Aqa 8464c2f QP Jun22 CR

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F
GCSE
COMBINED SCIENCE: TRILOGY
Foundation Tier
Chemistry Paper 2F
Time allowed: 1 hour 15 minutes

Materials
For Examiner’s Use
For this paper you must have:
• a ruler Question Mark
• a scientific calculator
1
• the periodic table (enclosed).
2
Instructions 3
• Use black ink or black ball-point pen.
4
• Pencil should only be used for drawing.
• Fill in the boxes at the top of this page. 5
• Answer all questions in the spaces provided. 6
• If you need extra space for your answer(s), use the lined pages at the end of 7
this book. Write the question number against your answer(s).
• Do all rough work in this book. Cross through any work you do not want to be TOTAL
marked.
• In all calculations, show clearly how you work out your answer.
Information
• The maximum mark for this paper is 70.
• The marks for questions are shown in brackets.
• You are expected to use a calculator where appropriate.
• You are reminded of the need for good English and clear presentation in your answers.
*jun228464c2F01*
IB/M/Jun22/E11 8464/C/2F
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0 1 This question is about the Earth’s atmosphere. box
0 1 . 1 The Earth’s atmosphere contains 21% oxygen.
Draw the bar for oxygen on Figure 1.

[1 mark]
Figure 1
0 1 . 2 What is used to test for oxygen gas?

[1 mark]
Tick () one box.
A burning splint
A glowing splint
Damp litmus paper
Limewater
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IB/M/Jun22/8464/C/2F
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The Earth’s early atmosphere was very different from the Earth’s atmosphere today. box
Figure 2 shows the composition of the Earth’s early atmosphere and of the Earth’s
atmosphere today.
Figure 2
0 1 . 3 The percentages of nitrogen and oxygen in the Earth’s atmosphere today are different
from the Earth’s early atmosphere.
Complete the sentences.
Choose answers from the box.
Use Figure 2.
Each answer can be used once, more than once or not at all.
[2 marks]
decreased increased stayed the same
Since the Earth’s early atmosphere, the percentage of nitrogen in the Earth’s
atmosphere has .
Since the Earth’s early atmosphere, the percentage of oxygen in the Earth’s
atmosphere has .
Turn over ►
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0 1 . 4 The Earth’s atmosphere today contains a small amount of carbon dioxide. box
Why has the percentage of carbon dioxide decreased since the Earth’s
early atmosphere?
[2 marks]
Tick () two boxes.
Dissolved in oceans
Formation of sedimentary rocks
Industrialisation
Respiration
Volcanic activity
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Oxides of nitrogen are produced when nitrogen reacts with oxygen in car engines. box
Figure 3 shows the concentration of oxides of nitrogen in the atmosphere during one
day in a city.
Figure 3
0 1 . 5 Which two times have the highest concentrations of oxides of nitrogen in

the atmosphere?
[2 marks]
0 1 . 6 Suggest why there are the highest concentrations of oxides of nitrogen at these times.
[1 mark]
Turn over ►
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0 2 This question is about fuels. box
Coal deposits were formed from the remains of trees.
0 2 . 1 Name the process in the leaves of trees that uses carbon dioxide.
[1 mark]
0 2 . 2 How is coal formed after trees die?

[1 mark]
Tick () one box.
The trees are burned.
The trees are compressed.
The trees are melted.
Coal contains small amounts of sulfur.
0 2 . 3 Name the gas produced when sulfur burns in oxygen.

[1 mark]
0 2 . 4 Give two problems caused by the gas produced when sulfur burns in oxygen.
[2 marks]
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0 2 . 5 Figure 4 shows the relative amount of electricity generated from different fuel sources box
in the UK from 2012 to 2018.
Figure 4
Describe what happens to the amounts of fuels used to generate electricity

in the UK from 2012 to 2018.
[3 marks]
Turn over for the next question
Turn over ►
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0 3 This question is about ammonia and its compounds. box
A student heated a sample of ammonium chloride.
The equation for the reaction is:
NH4Cl ⇌ NH3 + HCl

ammonium chloride ammonia
0 3 . 1 One product is ammonia.
What is the name of the product with the formula HCl?

[1 mark]
0 3 . 2 Ammonia is a gas.
What is the state symbol for ammonia?

[1 mark]
Tick () one box.
(aq) (g) (I) (s)
0 3 . 3 How does the equation show that the reaction is reversible?

[1 mark]
0 3 . 4 Complete the sentence.

[1 mark]
The forward reaction is endothermic,
so the reverse reaction is .
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0 3 . 5 Complete the sentence. box
Choose the answer from the box.

