Flowchem Ve Primer Euclpsds GB 01092021

Download as pdf or txt
Download as pdf or txt
You are on page 1of 9

Date Printed: 01/09/2021 Product: FLOWCHEM VE PRIMER

Safety Data Sheet according to


Regulation (EC) 'No. 2015/830

SECTION 1: Identification of the Substance/Mixture and the Company/Undertaking

1.1 Product Identifier FLOWCHEM VE PRIMER Revision Date: 01/09/2021

Product Name: Flowchem VE Primer Supersedes Date: 21/09/2018

UFI Code: Q0C1-E0V4-Q00N-9Y61


1.2 Relevant identified uses of the Washing and Cleaning Products (including solvent based products). Manual activities
substance or mixture and uses involving hand contact. For use by appropriately trained applicators. Advised against:
advised against Home DIY applications, because of the health hazards and training required.

1.3 Details of the supplier of the safety data sheet

Supplier: Flowcrete UK Ltd.


The Flooring Technology Centre
Booth Lane
Moston, Sandbach, Cheshire. UK
CW11 3QF

Tel: +44 (0)1270 753000


Fax: +44 (0)1270 753333
[email protected]
http://www.flowcrete.co.uk

[email protected]
Datasheet Produced by:

1.4 Emergency telephone number: CHEMTREC +001 703 5273887 (Outside US)
CHEMTREC 1-800-424-9300 (Inside US)

Giftinformasjonen: +47 22 59 13 00

SECTION 2: Hazard Identification

2.1 Classification of the substance or mixture

Classification according to Classification, Labeling & Packaging Regulation (EC) 1272/2008

HAZARD STATEMENTS

Flammable Liquid, category 3 H226


Skin Irritation, category 2 H315

Page 1 / 9
Date Printed: 01/09/2021 Product: FLOWCHEM VE PRIMER

Eye Irritation, category 2 H319


Acute Toxicity, Inhalation, category 4 H332
STOT, single exposure, category 3, RTI H335
Reproductive_ToxicityD_category_2 H361d
STOT, repeated exposure, category 1 H372
Hazardous to the aquatic environment, Chronic, category 3 H412
2.2 Label elements

Symbol(s) of Product

Signal Word
Danger

Named Chemicals on Label


Styrene
HAZARD STATEMENTS

Flammable Liquid, category 3 H226 Flammable liquid and vapour.


Skin Irritation, category 2 H315 Causes skin irritation.
Eye Irritation, category 2 H319 Causes serious eye irritation.
Acute Toxicity, Inhalation, category 4 H332 Harmful if inhaled.
STOT, single exposure, category 3, RTI H335 May cause respiratory irritation.
Reproductive_ToxicityD_category_2 H361d Suspected of damaging the unborn child.
STOT, repeated exposure, category 1 H372 Causes damage to organs through prolonged or repeated
exposure.
Hazardous to the aquatic environment, H412 Harmful to aquatic life with long lasting effects.
Chronic, category 3
PRECAUTION PHRASES

P210 Keep away from heat, hot surfaces, sparks, open flames and
other ignition sources. No smoking.
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P264 Wash hands thoroughly after handling.
P273 Avoid release to the environment.
P280 Wear protective gloves/protective clothing/eye protection/
face protection.
P284 Wear respiratory protection.
P304+340 IF INHALED: Remove victim to fresh air and keep at rest in a
position comfortable for breathing.
P305+351+338 IF IN EYES: Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do so.
Continue rinsing.
P308+313 IF exposed or concerned: Get medical advice/attention.
P314 Get medical advice/attention if you feel unwell.
P332+313 If skin irritation occurs: Get medical advice/attention.
P403+233 Store in a well-ventilated place. Keep container tightly
closed.
2.3 Other hazards
No Information

Results of PBT and vPvB assessment:


The product does not meet the criteria for PBT/VPvB in accordance with Annex XIII.

SECTION 3: Composition/Information On Ingredients


3.2 Mixtures

Page 2 / 9
Date Printed: 01/09/2021 Product: FLOWCHEM VE PRIMER

Hazardous ingredients
Name According to EEC EINEC No. CAS-No. % Classifications

Styrene 202-851-5 100-42-5 25 - <50 H226-304-315-319-332- Acute Tox. 4 Inhalation,


335-361d-372 Aquatic Chronic 3, Asp.
Tox. 1, Eye Irrit. 2,
Flam. Liq. 3, Repr. 2,
Skin Irrit. 2, STOT RE
1, STOT SE 3 RTI

CAS-No. M-Factors REACH Reg No.

