MSDS - 56990
MSDS - 56990
MSDS - 56990
VERSILINE 56990
Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II, as amended by Regulation (EU) No. 453/2010 - Europe
VERSILINE 56990
Product identity :
5699010710
Product type :
silicone paint
1.2 Relevant identified uses of the substance or mixture and uses advised against
Field of application :
metal industry
Identified uses :
Company details :
HEMPEL A/S
Lundtoftegrdsvej 91
DK-2800 Kgs. Lyngby
Denmark
Tel.: + 45 45 93 38 00
hempel@hempel.com
Date of issue :
24 April 2014
23 April 2014.
Mixture
R10
Xi; R36
N; R51/53
See Section 16 for the full text of the R-phrases declared above.
See Section 11 for more detailed information on health effects and symptoms.
2.2 Label elements
Hazard pictograms :
Signal word :
Danger
Hazard statements :
Precautionary statements :
Prevention :
Wear protective gloves. Wear eye or face protection. Keep away from heat, sparks, open flames and
hot surfaces. - No smoking. Use explosion-proof electrical, ventilating, lighting and all materialhandling equipment. Avoid release to the environment.
Response :
IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water or shower.
IF IN EYES: Immediately call a POISON CENTER or physician.
Storage :
Keep cool.
Version: 0.05
-
Page: 1/11
5699010710
Dispose of contents and container in accordance with all local, regional, national and international
regulations.
Hazardous ingredients :
Not applicable.
Not applicable.
None known.
Product/ingredient name
Identifiers
%
67/548/EEC
xylene
R10
Xn; R20/21
Xi; R38
N; R50/53
n-butanol
trizinc bis(orthophosphate)
Classification
Regulation (EC) No.
1272/2008 [CLP]
R10
Xn; R22
Xi; R41, R37/38
R67
Type
[1] [2]
[1] [2]
[1] [2]
[1]
There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are
classified as hazardous to health or the environment and hence require reporting in this section.
Type
[1] Substance classified with a health or environmental hazard
[2] Substance with a workplace exposure limit, see section 8.
[3] Substance meets the criteria for PBT according to Regulation (EC) No. 1907/2006, Annex XIII
[4] Substance meets the criteria for vPvB according to Regulation (EC) No. 1907/2006, Annex XIII
In all cases of doubt, or when symptoms persist, seek medical attention. Never give anything by mouth
to an unconscious person.
If breathing is irregular, drowsiness, loss of consciousness or cramps: Call 112 and give immediate
treatment (first aid).
Eye contact :
Check for and remove any contact lenses. Immediately flush eyes with plenty of water for at least 15
minutes, occasionally lifting the upper and lower eyelids. Seek immediate medical attention.
Inhalation :
Remove to fresh air. Keep person warm and at rest. If unconscious, place in recovery position and
seek medical advice.
Version: 0.05
-
Page: 2/11
5699010710
Remove contaminated clothing and shoes. Wash skin thoroughly with soap and water or use
recognized skin cleanser. Do NOT use solvents or thinners.
Ingestion :
If swallowed, seek medical advice immediately and show this container or label. Keep person warm
and at rest. Do not induce vomiting unless directed to do so by medical personnel. Lower the head so
that vomit will not re-enter the mouth and throat.
Protection of first-aiders :
No action shall be taken involving any personal risk or without suitable training. If it is suspected that
fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing
apparatus. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation.
Wash contaminated clothing thoroughly with water before removing it, or wear gloves.
4.2 Most important symptoms and effects, both acute and delayed
Potential acute health effects
Eye contact :
Inhalation :
May give off gas, vapor or dust that is very irritating or corrosive to the respiratory system.
Skin contact :
Ingestion :
Over-exposure signs/symptoms
Eye contact :
Inhalation :
No specific data.
Skin contact :
Ingestion :
4.3 Indication of any immediate medical attention and special treatment needed
Notes to physician :
Treat symptomatically. Contact poison treatment specialist immediately if large quantities have been
ingested or inhaled.
