Grand Test 07 September 2023 (Without Key
Grand Test 07 September 2023 (Without Key
Grand Test 07 September 2023 (Without Key
(c) Basified water (d) diethyl Zinc 107. In bas catalyzed reaction of carbonyl compound
the catalyst
100. Conversion of propyne to acetone requires three
(a) increases the nucleophilic characteristic of
important reagents. Identify which of the
reagent
following is not one of the three?
(a) Water (b) Zinc dust (b) increases the electrophilic characteristic of
carbonyl
(c) H2SO4 (d) HgSO4
(c) acidic character of reagent d) both a and b
101. Which carbonyl compound yields secondary
108. Which of following molecules does not form
alcohols when treated with LiAlH4?
alcohol when reacts with Grignard reagents?
(a) Aldehyde (b) Ketone
(a) Formaldehyde (b) propanal
(c) Carboxylic acid (d) Ester
(c) propanone (d) Carbon dioxide
102. Identify the catalyst in the hydration of alkenes
to produce alcohols. 109. What is the speed of a chemical reaction?
(a) HCl (b) FeCl3 (a) Is independent of the contact surface
(b) Is constant no matter what the temperature
(c) Pt (d) Ni is
103. The hydrolysis of tertiary butyl Chloride has (c) Varies inversely with the absolute
order? temperature
(a) First order (b) pseudo first order (d) Is extremely rapid between the ions in
(c) fractional order (d) zero order aqueous solution
104. What is the correct order of reactivity of 110. Which of the following compound don’t give
alcohols toward reactions involving cleavage of silver mirror test?
C-O bond? (a) CH3CHO (b) CH3COCH2CH3
(a) 1°>2°>3° (b) 3°>2°>1° (c) PhCH2OH (d) both b and c
(c) 1°>3°>2° (d) 3°>1°>2°
111. In wolf-kishner reduction the …… is converted
105. Which statement is wrong? into Methylene carbon
(a) Propan-2-ol dehydrated at high temperature (a) Amide carbonyl carbon
than propan-1-ol
(b) Ester Carbonyl carbon
(b) Methanol is the most reactive towards
(c) Ketone carbonyl
esterification reaction
(d) All of the above
(c) Phenol is more acidic than water
112. Identify the correct statement about enzymes.
(d) Reduction of ketone with Grignard reagent
(a) Enzymes increase the activation energy of a
produces 30 alcohol
reaction
106. The C-O bond in carbonyls is polarised, and (b) Enzymes need to be used in excess
hence the carbonyl carbon and carbonyl oxygen compared to the reagent to catalyze the reaction
act as _________ and ________ respectively. (c) Enzymes work only at their optimum
1
119. Which of the following is not a characteristic (a) kr,Ba,3on (b) O, H, on1
1
feature of a salt bridge? (c)Na, Cl. 5on (d) Th, Ba, 2 on1
(a) Salt bridge joins the two halves of an 129. When electron in H-atom jumps from infinity to
electrochemical cell 3rd orbit the emitted photon will be
(b) It completes the inner circuit (a) ultra valet (b) Infrared
(c) It is filled with a salt solution (or gel) (c) Visible (d) Micro