Date Printed: 04/15/2020 Product: 0250A1NL

Safety Data Sheet

Prepared in Accordance with HCS 29
C.F.R. 1910.1200

1. Identification of the Substance/Mixture and the Company/Undertaking

1.1 Product Identifier 0250A1NL

Product Name: CARBOZINC 11 / CARBOZINC Revision Date: 04/09/2019

11 FG BASE
Supercedes Date: 10/09/2018
Base component of 2
1.2 Relevant identified uses of the components coatings - Industrial
substance or mixture and uses use.
advised against

1.3 Details of the supplier of the safety data sheet

Manufacturer: Carboline Company

2150 Schuetz Road
St. Louis, MO USA 63146

Regulatory / Technical Information:

Contact Carboline Technical Services at
1-800-848-4645

Alotta, Vicki - [email protected]

Datasheet Produced by:

1.4 CHEMTREC 1-800-424-9300 (Inside US)

Emergency telephone number: CHEMTREC +1 703 5273887 (Outside US)
HEALTH - Pittsburgh Poison Control 1-412-681-6669

2. Hazard Identification

2.1 Classification of the substance or mixture

Acute Toxicity, Dermal, category 4

Acute Toxicity, Inhalation, category 4
Carcinogenicity, category 1A
Eye Irritation, category 2
Flammable Liquid, category 2
STOT, repeated exposure, category 1
Skin Irritation, category 2

2.2 Label elements

Symbol(s) of Product

Signal Word
Danger

Named Chemicals on Label

METHYL ALCOHOL, ETHYL SILICATE, ETHYL BENZENE, 2-BUTOXYETHANOL, MICROCRYSTALLINE SILICA

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HAZARD STATEMENTS

Flammable Liquid, category 2 H225 Highly flammable liquid and vapour.

Acute Toxicity, Dermal, category 4 H312 Harmful in contact with skin.
Skin Irritation, category 2 H315 Causes skin irritation.
Eye Irritation, category 2 H319 Causes serious eye irritation.
Acute Toxicity, Inhalation, category 4 H332 Harmful if inhaled.
Carcinogenicity, category 1A H350-1A May cause cancer.
STOT, repeated exposure, category 1 H372 Causes damage to organs through prolonged or repeated
exposure.
PRECAUTION PHRASES

P201 Obtain special instructions before use.

P202 Do not handle until all safety precautions have been read
and understood.
P210 Keep away from heat/sparks/open flames/hot surfaces. – No
smoking.
P235 Keep cool.
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P264 Wash hands thoroughly after handling.
P280 Wear protective gloves/protective clothing/eye protection/
face protection.
P284 Wear respiratory protection.
P302 IF ON SKIN:
P304+340 IF INHALED: Remove victim to fresh air and keep at rest in a
position comfortable for breathing.
P305+351+338 IF IN EYES: Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do so.
Continue rinsing.
P308+313 IF exposed or concerned: Get medical advice/attention
P312 Call a POISON CENTER or doctor/physician if you feel
unwell.
P314 Get medical advice/attention if you feel unwell.
P332+313 If skin irritation occurs: Get medical advice/attention.
P352 Wash with plenty of soap and water.
P403+233 Store in a well-ventilated place. Keep container tightly
closed.
2.3 Other hazards
No Information

Results of PBT and vPvB assessment:

Unknown

3. Composition/Information On Ingredients
3.2 Mixtures
Hazardous Ingredients
CAS-No. Chemical Name %
64-17-5 ETHYL ALCOHOL 25 - <50
14808-60-7 MICROCRYSTALLINE SILICA 10 - <25
67-63-0 ISOPROPANOL 10 - <25
111-76-2 2-BUTOXYETHANOL 10 - <25
67-56-1 METHYL ALCOHOL 2.5 - <10
78-10-4 ETHYL SILICATE 2.5 - <10
13463-67-7 TITANIUM DIOXIDE 2.5 - <10
12001-26-2 MICA 1.0 - <2.5
1333-86-4 CARBON BLACK 1.0 - <2.5
100-41-4 ETHYL BENZENE 0.1 - <1.0

CAS-No. GHS Symbols GHS Hazard Statements M-Factors

64-17-5 GHS02 H225 0
14808-60-7 GHS08 H350-372 0
67-63-0 GHS02-GHS07 H225-319-336 0
111-76-2 GHS07 H302-312-315-319-332 0
67-56-1 GHS02-GHS06-GHS08 H225-301-311-331-370 0
78-10-4 GHS02-GHS07 H226-319-332-335 0

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13463-67-7 0
12001-26-2 GHS07 H319-335 0
1333-86-4 0
100-41-4 GHS02-GHS07-GHS08 H225-304-315-319-332-351-373-412 0
Remarks: CASStatement

Additional Information: The text for GHS Hazard Statements shown above (if any) is given in Section 16.

