Adobe Scan Dec 24, 2024
Adobe Scan Dec 24, 2024
Adobe Scan Dec 24, 2024
STD -XII
F.M: 70
SUBJECT-CHEMISTRY
TIME: 3 hours
SET: 043/B
General Instructions:
Read the following instructions carefully.
a) There are 33 questions in this question paper with internal choice.
b) SECTION Aconsists of 16 multiple-choice questions carrying Imark each.
c) SECTION B consists ofS very short answer questions carrying 2 marks each.
d) SECTION Cconsists of 7 short answer questions carrying 3 marks each.
e) SECTION Dconsists of 2 case- based questions carrying 4 marks each.
) SECTION E consists of 3 long answer questions carrying 5 marks each.
g) Allquestions are compulsory.
h) Use of log tables and calculators is not allowed
SECTION-A
solution?
1. Which of the following condition is not satisfied by an ideal
D0. Which of the following compounds will show retention (100%) in configuration on
nucleophilic substitution by hydroxide ion?
(a) Br BI (©) Br (d) CH,Br
HCH, H
CHs H
CH H|CH,
OH OH
(a) OH OH (b)
X= Y= X= Y=
COOH
CHO COOH HO
OH OH
OH OH
(c) COOH
CHO COOH
CHO
2
one of the following amines cannot be identified by carbylanminc test?
(a)CH;NH2 (b) CH,CH,NH, 6 (CH)2NH (d) CoH_NH2
15. Assertion: When NaCl is added to water a depression in freczing point is observed.
Reason :The lowering of vapour pressure of a solution causes depression in the freezing
point.
a. Both Aand R are true and R is the correct explanation of A
w. Both A and R are true but R is not the correct explanation of A.
c. A is true but R is false.
d. A is false but R is true.
I Assertion: Alcohol and carboxylic acid are distinguished by sodium bicarbonate test
Reason: An aqueous solution of NaHCO; produces brisk effervescence due to the
evolution of CO; with a carboxylic acid.
a. Both A and R are true and R is the correct explanation ofA
b. Both Aand R are true but R is not the correct explanation of A.
C. A is true but R is false.
d. A is false but R is true.
SECTION-B
CH,0H
PCI_ AgNO,
HO
3
SECTION-C
(2s.GYGive mechanism for the acid catalysed dehydration of alcohol to form alkene.
CH,
i) B,H
ii)NaOH/H,02
ii) H,0
H
NaH
26 a) Give complete equation for the following reaction
A Phenol reacts with ethyl bromide in presence of NaOH.
)Bthyl magnesium bromide reacts with formaldehyde to produce an alcohol.
Y) Riemer-Tiemann reaction
a) Predict the reagent for the following conversion in one step
i)Acetylene to acetaldehyde i)Toluene to benzoic acid
iii) Propanone to propane iv) Benzene to benzaldehyde Csott
b) What happens when acetone react with 2,4-DNP
OR
Benzoic acid, 4-Nitröbenzoic acid,4-Methoxybenzoic acid,3,4-Dinitrobenzoic acid
arrange in increasing order of acid strength.
C¾SCHO, CGH;CHO0,HHO Arrange the following compounds in increasing order
of reactivity towards nucleophilic addition reaction.
()Write short notes on H.V.Z reaction
(RA) Write areaction which shows that five -OH group is present in glucose.
C) What do you mean by reducing and non-reducing sugar? Give one example each
What do you mean by zwitter ion.
4
SECTION-D
29. Read the passage given below andanswer the following questions:
group 3 to 12 and are known
The d-block of the periodic table contains the elements of the
configuration of these elements is (n-1)
as transition elements. In general, the electronic
receive electrons
dns, The d-orbitals of the penultimate energy level in their atoms However, Zn,
3d. 4d and Sd series.
giving rise to the three rows of the transition metals i.e,
elements. Transition elements exhibit certain
Cd and Hg are not regarded as transition
formation, formation of
characteristic properties like variable oxidation states, complex
coloured ions, alloys, catalytic activity etc.
exhibits +l oxidation state most
(2Which metal in the first transition series (3d series)
frequently and why?
aqueous solution? [1]
b Why is Ti* ion coloured while Sc ion is colourless in
(2]
(c) Explain the following observations: have low melting point.
WThe transition metals Zn, Cd and Hg quite soft and
transition elements are virtually the
)The metallic radii of the third (5d) series of series.
second
sme as those of the corresponding members of the
atom undergo areaction in the presence
130Atdehydes and ketones containing at least one a- H aldehydes
ketones. ß -hydroxy
of dilute alkali as catalyst to form ß- hydroxy aldehydes and
collectively called ketols. On heating the
are called aldols while B-hydroxy ketones are
reaction is called aldol
molecule loses water togive a-ß unsaturated carbonyl compound. The
atom then it
condensation. However, if the carbonyl compound does not contain any a-H
respectively.
willundergo disproportionation reaction to give alcohols and carboxylic acid
Then the reaction is called Cannizzaro reaction.
Ph
. (c) iy
dil. Na0H
2(CH3).CCHO
dil. NaOH/A
SECTION-E