100-42-5 01-2119457861-32

Additional Information: The text for CLP Hazard Statements shown above (if any) is given in Section 16.

SECTION 4: First-aid Measures


4.1 Description of First Aid Measures
GENERAL NOTES: When symptoms persist or in all cases of doubt seek medical advice. Show this safety data sheet to the
doctor in attendance. Remove contaminated clothing and shoes.
AFTER INHALATION: Move to fresh air. Remove person to fresh air. If signs/symptoms continue, get medical attention.
AFTER SKIN CONTACT: Use a mild soap if available. Wash off immediately with soap and plenty of water while removing
all contaminated clothes and shoes. If skin irritation persists, call a physician. Do NOT use solvents or thinners.
AFTER EYE CONTACT: Keep eye wide open while rinsing. Rinse immediately with plenty of water, also under the eyelids,
for at least 15 minutes. Remove contact lenses. In case of eye contact, remove contact lens and rinse immediately with
plenty of water, also under the eyelids, for at least 15 minutes. If eye irritation persists, consult a specialist.
AFTER INGESTION: Gently wipe or rinse the inside of the mouth with water. If symptoms persist, call a physician or Poison
Control Centre immediately. Give small amounts of water to drink. Do NOT induce vomiting. Never give anything by mouth
to an unconscious person. If swallowed, DO NOT induce vomiting unless directed to do so by medical personnel.
Self protection of the first aider:
No action shall be taken involving any personal risk or without suitable training. It may be dangerous to the person providing aid
to give mouth-to-mouth resuscitation. Wash contaminated clothing thoroughly with water before removing it, or wear gloves.

4.2 Most important symptoms and effects, both acute and delayed

No Information
4.3 Indication of any immediate medical attention and special treatment needed

No information available on clinical testing and medical monitoring. Specific toxicological information on substances, if
available, can be found in section 11.

SECTION 5: Fire-fighting Measures


5.1 Extinguishing Media:
Carbon Dioxide, Dry Chemical, Foam, Water Fog
FOR SAFETY REASONS NOT TO BE USED: Alcohol, Alcohol based solutions, any other media not listed above. Do not
use a solid water stream as it may scatter and spread fire.

5.2 Special hazards arising from the substance or mixture


Explosive reaction may occur on heating or burning. In use, may form flammable/explosive vapour-air mixture.

5.3 Advice for firefighters


Keep containers and surroundings cool with water spray. Fire will produce dense black smoke containing hazardous
combustion products (see section 10). Flash back possible over considerable distance. In the event of fire, wear self-
contained breathing apparatus. Do not use a solid water stream as it may scatter and spread fire. Hazardous decomposition
products formed under fire conditions. Collect contaminated fire extinguishing water separately. This must not be discharged
into drains. Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.

Page 3 / 9
Date Printed: 01/09/2021 Product: FLOWCHEM VE PRIMER

SECTION 6: Accidental Release Measures


6.1 Personal precautions, protective equipment and emergency procedures
Ensure adequate ventilation. Use personal protective equipment. Keep people away from and upwind of spill/leak. Remove
all sources of ignition.
6.2 Environmental precautions
Do not allow material to contaminate ground water system. Prevent product from entering drains.
6.3 Methods and material for containment and cleaning up

Prevent further leakage or spillage if safe to do so. Contain spillage, soak up with non-combustible absorbent material, (e.g.
sand, earth, diatomaceous earth, vermiculite) and transfer to a container for disposal according to local / national regulations
(see section 13). Ventilate the area. Refer to protective measures listed in sections 7 and 8.
6.4 Reference to other sections

FURTHER INSTRUCTIONS: Please refer to EU disposal requirements or country specific disposal requirements for this
material. See Section 13 for further information.

