Safety Data Sheet

According to Regulations (EC) No 1907/2006(REACH), Annex II as amended

regulation (EU) No. 2015/830
Trade Name : SP-RP-Oil
Version No. : 3.1, Nov 2015
st
Revision Date : 1 December 2020
Product Use : Industrial Use Only.

1.0 Identification of the substance/mixture and of the company/undertaking

1.1 Product Identifier
Rust Preventive Oil.
Mixtures/Article
Trade Name/ Designation: - SP-RP-Oil
REACH No. A registration number is not available for this article, as the article or its uses are
exempted from registration
CAS-No.: Not Applicable.
Other Means of Identification
Contact corrosion prevention Oil / Corrosion Preventing oil /Rust Preventing oil

1.2 Relevant Identified Uses of the Substance or Mixture and Uses advised against
Relevant Identified Uses
Corrosion Prevention Oil.
Uses advised against
This product is not recommended for any use other than the Identified Uses.

1.3 Details of the Supplier of the Safety Data Sheet

Supplier – Manufacturer
Safepack Industries Ltd., India.
Street : A-Symphony, 210, Ashok Nagar, Range Hills Road, Pune. INDIA.
Postal Code : 411 020
Telephone No : +91-20-25560200.
Telefax No : +91-20-25560888.
Information Contact : [email protected], www.safepack.com

1.4 Emergency Telephone Number

+91-20-25560200. (IST 11.00am to 3.00pm)

2.0 Hazards Identification

2.1 Classification of the Substance or Mixture
Product definition : Oil
Classification according to Regulation (EC) No 1272/2008(CLP/GHS)
Product being Article, according to REACH, not classified according to CLP regulation.

2.2 Label Elements

Labeling accordance with article 32(6) Regulation (EC) No. 1272/2008 [CLP]
Hazard Pictograms

Exclamation mark (GHS07)

Harmful, if swallowed 4
Causes skin irritation 2
Causes eye irritation 2B

Signal word
Warning

Hazard Statements
H303 - May be harmful, if swallowed.
H315 - Causes skin irritation
H320 - Causes Eye irritation

Precautionary Statements
P210 - Keep away from heat/spark/open flames/hot surface – No Smoking.
P234 - Keep only in original packing.
P264 - Wash arms and face thoroughly after handling.
P261 - Avoid breathing dust
P270 - Do not eat, drink or smoke when using this product.
P271 - Use only outdoors or in a well-ventilated area

Supplemental Hazard Information : Not applicable

Page 1 of 8 AP/SP/016/001
Safety Data Sheet
According to Regulations (EC) No 1907/2006(REACH), Annex II as amended
regulation (EU) No. 2015/830
Trade Name : SP-RP-Oil
Version No. : 3.1, Nov 2015
st
Revision Date : 1 December 2020
Product Use : Industrial Use Only.

Annex XVII- Restriction on : Not applicable. Product does not content any dangerous substances.
manufacture, placing on the
market and use of certain
dangerous substance, mixtures
and articles.

2.3 Other hazards

None. Restricted to professional users.
Labeling according to Regulation (EC) No. 1272/2008(CLP)
Refer section 16.0

3.0 Composition/ Information on Ingredients

3.1 Base oil blended with Vapor/Volatile Corrosion Inhibitors (VCI).

3.2 Article
Regulation (EC) No. 1272/2008
Description:
The Article contains no substances that fulfill criteria of PBT, vPvB & SVHC Candidate list of REACH. Mixture of
substances listed below with non hazardous additions.
Also comply TRGS-615 & RoHS.

Ingredients
Distillated (Petroleum) Hydrotreated Light
Formula : Mix of Hydrocarbons.
Molecular Weight : 143
EC No : Not Applicable.
CAS No. : 64742-47-8
Weight : 55-80%
Classification 1272/2008 [CLP] : Acute Tox.4; H302, Acute Tox.4; H332, Eye Irrit. 2B; H320

Rust Preventing Additive (trade secret)

Formula : Mixture of sulphonate.
EC No : Mixture
CAS No. : Mixture
Weight : 5-30%
Classification 1272/2008 [CLP] : H302, Acute Tox.4; H332, Eye Irrit. 2B; H320.

