RISHI SIR CLASSES

Std-12
Class-12th
Chapter-Solution NCERT SOLUTIONS. 📞 Date : 03/05/24
7355104168,8881010106
Section A
//X
• Write the answer of the following questions. [Each carries 1 Mark] [23]
1. Give an example of solid solution in which the solute is a gas.
2.
3.2) Define the following term : Molality
3. 1) Define the following term : Mole fraction
4. 3) Define the following term : Molarity
5. ) Define the following term : Mass percentage.
6. ) A sample of drinking water was found to be severely contaminated with chloroform (CHCl3 )
supposed to be a carcinogen. The level of contamination was 15 ppm (by mass). Express this in
percent by mass.
7. ) A sample of drinking water was found to be severely contaminated with chloroform (CHCl3 )
supposed to be a carcinogen. The level of contamination was 15 ppm (by mass). Determine the
molality of chloroform in the water sample.
8. What role does the molecular interaction play in a solution of alcohol and water ?
9. Why do gases always tend to be less soluble in liquids as the temperature is raised ?
10. At 27o C temperature, 36 gm glucose is in 1 litre aqueous solution has p = 4.98 bar. Find out
concentration if p = 1.52 bar at same temperature.
11. 1) Suggest the most important type of inter-molecular attractive interaction in the following pair :
n-hexane and n-octane
12. 2) Suggest the most important type of inter-molecular attractive interaction in the following pair :
I2 and CCl4
13. 3) Suggest the most important type of inter-molecular attractive interaction in the following pair :
NaClO4 and water
14. 4) Suggest the most important type of inter-molecular attractive interaction in the following pair :
Methanol and acetone
15. 5) Suggest the most important type of inter-molecular attractive interaction in the following pair :
Acetonitrile (CH3CN) and acetone (C3H6O).
16. Based on solute-solvent interactions, arrange the following in order of increasing solubility in n-
octane and explain. Cyclohexane, KCl, CH3OH, CH3CN.
17.
5.1) Is Phenol compound insoluble, partially soluble and highly soluble in water ? identify.
18.
5.2) Is Toluene compound insoluble, partially soluble and highly soluble in water ? identify.
19. 3) Is Formic acid compound insoluble, partially soluble and highly soluble in water ? identify.

20. 4) Is Ethylene glycol compound insoluble, partially soluble and highly soluble in water ? identify.

21.
5.5) Is Chloroform compound insoluble, partially soluble and highly soluble in water ? identify.
22.
5.6) Is Pentanol compound insoluble, partially soluble and highly soluble in water ? identify.
23. If the density of some lake water 1.25g mol–1 is and contains 92g of Na+ ions per kg of water,
calculate the molality of Na+ ions in the lake.
Don't Stress,Do your Best, Forget the Rest.
 If the density of some lake water 1.25g mol–1 is and contains 92g of Na+ ions per kg of water,
calculate the molality of Na+ ions in the lake.

Section B
//X
• Write the answer of the following questions. [Each carries 2 Marks] [42]
24. Define the term solution. How many types of solutions are formed ? Write briefly about each type
with an example.
25. Concentrated nitric acid used in laboratory work is 68 % nitric acid by mass in aqueous solution.
What should be the molarity of such a sample of the acid if the density of the solution 1.504 gm
L–1 is ?
26. A solution is obtained by mixing 300 g of 25% solution and 400 g of 40% solution by mass. Calculate
the mass percentage of the resulting solution.
27. An antifreeze solution is prepared from 222.6 g of ethylene glycol (C2H6O2) and 200 g of water.
Calculate the molality of the solution. If the density of the solution is 1.072 g mL–1, then what shall
be the molarity of the solution ?
28. A sample of drinking water was found to be severely contaminated with chloroform (CHCl3 )
supposed to be a carcinogen. The level of contamination was 15 ppm (by mass) :
(i) Express this in percent by mass.
(ii) Determine the molality of chloroform in the water sample.
29. The partial pressure of ethane over a solution containing 6.56 × 10–3 g of ethane is 1 bar. If the solution
contains 5.00 × 10–2 g of ethane, then what shall be the partial pressure of the gas ?
30. An aqueous solution of 2 % non-volatile solute exerts a pressure of 1.004 bar at the normal boiling
point of the solvent. What is the molar mass of the solute ?
31. The vapour pressure of water is 12.3 kPa at 300 K. Calculate vapour pressure of 1 molal solution of a
non-volatile solute in it.
32. Calculate the mass of a non-volatile solute (molar mass 40 g) which should be dissolved in 114 g
octane to reduce its vapour pressure to 80%.
33. Two elements A and B form compounds having formula AB2 and AB4 . When dissolved in 20 g of
benzene (C6H6), 1 g of AB2 lowers the freezing point by 2.3 K whereas 1.0 g of AB4 lowers it by 1.3 K.
The molar depression constant for benzene is 5.1 K kg mol–1. Calculate atomic masses of A and B.
34. Suggest the most important type of inter-molecular attractive interaction in the following pairs :
(i) n-hexane and n-octane
(ii) I2 and CCl4
(iii) NaClO4 and water
(iv) Methanol and acetone
(v) Acetonitrile (CH3CN) and acetone (C3H6O).
35. Amongst the following compounds, identify which are insoluble, partially soluble and highly soluble
in water ?
(i) Phenol (iv) Ethylene glycol
(ii) Toluene (v) Chloroform
(iii) Formic acid (vi) Pentanol.
36. If the solubility product of CuS is 6 ´ 10–16, calculate the maximum molarity of CuS in aqueous
solution.
37. Calculate the mass percentage of aspirin (C9H8O4) in acetonitrile (CH3CN) when 6.5 g of (C9H8O4)
is dissolved in 450 g of :

