Chem

REVISION ASSIGNMENT
CLASS XII
SOLUTIONS
1. Read the given passage and answer the questions that follow:
Solutions play a very important role in our daily life. Alloys, homogeneous mixture of metal
are solution of solid in solid. 1 ppm (parts per million) of fluoride ions prevent tooth decay.
All intravenous injections must be isotonic with our body fluids, i.e. should have same
concentration as blood plasma. Diabetic patients are more likely to have heart attack and high
blood pressure due to higher glucose level in blood. Common salt increases blood pressure
because Na+ mixes up with blood. Aquatic species are more comfortable in cold water than
warm water.
(a) 0.1 M glucose is not isotonic with 0.1 M KCl solutions. Why?
(b) What will happen if blood cells are placed in saline water (hypertonic solution)?
(c) What will happen if pressure applied on solution side is more than osmotic pressure,
when solvent and solution are separated by semi permeable membrane?
(d) Calculate the molality of ethanol solution in which mole fraction of water is 0.88.
2. 100 mg of protein is dissolved in enough water to make 10 ml solution. osmotic

pressure of solution is 13.3 mm Hg at 250C, find molar mass of protein? (R=0.0821 L
atm mol-1K-1 and 760 mm Hg =1atm) (Ans : 13963.42 g/mol)
3. Calculate the mass of compound( molar mass = 256g/mol) to be dissolved in 75 g of
benzene lower its freezing point by 0.48K ( Kf = 5.12 K kg/mol) (Ans : 18g)
4. A solution is prepared by dissolving 35.0 g of Haemoglobin (Hb) in enough water to
make up 1L in volume. If the osmotic pressure of the solution is found to be 10.0
mmHg at 250 C, calculate the molar mass of haemoglobin. (Ans :64871.2 g/mol)
5. 18 g of glucose (Molar mass=180 g/mol) is dissolved in 1kg of water. At what
temperature will this solution boil? ( Kb = 0.52 K kg/mol , B.P. of pure water=373.15
K) (Ans :373.202 K)
6. A 10% solution (by mass) of sucrose in water has freezing point of 269.15 K.
Calculate the freezing point of 10% glucose in water, if freezing point of pure water is
273.15 K.Given: (Molar mass of sucrose = 342 g mol―1)(Molar mass of glucose =
180 g mol―1)(Ans :265.55 K)
7. Calculate osmotic pressure of 5% solution of cane sugar (sucrose) at 15oC. (Ans.
3.453 atm)
8. On dissolving 10.8 glucose (m.w. = 180) in 240 g of water, its boiling point increases
by 0.13oC. Calculate the molecular elevation constant of water.(Ans. 5.2 oC)
9. By dissolving 13.6 g of a substance in 20 g of water, the freezing point decreased by
3.7oC. Calculate the molecular mass of the substance. [Molal depression constant for
water = 1.863 K kg mol−1] (Ans. 243.39)
10. What is the volume of solution containing 1 g mole of sugar that will give rise to an
osmotic pressure of 1 atmosphere at 0oC ? (Ans. 22.4 litre)
11. Non-ideal solutions exhibit either positive or negative deviations from Raoult’s law.
What are these deviations and why are they caused? Explain with one example for
each type.
12. State Raoult’s law. How is it formulated for solutions of non-volatile solutes?
13. State Henry’s law. Write its two applications.
14. State Raoult’s law for the solution containing volatile components. What is the
similarity between Raoult’s law and Henry’s law?
15. Define azeotropes. What type of azeotrope is formed by positive deviation from
Raoult’s law? Given an example.
16. Give reasons for the following:
a. Measurement of osmotic pressure method is preferred for the determination of

molar masses of macromolecules such as proteins and polymers.
b. Aquatic animals are more comfortable in cold water than in warm water.
1.An antifreeze solution is prepared from 222.6 g of ethylene glycol C2H4(OH)2 and 200
g of water.Calculate the molality of the solution. If the density of this solution be 1.072
gmL-1, what will be the molarity of the solution?
(a) 7.20 M (b) 12.03 M (c) 9.11 M (d) 6 M
2.When mercuric iodide is added to the aqueous solution of potassium iodide, the:
(a) Freezing point is raised
(b) Freezing point does not change
(c) Freezing point is lowered
(d) Boiling point does not change
3. The molal elevation constant depends upon
(a) nature of solute.
(b) nature of the solvent.
(c) vapour pressure of the solution.
(d) enthalpy change.
4.The osmotic pressure of a solution is directly proportional to

