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    Chem Jee Soln Set

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    swatilunawat2017

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    Chem Jee Soln Set

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    5 views2 pages

    Chem Jee Soln Set

    Uploaded by

    swatilunawat2017

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    © All Rights Reserved
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    of 2

    1 (a) Lucas rcagcnt is conc. HCl+ anhyd. ZnCl,.

    2 (c) Step 2: (CH,),C -0H,: (CH),c + H,0


    3. (a) Methyl alcohol (CH,0H) is also known as carbinol. Hence 3° Carbocation
    vinyl carbinol is CH, =CH-CH,OH
    4. (a) 3-methyl pentanol-3 willbe dehydrated most readily Step 3: (CH}); C* +CI(CH,),C -CI
    since it produces tertiary carbonium ion as intermediate. t-Butylchlornde
    10. (d) The two components should be (CH),CONa +
    CH, (CH),(Br. However, tert-alkyl halides tend to undergo
    climination rcaction rather than substitution kcading to
    CHy -CH, - -CH, -CH, the formation ofan alkene, Me,C= CH,
    OH 11. (d)
    12. (d)
    distill
    (C,H,0), Mg+ H,0- ’2C,H,OH+ Mg(OH);
    H,CH; -CH, -C -CH, -CH; (distillate ) (residue j
    13. (a) MnO, being a mild oxidising agent stops the
    5. (C) oxidation of - CH,OH group at aldehyde stage.
    14. () The tertiary alky halide undergo elimination reaction
    6. (c) CH,CHCHl to give alkenes

    7. (d) 2-Phenylethanol, CGHsCH,CH,OH, is a | alonhal CH;


    which can be prepared from C,,HMgBr by treating with
    ethylene oxide(note that HCHO will introduce only one CH -x +NaC,H’
    carbon atom, i.e. it will give C,H,CH,0H and not
    CH3
    C,H,CH,CH,OH).
    CGH,MgBr+ CGHsCH,CH,0H: CH:
    C,H,MgBr +HCHO C,H,CH,OH
    CHC=CH)
    (b) Methyl vinyl ether under anhydrous condition at ronm 2-methyl propene
    iemperature undergoes addition reaction.
    HRr
    OH OH OH
    CH= CH-OCH; ’CH; -CH-0-CH, COOH
    CH,
    Br 15. (d)
    9 (b) Tertiary alcohols react fastest with conc. HCI and 0-cresol Salicylic acid Phenol
    anhydrous ZnCl, (lucas reagent) as its mechanism
    proceeds through the formation of stable tertiary Electron releasing groups(-CH¡, -0CH,-NCH, etc)
    carbocation. intensify the negative charge of phenoxide ion, i.e.,
    Mechanism destablises it hence decrease ionization of parent
    phenol. Therefore decreases acidity while electron
    donating groups(-N0,,-COOH,-CHOetc.)increases
    ÇH, acidity.
    Sep I: CH,C -OH+ H-CI 16. (b) Number ofactive hydrogen in a compound corresponds
    to the number of moles of CII, evolved per mole of the
    CH, Compound.
    2 Methy Propan-2-ol
    -NH,- SH, -0H r -C= CH- CH,Mgl CI
    (CH ) C-OH +Cr (2CH, from - NH,)
    17.(b) 23. (b)
    18. (b) 24. (b) The commercial alcohol is made unfit for drinking by
    mixing in it some copper sulphate (to give it colour)
    -ONa and pyridine (a foul smelling liquid). It is known as
    19. (2) denaturation of alcohol.
    +CO,
    Oxidation
    Sodium 25. (b) CH,CH,CH,CH,OH ’ CH;CH,.CH,CHO
    Phenoxide

    OH OH OCH,
    OH
    H,SOA

    COONa
    26. (a) CH, Sc-CH, CHOH ,
    H,SO4 H,c-c-cH,
    COOH
    Salicylic acid CH, CH,
    27. (c) Electron withdrawing group stabilises the benzene ring
    JCH, CO), 0 due to delocalisation of charge.
    -CH, and-CH,OH are electron donating group and
    hence decrease the stability of benzenering-0CH,
    is weaker electron withdrawing group than -COCH,.
    co--u. Hence-COCH, group more stabilize the phenoxide
    ion at p-position.
    COOH
    +CH,COOH 28. (d) This method is suitable for the preparation ofa wide
    variety of unsymmetrical ethers. The nucleophilic
    Aspirin substitution of halides with alkoxide leads to desired
    (Acetyl Salicylate) product.
    29. (c) Due to presence of methyl alcohol in liquor.
    20. (b) CHçBr +C,H0Na ’CzHs-0-C,Hs
    -NaBr
    Sod. ethoxide diethyl ether 30. () CH-CH, -CH-CH-CH,-CH, HIO4,
    21. (b)
    CH, HNO, COOH
    22. (c) 2CH, -CH, -CHO
    CH,(Oxidation) COOH
    0-Xvlene

    Phenol
    Phenolpthalein
    H5SO4
    (Y

    Phthalic anhydride, X

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