Journal of Petrochemical Engineering

Department Politeknik Kuching Sarawak

ISSN 2289-8395 Volume 1, Issue 1, 2016

PRODUCTION OF BIODEGRADABLE PLASTIC FROM BANANA PEEL

Deeneshwaran S Manimaran, Kavin raj Nadaraja, John peter Vellu, Vinoth Francisco,
Kalaiarasen Kanesen, Zamri Bin Yusoff

Email: [email protected], [email protected], [email protected],

[email protected]
Department of Petrochemical Engineering,
Politeknik Kuching Sarawak,
Beg Berkunci 3094, KM 22, Jalan Matang, 93050 Kuching, Sarawak.

ABSTRACT
Plastic offers a variety of benefits, in a variety of shapes, such as sheets, panels, film, which can all be flexible
as the application requires. Plastic is a price competitive with other materials that offer similar advantages
in industrial applications, which is why it is used in a number of applications. It is light weight, strong,
visually aesthetic, flexible size and shape, and cheaper price. However, use of too many plastics results in
massive harmful effects. It takes longer time to degrade which is estimated about 500 years to degrade and
will become toxic after decomposed. Plastic pollution can unfavourably affect lands, waterways and oceans.
Humans are also affected by plastic pollution, such as through the disruption of the thyroid hormone axis or
hormone levels. Thus, the biodegradable plastic becomes a promising solution to solve all this problems.
The objective of this study is to produce biodegradable plastic from banana peels as a substitute for the
conventional plastic and to prove that the starch in the banana peel could be used in the production of the
biodegradable plastic. The strength of the film was determined using the elongation test by comparing the
biodegradable film with a control film and a synthetic plastic. In the soil burial degradation test, the intensity
of degradation was tested for all three types of film and the biodegradable film degraded at a rapid rate
compared to control film while the synthetic plastic did not degrade at all. Based on all the testing that was
carried out, the biodegradable film from banana peel is the best and ideal overall compared to the control
and synthetic plastic. Hence, it can be used in the industry for various application such as molding and
packaging, at the same time rescuing the environment from potential harm by synthetic plastics.

Keywords: Plastic, decompose, pollution, biodegradable film, degradation test

1.0 Introduction
Today’s plastics are designed with little consideration for their ultimate disposability or
recyclability. This has resulted in mounting worldwide concerns over the environmental
consequences of such materials when they enter the waste stream after their intended uses, Of
particular concern are polymers used in single use, disposable plastic applications. Plastics are
strong, light-weight, inexpensive, easily processable and energy efficient. They have excellent
barrier properties. They are disposable, and very durable. However, it is these very attributes of
strength and indestructibility that cause problems when these materials enter the waste stream. They
are not readily broken down by the natural elements in the environment or in waste management
infrastructures such as composting to become a part of the biological carbon cycle of our ecosystem.
This results in an irreversible build-up of these materials in the environment causing scaring of
landscapes, fouling of beaches, and posing a serious hazard to marine life. Plastics are resistant to
biological degradation because microorganisms do not have enzymes capable of degrading and
utilizing most man made polymers. In addition, the hydrophobic character of plastics inhibits
enzyme activity and the low surface area of plastics with their inherent high molecular weight
further compounds the problem.

Biodegradable plastics are a new generation of polymers emerging on the world market.
Biodegradable plastics have an expanding range of potential applications, and driven by the
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Journal of Petrochemical Engineering
Department Politeknik Kuching Sarawak
ISSN 2289-8395 Volume 1, Issue 1, 2016

growing use of plastics in packaging and the perception that biodegradable plastics are
‘environmentally friendly’, their use is predicted to increase. However, issues are also emerging
regarding the use of biodegradable plastics and their potential impacts on the environment and
effects on established recycling systems and technologies. The banana fruit’s peel was selected for
this experiment because it is a waste material rich of starch-according to Songklanakarin Journal of
Science and Technology, the proximate composition of a banana peel is shown Table 1.

Table 1: Banana peel content

Item Content (g/100 g dry matter)
Protein 8.6±0.1
Fat 13.1±0.2
Starch 12.78±0.9
Ash 15.25±0.1
Total Dietary Fat 50.25±0.2

According to The Packaging Bulletin Magazine’s January issue, it is a proven fact that starch and
cellulose are important raw materials used in the biodegradable plastic industry (Packaging Bulletin,
2009). Since they are rich with starch and this starch is very easy to extract, potatoes are the most
commonly used raw materials. For this experiment we use different type of material that is banana
peel because it also rich with starch. Actually, banana peel has no scientific name because only
living organisms could have it. Banana could have the scientific name of common banana that is
Musaceae musa. The propane-1, 2, 3-triol used in the experiment functions as a plasticizer, an
additive used to develop or improve the plasticity of a material. It disconnects the polymer chains
from one another; restraining them from becoming rows of chains and acquiring a crystalline
structure. The formation of the crystalline structure is undesired because it is a brittle and fragile
structure which makes the plastic brittle and fragile as well. Instead of the crystalline structure, the
formation of film (not becoming rows of chains of polymers) is desired.