4. First-aid Measures
4.1 Description of First Aid Measures
AFTER INHALATION: Give oxygen or artificial respiration if needed. Remove person to fresh air. If signs/symptoms
continue, get medical attention.
AFTER SKIN CONTACT: In case of contact, immediately flush skin with plenty of water for at least 15 minutes while
removing contaminated clothing and shoes. If skin irritation persists, call a physician.
AFTER EYE CONTACT: Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician.
AFTER INGESTION: Do NOT induce vomiting. Never give anything by mouth to an unconscious person. If swallowed, call
a poison control centre or doctor immediately.
4.2 Most important symptoms and effects, both acute and delayed
Harmful if swallowed. Irritating to eyes and skin. Risk of serious damage to the lungs (by aspiration). Vapours may cause
drowsiness and dizziness.
4.3 Indication of any immediate medical attention and special treatment needed

No information available on clinical testing and medical monitoring. Specific toxicological information on substances, if
available, can be found in section 11.
When symptoms persist or in all cases of doubt seek medical advice.

5. Fire-fighting Measures
5.1 Extinguishing Media:
Carbon Dioxide, Dry Chemical, Foam, Water Fog
UNUSUAL FIRE AND EXPLOSION HAZARDS: Flammable liquid. Vapours are heavier than air and may spread along
floors. Vapours may form explosive mixtures with air. Vapors may travel to areas away from work site before igniting/flashing
back to vapor source. Provide adequate ventilation. Prevent the creation of flammable or explosive concentrations of vapour
in air and avoid vapour concentration higher than the occupational exposure limits. Keep away from heat/sparks/open
flames/hot surfaces. - No smoking. Electrical installations / working materials must comply with the technological safety
standards. Wear shoes with conductive soles.

5.2 Special hazards arising from the substance or mixture

No Information

5.3 Advice for firefighters

In the event of fire, wear self-contained breathing apparatus. Cool containers / tanks with water spray. Flammable.

6. Accidental Release Measures

6.1 Personal precautions, protective equipment and emergency procedures

Ensure adequate ventilation. Evacuate personnel to safe areas. Remove all sources of ignition. To avoid ignition of vapours
by static electricity discharge, all metal parts of the equipment must be grounded. Wear personal protective equipment. For
personal protection see section 8.
6.2 Environmental precautions
Do not allow material to contaminate ground water system. Prevent product from entering drains.
6.3 Methods and material for containment and cleaning up
Prevent further leakage or spillage if safe to do so. Contain spillage, soak up with non-combustible absorbent material, (e.g.
sand, earth, diatomaceous earth, vermiculite) and transfer to a container for disposal according to local / national regulations
(see section 13).

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6.4 Reference to other sections

Please refer to disposal requirements or country specific disposal requirements for this material. See Section 13 for further
information.

7. Handling and Storage

7.1 Precautions for safe handling

INSTRUCTIONS FOR SAFE HANDLING : Keep containers dry and tightly closed to avoid moisture absorption and
contamination. Prepare the working solution as given on the label(s) and/or the user instructions. Do not breathe vapours or
spray mist. Ensure all equipment is electrically grounded before beginning transfer operations. Do not use sparking tools.
Do not get in eyes, on skin, or on clothing. Use only with adequate ventilation/personal protection. Wash thoroughly after
handling.
PROTECTION AND HYGIENE MEASURES : Handle in accordance with good industrial hygiene and safety practice. Wash
hands before breaks and at the end of workday. When using, do not eat, drink or smoke.

7.2 Conditions for safe storage, including any incompatibilities

CONDITIONS TO AVOID: Heat, flames and sparks.
STORAGE CONDITIONS: Keep container closed when not in use. Store in a dry, well ventilated place away from sources of
heat, ignition and direct sunlight.
7.3 Specific end use(s)

No specific advice for end use available.

