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SECONDARY

ADITYA ACADEMY SR. SECONDARY/ ADITYAACADEMY


PRE-BOARD EXAMINATION 2024-2025

STD -XII
F.M: 70
SUBJECT-CHEMISTRY
TIME: 3 hours
SET: 043/B

General Instructions:
Read the following instructions carefully.
a) There are 33 questions in this question paper with internal choice.
b) SECTION Aconsists of 16 multiple-choice questions carrying Imark each.
c) SECTION B consists ofS very short answer questions carrying 2 marks each.
d) SECTION Cconsists of 7 short answer questions carrying 3 marks each.
e) SECTION Dconsists of 2 case- based questions carrying 4 marks each.
) SECTION E consists of 3 long answer questions carrying 5 marks each.
g) Allquestions are compulsory.
h) Use of log tables and calculators is not allowed
SECTION-A

solution?
1. Which of the following condition is not satisfied by an ideal

AHmixing =0 (b) AVmixing 0 (c) Raoult's Law is obeyed

(Formation of an azeotropic mixture


not present in DNA?
DNA & RNA contains four bases each. Which of the following bases is

(a) Adenine 6) Uracil (c) Thymine (d) Cytosine


molecular shape i.e. fibrous
3. Proteins can be classified into two types on the basis of their
protein and globular proteins. Examples of globular proteins are:
Insulin (b) Keratin (c) Collagen (d) Myosin

O4. Which of the following is a secondary cell?


these
(a) Dry cell (b) Lead storage battery (c) Mercury cell ( Allof
5. Which order of reaction obeys the relation t1n =[A]o/2Ka
(a) First (b)Second (e) Zero (d) Third

6: The order of reactions is determined by


(a) Temperature (b) Reaction mechanism, and relative reactant concentrations,
Molecularity (d) Pressure.
7. Identify the correct naming for Ka[PdCla].
(a)Potassium tetrachlorinepalladium([) (b)Potassium tetrachlorinepalladate (l1)
ofotassium tetrachloridopalladium(11) () Potassiunm tetrachloridopalladate(11)
8. The total no of possible isomers for the complex [Co(NH)(Cl):] are
(a) 3 (b) 4 (c) 6
9. CuSO4 solution on treatment excess of KI gives white precipitate. The precipitate is
(a) Cul, (b) Cuzl, (c) Cu2SO4

D0. Which of the following compounds will show retention (100%) in configuration on
nucleophilic substitution by hydroxide ion?
(a) Br BI (©) Br (d) CH,Br
HCH, H
CHs H
CH H|CH,

CoH13 CH, ,Hs

1). ldentify Xand Y:

1. CHCI/NaOH CO, gas


X
2. Dil. HCI 400 K. 7 atm

OH OH
(a) OH OH (b)
X= Y= X= Y=
COOH
CHO COOH HO

OH OH
OH OH
(c) COOH
CHO COOH

CHO

The product of hydrolysis of ozonide of 1-butene are


saj Propanaland methanal Ethanal and methanal (c) Ethanol only (d) Methanal only
13. Which one of thefollowing is always true about the spontaneous cell reaction in a galvanic
cell ?
(a) AB'cell >0, AG <0 (b) AE'cell <0, AG'<0 oAEell > 0, AG° > 0
(d) AEOcell < 0, AG°<0

2
one of the following amines cannot be identified by carbylanminc test?
(a)CH;NH2 (b) CH,CH,NH, 6 (CH)2NH (d) CoH_NH2
15. Assertion: When NaCl is added to water a depression in freczing point is observed.
Reason :The lowering of vapour pressure of a solution causes depression in the freezing
point.
a. Both Aand R are true and R is the correct explanation of A
w. Both A and R are true but R is not the correct explanation of A.
c. A is true but R is false.
d. A is false but R is true.
I Assertion: Alcohol and carboxylic acid are distinguished by sodium bicarbonate test
Reason: An aqueous solution of NaHCO; produces brisk effervescence due to the
evolution of CO; with a carboxylic acid.
a. Both A and R are true and R is the correct explanation ofA
b. Both Aand R are true but R is not the correct explanation of A.
C. A is true but R is false.
d. A is false but R is true.
SECTION-B

does conductivity changes with dilution and why?


