SAFETY DATA SHEET

Prepared in accordance with Regulation No 1907/2006 (REACH) as amended

BASE OILS SN-100, SN-150, SN-500, SN-650

Made on: 14.01.2019 Updated on: - Version: 1.0 CLP Page 1 of 9

SECTION 1. IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING

1.1. Product identifier

Trade name: BASE OILS SN-100, SN-150, SN-500, SN-650

Name: Distillates (petroleum), hydrotreated heavy paraffinic

CAS no.: 64742-54-7
EC no.: 265-157-1
Index no.: 649-467-00-8
REACH registration no.: 01-2119484627-25-006

1.2. Relevant identified uses of the substance or mixture and uses advised against
Relevant identified uses: Base oils are used for the production of lubricating oils, oil products, lubricants,
plasticizers, car chemistry products, anti-caking products for spraying artificial fertilizers, as emulsifier for water-
asphalt dispersion in the construction industry

Uses advised against: other uses are not recommended

1.3. Details of the supplier of the safety data sheet

Manufacturer: Polski Koncern Naftowy ORLEN S.A.
Address: 09-411 Płock, ul. Chemików 7
Phone/Fax +48 (24) 365 00 00; fax: +48 24 365 40 40
No.:
E-mail: [email protected]

Distributor: ORLEN OIL Sp. z o.o.

Address: 31-323 Kraków, ul. Opolska 114
Phone/Fax +48 12 66 555 00 / +48 12 66 555 01
No.: Quality-related information: phone +48 24 201 03 67 or +48 13 438 44 15
E-mail: [email protected]
1.4. Emergency telephone number:
In case of emergency call 112 ( Emergency number), 998 ( Fire Brigade), 999 ( Ambulance Service)
National Help Center for the Transport of Hazardous Materials - SPOT: +48 (24) 365 70 32 and (24) 365 70 33

SECTION 2. HAZARDS IDENTIFICATION

2.1. Classification of the substance or mixture

Classification According to Regulation (EC)
risks No. 1272/2008 (CLP):
resulting from physicochemical Not classified as hazardous
properties:
for humans: Not classified as hazardous
for environment: Not classified as hazardous

2.2. Label elements

Pictogram: None
Signal word: None
Hazard statements: None
 SAFETY DATA SHEET
Prepared in accordance with Regulation No 1907/2006 (REACH) as amended
BASE OILS SN-100, SN-150, SN-500, SN-650

Made on: 14.01.2019 Updated on: - Version: 1.0 CLP Page 2 of 9

Precautionary statements: None

2.3. Other hazards

The substance does not meet PBT or vPvB criteria as per Annex XIII. Flammable product, high ignition
temperature. Exposure to high concentrations of vapours or mists of oil may cause irritation of respiratory tract
mucous membranes and eyes. Prolonged or repeated direct contact may cause skin irritation. In the event of a
release of large amounts of oils, they can pose a risk to aquatic organisms due to their limited biodegradability.

SECTION 3. COMPOSITION / INFORMATION ON INGREDIENTS

3.1. Substances:

Substance name/ REACH CAS No/ EC % wt. Index number Classification according to EC Regulation
registration number No No.1272/2008 (CLP)
Distillates (petroleum), 265-157-1/ <100 649-467-00-8 Not classified as hazardous
hydrotreated heavy
64742-54-7
paraffinic; Unspecified
base oils
01-2119484627-25-XXXX

A complex mixture of hydrocarbons obtained by hydrotreatment of crude oil fraction in the presence of a catalyst. Contains mostly
C20 to C50 hydrocarbons. It contains a relatively great amount of saturated hydrocarbons.