8. Exposure Controls/Personal Protection

8.1 Control parameters

Ingredients with Occupational Exposure Limits

(US)

Name CAS-No. ACGIH TWA ACGIH STEL ACGIH Ceiling

ETHYL ALCOHOL 64-17-5 N/E 1000 PPM N/E
MICROCRYSTALLINE SILICA 14808-60-7 0.025 MGM3 N/E N/E
ISOPROPANOL 67-63-0 200 PPM 400 PPM N/E
2-BUTOXYETHANOL 111-76-2 20 PPM 50 PPM N/E
METHYL ALCOHOL 67-56-1 200 PPM 250 PPM N/E
ETHYL SILICATE 78-10-4 10 PPM N/E N/E
TITANIUM DIOXIDE 13463-67-7 10 mg/m3 N/E N/E
MICA 12001-26-2 3 MGM3 N/E N/E
CARBON BLACK 1333-86-4 3 MGM3 N/E N/E
ETHYL BENZENE 100-41-4 20 PPM 125 ppm

Name CAS-No. OSHA PEL OSHA STEL

ETHYL ALCOHOL 64-17-5 1900 MGM3,

N/E
1000 PPM

MICROCRYSTALLINE SILICA 14808-60-7 0.05 MGM3 N/E

ISOPROPANOL 67-63-0 980 MGM3, 400 1225 MGM3,

PPM 500 PPM

2-BUTOXYETHANOL 111-76-2 120 MGM3, 25

N/E
PPM

METHYL ALCOHOL 67-56-1 260 MGM3, 200 325 MGM3, 250

PPM PPM

ETHYL SILICATE 78-10-4 85 MGM3, 10

N/E
PPM

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TITANIUM DIOXIDE 13463-67-7 15 MGM3 N/E

MICA 12001-26-2 20. MPPCF N/E

CARBON BLACK 1333-86-4 3.5 MG/M3 N/E

ETHYL BENZENE 100-41-4 435 MGM3, 100 545 MGM3, 125

PPM PPM

FURTHER INFORMATION: Refer to the regulatory exposure limits for the workforce enforced in each country.

8.2 Exposure controls

Personal Protection
RESPIRATORY PROTECTION: In order to avoid inhalation of spray-mist and sanding dust, all spraying and sanding must
be done wearing adequate respirator. Use only with ventilation to keep levels below exposure guidelines reported in this
document. User should test and monitor exposure levels to ensure all personnel are below guidelines. If not sure, or not able
to monitor, use State or federally approved supplied air respirator. For silica containing coatings in a liquid state, and/or if no
exposure limits are established above, air-supplied respirators are generally not required.
EYE PROTECTION: Ensure that eyewash stations and safety showers are close to the workstation location. Safety glasses
with side-shields.
HAND PROTECTION: Gloves should be discarded and replaced if there is any indication of degradation or chemical
breakthrough. Impervious gloves. Request information on glove permeation properties from the glove supplier. Lightweight
protective clothing
OTHER PROTECTIVE EQUIPMENT: No Information
ENGINEERING CONTROLS: Avoid contact with skin, eyes and clothing. Ensure adequate ventilation, especially in confined
areas.

9. Physical and Chemical Properties

9.1 Information on basic physical and chemical properties
Appearance: Viscous Green, Grey, Red Or

Physical State Liquid

Odor Solvent

Odor threshold N/D

pH N/D
Melting point / freezing point (°C) N/D
Boiling point/range 149 F (65 C) - 340 F (171 C)
Flash Point 56F (13C)
Evaporation rate Slower Than Ether

Flammability (solid, gas) Not determined

Upper/lower flammability or explosive 1.0 - 36.0

limits
Vapour Pressure, mmHg N/D
Vapour density Heavier than Air
Relative density Not determined
Solubility in / Miscibility with water N/D
Partition coefficient: n-octanol/water Not determined
Auto-ignition temperature (°C) Not determined
Decomposition temperature (°C) Not determined

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Viscosity Unknown
Explosive properties Not determined
Oxidising properties Not determined

9.2 Other information

VOC Content g/l: CZ11: 479; CZ11 FG: 515
(Shop Use Only)
Specific Gravity (g/cm3) 1.07

10. Stability and Reactivity

10.1 Reactivity
No reactivity hazards known under normal storage and use conditions.

10.2 Chemical stability

Stable under normal conditions.