Don't Stress,Do your Best, Forget the Rest.

38. Calculate the amount of benzoic acid (C6H5COOH) required for preparing 250 mL of 0.15 M solution
in methanol.
39. Nalorphene (C19H21NO3), similar to morphine, is used to combat withdrawal symptoms in narcotic
users. Dose of nalorphene generally given is 1.5 mg. Calculate the mass of 1.5 × 10–3 m aqueous
solution required for the above dose.
40. The depression in freezing point of water observed for the same amount of acetic acid,
trichloroacetic acid and trifluoroacetic acid increases in the order given above. Explain briefly.
41. Vapour pressure of water at 293 K is 17.535 mm Hg. Calculate the vapour pressure of water at 293K
when 25 g of glucose is dissolved in 450 g of water.
42. Henry’s law constant for the molality of methane in benzene at 298 K is 4.27 × 105. Calculate the
solubility of methane in benzene at 298 K under 760 mm Hg.
43. Determine the amount of CaCl2 (i = 2.47) dissolved in 2.5 litre of water such that its osmotic pressure is
0.75 atm 27°C at.
44. Determine the osmotic pressure of a solution prepared by dissolving 25 mg of K2SO4 in 2 liter of
water at 25°C, assuming that it is completely dissociated.

Section C
//X
• Write the answer of the following questions. [Each carries 3 Marks] [21]
45. Define the following terms :
(i) Mole fraction
(ii) Molality
(iii) Molarity
(iv) Mass percentage.
46. A solution of glucose in water is labelled as 10% w/w, what would be the molality and mole fraction
of each component in the solution? If the density of solution is 1.2 g mL–1, then what will be the
molarity of the solution ?
47. Heptane and octane form an ideal solution. At 373 K, the vapour pressures of the two liquid
components are 105.2 kPa and 46.8 kPa respectively. What will be the vapour pressure of a mixture
of 26.0 g of heptane and 35 g of octane ?
48. 100 g of liquid A (molar mass 140 g mol–1) was dissolved in 1000 g of liquid B (molar mass 180 g mol–1).
The vapour pressure of pure liquid B was found to be 500 torr. Calculate the vapour pressure of pure
liquid A and its vapour pressure in the solution if the total vapour pressure of the solution is 475 Torr.
49. Vapor pressure of pure acetone and chloroform at 328 K are 741.8 mm Hg and 632.8 mm Hg
respectively. Assuming that they form ideal solution over the entire range of composition, plot P total’
Pchloroform’ and Pacetone as a function of xacetone. The experimental data observed for different
compositions of mixture is :