[1 mark]
concentration rate temperature
Equilibrium is reached when the forward and reverse reactions happen at exactly the
same .
Question 3 continues on the next page
Turn over ►
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The industrial process to produce ammonia uses a catalyst. box
0 3 . 6 Figure 5 shows the reaction profile for the reaction with and without a catalyst.
Figure 5
Which letter represents the activation energy for the reaction with a catalyst?
[1 mark]
Tick () one box.
A B C D
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0 3 . 7 Give one reason why using a catalyst reduces costs. box
Do not answer in terms of activation energy.

[1 mark]
0 3 . 8 Ammonia is in a mixture that is used as a household cleaner.
What is a mixture that has been designed as a useful product called?

[1 mark]
8
Turn over ►
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0 4 A student investigates the effect of concentration on the rate of the reaction between box
sodium thiosulfate solution and hydrochloric acid.
Figure 6 shows the experiment.
The experiment was done in a fume cupboard.
Figure 6
This is the method used.
1. Pour 50 cm3 of sodium thiosulfate solution into a conical flask.
2. Put the conical flask on a black cross drawn on a piece of paper.
3. Pour 10 cm3 of hydrochloric acid into the conical flask and start a timer.
4. Stop the timer when the cross can no longer be seen.
5. Repeat the experiment with different concentrations of sodium thiosulfate solution.
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0 4 . 1 Draw one line from each type of variable to the correct example of the variable box
in this investigation.
[2 marks]
Type of variable Example of variable
Concentration of sodium
thiosulfate solution
Dependent
Temperature of reaction
mixture
Time taken for the cross

to no longer be seen
Independent
Volume of acid
Volume of the flask
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0 4 . 2 The experiment is done at room temperature. box
Figure 7
What is the temperature shown on the thermometer in Figure 7?

[1 mark]
Temperature = °C
Table 1 shows the student’s results.
Table 1
Concentration of sodium Time in

thiosulfate solution in mol/dm3 seconds
0.1 82
0.2 40
0.3 20
0.4 13
0.5 10
0.6 8
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0 4 . 3 Plot the data from Table 1 on Figure 8. box
Draw a line of best fit.

[3 marks]
Figure 8
0 4 . 4 Predict the time taken for the cross to no longer be seen at a concentration
of 0.7 mol/dm3
Use your graph in Figure 8.

[1 mark]
Time = s
0 4 . 5 Complete the sentence.

[1 mark]
As the concentration of sodium thiosulfate solution increases, the time taken for the
cross to no longer be seen .
Turn over ►
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0 4 . 6 In one experiment 0.725 g of sulfur is produced in 20 seconds. box
Calculate the mean rate of the reaction from 0 to 20 seconds.
Use the equation:
mass of sulfur produced in grams

mean rate of reaction =
time in seconds
[2 marks]
Mean rate of reaction =
0 4 . 7 What is the unit for the mean rate of reaction calculated in Question 04.6?
[1 mark]
Tick () one box.
g g/s s s/g
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0 4 . 8 The student did the experiment with 0.15 mol/dm3 sodium thiosulfate solution and box
repeated the experiment three more times.
Table 2 shows the results.
Table 2
Test 1 Test 2 Test 3 Test 4
Time in seconds for the cross to no

60.5 63.2 82.3 65.7
longer be seen
Calculate the mean time for this reaction.
Do not include the anomalous result in your calculation.
Give your answer to 3 significant figures.

[3 marks]
Mean time for the reaction (3 significant figures) = s 14
Turn over ►
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0 5 This question is about hydrocarbons. box
Figure 9 shows a hydrocarbon.
Figure 9
0 5 . 1 Complete the formula for the hydrocarbon shown in Figure 9.

[1 mark]
C H
0 5 . 2 What is the name of the hydrocarbon in Figure 9?

[1 mark]
0 5 . 3 Which homologous series does the hydrocarbon in Figure 9 belong to?

[1 mark]
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0 5 . 4 30 g of another hydrocarbon contains 24 g of carbon. box
Which calculation gives the percentage of carbon in the hydrocarbon?

[1 mark]
Tick () one box.
24 × 30
100
100 × 30
24
24 × 100
30
24
30 × 100
0 5 . 5 Table 3 shows boiling points of some hydrocarbons.
Table 3
Formula of hydrocarbon Boiling point in °C
C2H6 –89
C4H10 0
C6H14 69
C8H18 125
C10H22 174
Describe how the boiling points change as the number of carbon atoms in the
hydrocarbon increases.
[1 mark]
Turn over ►
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Hydrocarbons can be cracked. box
0 5 . 6 Give one condition used to crack hydrocarbons.

[1 mark]
0 5 . 7 Balance the equation for the cracking of C6H14

[1 mark]
C6H14 → C2H6 + C2H4
0 5 . 8 Give one reason why hydrocarbons are cracked.