10.3 Possibility of hazardous reactions

Hazardous polymerisation does not occur.

10.4 Conditions to avoid

Heat, flames and sparks.

10.5 Incompatible materials

Strong oxidizing agents.

10.6 Hazardous decomposition products

Carbon dioxide (CO2), carbon monoxide (CO), oxides of nitrogen (NOx), dense black smoke.

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11. Toxicological Information

11.1 Information on toxicological effects
Acute Toxicity:
Oral LD50: N/D
Inhalation LC50: N/D

Irritation: Eye Irritation and Skin Irritation, category 2

Corrosivity: Unknown

Sensitization: Unknown

Repeated dose toxicity: STOT, repeated exposure, category 1

Carcinogenicity: Carcinogenicity, category 1A

Mutagenicity: Unknown

Toxicity for reproduction: Unknown

STOT-single exposure: Unknown

STOT-repeated exposure: Unknown

Aspiration hazard: Unknown

If no information is available above under Acute Toxicity then the acute effects of this product have not been tested.
Data on individual components are tabulated below:

Chemical Name Oral LD50 Dermal LD50 Vapor LC50 Gas LC50 Dust/Mist
CAS-No.
LC50
20000
7060 mg/kg,
64-17-5 ETHYL ALCOHOL oral, rat
ppm/10 hrs, 0.000 0.000
rat, inhalation

14808-60-7 MICROCRYSTALLINE SILICA 22500 mg/kg Not Available Not Available 0.000 0.000

22500
4720 mg/kg 12800 mg/kg,
67-63-0 ISOPROPANOL rat, oral dermal, rabbit
ppm/8hrs rat, 0.000 0.000
inhalation
450 ppm/l /
1300 mg/kg, 2000 mg/kg,
111-76-2 2-BUTOXYETHANOL oral, rat dermal, rat
4H, rat, 0.000 0.000
Inhalation
2080 mg/kg
67-56-1 METHYL ALCOHOL rat oral
Not Available Not Available 0.000 0.000

>7.5 mg/L 4
>2000mg/kg
78-10-4 ETHYL SILICATE rat, oral
hrs. rat, 0.000 0.000
inhalation
25000 mg/kg, No No
13463-67-7 TITANIUM DIOXIDE oral (rat)
Not Available Not Available
Information Information

12001-26-2 MICA Not Available Not Available Not Available 0.000 0.000

8000 mg/kg
1333-86-4 CARBON BLACK oral, rat
Not Available Not Available

3500 mg/kg >5000 mg/l, 17.2 mg/L

100-41-4 ETHYL BENZENE rat, oral dermal rabbit
0.000 0.000
Inh, Rat, 4Hr

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Additional Information:
This product may contain Ethyl Benzene, which is listed by IARC as possibly carcinogenic to humans (Group 2B). This listing is
based on inadequate evidence of carcinogenicity in humans and sufficient evidence in experimental animals. This product contains
silica which is classified by IARC as a known human carcinogen (Group 1). Crystalline silica is known to cause silicosis. The
classification(s) is/are relevant when exposed to these respirable substances in dust or powder form only, including cured product
that is subject to sanding, grinding, cutting, or other surface preparation activities.

12. Ecological Information

12.1 Toxicity:

EC50 48hr (Daphnia): Unknown

IC50 72hr (Algae): Unknown

LC50 96hr (fish): Unknown

12.2 Persistence and degradability: Unknown

12.3 Bioaccumulative potential: Unknown

12.4 Mobility in soil: Unknown

12.5 Results of PBT and vPvB Unknown

assessment:

12.6 Other adverse effects: Unknown

CAS-No. Chemical Name EC50 48hr IC50 72hr LC50 96hr

64-17-5 ETHYL ALCOHOL 2 mg/l (Daphnia Magna) No information 42 mg/l (fish)

14808-60-7 MICROCRYSTALLINE SILICA No information No information No information
>1000 m/gL
13299 mg/l (Daphnia 9640 mg/L (pimphales
67-63-0 ISOPROPANOL Magna)
(desmodesmus
promelas)
subspicatus)
111-76-2 2-BUTOXYETHANOL 1800 mg/l (Water flea) 911 mg/l (Algae) 1474 mg/kg (Fish)
67-56-1 METHYL ALCOHOL No information No information No information
78-10-4 ETHYL SILICATE No information No information No information
13463-67-7 TITANIUM DIOXIDE No information No information No information
12001-26-2 MICA No information No information No information
1333-86-4 CARBON BLACK No information No information No information
1.8 mg/l (Daphnia
100-41-4 ETHYL BENZENE Magna)
4.6 mg/l (Green Algae) 4.2 mg/l (Rainbow Trout)

13. Disposal Considerations

13.1 WASTE TREATMENT METHODS: Do not burn, or use a cutting torch on, the empty drum. If recycling is not practicable,
dispose of in compliance with local regulations. Dispose of in accordance with local regulations. Empty containers should be
taken to an approved waste handling site for recycling or disposal.