SECTION 7: Handling and Storage


7.1 Precautions for safe handling

Take necessary action to avoid static electricity discharge (which might cause ignition of organic vapours). Vapours may form
explosive mixtures with air. Prevent the creation of flammable or explosive concentrations of vapour in air and avoid vapour
concentration higher than the occupational exposure limits. Electrical equipment should be protected to the appropriate
standard. Preparation may charge electrostatically: always use earthing leads when transferring from one container to
another. Use only in area provided with appropriate exhaust ventilation. Provide sufficient air exchange and/or exhaust in
work rooms. As a rule, at least 10 air changes per hour are recommended at the workplace. To avoid ignition of vapours by
static electricity discharge, all metal parts of the equipment must be grounded. Wear personal protective equipment. Do not
breathe vapours or spray mist. Use only explosion-proof equipment. Keep away from sources of ignition - No smoking.
Repeated or prolonged skin contact may cause skin irritation and/or dermatitis and sensitization of susceptible persons. In
the case of sensitisation to any of the ingredients, it is inadvisable to work with the product. Handle in accordance with good
industrial hygiene and safety practice. Wash hands before breaks and at the end of workday. Keep away from food, drink
and animal feeding stuffs. When using, do not eat, drink or smoke. Wash hands and face before breaks and immediately
after handling the product.
7.2 Conditions for safe storage, including any incompatibilities

CONDITIONS TO AVOID: Avoid temperatures above 40 °C, direct sunlight and contact with sources of heat. Heat, flames
and sparks. Direct sources of heat.
STORAGE CONDITIONS: Store in original container. Store at room temperature in the original container. Keep locked up or
in an area accessible only to qualified or authorised persons. Keep container closed when not in use. Store in a dry, well
ventilated place away from sources of heat, ignition and direct sunlight.
7.3 Specific end use(s)

No specific advice for end use available.

SECTION 8: Exposure Controls/Personal Protection

8.1 Control parameters


Ingredients with Occupational Exposure Limits
(UK WELS)

Name CAS-No. LTEL ppm STEL ppm STEL mg/m3 LTEL mg/m3
Styrene 100-42-5 100 250 1080 430

Name CAS-No. OEL Note

Styrene 100-42-5

FURTHER ADVICE: Refer to the regulatory exposure limits for the workforce enforced in each country. Some components may
not have been classified under the EU CLP Regulation.

8.2 Exposure controls


Personal Protection
RESPIRATORY PROTECTION: Preferably a compressed airline breathing apparatus. In case of insufficient ventilation wear

Page 4 / 9
Date Printed: 01/09/2021 Product: FLOWCHEM VE PRIMER

suitable respiratory equipment. Respirator with a vapor filter.


EYE PROTECTION: Safety goggles. Tightly fitting safety goggles. Safety glasses with side-shields conforming to EN 166.
HAND PROTECTION: Gloves should be discarded and replaced if there is any indication of degradation or chemical
breakthrough. Rubber or plastic gloves. Take note of the information given by the producer concerning permeability and
break through times, and of special workplace conditions (mechanical strain, duration of contact). Long sleeved clothing.
Remove and wash contaminated clothing before re-use. Protective suit. Remove contaminated clothing and protective
equipment before entering eating areas.
OTHER PROTECTIVE EQUIPMENT: No Information
ENGINEERING CONTROLS: As a rule, at least 10 air changes per hour are recommended at the workplace. Avoid contact
with skin, eyes and clothing. Maintain air concentrations below occupational exposure standards. Ensure adequate
ventilation, especially in confined areas.

Chemical Name:
Styrene
EC No.: CAS-No.:
202-851-5 100-42-5

DNELs - Derived no effect level

Workers Consumers
Route of Acute effect Acute effects Chronic Chronic effects Acute effect Acute effects Chronic Chronic effects
Exposure local systemic effects local systemic local systemic effects local systemic
Oral Not required
Inhalation 306 mg/m³ 289 mg/m³ 85 mg/m³
Dermal 406 mg/kg bw/
day
PNEC's - Predicted no effect concentration
Environmental protection target PNEC
Fresh water 0.028 mg/L
Fresh water sediments 0.614 mg/kg
Marine water 0.014 mg/L
Marine sediments 0.307 mg/kg
Food chain None
Microorganisms in sewage treatment 5 mg/L soil dw
soil (agricultural) 0.2 mg/kg
Air None

SECTION 9: Physical and Chemical Properties


9.1 Information on basic physical and chemical properties
Appearance: Colourless
Physical State Liquid
Odor characteristic
Odor threshold Not determined
pH Not determined
Melting point / freezing point (°C) Not determined
Boiling point/range (°C) 145 - N.D.
Flash Point, (°C) ~31
Evaporation rate Not determined
Flammability (solid, gas) Not determined

Upper/lower flammability or explosive 999 - -999


limits
Vapour Pressure Not determined
Vapour density Not determined
Relative density 1,04 g/ml (20°C)
Solubility in / Miscibility with water Not determined

Page 5 / 9
Date Printed: 01/09/2021 Product: FLOWCHEM VE PRIMER

Partition coefficient: n-octanol/water Not determined


Auto-ignition temperature (°C) Not determined
Decomposition temperature (°C) Not determined
Viscosity Not determined
Explosive properties Not determined
Oxidising properties Not determined

9.2 Other information


VOC Content g/l: <60
This is a calculated maximum VOC content for the mixed ready to use product (to Directive 2004/42/EC).