The specific identity and/or exact percentage (concentration) of composition has been withheld as a trade secret.

Additional information
Full text of H- and EU H-phrases: see section 16.0

4.0 First-aid Measures

4.1 Description of first aid measures
General information
When in doubt or if symptoms are observed, get medical advice. If unconscious place in recovery position and seek
medical advice.
After inhalation
Remove victim out of the danger area. Remove casualty to fresh air and keep warm and at rest. Where appropriate
artificial ventilation. In case of respiratory tract irritation, consult a physician.
In case of skin contact
Change contaminated, saturated clothing. After contact with skin, wash with plenty of water and soap. In case of
skin irritation, consult a physician.
After eye contact
Rinse immediately carefully and thoroughly with eye-bath or water. Remove contact lenses, if present and easy to
do. Continue rinsing. In case of eye irritation consult an ophthalmologist.
After ingestion
Call a physician immediately. Rinse mouth thoroughly with water. Never give anything by mouth to an unconscious
person or a person with cramps.
Self-protection of the first aider
Protect your self against exposure to chemicals or blood-borne diseases by wearing gloves and eye protection.
After providing first aid wash your exposed skin with soap and water.
Notes for Doctor
Please Refer Safety Data Sheet

Page 2 of 8 AP/SP/016/001
Safety Data Sheet
According to Regulations (EC) No 1907/2006(REACH), Annex II as amended
regulation (EU) No. 2015/830
Trade Name : SP-RP-Oil
Version No. : 3.1, Nov 2015
st
Revision Date : 1 December 2020
Product Use : Industrial Use Only.

4.2 Most important symptoms and effects, both acute and delayed
No information available.

4.3 Indication of any immediate medical attention and special treatment needed
First Aid, decontamination, treatment of symptoms.

5.0 Firefighting Measures

5.1 Extinguishing Media
The product itself does not burn. Co-ordinate fire-fighting measures to the fire surroundings.
Suitable Extinguishing Media-Foam, Extinguishing powder. Carbon dioxide (CO2). Water spray, Water mist.
Unsuitable Extinguishing Media-Strong Water jet.

5.2 Special hazards arising from the Substance or Mixture

Hazardous Combustion Products
In case of fire may be liberated: Carbon dioxide (CO2). Carbon monoxide. Nitrogen oxides (NOx). Smoke and
other incomplete combustion products.

5.3 Advice for firefighters

No action shall be taken involving any personal risk or without suitable training.
Special protective equipment for firefighters
Wear a self-contained breathing apparatus and chemical protective clothing.

5.4 Additional information

Do not inhale explosion and combustion gases. Move undamaged containers from immediate hazard area, if it can
be done safely. Use water spray to protect personnel and to cool endangered containers. Collect contaminated fire
extinguishing water separately. Do not allow entering drains or surface water.

6.0 Accidental Release Measures

6.1 Personal precautions, protective equipment and emergency procedures
Use personal protection equipment. Remove persons to safety. Avoid contact with skin, eyes and clothes. Provide
adequate ventilation. Wear breathing apparatus if exposed to vapours/dusts/aerosols. Special danger of slipping by
leaking/spilling product.

6.2 Environmental precautions

Cover drains. Do not allow to enter into surface water or drains. Do not allow to enter into soil/subsoil. Make sure
spills can be contained, e.g. in sump pallets or kerbed areas. In case of escape or entry of larger quantities into
waterways, soil or drains, inform the responsible authorities.

6.3 Methods and material for containment and cleaning up

For containment- Not applicable.
For cleaning up- Not applicable.

6.4 Reference to other sections

See Section 8 for information on appropriate personal protective equipment.
See Section 12 for environmental precautions.
See Section 13 for additional waste treatment information.