100 x xacetone 0 11.8 23.4 36.0 50.8 58.2 64.5 72.1

Pacetone / mm Hg 0 54.9 110.1 202.4 322.7 405.9 454.1 521.1

Pchloroform / mm Hg 632.8 548.1 469.4 359.7 257.7 193.6 161.2 120.7

From the question, we have the following data

50. Benzene and toluene form ideal solution over the entire range of composition. The vapour pressure
of pure benzene and toluene at 300 K are 50.71 mm Hg and 32.06 mm Hg respectively. Calculate
the mole fraction of benzene in vapour phase if 80 g of benzene is mixed with 100 g of toluene.
Don't Stress,Do your Best, Forget the Rest.
 Benzene and toluene form ideal solution over the entire range of composition. The vapour pressure
of pure benzene and toluene at 300 K are 50.71 mm Hg and 32.06 mm Hg respectively. Calculate
the mole fraction of benzene in vapour phase if 80 g of benzene is mixed with 100 g of toluene.
51. The air is a mixture of a number of gases. The major components are oxygen and nitrogen with
approximate proportion of 20% is to 79% by volume at 298 K. The water is in equilibrium with air at
a pressure of 10 atm. At 298 K if the Henry’s law constants for oxygen and nitrogen are 3.30 × 107 and
6.51 × 107 respectively, calculate the composition of these gases in water.

Section D
//X
• Write the answer of the following questions. [Each carries 4 Marks] [28]
52. How many mL of 0.1 M HCl are required to react completely with 1 g mixture of Na2CO3 and
NaHCO3 containing equimolar amounts of both ?
53. State Henry’s law and mention some important applications.
54. What is meant by positive and negative deviations from Raoult’s law and how is the sign of DSolH
related to positive and negative deviations from Raoult’s law ?
55. A solution containing 30 g of non-volatile solute exactly in 90 g of water has a vapour pressure of
2.8 kPa at 298 K. Further, 18 g of water is then added to the solution and the new vapour pressure
becomes 2.9 kPa at 298 K. Calculate :
(i) Molar mass of the solute.
(ii) Vapour pressure of water at 298 K.
56. A 5% solution (by mass) of cane sugar in water has freezing point of 271 K. Calculate the freezing
point of 5% glucose in water if freezing point of pure water is 273.15 K.
57. Calculate the depression in the freezing point of water when 10 g of CH3CH2CHCl COOH is added
to 250 g of water. Ka = 1.4 ´ 10–3, Kf = 1.86 K kg mol–1.
58. 19.5 g of CH2FCOOH is dissolved in 500 g of water. The depression in the freezing point of water
observed is 1.0°C. Calculate the Van’t Hoff factor and dissociation constant of fluoroacetic acid.

Don't Stress,Do your Best, Forget the Rest.

 RISHI SIR CLASSES
Std-12
Class-12th
Chapter-Solution NCERT SOLUTIONS. 📞 Date : 03/05/24
7355104168,8881010106

Section [ A ] : 1 Marks Questions

No Ans Chap Sec Que Universal_QueId

1. - Chap 1 S3 2 QP23P11B1212_P1C1S3Q2
2. - Chap 1 S3 3.2 QP23P11B1212_P1C1S3Q3.2
3. - Chap 1 S3 3.1 QP23P11B1212_P1C1S3Q3.1
4. - Chap 1 S3 3.3 QP23P11B1212_P1C1S3Q3.3
5. - Chap 1 S3 3.4 QP23P11B1212_P1C1S3Q3.4
6. - Chap 1 S3 9.1 QP23P11B1212_P1C1S3Q9.1
7. - Chap 1 S3 9.2 QP23P11B1212_P1C1S3Q9.2
8. - Chap 1 S3 10 QP23P11B1212_P1C1S3Q10
9. - Chap 1 S3 11 QP23P11B1212_P1C1S3Q11
10. - Chap 1 S3 22 QP23P11B1212_P1C1S3Q22
11. - Chap 1 S3 23.1 QP23P11B1212_P1C1S3Q23.1
12. - Chap 1 S3 23.2 QP23P11B1212_P1C1S3Q23.2
13. - Chap 1 S3 23.3 QP23P11B1212_P1C1S3Q23.3
14. - Chap 1 S3 23.4 QP23P11B1212_P1C1S3Q23.4
15. - Chap 1 S3 23.5 QP23P11B1212_P1C1S3Q23.5
16. - Chap 1 S3 24 QP23P11B1212_P1C1S3Q24
17. - Chap 1 S3 25.1 QP23P11B1212_P1C1S3Q25.1
18. - Chap 1 S3 25.2 QP23P11B1212_P1C1S3Q25.2
19. - Chap 1 S3 25.3 QP23P11B1212_P1C1S3Q25.3
20. - Chap 1 S3 25.4 QP23P11B1212_P1C1S3Q25.4
21. - Chap 1 S3 25.5 QP23P11B1212_P1C1S3Q25.5
22. - Chap 1 S3 25.6 QP23P11B1212_P1C1S3Q25.6
23. - Chap 1 S3 26 QP23P11B1212_P1C1S3Q26

