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    Adobe Scan 29-Jun-2023

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    Sudhir Kumar
    1. The document discusses Markovnikov's rule for addition reactions and how the negative part of the molecule being added attaches to the carbon of the double bonded atoms. 2. It asks which reaction follows Markovnikov's rule out of several options and which compound will have the highest melting point out of several dichlorobenzene options. 3. It also addresses questions about the order of boiling points of alkyl halides, why alkyl halides are immiscible in water despite being polar, and cyanide ion acting as a stronger nucleophile from the carbon or nitrogen end.

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    Adobe Scan 29-Jun-2023

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    Sudhir Kumar
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    1. The document discusses Markovnikov's rule for addition reactions and how the negative part of the molecule being added attaches to the carbon of the double bonded atoms. 2. It asks which reaction follows Markovnikov's rule out of several options and which compound will have the highest melting point out of several dichlorobenzene options. 3. It also addresses questions about the order of boiling points of alkyl halides, why alkyl halides are immiscible in water despite being polar, and cyanide ion acting as a stronger nucleophile from the carbon or nitrogen end.

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    1. The document discusses Markovnikov's rule for addition reactions and how the negative part of the molecule being added attaches to the carbon of the double bonded atoms. 2. It asks which reaction follows Markovnikov's rule out of several options and which compound will have the highest melting point out of several dichlorobenzene options. 3. It also addresses questions about the order of boiling points of alkyl halides, why alkyl halides are immiscible in water despite being polar, and cyanide ion acting as a stronger nucleophile from the carbon or nitrogen end.

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
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    17 views1 page

    Adobe Scan 29-Jun-2023

    Uploaded by

    Sudhir Kumar
    1. The document discusses Markovnikov's rule for addition reactions and how the negative part of the molecule being added attaches to the carbon of the double bonded atoms. 2. It asks which reaction follows Markovnikov's rule out of several options and which compound will have the highest melting point out of several dichlorobenzene options. 3. It also addresses questions about the order of boiling points of alkyl halides, why alkyl halides are immiscible in water despite being polar, and cyanide ion acting as a stronger nucleophile from the carbon or nitrogen end.

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    addendum (thc (b) CH.

    (CH),CI>cH(CH),CI
    20. The ncgative part of the
    molccule to be added ) adds on to the
    carhon atom () (CH)iCl > CHCH,
    is known as (dy Cil:(CH);Cl>CH;CH,CHCICH,
    of the double atoms. This rule
    (a)Satzcfrs rulc (b) Peroxide rule 28. Arrange the following compounds in decreasing
    (c) Markovnikov's (d)Hoffman ruBe. order of their boiling points.
    21. Which of the following reaction follows ()CH,Br (ii) CH;CH,Br
    Markovnikov's rule? (iii) CH,CH,CH,Br (iv) CH,CH,CH,CH2Br
    (a)CzH4 + HBr (b) C;He + CI; (a) (i)>(i)>(ii)>(iv)
    (c) CzHs+ HBr (d) CaH, + Brz (b) (iv) >(iii)>(i1)>()
    CH=H-CH, (o) (i)> (iii)> (i)> (iv)
    + X in the reaction is
    (d) (ii)> (iv)>()> (i)
    - HBr
    29. Which of the following compounds will have
    OH highest melting point?
    Br Br
    (a)Chlorobenzene (b)0-Dichlorobenzene
    CH-CH,CH, CH,-H-CH, (c) m-Dichlorobernzene (d)p- Dichlorobenzene
    density
    30. Choose the correct increasing order of
    (a) (b) of the following compound.
    (a) C;H,CI<C,H,l<CH2Cl,<CCl,
    Br Br (b) CH,l<C,H;CI<CH,Cl;<CCl4
    CH,-H-CH, (c) C;H,1< C,H,ClkCCl,<CHClh
    CH-CH,CH, (d)CCl4<CH-Cl;<CaHl<CzH,ClI
    though
    (c) 31. Alkyl halides are immiscible in water
    they are polar because.
    Br
    (a) they react with water to given alcothols
    water.
    (b) they cannot form hydrogen bonds with
    23. ldentify the products Xand Y formed in the (c)C- X bondcannot be broken easily
    reactive.
    following reaction. (d) they are stable compounds and are not
    CH3-CH2-CH=CH-CH3+HCI+X+Y 32. Cyanide ion acts as an ambident nucleophile.
    AX= CH,CH-CHCH,CH,CU, From which end it açts as a stronger nucleophile in
    Y= CACH,- CH -CH,CE, aqueous medium?
    from carbon
    BX=CH,CH, CH- CH,CH, Y= CH,CH,CH, CH- CH, a) It acts as.a stronger nuclophile
    CH CACH, end.
    CX= CH;CH; CH CHCHs, Y= CHs CH
    b) It acts as a stronger nucleophile from nitrogen
    end.
    D
    X=CiCH, - CH, - CH = CH CH, Y= CH,CH, CH= CH halide.
    - CE;CI (c) It depends on the nature of the alkyl
    (d) It has same strength form both the ends.
    24. Methyl bromide reacts with AgF to give methyl 33. Indentify the products (A) and (B) in the
    fluoride and silver bromide. This reaction-is called. reaction.
    (a) Fitting reaction (b)Swarts reaction RX + AgCN ’ (A) +AgX
    (c) Wurtz reaction (d) Finkelstein reaction. RX + KCN ’ B)_+ KX
    highest
    25. Which of the following molecules has (a) (A) - RCN, (B)-RCN
    dipole moment? (b) (A)-RCN, (B)-RNC
    (a)CH,CI (b) CH,Cl, (c) (A)-RCN, (B)-RCN
    (c) CHCls (a) cC4 (d) (A)-RNC, (B)-RNC
    26. Which of the following compounds has the 34. Butane nitrile can be prepared by heating
    highest boiling point?
    (b) CH3CH,CH,CH,CI
    (a) propyl alcohol with KCN
    (a) CHsCHzCI (b) butyl chloroide with KCN
    (c) CH;CH(CH:)CH,C! (d) (CH3)3CCI (c) butyl alcohol with KCN
    27. Which one of the following is not correct order (d) propyl chloride with KCN
    of boiling points of the alkyi/arey halides? chlortde
    35. Ethy! alcohol is obtained when cthyl
    (a)CHCl, > CHzCla boiled with

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