7.0 Handling and Storage

7.1 Precautions for safe handling
Wear personal protection equipment. (see chapter 8). Use only in well-ventilated areas. Open and handle
container with care. Always close containers tightly after the removal of product. Avoid contact with skin, eyes and
clothes. Avoid breathing vapour/mist.
Protective measures
Fire prevent measures
Usual measures for fire prevention.
Environmental precautions
Do not allow to enter into surface water or drains. Do not allow to enter into soil/subsoil. Shafts and sewers must be
protected from entry of the product.
Advices on general occupational hygiene
When using do not eat, drink, smoke. Wash hands before breaks and after work. Do not put any product-
impregnated cleaning rags into your trouser pockets. Use protective skin cream before handling the product.
Transport Temperature-Ambient condition

7.2 Conditions for safe storage, including any incompatibilities

Packaging Materials- Not applicable.
Requirements for storage rooms and vessels

Page 3 of 8 AP/SP/016/001
Safety Data Sheet
According to Regulations (EC) No 1907/2006(REACH), Annex II as amended
regulation (EU) No. 2015/830
Trade Name : SP-RP-Oil
Version No. : 3.1, Nov 2015
st
Revision Date : 1 December 2020
Product Use : Industrial Use Only.

Keep tightly wrapped & store in a cool, well-ventilated place. Protect against damage. Floors should be impervious,
resistant to liquids and easy to clean.
Hints on storage assembly:
Avoid heat, Sparks, Open flames & other ignition sources.
Storage Class : 12.
Do not store together with: Food, Drink and Feeding stuffs
Further information on storage conditions
Recommended storage temperature: 10-40°C
Protect against :Heat. UV-radiation/Sunlight. Frost.
Storage stability :Product may be stored for up to 12 months under described conditions.
Storage Temperature-Max 50 °C

7.3 Specific end uses

Corrosion Preventing Oil.

8.0 Exposure controls / Personal Protection

8.1 Control parameters
Occupational exposure limit values
Non of the volatile substances have a volume related limit value at workplace. As no dust generation is expected at
normal conditions of use, mass related limit at workplace are not relevant.
Biological Limit Values- No limits noted for ingredients.
Exposure limits at intended use
No decomposition product known for having a limit value at workplace at intended use.

DNEL/DMEL- Not Available.

PNEC- Not Available.

8.2 Exposure Controls

Appropriate Engineering Controls
Use only in well-ventilated areas. If handled uncovered, arrangements with local exhaust ventilation should be used
if possible. If local exhaust ventilation is not possible or not sufficient, the entire working area should be ventilated
by technical means. Technical measures and the application of suitable work processes have priority over personal
protection equipment.
Personal Protective Equipment
Personal protective equipment selections vary based on potential exposure conditions such as applications,
handling practices, concentration and ventilation. Information on the selection of protective equipment for use with
this material, as provided below, is based upon intended, normal usage.

Eye / Face Protection

Eye glasses with side protection (DIN EN 166)

Skin protection
Hand protection
The quality of the protective gloves resistant to chemicals must be chosen as a function of the specific working
place concentration and quantity of hazardous substances. Tested protective gloves must be worn: (DIN EN 374).
Do not wear gloves near rotary machines and tools.

Suitable Material :
Permanent Contact : Material: NBR (Nitrile rubber). CR (neoprene rubber). Thickness of the glove
material: 0,70 mm Breakthrough time > 480 min
Occasional Contact (splashes): Material: NBR (Nitrile rubber). CR (neoprene rubber). Thickness of the
glove material: 0,40 mm Breakthrough time > 30 min.
Breakthrough Time : For special purposes, it is recommended to check the resistance to chemicals of
the protective gloves together with the supplier of these gloves. Check leak tightness / impermeability prior
to use.

Body Protection : If prolonged or repeated contact is likely, chemical, and oil resistant clothing is recommended.
Additional Body Protection Measures : When handling product in drums, safety footwear should be worn and
proper handling equipment should be used.
Respiratory Protection:
Usually no personal respirative protection necessary. If technical exhaust or ventilation measures are not possible
or insufficient, respiratory protection must be worn.
Respiratory protection necessary at: exceeding exposure limit values. Insufficient ventilation.
Thermal Hazards- Unknown.
General Health and Safety Measures
When using do not eat, drink, smoke. Wash hands before breaks and after work. Do not put any product-

Page 4 of 8 AP/SP/016/001
Safety Data Sheet
According to Regulations (EC) No 1907/2006(REACH), Annex II as amended
regulation (EU) No. 2015/830
Trade Name : SP-RP-Oil
Version No. : 3.1, Nov 2015
st
Revision Date : 1 December 2020
Product Use : Industrial Use Only.

impregnated cleaning rags into your trouser pockets. Wash contaminated clothing prior to re-use. Apply skin care
products after work.