Base oils applied are not classified as carcinogenic. DMSO extract content (according to IP 346) <3%. Based on its viscosity
product does not pose aspiration hazard.
3.1. Mixtures: - not applicable

SECTION 4. FIRST AID MEASURES

4.1. Description of first aid measures

Inhalation:
Remove the victim (move/carry) from the exposure area to fresh air and keep warm and quiet. Place an
unconscious person in he recovery position, loosen tight parts of clothes; control and maintain patency of the
airways. Give oxygen in the case of breathing disorders; if not breathing, use artificial ventilation. In the case of
loss of consciousness, respiratory disorders or persisting symptoms obtain medical aid immediately.
Skin contact:
Immediately remove contaminated/soaked clothes and shoes. Thoroughly wash contaminated skin with soapy
water or mild detergent, and then rinse with water. Consult a doctor if irritation symptoms appear and persist.
NOTE: Take off contaminated/soaked clothes and remove it to a safe place, far from heat and ignition sources.
Eye contact:
Flush the contaminated eyes with running water, remove contact lenses (if worn) and continue flushing for
approx. 15 minutes. When flushing, keep the eyelids wide open and move the eyeball. Consult a doctor if
symptoms appear and persist.
NOTE: Do not use a stream of water which is too strong, it may damage the cornea.
Ingestion:
Obtain medical aid immediately. DO NOT induce vomiting – increased aspiration risk. In the case when
spontaneous vomiting occurs, keep the victim leaning forward, with her/his face directed to the ground. If the
victim is conscious, let her/him drink 200 ml of liquid paraffin. Do not give milk, fat or alcohol.
 SAFETY DATA SHEET
Prepared in accordance with Regulation No 1907/2006 (REACH) as amended
BASE OILS SN-100, SN-150, SN-500, SN-650

Made on: 14.01.2019 Updated on: - Version: 1.0 CLP Page 3 of 9

4.2. Most important symptoms and effects, both acute and delayed
Refer also to section 11 of the SDS.
4.3. Indication of any immediate medical attention and special treatment needed
Do not induce vomiting and do not give anything by mouth to an unconscious person. Show the safety data
sheet or label / packaging to medical personnel providing assistance. Persons providing assistance in an area of
unknown concentration of vapor / mist should be equipped with appropriate respiratory protection
Indications for a doctor: symptomatic treatment.

SECTION 5. FIREFIGHTING MEASURES

5.1. Extinguishing media

Suitable extinguishing media: carbon dioxide, dry powder, foam; water spray or water fog.
Unsuitable extinguishing media: water jet.
5.2. Special hazards arising from the substance or mixture
Flammable liquid of high ignition point. In the fire environment smokes containing carbon oxides and other
unidentified thermal decomposition products of higher hydrocarbons are formed. Avoid breathing products being
released in the fire environment - they may be hazardous for health.
5.3. Advice for fire fighters
Proceed in accordance with procedures applicable for extinguishing chemical fire. In the case of fire involving
great amounts of the product, remove all bystanders not participating in action; call emergency brigades and the
Fire Brigade.
Cool the containers exposed to fire or high temperature with water spray from a safe distance, if possible and
remove them from the endangered area.
Prevent the wastewater after fire extinguishing from penetrating sewage and water tanks. Remove wastewater
and residue after firefighting in accordance with valid regulations.
People participating in the fire-extinguishing action should be properly trained, equipped with a full protective
clothing and a self-containing breathing apparatus.

SECTION 6. ACCIDENTAL RELEASE MEASURES

6.1. Personal precautions, protective equipment and emergency procedures

Use individual protection measures – see section 8 of the Safety Data Sheet.
Limit the access of bystanders to the endangered area until proper cleaning operations are finished. In the case
of great leakage isolate the endangered area. Ensure that breakdown and its results are eliminated by a properly
trained staff only.
Avoid contact with the eyes, skin and clothes. Do not inhale vapours or mist. If release occurred in closed area,
ensure adequate ventilation/ airing.
NOTE: Spilled oils can make surfaces slippery. Remove ignition sources, extinguish open fire, do not smoke.
6.2. Environmental precautions
If it is possible and safe, stop or limit product release. Limit spreading of the great leakages by embanking the
area. Prevent the product from penetrating drains, waters or soil. Notify respective authorities (occupational
safety and hygiene, emergency brigades, environmental brigades and organs of administration).
6.3. Methods and material for containment and cleaning up
Cover up small spillage with non-flammable, neutral absorbent material (sand, soil, diatomic earth, vermiculite)
and collect in an appropriate, closed, labelled waste bin. Clean the contaminated area with water with detergent,
and then rinse with water. Pump off large amounts of liquid. Dispose of according to the applicable regulations.
If necessary, obtain help from specialist companies dealing with waste transport and utilisation in order to
remove the product/absorbent material contaminated with the product. Use the services of professional waste
transport/ utilization companies.
6.4. Reference to other sections
See also sections 8 and 13 of the Safety Data Sheet.
 SAFETY DATA SHEET
Prepared in accordance with Regulation No 1907/2006 (REACH) as amended
BASE OILS SN-100, SN-150, SN-500, SN-650

