Chem c2 Exer1
Chem c2 Exer1
Chem c2 Exer1
5. What is the general formula of the alcohol family? 6. Name the functional group of the alcohol family. 7. When ethanol is dissolved in water, the solution does not affect litmus paper. However, when sodium hydroxide is dissolved in water, the solution turns red litmus paper into blue. With relevant equations, explain this observation. 8. What is the role that the functional group plays in the chemical properties of the alcohol family? 9. Give the IUPAC name of the organic compound given below
a) Write the structural formula for 2-methylpropan-1-ol. b) State the similarity and difference between the organic compounds above with butan-2-ol 10. Write the chemical equation for the complete combustion of propan-2-ol 11. Write the chemical equation for each of the following reactions and name the organic product obtained. a) Propan-1-ol + mixture of potassium dichromate(VI) and dilute sulphuric acid b) Butan-2-ol + concentrated sulphuric acid at 180C c) Butan-1-ol vapour passed over hot porous pot chips 12. Which of the following molecular formulae represents the first three members of the alcohol family? A. C2H5OH, C3H7OH, C4H9OH B. CH4OH, C2H6OH, C3H8OH C. CH3OH, C2H5OH, C3H7OH D. CHOH, C2H4OH, C3H6OH 13. When ethanol vapour is channeled through hot porous clay pieces, a certain gas is produced. Which of the following is not the characteristic of the gas produced? A. Changes the litmus solution colour to red B. Decolourises bromine water C. Decolourises acidified potassium manganate(IV) solution D. Produces carbon dioxide gas and water when burnt 14. Discuss the order of change in the boiling points of members of alcohol homologous series as the number of carbon atoms per molecule increases. 15. Ethanol reacts with sodium according to the following equation 2C2H5OH (aq) + 2Na (s) 2C2H5ONa (aq) + H2 (g) Sodium ethoxide and hydrogen gas are formed. Predict the reaction of butan-1-ol with sodium. 16. Ethanol can be produced by the fermentation of glucose using yeast in the laboratory. Write the equation for this process. 17. Complete the following table Process Oxidation Alcohol Ethanol Propanol Product Propene
19. Butane can be converted to butanol at a temperature of 300C and in the presence of a catalyst which is A. Potassium manganite(VII) B. Copper(II) oxide C. Nickel D. Phosphoric acid 20. Ethanol can be prepared in laboratory from the reaction between A. Ethene and hydrogen B. Ethene and steam C. Ethane and hydrogen D. Ethane and steam 21. When ethanol vapour is channeled through hot porous clay pieces, a certain gas is produced. Which of the following is not the characteristic of the gas produced? A. Changes the litmus solution colour to red B. Decolourises bromine water C. Decolourises acidified potassium manganite(VII) solution D. Produces carbon dioxide and water when burnt 22. Which of the following reactions will produce carbon dioxide? I. Fermentation II. Combustion of alcohol III. The reaction between carboxylic acid with sodium carbonate IV. The reaction between alcohol and carboxylic acid A. I and III only B. II and IV only C. I, II and III only D. I, II, III and IV 23. Which of the following statements describes the characteristic of ethanol? A. Ethanol has the OH group which makes it alkaline B. Ethanol has the OH group which forms a bond with water when it dissolves in water C. Ethanol can react with water when it dissolves in water D. Ethanol can be oxidised into ethane 24. What is the general formula of carboxylic acid? 25. Draw the structural formula for ethanoic acid and propanoic acid. 26. Which of the following compounds belong to the same homologous series as ethanoic acid? A. C2H5CH2OH B. CH3COOCH3 C. C2H5COOH D. HCOOC2H5 27. Give two physical properties of ethanoic acid. 28. Name the products of reaction between ethanoic acid and nagnesium. 29. Name the reaction between ethanoic acid and sodium hydroxide.Write an equation for reaction. 30. Write the equation for the reaction between calcium carbonate with ethanoic acid. 31. Name the first member of the carboxylic acid family. Draw the structural formula of the acid molecule. With the help of relevant equations, describe how the acid in reacts with a) Sodium b) Magnesium carbonate c) Copper(II) hydroxide 32. Compounds P and Q have the same number of carbon atoms. When 1 mole of compound P is burned completely, 3 moles of carbon dioxide are produced. Compound P is neutral whereas compound Q is acidic.
18. Name the alcohol used to manufacture butane. Write an equation for the reaction.
a) Name the compounds P and Q. b) Compound P is converted into compound Q by process i. name the reaction in process i. c) Write an equation for process i. d) What is the name of compound R? e) Name the process ii. f) Give an equation to represent process ii. 33. Give the general formula of the ester family. 34. A carboxylic acid reacts with an alcohol in the presence of concentrated sulphuric acid to produce a salt and water. Is this statement correct? Explain your answer.