Specific treatments :
No specific treatment.
Flammable liquid and vapor. In a fire or if heated, a pressure increase will occur and the container may
burst, with the risk of a subsequent explosion. Runoff to sewer may create fire or explosion hazard.
This material is harmful to aquatic life with long lasting effects. Fire water contaminated with this
material must be contained and prevented from being discharged to any waterway, sewer or drain.
Decomposition products may include the following materials: carbon oxides metal oxide/oxides
Version: 0.05
-
Page: 3/11
5699010710
xylene
n-butanol
Version: 0.05
-
Page: 4/11
5699010710
Gloves must be worn for all work that may result in soiling. Apron/coveralls/protective clothing must be
worn when soiling is so great that regular work clothes do not adequately protect skin against contact
with the product. Safety eyewear should be used when there is a likelihood of exposure.
Hygiene measures :
Wash hands, forearms, and face thoroughly after handling compounds and before eating, smoking,
using lavatory, and at the end of day.
Eye/face protection :
Safety eyewear complying with an approved standard should be used when a risk assessment
indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. If contact is
possible, the following protection should be worn, unless the assessment indicates a higher degree of
protection: chemical splash goggles and/or face shield. If inhalation hazards exist, a full-face
respirator may be required instead.
Hand protection :
Wear chemical-resistant gloves (tested to EN374) in combination with 'basic' employee training. The
quality of the chemical-resistant protective gloves must be chosen as a function of the specific
workplace concentrations and quantity of hazardous substances.
Since the actual work situation is unknown. Supplier of gloves should be contacted in order to find the
appropriate type. Below listed glove(s) should be regarded as generic advice:
May be used: neoprene rubber, butyl rubber, nitrile rubber
Recommended: Silver Shield / 4H gloves, Viton, polyvinyl alcohol (PVA)
Not recommended: polyvinyl chloride (PVC), natural rubber (latex)
Body protection :
Personal protective equipment for the body should be selected based on the task being performed and
the risks involved handling this product.
Wear suitable protective clothing. Always wear protective clothing when spraying.
Respiratory protection :
If working areas have insufficient ventilation: When the product is applied by means that will not
generate an aerosol such as, brush or roller wear half or totally covering mask equipped with gas filter
of type A, when grinding use particle filter of type P. When the product is applied by spraying and for
continuous or prolonged work always wear an air-fed respirator e.g. hood with supply of fresh or
compressed air or a full face, powered air purifying filter. Be sure to use an approved/certified
respirator or equivalent.
Version: 0.05
-
Page: 5/11
5699010710
Liquid.
Color :
Dark grey.
Odor :
Solvent-like
pH :
1565C This is based on data for the following ingredient: Iron oxide (Fe2O3)
Flash point :
Evaporation rate :
Flammability :
Highly flammable in the presence of the following materials or conditions: open flames, sparks and
static discharge and heat.
Flammable in the presence of the following materials or conditions: oxidizing materials.
Slightly flammable in the presence of the following materials or conditions: reducing materials.
Vapor pressure :
Vapor density :
Relative density :
1.902 g/cm
Solubility(ies) :
Partially soluble in the following materials: cold water and hot water.
Auto-ignition temperature :
Lowest known value: 280 - 470C (536 - 878F) (solvent naphtha (petroleum), light arom.).
Decomposition temperature :
Viscosity :
Explosive properties :
Explosive in the presence of the following materials or conditions: open flames, sparks and static
discharge and heat.
Oxidizing properties :
Weighted average: 20 %
Water % by weight :
Weighted average: 0 %
VOC content :
377.3 g/l
TOC Content :
Solvent Gas :
Version: 0.05
-
Page: 6/11
5699010710
n-butanol
Result
Species
Dose
Exposure
Rat
>5 mg/l
4 hours
LD50 Dermal
LD50 Oral
LC50 Inhalation Gas.
