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EXAM PAPER
Name : ………………………………….. Batch : ………………………………….
PET-6_EX_CPK_CHEMICAL EQUILIBRIUM_05.09.15

61. If  is the fraction of HI dissociated at equilibrium, starting with one mole of HI, the total number of
moles of H2, I2 and HI at equilibrium is
(A) 2 (B) 2  (C) 1 + 2  (D) 1

62. 0.5 mole each of H2 and I2 are reacted in an evacuated vessel at 445C, to establish the equilibrium
H2 + I2 ⇇ 2HI. The equilibrium constant of the reaction is 64. Then the amount of H 2 remaining
unreacted at equilibrium is
(A) 0.1 (B) 0.40 (C) 0.30 (D) 0.24

63. The equilibrium constant of the reaction

1 1
𝐻2 (𝑔) + 𝐼2 (𝑔) ⇇ 2𝐻𝐼(𝑔) is K1, that for 𝐻𝐼(𝑔) ⇇ 𝐻2 (𝑔) + 𝐼2 (𝑔) is K2 and that for
2 2

𝑛𝐻2 (𝑔)&𝑛𝐼2 (𝑔) ⇇ 2𝑛𝐻𝐼(𝑔) is K3. Then the wrong statement is :

1
− 1
(A) 𝐾2 = 𝐾1 2 (B) 𝐾3 = 𝐾1𝑛 (C) 𝐾1 = (D) 𝐾3 = 𝐾22𝑛
𝐾22

64. A 1000 mL vessel contains 2 M each of P, Q, R and S at equilibrium. If 1 M each of P and Q are
taken out, the value of equilibrium constant for P + Q ⇇ R + S at the same temperature would be
1 1
(A) 2 (B) 1 (C) (D)
2 4

65. Two moles of PCl5 were heated to 227C in a closed two litre vessel, and the extent of dissociation
at equilibrium was found to be 40%. The equilibrium constant Kp of the reaction is
(A) 0.267 atm (B) 1.315 atm (C) 10.95 atm (D) 0.3214 atm

66. In the dissociation of AB2 as 𝐴𝐵2 (𝑔) ⇇ 𝐴𝐵(𝑔) + 𝐵(𝑔), the equilibrium concentration of AB2 is 400
mm and equilibrium constant is 100 mm. The initial concentration of AB 2 was
(A) 600 mm (B) 200 mm (C) 400 mm (D) 800 mm

67. Reactants A and B are mixed in the molar ratio 1 : 1.5 to establish the equilibrium 𝐴 + 2𝐵 ⇇ 2𝐶 + 𝐷.
At equilibrium the concentrations of A and B are found to be equal. The equilibrium constant K C for
the reaction is
(A) 0.25 (B) 4 (C) 1 (D) 2

68. For a reaction to proceed in the backward direction, conditions for reaction quotient is
(A) QC > KC (B) QC < KC (C) QC = KC (D) QC = 0

69. The yield of product in the reaction 𝐴2 (𝑔) + 2𝐵(𝑔) ⇇ 𝐶(𝑔) + 𝑄𝑘𝐽 will be higher at
(A) low temperature and high pressure (B) high temperature and high pressure
(C) low temperature and low pressure (D) high temperature and low pressure

70. The ratio of Kp to KC for the equilibrium reaction 𝑁𝐻4 𝐶𝑙(𝑠) ⇇ 𝑁𝐻3 (𝑔) + 𝐻𝐶𝑙(𝑔) at 300 K is
(A) 24.63 I atm mol–1 (B) 0.0406 I–1 atm–1 mol
(C) 606.6 I2 atm2 mol–2 (D) 1.6 x 10–3 I–2 atm–2 mol2

71. For which one of the following gaseous equilibria will an increase in pressure increase the yield of
the product?
(A) 2HI ⇇ H2 + I2 (B) 2SO2 + O2 2SO3
(C) H2O + CO ⇇ H2 + CO2 (D) H2 + Br2 2HBr

72. In which of the following ‘Kp’ is less than KC.

(A) N2O4 ⇇ 2NO2 (B) 2HI H2 + I 2

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(C) 2SO2 + O2 ⇇ 2SO3 (D) N2 + O2 ⇇ 2NO

73. Which of the following is not effected by change in pressure

(A) N2 + O2 ⇇ 2NO (B) N2 + 3H2 ⇇ 2NH3
(C) PCl5 ⇇ PCl3 + Cl2 (D) 2SO2 + O2 ⇇ 2SO3

74. In the reaction H2(g) + Cl2(g) ⇇ 2HCl(g)

(A) Kp = Kc (B) Kp  Kc (C) Kp > Kc (D) Kp < Kc

75. The equilibrium constant K for the reaction, HA + B ⇇ BH+ + A– is 100. If the rate constant for the
forward reaction is 105, the rate constant for the reverse reaction is
(A) 10–3 (B) 10–5 (C) 107 (D) 103

76. The role of catalyst in a reversible reaction is

(A) It increases the rate of forward reaction
(B) It decreases the rate of backward reaction
(C) It alters the equilibrium constant of the reaction
(D) It allows the equilibrium to be achieved quickly