Environmental Exposure Controls

Protect the environment by applying appropriate control measures to prevent or limit emissions.

9.0 Physical and Chemical Properties

9.1 Information on basic physical and chemical properties
Appearance
Physical State Liquid
Colour Brown.
Odour Low Characteristic
Safety Relevant Basis Data
pH Value(25°C/5% b.w) Not Applicable.
Melting Point/Range Not Applicable
Boiling Point / Range >250°C
Flash Point > 40°C
Pour Point -2 °C. max
Flammability (Solid, Gas) No Data Available
Explosion limit in Air No Data Available
Vapour pressure (20 °C) 0.27 kPa (2.03 mm Hg)
Vapour Density (Air=1) 4.9 at 101 kPa
Evaporation Rate No Data Available
Density 0.80 +/- 0.02 g/cm3
Solubility in water Insoluble
Partition Coefficient (n-octanol/water) Not Applicable
Viscosity (40°C) 2-4 cSt
Ignition Temperature No Data Available
Decomposition point/range > 360°C
Explosive Properties Not Explosive
Oxidizing Properties Not Oxidizing

9.2 Other information

Do not contain secondary amines. No relevant additional information available.

10.0 Stability and Reactivity

10.1 Reactivity
The product is stable & non reactive under normal conditions of Use, Storage, Handling & Transportation.

10.2 Chemical Stability

Stable under recommended storage and handling conditions (see section 7).

10.3 Possibility of hazardous reactions

No dangerous reactions known under normal use.

10.4 Conditions to avoid

Moisture, Avoid heat, Sparks, Open flames & other ignition sources.

10.5 Incompatible materials

Oxidizing agent, Strong acids.

10.6 Hazardous decomposition products:

Hazardous decomposition products are not expected to form during normal storage.

11.0 Toxicological information

11.1 General Information
No test data available for this article.
Information on likely routes of exposure
Ingestion- Harmful, If swallowed. Irritating. May cause nausea, stomach pain & vomiting.
Inhalation-Prolongated inhalation may be harmful.
Skin Contact- No adverse effects due to skin contact.
Eye Contact-Direct contact with eye may cause temporary irritation.
Symptoms- Nausea, Vomiting, Irritation to eyes.

11.2 Information on Toxicological Effects

For the article toxicological data are not available. The statements are derived from the properties of the single

Page 5 of 8 AP/SP/016/001
Safety Data Sheet
According to Regulations (EC) No 1907/2006(REACH), Annex II as amended
regulation (EU) No. 2015/830
Trade Name : SP-RP-Oil
Version No. : 3.1, Nov 2015
st
Revision Date : 1 December 2020
Product Use : Industrial Use Only.

components. As no ingredient substance is classified as Hazardous, LD50/LC50 values are not available. Based on
available data, the classification criteria are not met.
Acute effects
Irritant to eyes.
Product Acute-Oral LD50 Dermal LC 50

SP-RP-Oil >5000mg/Kg (Calculated ATE) >1000mg/kg (Calculated ATE)

Components Acute-Oral LD50 Dermal LC 50

Naphtha (Petroleum) Hydrotreated
> 10000 mg/kg > 3160 mg/kg
Heavy
Rust Protection Additive >6000 mg/kg (Rat) >2000 mg / kg (rabbits)

Irritant and Corrosive Effects

Primary irritation to the skin
Frequently or prolonged contact with skin may cause dermal irritation.
Irritation to eyes
No known significant effects or critical hazards.
Sensitization
No much sensitizing.
CMR effects (carcinogenicity, mutagenicity and toxicity for reproduction)
Carcinogenicity
No known significant effects or critical hazards.
Germ cell mutagenicity/Genotoxicity
No known significant effects or critical hazards.
Reproductive toxicity
No known significant effects or critical hazards.
Specific Target Organ Toxicity (Single Exposure)-STOT SE 1 and 2
Not expected to cause organ damage from a single exposure.
Specific target organ toxicity (Repeated Exposure)-STOT RE 1 and 2
Not expected to cause organ damage from prolonged or repeated exposure.
Aspiration Hazard
Based on the available data the classification criteria for aspiration toxicity are not met. For viscosity data, see
chapter 9.