LC50 Inhalation Vapor
LD50 Dermal
LD50 Oral
LC50 Inhalation Vapor
LD50 Dermal
LD50 Oral
Rabbit
Rat
Rat
Rat
Rabbit
Rat
Rat
Rabbit
Rat
>2000 mg/kg
8400 mg/kg
5000 ppm
6350 ppm
>2000 mg/kg
4300 mg/kg
24000 mg/m
3400 mg/kg
790 mg/kg
4 hours
4 hours
4 hours
-
ATE value
Oral
Dermal
Inhalation (gases)
Inhalation (vapors)
21358.5 mg/kg
32693.8 mg/kg
148608 ppm
91.46 mg/l
Irritation/Corrosion
Product/ingredient name
solvent naphtha (petroleum), light
arom.
xylene
n-butanol
Result
Species
Score
Exposure
Rabbit
Rabbit
Rabbit
Rabbit
Rabbit
24 hours 5 milligrams
24 hours 500 milligrams
24 hours 2 milligrams
24 hours 20 milligrams
Category
Category 3
Category 3
Route of exposure
Target organs
Not applicable.
Not applicable.
Category
Route of exposure
Target organs
Aspiration hazard
Product/ingredient name
solvent naphtha (petroleum), light arom.
Version: 0.05
-
Result
ASPIRATION HAZARD - Category 1
Page: 7/11
5699010710
Result
Species
Exposure
96 hours
48 hours
96 hours
96 hours
96 hours
Test
-
Dose
Inoculum
Product/ingredient name
solvent naphtha (petroleum), light
arom.
xylene
n-butanol
Result
Aquatic half-life
Photolysis
Biodegradability
Readily
Readily
Readily
LogPow
3.12
1
-
BCF
10 - 2500
8.1 - 25.9
60960
Potential
high
low
low
high
Mobility :
Not applicable.
vPvB :
Not applicable.
Version: 0.05
-
Page: 8/11
5699010710
ADR/RID
Class
14.1
UN no.
14.2
Proper shipping name
UN1263
PAINT
14.3
Transport hazard class(es)
3
14.4
PG*
14.5
Env* Additional information
III
No.
Special provisions
640 (E)
Tunnel code
(D/E)
IMDG
Class
UN1263
III
IATA
Class
UN1263
PAINT
III
No.
Seveso category
P5c: Flammable liquids 2 and 3 not falling under P5a or P5b
C6: Flammable (R10)
C9ii: Toxic for the environment
Version: 0.05
-
Page: 9/11
5699010710
R10- Flammable.
R20- Harmful by inhalation.
R22- Harmful if swallowed.
R20/21- Harmful by inhalation and in contact with skin.
R65- Harmful: may cause lung damage if swallowed.
R41- Risk of serious damage to eyes.
R36- Irritating to eyes.
R38- Irritating to skin.
R37/38- Irritating to respiratory system and skin.
R36/37/38- Irritating to eyes, respiratory system and skin.
R67- Vapors may cause drowsiness and dizziness.
R50/53- Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
R51/53- Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
Xn - Harmful
Xi - Irritant
N - Dangerous for the environment
H226
H302
H304
H312
H315
H318
H319
H332
H335
H335 and H336
H400
H410
H411
H412
STOT SE 3, H335
and H336
Procedure used to derive the classification according to Regulation (EC) No. 1272/2008 [CLP/GHS]
Classification
FLAMMABLE LIQUIDS - Category 3
SKIN CORROSION/IRRITATION - Category 2
SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 1
AQUATIC TOXICITY (CHRONIC) - Category 3
Justification
On basis of test data
Calculation method
Calculation method
Calculation method
Notice to reader
Indicates information that has changed from previously issued version.
Version: 0.05
-
Page: 10/11
5699010710
Version: 0.05
-
Page: 11/11