Made on: 14.01.2019 Updated on: - Version: 1.0 CLP Page 4 of 9

SECTION 7. HANDLING AND STORAGE

7.1. Precautions for safe handling

Provide effective ventilation. Avoid contact with the eyes, skin and clothes. Avoid vapour and fog inhalation. Keep
unused containers tightly closed.
Essential hygiene rules should be observed: do not eat, drink or smoke during work, wash hands with soapy
water after work/after break in work. Do not use contaminated clothing; Immediately remove contaminated
clothing and wash before reuse. NOTE: Take off contaminated/soaked clothes and remove it to a safe place, far
from heat and ignition sources. Use individual protection measures in accordance with the information contained
in section 8 of the Safety Data Sheet.
7.2. Conditions for safe storage, including any incompatibilities
Store in tightly sealed and properly labelled containers, in a cool, well ventilated place with a non-absorbing ground.
The product may be stored in storage tanks in accordance with applicable regulations. Store far from heat sources,
protect from direct sunlight. Protect against contamination and water accumulation. Keep away from strong
oxidisers. Storage temperature: -20 – 400C.
7.3. Specific end use(s)
None.

SECTION 8. EXPOSURE CONTROL AND PERSONAL PROTECTION EQUIPMENT

8.1. Control parameters

The substance has no occupational exposure limit values established on the Community level.

Legal basis: Commission Directive 2006/15/EC, 2000/39/EC, 2009/161/EC, 2017/164/EU.

Please check also national legislation.

8.2. Exposure controls
Recommended methods of exposure assessment in the air:
- PN-Z-04008-7:2002 – “Air purity protection -- Sampling methods -- Principles of air sampling in work place and
interpretation of results”
- PN-Z-04108-6:2006 „Air purity protection -- Determination of mineral oil (liquid phase aerosol) in work places by
absorption spectrometry method in ultra-violet ”.
-PN-Z-04108-5:2006 „Air purity protection -- Tests for content of oils -- Determination of mineral oil (liquid phase of
aerosol) in work places by absorption spectrometry method in infra-red”

Appropriate engineering controls:

General ventilation and / or local exhaust to maintain the concentration of the harmful agent in the air below the
established concentration limits. Local exhaust is preferred, since it enables emission control at source and
prevents spreading throughout the working area.
Eye/ face protection:
Use tightly fitting protective glasses (goggles). It is recommended to equip a working place with an eyewash
station with water to rinse the eyes.
Skin protection:
In case of prolonged contact wear impermeable, oil resistant gloves (e.g. perbutane, viton, butyl rubber). The
selection of the glove material should be made taking into account the breakthrough time (recommended:
minimum 30 minutes), permeation rate (recommended: minimum level 2) and degradation. It is recommended
to regularly change gloves and replace them immediately, if there are any signs of wear, damage (tearing,
perforation) or changes in appearance (color, elasticity, shape). Wear an apron or protective clothing made of
coated, product-resistant materials; oil-resistant and non-slip protective footwear.
Respiratory protection:
Not required under normal conditions of use. If the concentrations exceed the admissible exposure values or the
ventilation is inadequate, use an approved respirator with an appropriate filter or a filtering and absorbing
equipment. In case of working in confined space, insufficient oxygen content in the air, high uncontrolled
 SAFETY DATA SHEET
Prepared in accordance with Regulation No 1907/2006 (REACH) as amended
BASE OILS SN-100, SN-150, SN-500, SN-650

Made on: 14.01.2019 Updated on: - Version: 1.0 CLP Page 5 of 9

emissions or other circumstances, when the mask does not give sufficient protection, use a breathing apparatus
with independent air supply.
Thermal hazards:
Not applicable
Environmental exposure controls:
It should be considered to take precautions to protect the area around the storage tanks.

SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

9.1. Information on basic physical and chemical properties

a) Appearance : Clear liquid/ colour: colourless/pale yellow to dark brown
b) Odour : Faint, characteristic
c) Odour threshold : Not applicable
d) pH : Not applicable
e) Melting/solidification temperature : SN 100: max. -15°C
SN 150: max. -12°C
SN 500: max. -9°C
SN 650: max. -9°C
f) Initial boiling temperature and melting : 350 - 580 ˚C
temperature range
g) Flash point : SN 100: min. 190°C
SN 150: min. 210°C
SN 500: min. 220°C
SN 650: min. 240°C
h) Evaporation rate : Not determined
i) Flammability (solid, gas) : Not applicable
j) Upper/lower flammability limit or upper/lower : flammability of oil mist at a concentration of approx. 45
explosion limit g/cm3
k) Vapour pressure : <0.1 hPa w 20°C
l) Vapour density : Not determined
m) Relative density : SN 100: 0.860 g/cm3 w 15°C
SN 150: 0.870 g/cm3 w 15C
SN 500: 0.889 g/cm3 w 15°C
SN 650: 0.894 g/cm3 w 15°C
n) Solubility : Insoluble in water, soluble in hydrocarbons
o) Partition coefficient n-octanol/ water : log Kow 3.9-6 (estimated)

p) Auto-ignition point : Not determined

q) Decomposition temperature : Not determined
r) Kinematic viscosity : SN 100: 3,8-4,3mm2/s (100 oC), min. 20,5mm2/s (40 oC)
SN 150: 5,0-5,5mm2/s (100 oC), 28,8-33.5 32mm2/s(40 oC)
SN 500: 10,5-12mm2/s (100 oC), min. 80mm2/s (40 oC)
SN 650: 13 -16,2mm2/s (100 oC), min. 135mm2/s (40 oC)
s) Explosive properties : Not applicable
t) Oxidizing properties : Not applicable

9.2. Other information

None

SECTION 10. STABILITY AND REACTIVITY

10.1. Reactivity
 SAFETY DATA SHEET
Prepared in accordance with Regulation No 1907/2006 (REACH) as amended
BASE OILS SN-100, SN-150, SN-500, SN-650

Made on: 14.01.2019 Updated on: - Version: 1.0 CLP Page 6 of 9

The product is not reactive.

10.2. Chemical stability
The product is stable under normal conditions, at ambient temperature and under normal pressure.
10.3. Possibility of hazardous reactions
None known.
10.4. Conditions to avoid
High temperature, open flame and other ignition sources.
10.5. Incompatible materials
Strong oxidisers
10.6. Hazardous decomposition products
Not known.

SECTION 11. TOXICOLOGICAL INFORMATION

11.1 Information on toxicological effects

Acute toxicity:
Classification criteria have not been met based on the available data.
LD50: > 5000 mg/kg (oral, rat)
LC50: >5 mg/l (inhalation, rat, 4h)
LD50: >5,000 mg/kg (skin, rabbit)
In normal conditions, due to its high boiling point and low vapour pressure, the product poses hazard by little
inhalation. It may occur in the case of exposure to vapour released from heated product or mists. Intoxication by
ingestion is unlikely due to organoleptic properties.

Skin corrosion/irritation:
Based on available data, the classification criteria are not met. Prolonged contact with the product may cause
skin irritation
Serious eye damage/irritation:
Based on available data, the classification criteria are not met.
Respiratory or skin sensitisation:
Based on available data, the classification criteria are not met.
Germ cell mutagenicity:
Based on available data, the classification criteria are not met.
Carcinogenicity:
Based on available data, the classification criteria are not met.
Reproductive toxicity:
Based on available data, the classification criteria are not met.
STOT – single exposure:
Based on available data, the classification criteria are not met.
Accidental ingestion may cause stomach upset (nausea, vomiting, abdominal pain); irritation of the
gastrointestinal tract. High concentrations of vapours/mist may cause moderate irritation of the respiratory tract
mucosa (sore throat, cough), headache, dizziness and nausea; at prolonged exposure breathing disturbances,
central nervous system disorders, disturbances in the coordination of movements, disorientation, drowsiness, loss
of consciousness.
 SAFETY DATA SHEET
Prepared in accordance with Regulation No 1907/2006 (REACH) as amended
BASE OILS SN-100, SN-150, SN-500, SN-650