Writedown Faraday's lst law of electrolysis.
OR
2A
Calculate the time (in minute) to deposit 1.27g of copper at cathode when a current of
Cu-63.5g/mol, IF = 96500
was passed through the solution of CuSO4. [Molar mass of
Cmol]
respect to reactant Y.
A reaction is of 1 order with respect to reactant X and of 2nd order with
How is the rate affected when

The concentration of Y alone is increased to three times.


Mi) The concentration of both X and Y are doubled
CaHsNH,
19. Arange the following- CoHsNH2, (CzHs)2NH, (CHs);N,
Vi)In increasing order of basic strength in water.
Yín decreasing order of basic'strength in gas phase.
(20 Complete and balance the following chemical equation
( Cn0, + Fez* + H* ’
+ S²+ H

A. Write the major product ofthe following: CI

CH,0H
PCI_ AgNO,

HO
3
SECTION-C

dissolving 25g of KzSO, in 2 L


22 Determine the osmotic pressure of a solution prepared by
R-0.082 L-atm K'mol', atomic
of water at 25'C assuming complete dissociation. [Given
mass of K=39 g & S=32 g mol']
V3. Formulate the electrochemical cell representing the reaction T 12 32416 126
Cr (s) + Fe (aq) ’ C (ag) + Fe(s)
Calculate E®celland Ecel at 25°C if[CP]=0.IM and [Fe]=0.01M
[given Ecc-0.74V and E FeFe=-0.44 V)
24. a) Give reason
, )Alkyl halides though polar are immiscible in water.
M)Chloroform nceds to be stored in dark coloured air tight bottle.
) Give one suitable chemical test todistinguish between Chlorobenzene and Cyclohexyl
chloride.

(2s.GYGive mechanism for the acid catalysed dehydration of alcohol to form alkene.
CH,
i) B,H
ii)NaOH/H,02
ii) H,0
H
NaH
26 a) Give complete equation for the following reaction
A Phenol reacts with ethyl bromide in presence of NaOH.
)Bthyl magnesium bromide reacts with formaldehyde to produce an alcohol.
Y) Riemer-Tiemann reaction
a) Predict the reagent for the following conversion in one step
i)Acetylene to acetaldehyde i)Toluene to benzoic acid
iii) Propanone to propane iv) Benzene to benzaldehyde Csott
b) What happens when acetone react with 2,4-DNP
OR
Benzoic acid, 4-Nitröbenzoic acid,4-Methoxybenzoic acid,3,4-Dinitrobenzoic acid
arrange in increasing order of acid strength.
C¾SCHO, CGH;CHO0,HHO Arrange the following compounds in increasing order
of reactivity towards nucleophilic addition reaction.
()Write short notes on H.V.Z reaction
(RA) Write areaction which shows that five -OH group is present in glucose.
C) What do you mean by reducing and non-reducing sugar? Give one example each
What do you mean by zwitter ion.
4
SECTION-D