Section [ B ] : 2 Marks Questions

No Ans Chap Sec Que Universal_QueId

24. - Chap 1 S3 1 QP23P11B1212_P1C1S3Q1
25. - Chap 1 S3 4 QP23P11B1212_P1C1S3Q4
26. - Chap 1 S3 7 QP23P11B1212_P1C1S3Q7
27. - Chap 1 S3 8 QP23P11B1212_P1C1S3Q8
28. - Chap 1 S3 9 QP23P11B1212_P1C1S3Q9
29. - Chap 1 S3 13 QP23P11B1212_P1C1S3Q13

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30. - Chap 1 S3 15 QP23P11B1212_P1C1S3Q15
31. - Chap 1 S3 17 QP23P11B1212_P1C1S3Q17
32. - Chap 1 S3 18 QP23P11B1212_P1C1S3Q18
33. - Chap 1 S3 21 QP23P11B1212_P1C1S3Q21
34. - Chap 1 S3 23 QP23P11B1212_P1C1S3Q23
35. - Chap 1 S3 25 QP23P11B1212_P1C1S3Q25
36. - Chap 1 S3 27 QP23P11B1212_P1C1S3Q27
37. - Chap 1 S3 28 QP23P11B1212_P1C1S3Q28
38. - Chap 1 S3 30 QP23P11B1212_P1C1S3Q30
39. - Chap 1 S3 29 QP23P11B1212_P1C1S3Q29
40. - Chap 1 S3 31 QP23P11B1212_P1C1S3Q31
41. - Chap 1 S3 34 QP23P11B1212_P1C1S3Q34
42. - Chap 1 S3 35 QP23P11B1212_P1C1S3Q35
43. - Chap 1 S3 40 QP23P11B1212_P1C1S3Q40
44. - Chap 1 S3 41 QP23P11B1212_P1C1S3Q41

Section [ C ] : 3 Marks Questions

No Ans Chap Sec Que Universal_QueId

45. - Chap 1 S3 3 QP23P11B1212_P1C1S3Q3
46. - Chap 1 S3 5 QP23P11B1212_P1C1S3Q5
47. - Chap 1 S3 16 QP23P11B1212_P1C1S3Q16
48. - Chap 1 S3 36 QP23P11B1212_P1C1S3Q36
49. - Chap 1 S3 37 QP23P11B1212_P1C1S3Q37
50. - Chap 1 S3 38 QP23P11B1212_P1C1S3Q38
51. - Chap 1 S3 39 QP23P11B1212_P1C1S3Q39

Section [ D ] : 4 Marks Questions

No Ans Chap Sec Que Universal_QueId

52. - Chap 1 S3 6 QP23P11B1212_P1C1S3Q6
53. - Chap 1 S3 12 QP23P11B1212_P1C1S3Q12
54. - Chap 1 S3 14 QP23P11B1212_P1C1S3Q14
55. - Chap 1 S3 19 QP23P11B1212_P1C1S3Q19
56. - Chap 1 S3 20 QP23P11B1212_P1C1S3Q20
57. - Chap 1 S3 32 QP23P11B1212_P1C1S3Q32
58. - Chap 1 S3 33 QP23P11B1212_P1C1S3Q33

Welcome To Future - Quantum Paper

 RISHI SIR CLASSES
Std-12
Class-12th
Chapter-Solution NCERT SOLUTIONS. 📞 Date : 03/05/24
7355104168,8881010106
Section A
//X
• Write the answer of the following questions. [Each carries 1 Mark] [23]
1.

2.

3.

4.

5.

6.

Welcome To Future - Quantum Paper

7.

8.

9.

10.

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11.

12.

13.

14.

15.

16.

17.

18.

19.

20.

21.

22.

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23.

Section B
//X
• Write the answer of the following questions. [Each carries 2 Marks] [42]
24.

25.

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26.

27.

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28.

29.

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30.

31.

32.

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33.

34.

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35.

36.

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37.

38.

39.

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40.

41.

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42.

43.

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44.

Section C
//X
• Write the answer of the following questions. [Each carries 3 Marks] [21]
45.

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46.

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47.

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48.

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49.

50.

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51.

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 Section D
//X
• Write the answer of the following questions. [Each carries 4 Marks] [28]
52.

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53.

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54.

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55.

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56.

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57.

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58.

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Welcome To Future - Quantum Paper