(a)the molecular concentration of the solute
(b)the absolute temperature at a given concentration
(c)the lowering of vapour pressure
(d) all the above.
5.Which of the following aqueous solutions containing 10 g of solute in each case, has
highest m.p.?
(a) NaCl solution
(b) KC1 solution
(c) sugar solution
(d) glucose solution
6. Equimolar solutions in the same solvent have-
(a) Same boiling point but different freezing point
(b) Same freezing point, but different boiling point
(c) Same boiling and same freezing point
(d) Different boiling and different freezing points
7. The average osmotic pressure of human bloood is 7.8 bar at 37°C. What is the
concentration of anaqueous solution of NaCl that could be used in blood stream?
(a) 0.15 mol L-1
(b) 0.30 mol L-1
(c) 0.60 mol L-1
(d) 0.45 mol L-1
8.Low concentration of oxygen in the blood and tissues of people living at high altitude is due
to-
(a) low temperature
(b) low atmospheric pressure
(c) high atmospheric pressure
(d) both low temperature and high atmospheric pressure
Assertion- Reason type
(a)If both Assertion and Reason are correct and reason is the correct
explanation ofAssertion .
(b)If both Assertion and Reason are correct and reason is not correct
explanation ofAssertion
(c)If Assertion is correct but Reason is incorrect.
(d)If Assertion is incorrect and Reason is correct.
9.Assertion: An aqueous solution of NaCl freezes below 273 K.

Reason: Vapour pressure of the solution is less than that of the
pure solvent.
10. Assertion: 1 M glucose will have a higher boiling point than 2 M glucose
Reason: Elevation in boiling point is a colligative property which depends upon the
number of particlesof solute in the solution
Revision Assignment
Electrochemistry
1. The value of λ0 m of Al2(SO4)3 is 858 S cm2 mol-1 , while limiting ionic conductivity
of SO4 2- is 160 S cm2 mol-1 . The limiting ionic conductivity of Al3+is:-----------
2. Molar conductivity for NaOH, Al2(SO4)3 and Na2SO4 are a, b and c numerically then
molar conductivity for Al(OH)3 is
a) a+3b-2c/2
b) 6a+b-3c/2
c) 6a-b+3c/2
d) None of these
3. A voltaic cell is set up at 250 C with the following half cells Al 3+
(0.001M) and Ni 2+ (0.50M). Write an equation for the reaction that occurs when the
cell generates an electric current and determine the cell potential.(Given : E0 (Ni2+/
Ni) = -0.25V, E0 (Al3+/ Al) = -1.66V
4. a) Calculate the potential of hydrogen electrode in contact with a solution whose pH is
10.
b) Define molar conductivity. Give its SI unit.
c) Draw a graph between Λm Vs C1/2 for a strong and a weak electrolyte.
5. Predict the product of electrolysis of the following:

i) An aqueous solution of AgNO3 with platinum electrodes.
ii) A dilute solution of H2SO4 with platinum electrodes
6. a)A copper silver cell is set up. The copper ion concentration is 0.10M.
The cell potential was 0.422V. Determine the concentration of silver ions
in the cell.
0
(E
Ag+/Ag E0
= +0.80, Cu2+/Cu = +0.34 V)
7.
8.
9.
10.

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REVISION ASSIGNMENT

2. 100 mg of protein is dissolved in enough water to make 10 ml solution. osmotic

a. Measurement of osmotic pressure method is preferred for the determination of

4.The osmotic pressure of a solution is directly proportional to

Assertion- Reason type

9.Assertion: An aqueous solution of NaCl freezes below 273 K.

5. Predict the product of electrolysis of the following:

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