29. Read the passage given below andanswer the following questions:
group 3 to 12 and are known
The d-block of the periodic table contains the elements of the
configuration of these elements is (n-1)
as transition elements. In general, the electronic
receive electrons
dns, The d-orbitals of the penultimate energy level in their atoms However, Zn,
3d. 4d and Sd series.
giving rise to the three rows of the transition metals i.e,
elements. Transition elements exhibit certain
Cd and Hg are not regarded as transition
formation, formation of
characteristic properties like variable oxidation states, complex
coloured ions, alloys, catalytic activity etc.
exhibits +l oxidation state most
(2Which metal in the first transition series (3d series)
frequently and why?
aqueous solution? [1]
b Why is Ti* ion coloured while Sc ion is colourless in
(2]
(c) Explain the following observations: have low melting point.
WThe transition metals Zn, Cd and Hg quite soft and
transition elements are virtually the
)The metallic radii of the third (5d) series of series.
second
sme as those of the corresponding members of the
atom undergo areaction in the presence
130Atdehydes and ketones containing at least one a- H aldehydes
ketones. ß -hydroxy
of dilute alkali as catalyst to form ß- hydroxy aldehydes and
collectively called ketols. On heating the
are called aldols while B-hydroxy ketones are
reaction is called aldol
molecule loses water togive a-ß unsaturated carbonyl compound. The
atom then it
condensation. However, if the carbonyl compound does not contain any a-H
respectively.
willundergo disproportionation reaction to give alcohols and carboxylic acid
Then the reaction is called Cannizzaro reaction.

(arWhich combination of carbonyl compounds gives 1-phenylbut-2-en-1-one by an aldol


condensation?

Ph

() Acetophenone and Formaldehyde (ii)Acetophenone and acetaldehyde


,i) Benzaldehyde and acetaldehyde (iv) Benzaldehyde and acetone
Name<one aliphatic and one aromatic aldehyde that do not undergo aldol condensation
reaction.

. (c) iy
dil. Na0H
2(CH3).CCHO

dil. NaOH/A
SECTION-E

. Carry out the following conversion [2+2+1]


Benzoic acid to aniline (i)Aniline to phenol
(6) Give a suitable chemical test to distinguish betvween
) Dimethylamine &Methylamine 1) Aniline & Ethylamine
\e) Write short notes on - Hoffmann bromamide reaction
OR
(a) Write the structure of the following compound A, B & C: (3+2]
Sn/HCI HNO, CzHsOH
(i) CoHsNO2 A B

KCN LiAlH4 HNO2


(ii) CH3Cl ’ A B C

(b) Account for the following


(i) FriedelCraft reaction is not possible for aromatic amines.
(ii)Aniline cannot be prepared by Gabriel's Phthalimide synthesis
32. (a) A first order reaction takes 20 minutes for 25% decomposition. Calculate the time when
75% ofthe reaction willbe completed. [Given log2-0.301, log3-0.477]
[3+1+1]
(b) Write two differences between order and molecularity of a
reaction.
(c) Define rate of a reaction. What is the unit of rate constant 'k'
for a first order reaction?
OR
((aThe rate of a reaction becomes four times when the temperature changes
3Y3K. Calculate the value of activation energy assuming that it does fromn293K to
not change with
temperature. [Given log 2 =0.301, R= 8.3 14 JK-'mol']
6) Define the following terms- JMalf-life, i) Thresholdenergy
[3+2]
,33. (a) Co(SO4)C1.SNH; exist in two isomeric form A and B. Isomer A
give white ppt, but does not react with BaClz. Isomer B react react with AgNO3 to
but does not react with AgNO3.Answer the with BaCl2 to give white ppt,
following
() Identify A and Band write their IUPAC name with
formula.
(ii) Name the typeof isomerism involved.
(b) Write the state of hybridisation, structure and
complexes magnetic þehaviour of,the following
() [MnCl4) () (Fe(CN)aJt
OR [2+3]
(a) Using IUPAC norms write the name of the
n-2- 1: 0. following complexes:
CrNH,)hlaen)]Ci o Ks[Fe(C;04):)
(b}Draw the sructure of one isomer and state what type of
the following complexes- isomeric relation they have for
(Co(en)>Cl]* (iTCo(NH3)6][Cr(CN)6]
, ( With the help of crystal field theory write down the electronjc configuration of Co (III)
[Atomic no-27] in presence of (jYstrong field ligand and (jif weak field ligand. [2+2+1]
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