Made on: 14.01.2019 Updated on: - Version: 1.0 CLP Page 7 of 9

STOT-repeated exposure
Based on available data, the classification criteria are not met. Repetitive or prolonged exposure may cause
drying, cracking or chronic inflammation of the skin. Prolonged exposure to vapours may cause neurotoxic
disorders.
Aspiration hazard:
Based on available data, the classification criteria are not met for a substance of viscosity ≥20.5 mm2/s at 40°C.

SECTION 12. ECOLOGICAL INFORMATION

12.1. Toxicity:
Aquatic environment:
NOEL: ≥10000 mg/l - acute toxicity test on fresh-water invertebrate; Daphnia magna, 48h
NOEL: 100 mg/l - chronic toxicity test on invertebrates; Daphnia magna, 21 days
NOEL: ≥100 mg/l - acute toxicity test on fresh-water algae; Pseudokirchinella subcapitata, 72h
NOEL: ≥100 mg/l - acute toxicity test on fresh-water fish; Pimephales promelas , 96h
NOEL: >1000 mg/l - hronic toxicity test on fresh-water fish; Oncorhynchus mykiss , QSAR, 28
days
Sediment:
Toxicity test on sediment microorganisms: n/a (test scientifically unjustifiable)
Land environment:
Chronic toxicity test on invertebrates: n/a (test scientifically unjustifiable)
Toxicity test on plants: n/a (test scientifically unjustifiable)
Toxicity test on birds: n/a (test scientifically unjustifiable)

12.2. Persistence and degradability

Biodegradation potential: hardly biodegradable (31.13% in 28 days)
Hydrocarbons which penetrate into air photo-degrade rapidly by reaction with hydroxyl radicals when
exposed to sunlight. The half-life is shorter than 1 day.
12.3. Bioaccumulative potential
Not applicable – UVCB substance.
Bioaccumulation factor (BCF) is not determined. Studied proved that for some petroleum products this factor
slight due to their poor solubility.
It is potentially considered that components of this group of product can bioaccumulate.
12.4. Mobility in soil
Adsorption/desorption test – not applicable – UVCB substance .
12.5. Results of PBT and vPvB assessment
PBT or vPvB criteria according to Annex XIII of REACH Regulation have not been met.
12.6. Other adverse effects
The product is classified as harmful to aquatic organisms. Hydrocarbons of which this product is composed have
low tendency or no tendency to penetrate to the atmosphere. The product is insoluble in water and lighter than
water. It accumulates on the water surface creating a layer impeding the exchange of oxygen. Hydrocarbons of
higher molecular mass may be sedimented in water. The product is limitedly dispersed in soil; it may penetrate
into soil and contaminate surface waters.
SECTION 13. HANDLING OF WASTES

13.1. Waste treatment methods

 SAFETY DATA SHEET
Prepared in accordance with Regulation No 1907/2006 (REACH) as amended
BASE OILS SN-100, SN-150, SN-500, SN-650

Made on: 14.01.2019 Updated on: - Version: 1.0 CLP Page 8 of 9

Recommended waste code: 13 08 99* Oil wastes not specified in other groups. Wastes not otherwise specified

NOTE: Since waste code is assigned based on the source of origin, the end user should define the obtained wastes
and assign a proper code, taking into consideration specific conditions of use, in accordance with applicable
regulations.
Do not dispose to sewer. Avoid contamination of surface and ground waters. Consider reuse. Waste product
should be recovered or utilised at professional, approved furnaces or waste recycling/neutralization facilities, in
accordance with applicable regulations.
Recovery / recycling / utilisation of package wastes should be performed according to the applicable regulations.
NOTE: Only completely emptied and cleaned packages may be returned for recycling. Use services of authorised
companies.
Legal basis: Directive 2008/98/EC, 94/62/EC.