11.3 Other Adverse Effects

Not applicable.

12.0 Ecological information

12.1 Toxicity
The product is not classified as environmentally hazardous. For the product ecotoxicological data are not available.
Aquatic toxicity
With high probability, acutely not harmful to aquatic organisms.

12.2 Persistence and degradability Biodegradation

Major part of the article is inert & degrades under solar radiation.

12.3 Bioaccumulative potential

No significant accumulation.

12.4 Mobility in soil

No information available.

12.5 Results of PBT and vPvB assessment

The article contains no substance fulfilling all screening criteria for persistence, bioaccumulation and toxicity and
hence is not considered to be PBT or vPvB.

12.6 Other adverse effects

No information available.

12.7 Further Ecological Information

No other adverse environmental effects (E.g. Ozone depletion, Photochemical ozone creation, potential, Endocrine
disruptions, Global warming potential) are expected from this components.
Do not allow uncontrolled discharge of product into the environment.

Page 6 of 8 AP/SP/016/001
Safety Data Sheet
According to Regulations (EC) No 1907/2006(REACH), Annex II as amended
regulation (EU) No. 2015/830
Trade Name : SP-RP-Oil
Version No. : 3.1, Nov 2015
st
Revision Date : 1 December 2020
Product Use : Industrial Use Only.

13.0 Disposal Considerations

13.1 Waste Treatment Methods
Product/Packaging Disposal
Waste Codes / Waste Designations according to EWC / AVV
The allocation of waste identity numbers/waste descriptions must be carried out according to the EEC, specific to
the industry and process.
Waste Code Product- 13 08 99
However, deviation from the intended use and/or the presence of any potential contaminants may require an
alternative waste disposal code to be assigned by the end user.
Waste Code Packaging Waste Name
Waste Plastic Film
Waste Treatment Options
Appropriate Disposal / Product
Consult the appropriate local waste disposal expert about waste disposal. Dispose according to legislation.
Appropriate disposal / Package
Non-contaminated packages may be recycled. Dispose of waste according to applicable legislation.

14.0 Transport Information

14.1 ADR-Not regulated as dangerous goods.
14.2 IATA-Not regulated as dangerous goods.
14.3 IMDG-Not regulated as dangerous goods.
14.4 Packing group- No dangerous good in sense.
14.5 Environmental hazards-No dangerous good in sense.
14.6 Special precautions for user-None.

15.0 Regulatory Information

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
EU regulations
Regulation (EC) No. 1907/2006, REACH Article 59(1) Candidate List as currently published by ECHA
Not listed.
Authorizations-
Regulation (EC) No. 143/2011 Annex XIV Substances Subject to Authorization-Not listed.
Restrictions On Use
Regulation (EC) No. 1907/2006, REACH Annex XVII Substances subject to restriction on marketing and use as
amended-Not listed.
Other EU Regulations
Directive 96/82/EC (Seveso II) on the control of major-accident hazards involving dangerous substances-Not
regulated.
Other Regulations
The product is classified and labeled in accordance with EC directives or respective national laws. This Safety Data
Sheet complies with the requirements of Regulation (EC) No 1907/2006.
National Regulations- Follow National regulations for work with chemical agents

15.2. Chemical Safety Assessment

No Chemical Safety Assessment has been carried out.
Water hazard class (WGK)
WGK-2