SECTION 10: Stability and Reactivity


10.1 Reactivity
No reactivity hazards known under normal storage and use conditions.
10.2 Chemical stability
Stable under recommended storage conditions. Risk of ignition.
10.3 Possibility of hazardous reactions
Polymerisation occurs when exposed to white light, ultraviolet light or heat.
10.4 Conditions to avoid
Avoid temperatures above 40 °C, direct sunlight and contact with sources of heat. Heat, flames and sparks. Direct sources of heat.
10.5 Incompatible materials
Oxidizing agents. Strong oxidizing agents. Amines. Reducing agents. Heavy metal salts. Avoid radical-forming starting
agents, peroxides and reactive metals.

10.6 Hazardous decomposition products


In case of fire hazardous decomposition products may be produced such as: Carbon monoxide, carbon dioxide and
unburned hydrocarbons (smoke). No dangerous reaction known under conditions of normal use.

SECTION 11: Toxicological Information


11.1 Information on toxicological effects
Acute Toxicity:
Oral LD50: No Information
Inhalation LC50: No Information

Irritation: No information available.

Corrosivity: No information available.

Sensitization: No information available.

Repeated dose toxicity: No information available.

Carcinogenicity: No information available.

Mutagenicity: No information available.

Toxicity for reproduction: No information available.

STOT-single exposure: No information available.

STOT-repeated exposure: No information available.

Page 6 / 9
Date Printed: 01/09/2021 Product: FLOWCHEM VE PRIMER

Aspiration hazard: No information available.

If no information is available above under Acute Toxicity then the acute effects of this product have not been tested.
Data on individual components are tabulated below:

CAS-No. Name According to EEC Oral LD50 Dermal LD50 Vapor LC50 Gas LC50 Dust/Mist LC50

100-42-5 Styrene 5000 mg/kg (rat) 2001 mg/kg (rat) 12 mg/l (rat) 2770 ppm 1.5 mg/l (rat)

Additional Information:
In the case of sensitisation to any of the ingredients, it is inadvisable to work with the product. Repeated or prolonged skin contact
may cause skin irritation and/or dermatitis and sensitization of susceptible persons.

SECTION 12: Ecological Information


12.1 Toxicity:

EC50 48hr (Daphnia): No information


IC50 72hr (Algae): No information
LC50 96hr (fish): No information

12.2 Persistence and degradability: No information

12.3 Bioaccumulative potential: No information

12.4 Mobility in soil: No information

12.5 Results of PBT and vPvB The product does not meet the criteria for PBT/VPvB in accordance with Annex XIII.
assessment:

12.6 Other adverse effects: No information

CAS-No. Name According to EEC EC50 48hr IC50 72hr LC50 96hr

100-42-5 Styrene 4.7 mg/l 4.8 mg/l 4.02 mg/l

SECTION 13: Disposal Considerations


13.1 WASTE TREATMENT METHODS: Do not burn, or use a cutting torch on, the empty drum. If recycling is not practicable,
dispose of in compliance with local regulations. Container hazardous when empty. Empty containers should be taken to an
approved waste handling site for recycling or disposal.
European Waste Code: 080111*
Packaging Waste Code: 150110

SECTION 14: Transport Information


14.1 UN number UN1263
14.2 UN proper shipping name Paint
Technical name Not applicable
14.3 Transport hazard class(es) 3
Subsidiary shipping hazard Not applicable
14.4 Packing group III
14.5 Environmental hazards Not applicable
14.6 Special precautions for user Not applicable
EmS-No.: Not applicable