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14. Transport Information

14.1 UN number UN 1263
14.2 UN proper shipping name Paint
Technical name N/A
14.3 Transport hazard class(es) 3
Subsidiary shipping hazard N/A
14.4 Packing group II
14.5 Environmental hazards Unknown
14.6 Special precautions for user Unknown
EmS-No.: F-E, S-E

14.7 Transport in bulk according to Annex II Unknown

of MARPOL 73/78 and the IBC code

15. Regulatory Information

15.1 Safety, health and environmental regulations/legislation for the substance or mixture:

U.S. Federal Regulations: As follows -

CERCLA - Sara Hazard Category
This product has been reviewed according to the EPA ‘Hazard Categories’ promulgated under Sections 311 and 312 of the
Superfund Amendment and Reauthorization Act of 1986 (SARA Title III) and is considered, under applicable definitions, to
meet the following categories:
Flammable (gases, aerosols, liquids, or solids), Carcinogenicity, Acute Toxicity (any route of exposure), Skin Corrosion or
Irritation, Serious eye damage or eye irritation, Specific target organ toxicity (single or repeated exposure)
Sara Section 313:
This product contains the following substances subject to the reporting requirements of Section 313 of Title III of the
Superfund Amendment and Reauthorization Act of 1986 and 40 CFR part 372:
Chemical Name CAS-No.
ISOPROPANOL 67-63-0
METHYL ALCOHOL 67-56-1
ETHYL BENZENE 100-41-4
Toxic Substances Control Act:
All components of this product are either listed on the TSCA Inventory or are exempt.

This product contains the following chemical substances subject to the reporting requirements of TSCA 12(B) if exported from
the United States:
Chemical Name CAS-No.
No TSCA 12(b) components exist in this product.
U.S. State Regulations: As follows -
New Jersey Right-to-Know:

The following materials are non-hazardous, but are among the top five components in this product.

Chemical Name CAS-No.

No NJ Right-To-Know components exist in this
product.
Pennsylvania Right-To-Know

The following non-hazardous ingredients are present in the product at greater than 3%.

Chemical Name CAS-No.

ALUMINUM SILICATE 1332-58-7
WATER 7732-18-5

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CALIFORNIA PROPOSITION 65

WARNING: Cancer and Reproductive Harm -- www.P65Warnings.ca.gov

International Regulations: As follows -

* Canadian DSL:

All chemical ingredients included on inventory (DSL)

15.2 Chemical Safety Assessment:

No Chemical Safety Assessment has been carried out for this substance/mixture by the supplier.

16. Other Information

Text for GHS Hazard Statements shown in Section 3 describing each ingredient:
H225 Highly flammable liquid and vapour.
H226 Flammable liquid and vapour.
H301 Toxic if swallowed.
H302 Harmful if swallowed.
H304 May be fatal if swallowed and enters airways.
H311 Toxic in contact with skin.
H312 Harmful in contact with skin.
H315 Causes skin irritation.
H319 Causes serious eye irritation.
H331 Toxic if inhaled.
H332 Harmful if inhaled.
H335 May cause respiratory irritation.
H336 May cause drowsiness or dizziness.
H350 May cause cancer.
H351 Suspected of causing cancer.
H370 Causes damage to organs.
H372 Causes damage to organs through prolonged or repeated exposure.
H373 May cause damage to organs through prolonged or repeated exposure.
H412 Harmful to aquatic life with long lasting effects.

Reasons for revision

No Information

The information contained herein is, to the best of our knowledge and belief accurate. However,
since the conditions of handling and use are beyond our control, we make no guarantee of results,
and assume no liability for damages incurred by use of this material. It is the responsibility of
the user to comply with all applicable federal, state, and local laws and regulations.

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