16.0 Other information

16.1 Indication of changes
Classifications of ingredients, Label Pictogram & Signal word corrected.

16.2 Abbreviations and Acronyms

ADR : European Agreement concerning the International Carriage of Dangerous Goods by Road
RID : Regulations Concerning the International Transport of Dangerous Goods by Rail
IMDG : International Maritime Code for Dangerous Goods IATA: International Air Transport association
IATA-DGR : Dangerous Goods Regulations by the "International Air Transport Association" (IATA)
ICAO : International Civil Aviation Organization
ICAO-TI : Technical Instructions by the "International Civil Aviation Organization" (ICAO)
CAS : Chemical Abstracts Service (division of the American Chemical Society)
CLP : Regulation (EC) 1272/2008 on classification, labeling and packaging of substances and
mixtures (CLP Regulation)
DIN : German Institute for standardization(Deutsches Institute fur Normung)
GHS : Globally Harmonized System of Classification and Labeling of Chemicals
EN : European Norm

Page 7 of 8 AP/SP/016/001
Safety Data Sheet
According to Regulations (EC) No 1907/2006(REACH), Annex II as amended
regulation (EU) No. 2015/830
Trade Name : SP-RP-Oil
Version No. : 3.1, Nov 2015
st
Revision Date : 1 December 2020
Product Use : Industrial Use Only.

SDS : Safety Data Sheet

LC50 : Lethal concentration, 50 percent
LD50 : Lethal dose, 50 percent
EC50 : Effective concentration, 50 percent
DNEL : Derived No Effect Level
PNEC : Predicted No Effect Concentration
PBT : Persistent, Bioaccumulative and Toxic
vPvB : very Persistent and very Bioaccumulative
VCI : Volatile Corrosion Inhibitor

16.3 Key literature references and sources for data

Sources of information used in preparing this SDS included one or more of the following: Product Dossiers and
SDS from suppliers, complemented by public sources, as appropriate (GESTIS, the EU IUCLID Data Base, U.S.
NTP publications, e.g.).

16.4 Classification for mixtures and used evaluation method according to regulation (EC) 1207/2008 [CLP]
Classification according to Regulation (EC) No. 1272/2008 [CLP]
Product being Article, according to REACH, not classified according to CLP regulation.
Labeling according to Regulation (EC) No. 1272/2008 [CLP]

Exclamation mark (GHS07)

Harmful, if swallowed 4
Causes skin irritation 2
Causes eye irritation 2B
Signal word
Warning
Hazard Statements
H303 - May be harmful, if swallowed
H315 - Causes skin irritation
H320 - Causes Eye irritation
Precautionary Statements
P210 - Keep away from heat/spark/open flames/hot surface – No Smoking.
P234 - Keep only in original packing.
P264 - Wash arms and face thoroughly after handling.
P261 - Avoid breathing dust
P270 - Do not eat, drink or smoke when using this product.
P271 - Use only outdoors or in a well-ventilated area
P280 - Wear protective gloves, eye protection
P301/310 - If Swallowed, Immediately call a POISON CENTER or doctor/physician.
P302+P352 - IF ON SKIN: Wash with plenty of soap and water
P305+P351+P338 - If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present
and easy to do. Continue rinsing
P312 - Call a POISON CENTER or doctor/physician if you feel unwell
P332+P313 - If skin irritation occurs: Get medical advice/attention
P337+P313 - If eye irritation persists: Get medical advice/attention
P362+P364 - Take off contaminated clothing and wash it before reuse
P403+P233 - Store in a well-ventilated place. Keep container tightly closed
P405 - Store locked up
P501 - Dispose of packing material in accordance with national regulations.

16.5 Relevant H- and EU H-phrases (Number and full text)

H303 - May be harmful, if swallowed.
H320 - Causes eye irritation.
20/22 - Harmful by inhalation and if swallowed.
36 - Irritating to eyes.

16.6 Training advice

Provide adequate information, instruction and training for operators. The above information describes exclusively
the safety requirements of the product and is based on our present-day knowledge. The information is intended to
give you advice about the safe handling of the product named in this safety data sheet, for storage, processing,
transport and disposal. The information cannot be transferred to other products. In the case of mixing the product
with other products or in the case of processing, the information on this safety data sheet is not necessarily valid for
the new made-up material.

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