Levels Structure: of Materials

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Properties 115

Levels of Structure of materials


Engineering lntegroted ciruits Chinese wall
7 structure t 4

II I Diameter of grain or phase boundary Large grain size


r
9 5
6 Microstructure

Phose

M 4 Molecule
Small
- I

Monomers
t
Lorge elementory cells

High polymer
I
I

A 3 Atom U

N 2 Nucleus I+

E I Elementary
particle
U
I I I I I 1 I C
Level of 1~-15 10-12 10-9 10-6 10-3 100 to3
structure Size of structural objects (mi

Figure 1: The seven levels of structure suggested by Hornbogen (4).


Reprinted with permission of Pergamon Press Ltd.

with strength, ductility, hardness, elastic modulus, and the like are properly
called mechanical properties, not physical properties. The latter term is
reserved for electrical conductivity, thermal conductivity, magnetic behavior,
thermoelectric effects, density, melting point, lattice structure, etc. Perhaps
the easiest way to divide non-chemical properties into their proper
categories is simply to remember that properties which relate the
deformation of a metal to a force which caused it are mechanical properties
and all others are physical properties (5).

TENSILE PROPERTIES

The practical significance of the measurement of mechanical


properties lies in the use of these data to predict the performance of a
material in a specific type of application. Properties obtained from tensile
testing are often used for engineering purposes.
A tensile stress-strain curve is constructed from load/elongation
measurements made on a test specimen (6). Typically, original dimensions
are used to calculate the stress based on load measurements and dimensions
of the test specimen. This disregards any thinning or necking during testing
and results in what is referred to as nominal or engineering stress. The
terms true stress and true strain are used when actual dimensions during
testing are used in the calculations (6).
116 Electrodeposition

The shape of a stress-strain curve (Figure 2) is an indication of both


the strength and ductility of a material. The elastic region is the early,
approximately linear portion of the curve (7). In this region material that
is stressed will not suffer any permanent deformation when the stress is
relaxed. The onset of permanent deformation, which is a measure of yield
strength, is that location where the curve leaves the elastic region by
bending toward the horizontal. Beyond this is the inelastic or plastic flow
region of the curve. The slope of the curve in each region provides
information: in the elastic region it is the elastic modulus which is a
measure of the material’s stiffness and in the plastic flow region it is a

Figure 2: A representative stress-strain curve. Adapted from reference 7.

measure of work hardening since a steeper slope means more stress must be
applied to create a given amount of deformation (7). Figure 3 shows the
influence of strain rate on the strength and behavior of depleted uranium.
Stress-strain curves are presented at strain rates of 5000 (dynamic) and
0.001 per second (static). The dynamic, or high strain rate curve reveals a
higher yield point and, initially higher work hardening, followed by lower
work hardening as the material thermally softens (7). Crack-free chromium
is an example of an electrodeposit with a low strain hardening rate. With
this low strain hardening rate, rapid localization of deformation occurs and
this leads to early fracture and an increased wear rate unlike the behavior
noted for conventional chromium deposits (8.9).

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