35. Name and draw the structural formula of the ester produced from a reaction between a) Methanol + propanoic acid b) Ethanol + butanoic acid c) Propan-1-ol + ethanoic acid 36. An esterification is carried out to prepare an ester from the first member of the carboxylic acid family. The ester has a total of three carbon atoms. a) What is the functional group of the esters? b) Name the alcohol needed to prepare the ester c) Write an equation for the reaction d) Briefly describe how the reaction can be carried out 37. An ester R is prepared from an alcohol P and a carboxylic acid Q. the molar mass P and Q are given below Substa Molar mass (g nce mol-1) P 46 Q 74 a) Given that the relative atomic mass of H: 1, C: 12 and O: 16. Determine the molecular formula of alcohol P and carboxylic acid Q b) How and under what conditions will alcohol P and carboxylic acid Q react to produce an ester R? c) Write an equation for the reaction in b. 38. Name the elements that make up fats 39. Name the sources of each the following fats Common Source name Stearic acid Lauric acid Palmitic acid 40. Name glycerol using the IUPAC system. Draw the structural formula for glycerol 41. State the two uses of fat in human 42. Our bodies need fats and oils. They are essential in helping us maintain healthy and strong bodies. Discuss the roles fats and oils play in helping us to maintain a healthy body. 43. State one importance of fats to our health 44. State one adverse effect of excessive intake of fats to our blood vessels 45. Based on the diagram below
48. Palm oil has many uses. It is widely used in the food industry as well as for industrial processes a) Give one reason why palm oil is considered as a better source of cooking oil compared to other plant oils b) Name the vitamin which is rich in palm oil that can help in delaying ageing and fight against arteriosclerosis c) Name a substance which imparts the reddish colour to palm oil and has anti-cancer properties d) Name one palm oil product which is used in making cakes and biscuits e) Name one cleaning agent in our household that is made from palm oil 49. A natural polymer has a structure shown in figure below.
What is a polymer? What class of polymer is shown above? Name the monomer for this polymer. Carbohydrate is another example of a natural polymer. i. Name two examples of carbohydrates. ii. What is the monomer of carbohydrates? 50. Part of the structure of a natural rubber chain is shown below.
a) b) c) d)
Give the molecular formula of the fat molecule shown above How can this molecule be prepared in the laboratory? Explain the meaning of saturated fat and unsaturated fat. How can an unsaturated fat be converted into a saturated fat? 46. The following equation shows the formation of fat and oil from a fatty acid and glycerol. Fatty acid + Glycerol Fat and oil a) Name the functional group found in fatty acids b) Name the functional group found in glycerol c) When a fatty acid and glycerol are combined, fat is formed. What can one deduce about the chemical nature of fat? d) Give one example of a saturated fatty acid e) Name the fat or oil produced when the saturated fatty acid reacts with glycerol 47. Fats and oils are classified as saturated fats and unsaturated fats. Saturated fats are made from saturated fatty acids whereas unsaturated fats are made from unsaturated fatty acids. a) Give one effect of eating a diet high in saturated fats b) Give one health benefit of consuming palm oil c) The structure of an unsaturated fatty acid is shown below
a) b) c) d)
a) Name the monomer of this polymer b) What is the type of reaction that joins the monomers together to form natural rubber? c) Briefly describe how coagulation of latex taken place when an acid is added? 51. Figure below shows a section of vulcanized rubber a) How is vulcanization of rubber carried out in the school laboratory? b) Identify the atoms that link the rubber chains together c) What is the structure in the rubber chain allows vulcanization to occur? d) State three properties in which vulcanized rubber is better than unvulcanised rubber 52. Which of the following are the properties of vulcanized rubber? i. Vulcanized rubber is harder than unvulcanised ii. Vulcanized rubber is black in colour iii. Vulcanized rubber has sulphur linkages between the polymer chains iv. Vulcanized rubber is more elastic than unvulcanised rubber A. i, ii and iii B. i, ii and iv C. i, iii and iv D. ii, iii and iv 53. Which of the following chemicals can prevent the coagulation of latex? A. Sulphur dichloride B. Hydrochloric acid C. Sodium hydroxide D. Propanol 54. Freshly-taped rubber latex will coagulate if it is left for a day without any chemical added. This is due to the presence of Z in the latex. Which of the following is Z? A. Bacteria B. Sodium hydroxide C. Ammonia D. Sulphuric acid 55. The diagram shows the conversion of latex to vulcanised rubber
i. What is observed when this fatty acid is shaken with bromine water? ii. 0.10 mole of this fatty acid is reacted with excess bromine. Calculate the number of moles of bromine reacted
a) Name the reaction i b) Name the chemical that is added to latex in reaction i c) Draw the structural formula of the monomer of natural rubber and name it d) Draw the repeating unit for natural rubber e) How is reaction ii carried out in the industry 56. Just like alkanes, ester compounds also form a homologous series. Diagram below shows the part structure of an ester.
O H C O
a) What is a homologous series? b) Copy and complete the structure in diagram above to show an ester obtained from an esterification reaction between propan1-ol and methanoic acid. c) Write an equation for the esterification reaction in b. d) Give the reaction conditions for the esterification reaction