Starch consists of two different types of polymer chains, called amylose and amylopectin, made up
of adjoined glucose molecules. The hydrochloric acid is used in the hydrolysis of amylopectin,
which is needed in order to aid the process of film formation due to the H-bonding amongst the
chains of glucose in starch, since amylopectin restricts the film formation. The sodium hydroxide
used in the experiment is simply used in order to neutralize the pH of the medium.

2.0 Methodology
Methodology consist of extraction of starch from banana peel, production of developing the
biodegradable plastic, biodegradation test of the biodegradable plastic and elongation experiment
of biodegradable plastic.

2.1 Extraction of starch from banana peel

The peels of the bananas were removed using a stainless steel knife and cut into small sizes. The
banana peels were dipped in 0.5% Na2S2O5 solution prior to the boiling processes. An 800ml
beaker was filled with distilled water and placed over a Bunsen burner. The banana peels were
placed in the beaker and were boiled for 30 minutes. After the boiling process, the beaker was
removed from the Bunsen burner and the peels were decanted off the water and placed on and
covered with a dry gauze pad, left to dry for 30 minutes. Using a hand blender, the peels were
pureed until a fluid paste was formed. The fluid paste was filtered to produce banana peel starch.

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Journal of Petrochemical Engineering
Department Politeknik Kuching Sarawak
ISSN 2289-8395 Volume 1, Issue 1, 2016

2.2 Production of developing the biodegradable plastic

The amount of 25ml of banana peel starch was measured and placed in 500ml beaker. After that
3ml of acetic acid was added and the mixture was mixed using a glass stirring rod. And then 2ml
of propan-1, 2, 3-triol was added to beaker. The mixture was stirred again. The mixture was
poured into a petri dish and put in the oven at 60°C. It was baked for half an hour.

2.3 Biodegradation test of the biodegradable plastic

The biodegradable film was cut into 2.5cm x 2.5cm. Then, the film was buried in 5cm depth. At
regular time interval, water will be sprinkled. About 2 days times interval, the specimens from the
soil was taken and washed with distilled water. After that, the specimens was dried and the weight
taken.

2.4 Elongation experiment of biodegradable plastic

The biodegradable plastic was cut. The initial length of the biodegradable plastic was measured
and recorded. The biodegradable plastic was stretched until it higher than initial length. The
length of plastic was measured again and recorded.

3.0 Result and discussion

In this project, the experiment conducted in order to form biodegradable plastic from banana
peel. The plastic was formed after several experiment was made. The plastic sample produced may
not achieving the ideal characteristic of a plastic but it is good in biodegradability as it can be
composted in just 6 days. As the second test that is tensile strength test was made out to prove that
the biodegradable plastic can be stretched as petroleum plastic can be stretched.
To prove that we made the biodegradable plastic moulding process was carried out where the
biodegradable plastic was moulded into several shape and dried until to get the moisture out and
become hard. These results supported my hypothesis, meaning that we succeeded and manufactured
biodegradable plastic from banana peels.

3.1 Degradation test

The biodegradation test was recorded in the Figure 1 as the amount of glycerine against the
mass of the biodegradable plastic mould. Based on figure 1, it shown that the amount of glycerine
increases so the degradation of plastic also much quicker. The amount of glycerine mixed is very
important in making biodegradable plastic it gives elasticity and make the biodegradable plastic
easy to degrade. As the graph stated that Initial weight have been taken is 100 gram with different
amount of glycerine that is 20ml, 25ml and 30ml was used in biodegradable plastic. For the second
day, the weight of the biodegradable plastic contains 20ml glycerine as reduced 0.03g, 25ml
glycerine as reduced 0.8g, and 30ml glycerine as reduced 0.13g. At the fourth day the weight taken
for 20ml glycerine is reduced 2.43g, 25ml glycerine as reduced 3.17, and 30ml glycerine as reduced
3.97g. As the Figure 1 shown the 25ml of glycerine was reduced the amount of weight higher than
the 30ml of glycerine but for the following fourth day the 30ml of glycerine was recorded reduced
higher than 25ml of glycerine. At the last day the 20ml of glycerine was reduced 3.54g, 25ml of
glycerine was reduced 5.12g, and the 30ml of glycerine was reduced 6.60. As the Figure 1 shown
the 30 ml of glycerine is faster degrade than the 25ml and 20 ml of glycerine. As the biodegradation
test happens the darkening of the plastic suggested decay.