SECTION 14. TRANSPORT INFORMATION

The substance is not a subject to transport regulations on hazardous goods included in ADR (road transport), RID (rail
transport), IMDG (marine transport) and ICAO/IATA (air transport).
14.1. UN number Not applicable
14.2. UN Proper shipping name Not applicable
14.3. Transport hazard class(es) Not applicable
14.4. Packing group Not applicable
14.5. Environmental hazards Not applicable
14.6. Special precautions for users Not applicable
14.7. Transport in bulk according to Annex II of MARPOL Not applicable
and the IBC Code

SECTION 15. REGULATORY INFORMATION

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18 December 2006 concerning the
Registration, Evaluation, Authorization and Restriction of Chemicals (REACH), establishing a European Chemicals Agency,
amending Directive 1999/45/EC and repealing Council Regulation (EEC) No 793/93 and Commission Regulation (EC) No
1488/94 as well as Council Directive 76/769/EEC and Commission Directives 91/155/EEC, 93/67/EEC, 93/105/EC and
2000/21/EC as amended.
Regulation (EC) No 1272/2008 of the European Parliament and of the Council of 16 December 2008 on classification,
labelling and packaging of substances and mixtures, amending and repealing Directives 67/548/EEC and 1999/45/EC, and
amending Regulation (EC) No 1907/2006 (Text with EEA relevance) as amended.
Commission Regulation (EU) No 2015/830 of 28 May 2015 amending Regulation (EC) No 1907/2006 of the
European Parliament and of the Council on the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH)
(Text with EEA relevance).
Directive 2008/98/EC of the European Parliament and of the Council of 19 November 2008 on waste and repealing
certain Directives.
European Parliament and Council Directive 94/62/EC of 20 December 1994 on packaging and packaging waste.

15.2. Chemical safety assessment

Not required.
 SAFETY DATA SHEET
Prepared in accordance with Regulation No 1907/2006 (REACH) as amended
BASE OILS SN-100, SN-150, SN-500, SN-650

Made on: 14.01.2019 Updated on: - Version: 1.0 CLP Page 9 of 9

SECTION 16. OTHER INFORMATION

Abbreviations and acronyms in the Safety Data Sheet

TLV-TWA Threshold Limit Value
TLV-STEL Threshold Limit Value, Short Term Exposure Limit
TLV-C Ceiling exposure limit
vPvB very Persistent, very Bioaccumulative (substance)
PBT Persistent, bioaccumulative, and toxic (substance)
PNEC Predicted No Effect Concentration
DN(M)EL Derived No Effect Level
LD50 Dose that will kill 50% of the test animals
LC50 Concentration that will kill 50% of the test animals
ECX Concentration at which x% inhibition of growth or growth rate is observed
LOEC Lowest Observed Effect Concentration
NOEL No Observed Effect Concentration
RID Regulations Concerning the International Carriage of Dangerous Goods by Rail
ADR Agreement on Dangerous Goods by Road
IMDG International Maritime Transport of Dangerous Goods
IATA International Air Transport Association
UVCB Unknown substances, of Variable Composition, or of Biological Origin
References:
Legal regulations quoted in sections 2 – 15 of the Safety Data Sheet.
Chemical safety assessment report for the mixture ingredients.

The list of applicable H-phrases in Section 3

None

The full text of CLP classification:

none

Advice on training for employees:

Employees who use the product should be trained on risks for health, hygiene, use of individual protection,
accident preventive actions, rescue actions, etc.,

Additional information: Classification was made on basis of data for hazardous ingredients content by calculation
method according to the guidelines of Regulation 1272/2008 / EC (CLP) with amendments.

This SDS is not a quality certificate for the product. All data presented in this sheet are to be taken only as a help in
safe handling in transport, distribution, use and storage. Persons handling the product should be informed about risks
and precautionary measures. Information in the Safety Data Sheet relates to the above mentioned product and its
specified uses only. They may be obsolete or insufficient for this product used in conjunction with other materials or in
different applications than those specified in the Safety Data Sheet.
The user is obliged to follow all applicable standards and regulations and is also responsible for inappropriate use of
information contained in this sheet or for an inappropriate use of the product. In the case of special applications
evaluate exposure and develop the appropriate procedure and training programs in order to ensure safety at work.