Alcohols, Carboxylic Acids, and Esters IGCSE
Alcohols, Carboxylic Acids, and Esters IGCSE
Alcohols, Carboxylic Acids, and Esters IGCSE
CHEMISTRY
UNIT TEST
GRADE 8
Please write clearly, in block capitals.
Centre number
9
6
2
0
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Student Number
2. Which compound does not belong to the same homologous series as the other three compounds?
A. CH3OH C. C2H5OH
B. C2H5COOH D. C7H15OH
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4. The diagram represents the molecule of an organic compound.
5. Compounds containing five carbon atoms in a molecule may have names beginning with ‘pent…’.
What is the name of the compound shown?
A. Pentane C. Pentanol
B. Pentanoic acid D. Pentene
7. When …………… reacts with sodium metal, the sodium effervesces (gives off a bubble of gas),
producing hydrogen gas.
A. Benzoic acid C. Carboxylic acid
B. Alcohol D. Ester
11. What are the products of the reaction between methanol and ethanoic acid?
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A. Ethyl methanoate and water C. Methyl ethanoate and water
B. CH3COOCH3 and hydrogen D. CH3COOCH3 and hydrogen
C.
D.
B.
13. Upon oxidation with potassium dichromate(VI), ethanol turns into ………….
A. Ethanoic acid C. Sodium etoxide
B. Metahoic acid D. Butanol
B.
D.
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Read the questions carefully and answer in the space provided. (30 marks)
1.
This question is about alcohols and carboxylic acids.
Table 1 shows the names and formulae of the first three members of a homologous series of
alcohols.
Table 1
Alcohol Formula
Methanol CH3OH
Ethanol CH3CH2OH
Propanol CH3CH2CH2OH
(a) How do the formulae of alcohols show that they are members of the same homologous
series?
Use Table 1 .
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(1)
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(1)
(c) Propanol can be oxidised to produce propanoic acid. Complete the figure below to show
the displayed structure of propanoic acid (CH3CH2COOH).
C—C—C
(1)
(d) Table 2 shows information about the first three members of a homologous series of
carboxylic acids.
Table 2
pH of 1.0
Carboxylic acid Formula
mol/dm3solution
Methanoic acid HCOOH 2.91
Ethanoic acid CH3COOH 3.39
Propanoic acid CH3CH2COOH 3.44
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Describe how the pH changes when the number of carbon atoms in the carboxylic acid
changes.
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(1)
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(Total 5 marks)
2.
This question is about carboxylic acids and esters.
(a) What is the displayed structure of ethanoic acid? Tick (✓) one box.
(1)
(1)
(c) Ethanoic acid reacts with ethanol to produce ethyl ethanoate and one other substance.
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Carbon dioxide Methane
Hydrogen Water
(1)
(d) Ethyl ethanoate is an ester. Which is a use of esters? Tick (✓) one box.
(1)
(e) Which is the ester functional group? Tick (✓) one box.
(1)
(Total 5 marks)
3.
Alcohols, carboxylic acids and esters are organic compounds with different functional groups.
(a) What type of reaction can be used to convert ethanol into ethanoic acid? Tick one box.
addition polymerisation
oxidation reduction
(1)
(b) Ethanol and ethanoic acid react together in the presence of a catalyst to form the ester
shown in Figure 1.
Figure 1
(1)
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(c) Which type of chemical is used as a catalyst in this reaction?
_________________________________________________________________ (1)
Table 1
Substance Boiling point in °C
Ethanol 78
Ethanol acid 118
Why does ethanoic acid have a higher boiling point than ethanol?
Tick one box.
(1)
5 9
7 11
(1)
(Total 5 marks)
4.
The diagrams represent two compounds, A and B.
Compound A Compound B
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(1)
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(2)
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(1)
Name compound C.
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(1)
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(1)
(Total 6 marks)
5.
Propyl propanoate is the ester responsible for the odor of pineapple or pear essence.
a) Write an equation for the formation of this ester from an alcohol and a carboxylic acid.
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(1)
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b) Name the carboxylic acid used.
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(1)
6.
The structures of substances X and Y are shown below:
a) Write a balanced equation for the reaction between substance X and sodium carbonate,
Na2CO3.
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(3)
b) Substance Y can be synthesized from substance X in a single-step process.
Give the name of the other reagent necessary for this synthesis and name the type of
reaction.
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(2)
(Total 5 marks)
Good luck!
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