14.7 Transport in bulk according to Annex II of Not applicable


MARPOL 73/78 and the IBC code

SECTION 15: Regulatory Information

Page 7 / 9
Date Printed: 01/09/2021 Product: FLOWCHEM VE PRIMER

15.1 Safety, health and environmental regulations/legislation for the substance or mixture:
National Regulations:

Denmark Product Registration Number: Not available

Danish MAL Code: Not available

Danish MAL Code - Mixture: Not available

Sweden Product Registration Number: Not available

Norway Product Registration Number: 100121

Germany WGK Class: Not available

Directive 2004/42/CE : <60

Covered by Directive 2012/18/EC (Seveso III): Not applicable

Restrictions to product or to substances according


to Annex XVII, Regulation (CE) 1907/2006: Not applicable

Annex XIV - Authorisation List:


CAS-No. Name According to EEC

Not Applicable

SVHC - Substances of very high concern (Candidate List):

CAS-No. Name According to EEC

Not Applicable

15.2 Chemical Safety Assessment:


No Chemical Safety Assessment has been carried out for this substance/mixture by the supplier.

SECTION 16: Other Information

Text for CLP Hazard Statements shown in Section 3 describing each ingredient:

H226 Flammable liquid and vapour.


H304 May be fatal if swallowed and enters airways.
H315 Causes skin irritation.
H319 Causes serious eye irritation.
H332 Harmful if inhaled.
H335 May cause respiratory irritation.
H361d Suspected of damaging the unborn child.
H372 Causes damage to organs through prolonged or repeated exposure.
Reasons for revision
Substance Hazard Threshold % Changed
Substance and/or Product Properties Changed in Section(s):
01 - Identification
08 - Exposure Controls/Personal Protection
11 - Toxicological Information
12 - Ecological Information
15 - Regulatory Information
Substance CAS Number Changed
Revision Statement(s) Changed

This Safety Data Sheet (SDS) has been revised to meet the new EU CLP requirements. There have been

Page 8 / 9
Date Printed: 01/09/2021 Product: FLOWCHEM VE PRIMER

both formatting and content changes based on the CLP classification (if applicable), please review
each section of the SDS for specific changes.

List of References:

This Safety Data Sheet was compiled with data and information from the following sources:

The Ariel Regulatory Database provided by the 3E Corporation in Copenhagen, Denmark;


European Union Commission Regulation No. 1907/2006 on REACH as amended within Commission Regulation
(EU) 2015/830;
European Union (EC) Regulation No. 1272/2008 on the classification, labelling and packaging of
substances and mixtures (CLP Regulation) and subsequent technical progress adaptations (ATP);
EU Council Decision 2000/532/EC and its Annex entitled "List of Wastes".

Acronym & Abbreviation Key:

CLP Classification, Labeling & Packaging Regulation


EC European Commission
EU European Union
US United States
CAS Chemical Abstract Service
EINECS European Inventory of Existing Chemical Substances
REACH Registration, Evaluation, Authorization of Chemicals Regulation
GHS Globally Harmonized System of Classification and Labeling of Chemicals
LTEL Long term exposure limit
STEL Short term exposure limit
OEL Occupational exposure limit
ppm Parts per million
mg/m3 Milligrams per cubic meter
TLV Threshold Limit Value
ACGIH American Conference of Governmental Industrial Hygienists
OSHA Occupational Safety & Health Administration
PEL Permissible Exposure Limits
VOC Volatile organic compounds
g/l Grams per liter
mg/kg Milligrams per kilogram
N/A Not applicable
LD50 Lethal dose at 50%
LC50 Lethal concentration at 50%
EC50 Half maximal effective concentration
IC50 Half maximal inhibitory concentration
PBT Persistent bioaccumulative toxic chemical
vPvB Very persistent and very bioaccumulative
EEC European Economic Community
ADR International Transport of Dangerous Goods by Road
RID International Transport of Dangerous Goods by Rail
UN United Nations
IMDG International Maritime Dangerous Goods Code
IATA International Air Transport Association
MARPOL International Convention for the Prevention of Pollution From Ships, 1973 as
modified by the Protocol of 1978
IBC International Bulk Container
RTI Respiratory Tract Irritation
NE Narcotic Effects

For further information, please contact: Technical Services Department

The information on this sheet corresponds to our present knowledge. It is not a specification and
it does not guarantee specific properties. The information is intended to provide general
guidance as to health and safety based upon our knowledge of the handling, storage, and use of the
product. It is not applicable to unusual or non-standard uses of the product or where instructions
and recommendations are not followed.

Page 9 / 9

You might also like