77. For the equilibrium reaction A(g) + 2B(g) ⇇ C(g) + D(g) the equilibrium constant (Kc) is given by the
expression
[𝐶][𝐷] [𝐶][𝐷]2 [𝐴][𝐵]2 [𝐶][𝐷]
(A) Kc = (B) Kc = (C) Kc = (D) Kc =
[𝐴][𝐵] [𝐴][𝐵] [𝐶][𝐷] [𝐴][𝐵]2

78. N2 + 3H2 ⇇ 2NH3 + 21.8 K.cals. The effect of increase in pressure

(A) increases the rate of forward reaction (B) increases the rate of backward reaction
(C) produces no change in the reaction (D) results in an increase in the volume

79. The equilibrium concentration of C 2H4 in the following gas phase reaction can be increased by
C2H4(g) + H2(g) ⇇ C2H6 (g) H = – 32.7 K. cal
(A) removal of C2H6 (B) removing H2
(C) decrease in temperature (D) increase in pressure

80. In the equilibrium reaction, A + B ⇇ C + D, the activation energy for the forward reaction is 25 K cal
/ mole and that of the backward reaction is 15 K.cal/mole. Which one of the following statements is
correct?
(A) It is an exothermic process (B) It is an endothermic process
(C) It is a reaction for which H = 0 (D) It is a sublimation process

81. The value of Kp for the reaction

2H2 S(g) ⇇ 2H2(g) + S(g) is 1.2 x 10–2 at 1065oC. The value of Kc for this reaction
(A) 1.2 x 10–2 (B) < 1.2 x 10–2 (C) 3 x 10–2 (D) < 3 x 10–2

82. If K1 and K2 are the equilibrium constants of the equilibria (P) & (Q) respectively. What is the
relationship between the two constants?
1
(P) SO2(g) + O2(g) ⇇ SO3(g), K1 (Q) 2SO3(g) ⇇ 2SO2(g) + O2(g), K2
2
1 1
(A) K1 = K2 (B) K1 = (C) K2 = K⬚12 (D) K⬚12 =
𝐾2 𝐾2

83. For the reaction C(s) + CO2(g) ⇇ 2CO(g), the partial pressures of CO 2 and CO are 2.0 and 4.0
respectively at equilibrium. What is the value of Kp for the reaction
(A) 0.5 (B) 4.0 (C) 8.0 (D) 32

84. If the equilibrium constant for the reaction

2AB ⇇ A2 + B2 is 49, what is the value of equilibrium constant for AB ⇇ ½ A2 + ½ B2

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(A) 49 (B) 2.401 (C) 7 (D) 0.02

85. 4 moles of HI is taken in a litre closed vessel and heated till equilibrium is reached. At equilibrium,
the concentration of H2 is 1 mol lit–1. What is the equilibrium constant for dissociation of HI?
1 1
𝐻𝐼(𝑔) ⇇ 𝐻2 (𝑔) + 𝐼2 (𝑔)
2 2
(A) 4 (B) 0.5 (C) 2 (D) 0.25

86. The equilibrium constant for the reaction SO2(g) + ½ O2 ⇇ SO3(g) is 5 x 10–3 atm–1/2. The
equilibrium constant of the reaction 2SO3(g) ⇇ 2SO2(g) + O2(g) would be
(A) 100 atm (B) 200 atm (C) 4 x 104 atm (D) 6.25 x 104 atm

87. Consider the following reaction equilibrium N2(g) + 3H2(g) ⇇ 2NH3(g). Initially, 1 mole of N2 and 3
moles of H2 are taken in a 2 litre flask. At equilibrium state if, the number of moles of N 2 is 0.6, what
is the total number of moles of all gases present in the flask?
(A) 0.8 (B) 1.6 (C) 3.2 (D) 6.4

88. For a chemical reaction at the state of equilibrium, which of the following statements is incorrect?
(A) none of the variables, temperature, pressure or volume appear to change
(B) reaction system has maximum stability with minimum energy content.
(C) addition of catalyst disturbs the point of equilibrium
(D) addition of inert gas at equilibrium for constant pressure system will move the equilibrium in the
direction where more number of moles of gases are present.

89. The equilibrium pressure in the reaction system: 2NF3(g) N2(g) + 3F2(g) is increased ten
times, the equilibrium constant in terms of mole fractions (Kx) would:
(A) increase ten times (B) decrease ten times
(C) increase hundred times (D) decrease hundred times
1
90. AB3(g) is dissociates as AB3(g) AB2(g) + B2(g). When the initial pressure of AB3 is 800 torr
2
and the total pressure developed at equilibrium is 900 torr. What fraction of AB 3(g) is dissociated?
(A) 10% (B) 20% (C) 25% (D) none of these

ANSWERS

61. D 62. A 63. D 64. B

65. C 66. A 67. B 68. A
69. A 70. C 71. B 72. C
73. A 74. A 75. D 76. D
77. D 78. A 79. B 80. B
81. B 82. D 83. C 84. C
85. B 86. C 87. C 88. C
89. D 90. C

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