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Journal of Petrochemical Engineering
Department Politeknik Kuching Sarawak
ISSN 2289-8395 Volume 1, Issue 1, 2016

Mass (% of mass, g)

Figure 1: The amount of glycerine against the mass of the biodegradable plastic mould.

3.2 Elongation test

Figure 2 shows the elongation test on biodegradable plastic. As the figure 2 showing the
initial length of the biodegradable plastic is 4.5cm and after it been stretched it become 6.5 length
where it is the maximum strength of the biodegradable plastic that has been made. The strength of
a strip of plastic is technically the force it can bear, under tension, per unit cross sectional area of
the film, without breaking. The “cross sectional area” is measured as the width times the thickness.
If want to do is increase the strength of your piece of plastic, the simplest thing to do is make it
thicker: this would allow the piece of plastic to bear a greater load under tension without breaking.
However, it would not increase the strength, which is a technical property of a plastic that doesn’t
change with the size and shape of the piece of plastic you are considering. Tensile testing determines
the amount of stress each material can sustain prior to failure as well as the amount of elongation at
the time of failure.

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Journal of Petrochemical Engineering
Department Politeknik Kuching Sarawak
ISSN 2289-8395 Volume 1, Issue 1, 2016

Figure 2: Elongation test on biodegradable plastic

3.3 Moulding test

Figure 3 shows the biodegradable plastic mould. Moulding is the process of manufacturing
by shaping liquid or pliable raw material using a rigid frame called a mould or matrix. This it may
have been made using a pattern or model of the final object. Moulding is the process of forcing
melted plastic in to a mould cavity. Once the plastic has cooled, the part can be ejected. As the
figure 3 showing the biodegradable plastic that has been made is mouldable into various shape.
Therefore, biodegradable plastic that have been made is a conventional plastic where it can replace
the petroleum based plastic that is most popular amount the plastic moulding.

Figure 3: Biodegradable plastic mould

3.4 Biodegradability test (soil burial method)

The soil burial test provided a realistic environment where soil humidity, temperature, types
and the amount of microorganisms were less in control and changed with seasons. All the tested
films had same shape and size in order to avoid the effects of film’s shape on it biodegradability.
The loss of weight of the films monitored by means of sample collected from the soil at regular
time interval. The films were buried in the soil and the sample was removed for evaluation at 2 days
interval. It was observed that the degradation rate of the banana peel starch films increased
continuously with the increase in the number of the days. Through the result obtained, it was

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Journal of Petrochemical Engineering
Department Politeknik Kuching Sarawak
ISSN 2289-8395 Volume 1, Issue 1, 2016

observed that all the biodegradable bio-composite film expected for degradation process completely
within 90 days whereas the film degraded completely within 15 days.

3.5 Mechanical properties test

A biodegradable composite film must withstand the normal stress encountered during its
application. Elongation at break indicates the flexibility and stretch of the biodegradable composite
films which determined at the point when the composite film breaks under tensile strength. The
elongation at break value increased as the amount of starch increased. The elongation at break
values was increased due to the decreased of banana peel starch crystallinity in the banana peel
starch films. Moreover, the introduction of plasticizer (glycerol) into the films also resulted in
higher elongation values as these decrease the intermolecular attractive force, improving the films
flexibility and extensibility.

4.0 Conclusions
The film were prepared successfully by the mixing and casting method. The characteristics of the
films with different glycerine content (20ml, 25ml, and 30ml) were evaluated using soil burial
degradation test and manual. In soil burial degradation test, the compactness of biodegradable
composite films was destroyed as the degradation time increases. A rapid degradation occurred for
all the films in the initial 6 days, followed by 100% composting within expected 90days. As
conclusion the films produced from banana peels had potential application to be used as food
packaging because it can enhance the food quality and at the same time can protect the environment.

Acknowledgements
We offer our sincerest gratitude to Polytechnic Kuching Sarawak for providing a precious
opportunity to pursue our interest in Diploma in Process Engineering (Petrochemical) by
conducting our final year project in the specified area. Besides that, we owe our deepest gratitude
to our supervisor, Dr. Hj Zamri Bin Yusoff who has supported us throughout our journey
completing our final year project programme with his patience and knowledge whilst allowing us
the room to work with him without any position borders.

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ISSN 2289-8395 Volume 1, Issue 1, 2016

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