources of ignition.

Incompatibility with various

substances

: Extremely reactive or incompatible with the following materials: oxidizing materials.

Hazardous decomposition
products

: Under normal conditions of storage and use, hazardous decomposition products should
not be produced.

Hazardous polymerization

: Under normal conditions of storage and use, hazardous polymerization will not occur.

Section 11. Toxicological information

Information on toxicological effects
Acute toxicity
Not available.
Irritation/Corrosion
Not available.
Sensitization
Not available.
Mutagenicity
Not available.
Carcinogenicity
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: 10/15/2014.

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: 10/2/2014.

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Section 11. Toxicological information

Not available.
Reproductive toxicity
Not available.
Teratogenicity
Not available.
Specific target organ toxicity (single exposure)
Not available.
Specific target organ toxicity (repeated exposure)
Not available.
Aspiration hazard
Not available.
Information on the likely
routes of exposure

: Not available.

Potential acute health effects

Eye contact
: Contact with rapidly expanding gas may cause burns or frostbite.
Inhalation

: No known significant effects or critical hazards.

Skin contact

: Contact with rapidly expanding gas may cause burns or frostbite.

Ingestion

: As this product is a gas, refer to the inhalation section.

Symptoms related to the physical, chemical and toxicological characteristics

Eye contact
: No specific data.
Inhalation

: No specific data.

Skin contact

: No specific data.

Ingestion

: No specific data.

Delayed and immediate effects and also chronic effects from short and long term exposure
Short term exposure
Potential immediate
: Not available.
effects
Potential delayed effects : Not available.
Long term exposure
Potential immediate
effects
Potential delayed effects

: Not available.
: Not available.

Potential chronic health effects

Not available.
General

: No known significant effects or critical hazards.

Carcinogenicity

: No known significant effects or critical hazards.

Mutagenicity

: No known significant effects or critical hazards.

Teratogenicity

: No known significant effects or critical hazards.

Developmental effects

: No known significant effects or critical hazards.

Fertility effects

: No known significant effects or critical hazards.

Date of issue/Date of revision

: 10/15/2014.

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: 10/2/2014.

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Section 11. Toxicological information

Numerical measures of toxicity
Acute toxicity estimates
Not available.

Section 12. Ecological information

Toxicity
Not available.
Persistence and degradability
Not available.
Bioaccumulative potential
Not available.
Mobility in soil
Soil/water partition
coefficient (KOC)

: Not available.

Other adverse effects

: No known significant effects or critical hazards.

Section 13. Disposal considerations

Disposal methods

: The generation of waste should be avoided or minimized wherever possible. Disposal

of this product, solutions and any by-products should at all times comply with the
requirements of environmental protection and waste disposal legislation and any
regional local authority requirements. Dispose of surplus and non-recyclable products
via a licensed waste disposal contractor. Waste should not be disposed of untreated to
the sewer unless fully compliant with the requirements of all authorities with jurisdiction.
Empty Airgas-owned pressure vessels should be returned to Airgas. Waste packaging
should be recycled. Incineration or landfill should only be considered when recycling is
not feasible. This material and its container must be disposed of in a safe way. Empty
containers or liners may retain some product residues. Do not puncture or incinerate
container.

Section 14. Transport information

DOT

TDG

Mexico

IMDG

IATA

UN number

UN1049

UN1049

UN1049

UN1049

UN1049

UN proper
shipping name

HYDROGEN,
COMPRESSED

HYDROGEN,
COMPRESSED

HYDROGEN
COMPRESSED

HYDROGEN,
COMPRESSED

HYDROGEN,
COMPRESSED

Transport
2.1
hazard class(es)

2.1

2.1

2.1

2.1

Packing group

Environment

No.

No.

No.

No.

No.

Date of issue/Date of revision

: 10/15/2014.

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: 10/2/2014.

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Section 14. Transport information

Additional
information

Limited quantity
Yes.
Packaging instruction
Passenger aircraft
Quantity limitation:
Forbidden.
Cargo aircraft
Quantity limitation: 150
kg

Explosive Limit and

Limited Quantity Index
0.125

ERAP Index
3000

Passenger and Cargo

AircraftQuantity
limitation: 0 Forbidden
Cargo Aircraft Only
Quantity limitation: 150
kg

Passenger Carrying
Ship Index
Forbidden
Passenger Carrying
Road or Rail Index
Forbidden

Refer to CFR 49 (or authority having jurisdiction) to determine the information required for shipment of the
product.
Special precautions for user : Transport within users premises: always transport in closed containers that are
upright and secure. Ensure that persons transporting the product know what to do in the
event of an accident or spillage.
Transport in bulk according
to Annex II of MARPOL
73/78 and the IBC Code

: Not available.

Section 15. Regulatory information

U.S. Federal regulations

: TSCA 8(a) CDR Exempt/Partial exemption: This material is listed or exempted.

United States inventory (TSCA 8b): This material is listed or exempted.
Clean Air Act (CAA) 112 regulated flammable substances: hydrogen

Clean Air Act Section 112

(b) Hazardous Air
Pollutants (HAPs)

: Not listed

Clean Air Act Section 602

Class I Substances

: Not listed

Clean Air Act Section 602

Class II Substances

: Not listed

DEA List I Chemicals

(Precursor Chemicals)

: Not listed

DEA List II Chemicals

(Essential Chemicals)

: Not listed

SARA 302/304
Composition/information on ingredients
No products were found.
SARA 304 RQ

: Not applicable.