[1 mark]
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0 5 . 9 Window frames can be manufactured from wood or plastic. box
Table 4 shows the results of a life cycle assessment (LCA) for making one wooden
and one plastic window frame.
Both window frames are the same size.
Table 4
Wooden frame Plastic frame
Total energy used in MJ 9150 9713

TableCoal
4 notand
reproduced
oil used in here
kg due to third-party
5 copyright restrictions
18
Waste produced in kg 16 28
Cost to buy and maintain in £ 147 102
Give three advantages of using wood instead of plastic in the manufacture of

window frames.
[3 marks]
Advantage of wood 1
Advantage of wood 2
Advantage of wood 3
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0 6 A student investigated the colours in a brown ink using chromatography. box
0 6 . 1 Figure 10 shows the apparatus used.
Figure 10
Give two errors made by the student.
Describe the problem each error would cause.

[4 marks]
Error 1
Problem 1
Error 2
Problem 2
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A different student set up the apparatus correctly. box
Figure 11 shows the results.
Figure 11
0 6 . 2 Give two conclusions the student can make from Figure 11 about the four colours
in the brown ink.
[2 marks]
Turn over ►
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0 6 . 3 Why was the green colour still on the start line at the end of the experiment? box
[1 mark]
Tick () one box.
The experiment was left for too long.
The green colour was insoluble in the solvent.
The green spot contained too many colours.
The green spot was too small.
0 6 . 4 A student calculated the Rf value of a colour to be 0.24
The colour moved 1.8 cm from the start line.
Calculate the distance the solvent moved.
Use the equation:
distance moved by colour

Rf =
distance moved by solvent
[3 marks]
Distance moved by solvent = cm 10
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0 7 . 1 Water that is safe to drink is called potable water. box
Compare how easily potable water can be obtained from:
• waste water (sewage)

• ground water (fresh water).
[6 marks]
Turn over ►
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A scientist produced potable water from 150 cm3 of salty water. box
0 7 . 2 Which process can be used to produce potable water from salty water?
[1 mark]
Tick () one box.
Distillation
Electrolysis
Filtration
Sterilisation
0 7 . 3 The salty water contains sodium chloride.
The scientist collected 2.40 g of sodium chloride from 150 cm3 of salty water.
Calculate the concentration of sodium chloride in grams per dm3

[3 marks]
Concentration of sodium chloride = g/dm3 10
END OF QUESTIONS
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ANSWER IN THE SPACES PROVIDED
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Please write clearly in block capitals.

Centre number Candidate number

Time allowed: 1 hour 15 minutes

0 1 . 1 The Earth’s atmosphere contains 21% oxygen.

Draw the bar for oxygen on Figure 1.

0 1 . 2 What is used to test for oxygen gas?

Damp litmus paper

Complete the sentences.

Choose answers from the box.

decreased increased stayed the same

Formation of sedimentary rocks

0 1 . 5 Which two times have the highest concentrations of oxides of nitrogen in

Coal deposits were formed from the remains of trees.

0 2 . 2 How is coal formed after trees die?

The trees are burned.

The trees are compressed.

The trees are melted.

Coal contains small amounts of sulfur.

0 2 . 3 Name the gas produced when sulfur burns in oxygen.

in the UK from 2012 to 2018.

Describe what happens to the amounts of fuels used to generate electricity

Turn over for the next question

A student heated a sample of ammonium chloride.

The equation for the reaction is:

NH4Cl ⇌ NH3 + HCl

0 3 . 1 One product is ammonia.

What is the name of the product with the formula HCl?

What is the state symbol for ammonia?

(aq) (g) (I) (s)

0 3 . 3 How does the equation show that the reaction is reversible?

0 3 . 4 Complete the sentence.

The forward reaction is endothermic,

so the reverse reaction is .

Choose the answer from the box.

concentration rate temperature

Question 3 continues on the next page

Do not answer in terms of activation energy.

0 3 . 8 Ammonia is in a mixture that is used as a household cleaner.

What is a mixture that has been designed as a useful product called?

Turn over for the next question

sodium thiosulfate solution and hydrochloric acid.

Figure 6 shows the experiment.

The experiment was done in a fume cupboard.

This is the method used.

1. Pour 50 cm3 of sodium thiosulfate solution into a conical flask.

2. Put the conical flask on a black cross drawn on a piece of paper.

4. Stop the timer when the cross can no longer be seen.

5. Repeat the experiment with different concentrations of sodium thiosulfate solution.

Type of variable Example of variable

Time taken for the cross

Volume of the flask

Question 4 continues on the next page

What is the temperature shown on the thermometer in Figure 7?

Table 1 shows the student’s results.

Concentration of sodium Time in

Draw a line of best fit.

Use your graph in Figure 8.

0 4 . 5 Complete the sentence.

cross to no longer be seen .