SARA 311/312
Classification

: Fire hazard
Sudden release of pressure
Composition/information on ingredients

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: 10/15/2014.

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: 10/2/2014.

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Section 15. Regulatory information

Name

Fire
Sudden
hazard release of
pressure

Reactive

Immediate
(acute)
health
hazard

Delayed
(chronic)
health
hazard

hydrogen

100

Yes.

No.

No.

No.

Yes.

State regulations
Massachusetts

: This material is listed.

New York

: This material is not listed.

New Jersey

: This material is listed.

Pennsylvania

: This material is listed.

Canada inventory

: This material is listed or exempted.

International regulations
International lists

Chemical Weapons
Convention List Schedule
I Chemicals

: Australia inventory (AICS): This material is listed or exempted.

China inventory (IECSC): This material is listed or exempted.
Japan inventory: Not determined.
Korea inventory: This material is listed or exempted.
Malaysia Inventory (EHS Register): This material is listed or exempted.
New Zealand Inventory of Chemicals (NZIoC): This material is listed or exempted.
Philippines inventory (PICCS): This material is listed or exempted.
Taiwan inventory (CSNN): Not determined.
: Not listed

Chemical Weapons
Convention List Schedule
II Chemicals

: Not listed

Chemical Weapons
Convention List Schedule
III Chemicals

: Not listed

Canada
WHMIS (Canada)

: Class A: Compressed gas.

Class B-1: Flammable gas.
CEPA Toxic substances: This material is not listed.
Canadian ARET: This material is not listed.
Canadian NPRI: This material is not listed.
Alberta Designated Substances: This material is not listed.
Ontario Designated Substances: This material is not listed.
Quebec Designated Substances: This material is not listed.

Section 16. Other information

Canada Label requirements

: Class A: Compressed gas.

Class B-1: Flammable gas.
Hazardous Material Information System (U.S.A.)
Health

Flammability

Physical hazards

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: 10/15/2014.

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: 10/2/2014.

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Section 16. Other information

Caution: HMIS ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4
representing significant hazards or risks Although HMIS ratings are not required on SDSs under 29 CFR 1910.
1200, the preparer may choose to provide them. HMIS ratings are to be used with a fully implemented HMIS
program. HMIS is a registered mark of the National Paint & Coatings Association (NPCA). HMIS materials
may be purchased exclusively from J. J. Keller (800) 327-6868.
The customer is responsible for determining the PPE code for this material.
National Fire Protection Association (U.S.A.)
Flammability

4
Health

Instability/Reactivity
Special

Reprinted with permission from NFPA 704-2001, Identification of the Hazards of Materials for Emergency
Response Copyright 1997, National Fire Protection Association, Quincy, MA 02269. This reprinted material is
not the complete and official position of the National Fire Protection Association, on the referenced subject
which is represented only by the standard in its entirety.
Copyright 2001, National Fire Protection Association, Quincy, MA 02269. This warning system is intended to
be interpreted and applied only by properly trained individuals to identify fire, health and reactivity hazards of
chemicals. The user is referred to certain limited number of chemicals with recommended classifications in
NFPA 49 and NFPA 325, which would be used as a guideline only. Whether the chemicals are classified by NFPA
or not, anyone using the 704 systems to classify chemicals does so at their own risk.
History
Date of printing

: 10/15/2014.

Date of issue/Date of
revision
Date of previous issue

: 10/15/2014.

Version

: 0.02

Key to abbreviations

Date of issue/Date of revision

: 10/2/2014.
: ATE = Acute Toxicity Estimate
BCF = Bioconcentration Factor
GHS = Globally Harmonized System of Classification and Labelling of Chemicals
IATA = International Air Transport Association
IBC = Intermediate Bulk Container
IMDG = International Maritime Dangerous Goods
LogPow = logarithm of the octanol/water partition coefficient
MARPOL 73/78 = International Convention for the Prevention of Pollution From Ships,
1973 as modified by the Protocol of 1978. ("Marpol" = marine pollution)
UN = United NationsACGIH American Conference of Governmental Industrial
Hygienists
AIHA American Industrial Hygiene Association
CAS Chemical Abstract Services
CEPA Canadian Environmental Protection Act
CERCLA Comprehensive Environmental Response, Compensation, and Liability Act
(EPA)
CFR United States Code of Federal Regulations
CPR Controlled Products Regulations
DSL Domestic Substances List
GWP Global Warming Potential
IARC International Agency for Research on Cancer
ICAO International Civil Aviation Organisation
Inh Inhalation
LC Lethal concentration
LD Lethal dosage
NDSL Non-Domestic Substances List
NIOSH National Institute for Occupational Safety and Health
: 10/15/2014.

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Section 16. Other information

References

TDG Canadian Transportation of Dangerous Goods Act and Regulations

TLV Threshold Limit Value
TSCA Toxic Substances Control Act
WEEL Workplace Environmental Exposure Level
WHMIS Canadian Workplace Hazardous Material Information System
: Not available.

Indicates information that has changed from previously issued version.

Notice to reader
To the best of our knowledge, the information contained herein is accurate. However, neither the above-named
supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the
information contained herein.
Final determination of suitability of any material is the sole responsibility of the user. All materials may present
unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot
guarantee that these are the only hazards that exist.

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: 10/15/2014.

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