Chapter 2
Chapter 2
Chapter 2
1.2 Manufacture 1.5.2 The thickness of the plates and strips is to be meas-
ured at random locations, whose distance from the longitu-
1.2.1 Steel is to be manufactured by the electric furnace, dinal edge is to be at least 10 mm.
basic oxygen or open hearth processes. The under thickness requirements are indicated in the Arti-
The use of other processes may be specially approved by cles relevant to the various products.
the Society.
1.6 Rectification of surface defects
1.2.2 The steel is to be cast in ingot moulds or by a contin-
uous casting process. 1.6.1 Rectification of surface defects by grinding
Provision is to be made for sufficient discard such as to Defects which need to be repaired may be removed by
ensure: grinding.
• at both ends of the ingots, the soundness of the material The general provisions of Ch 1, Sec 1 and specific require-
• at the transitory zones of continuous casting material, a ments for the various products as specified in the relevant
homogeneous chemical composition along the longitu- Articles of this Section apply.
dinal axis. The repaired areas are to be ground smooth to the adjacent
surface of the plate.
1.3 Approval
The Surveyor may request that the complete removal of
1.3.1 The manufacturing process is to be approved by the defects is verified by suitable non-destructive examination.
Society for individual steelmakers, grade of steel and prod-
1.6.2 Rectification of surface defects by welding
ucts, as specified in the applicable Articles.
Surface defects of products which cannot be removed as
Provisions for the approval are given in the document stated in [1.6.1] may be repaired by chipping or grinding
NR480 “Approval of the manufacturing process of metallic followed by welding subject to the Surveyor’s consent and
materials”. under his supervision.
1.3.2 It is the manufacturer’s responsibility to assure that The general provisions of Ch 1, Sec 1 and specific require-
effective process and production controls in operation are ments for the various products as specified in the relevant
adhered to within the manufacturing specifications. Where Articles of this Section apply.
control imperfection inducing possible inferior quality of
product occurs, the manufacturer is to identify the cause 1.7 Condition of supply
and establish a countermeasure to prevent its recurrence.
Also, the complete investigation report is to be submitted to 1.7.1 The conditions of supply are specified in the Articles
the surveyor. For further use, each affected piece is to be relevant to the various products.
tested to the Surveyor’s satisfaction. The frequency of testing Where alternative supply conditions are agreed, the choice
for subsequent products offered may be increased at the dis- of the supply condition, unless otherwise required, is left to
cretion of the Society. the Manufacturer; the condition of supply is always to be
mentioned in the testing documentation.
1.4 Quality of materials
1.7.2 When acceptable as an alternative to normalising,
1.4.1 All products are to have a workmanlike finish and to the procedures relevant to controlled or thermo-mechanical
be free from surface or internal defects which may impair rolling process are to be specially approved for individual
their proper workability and use. steelworks.
1.7.3 The rolling practice applied is to comply with the 1.8 Sampling and tests
appropriate condition of supply. The applicable procedures
are defined as follows: 1.8.1 General
All products are to be presented for testing in the final sup-
a) As Rolled, AR ply condition in batches or rolled units as specified in the
This procedure involves the rolling of steel at high tem- Articles relevant to the various products.
perature followed by air cooling. The rolling and finish-
ing temperatures are typically in the austenite 1.8.2 Sampling
recrystallization region and above the normalising tem- The samples required for the preparation of test specimens
perature. The strength and toughness properties of steel are, in general, to be cut from:
produced by this process are generally less than those of a) the end of the plate or section corresponding to the top
steel either heat treated after rolling or produced by position of the ingot, in the case of casting in ingot
advanced process. moulds
b) Normalising, N b) any end of the plate or section, where such products are
rolled from blooms or billets manufactured by continu-
Normalising involves heating rolled steel above the crit- ous casting, on the understanding that sufficient discard
ical temperature, Ac3 , and in the lower end of the is taken from the transitory zones of the cast beginning
austenite recrystallization region followed by air cool- and end
ing. The process improves the mechanical properties of
c) both the ends of the coil for plates fabricated in coils.
as rolled steel by refining the grain size.
Samples are to be taken from the following positions:
c) Controlled Rolling, CR (Normalising Rolling, NR) • plates and flats having width ≥ 600 mm: at approxi-
This is a rolling procedure in which the final deforma- mately one quarter of the width from an edge (see Fig 1)
tion is carried out in the normalising temperature range,
resulting in a material condition generally equivalent to Figure 1 : Plates and flats
that obtained by normalising.
1/4 W
Figure 4 : Sections ucts and only one individual value may be less than the
average required, provided that it is not less than 70% of it.
A
The minimum average values are relevant to the standard
specimen 10x10 mm2.
For subsize specimen dimensions and requirements, refer-
1/3 A
1/4 B
ence is to be made to Ch 1, Sec 2, [4.2.2].
B
For tensile re-test procedure, reference is made to Ch 1, Sec
2, [2.3].
For Charpy V-notch re-test procedure, reference is made to
Ch 1, Sec 2, [4.4].
The workshop where the steel was produced is to be 2.2 Steel grades
approved by the Society.
2.2.1 The steels are classed, on the basis of a minimum
The Society’s Surveyors are to have free access to the work- yield strength level ReH (N/mm 2), into normal strength
shop of the original Manufacturer, who is fully responsible (ReH=235) and higher strength (32: ReH=315 - 36: ReH=355 -
for complying with all applicable requirements. 40: ReH = 390).
Normal strength steels are divided into four grades A, B, D
2 Normal and higher strength steels for and E. For normal strength steels, the letters A, B, D and E
mean impact properties at +20, 0, −20 and −40°C, respec-
hull and other structural applications tively.
Higher strength steels are divided into four grades identified
2.1 Scope by the letters AH, DH, EH and FH followed by a number
related to the yield strength level. For higher strength steels,
2.1.1 The requirements of this Article apply to weldable the letters AH, DH, EH and FH mean impact properties at 0,
normal and higher strength steel hot rolled plates, wide −20, −40 and −60°C, respectively.
flats, sections and bars intended for use in hull construction
2.2.2 Steels differing in chemical composition, deoxidation
and other structural applications.
practice, conditions of supply and mechanical properties
may be accepted, subject to the special approval of the
2.1.2 Provision is made for: Society. Such steels are to be given a special designation.
• plates and wide flats of all grades not exceeding
100 mm in thickness 2.3 Manufacture
Steel grade A B D E
Deoxidation practice for t ≤ 50 mm: any method t ≤ 50 mm: any method t ≤ 25 mm: killed killed and fine
thickness t (mm) except rimmed (1) except rimmed t > 25 mm: killed and grain treated
t > 50 mm: killed t > 50 mm: killed fine grain treated
Chemical composition
(%) (2) (3) (4)
C max (5) 0,21 (6) 0,21 0,21 0,18
Mn min (5) 2,5 x C 0,80 (7) 0,60 0,70
Si max 0,50 0,35 0,35 0,35
P max 0,035 0,035 0,035 0,035
S max 0,035 0,035 0,035 0,035
Al (acid soluble) min 0,015 (8) (9) 0,015 (9)
(1) For sections up to a thickness of 12,5 mm, rimmed steel may be accepted subject to the special approval of the Society.
(2) When any grade of steel is supplied in the thermo-mechanically rolled condition, variations in the specified chemical composi-
tion may be allowed or required by the Society and are to be stated at the approval.
(3) The Society may limit the amount of residual elements which may have an adverse effect on the working and use of the steel,
e.g. copper and tin.
(4) Where additions of any other element have been made as part of the steelmaking practice, the content is to be indicated in the
ladle analysis certificate.
(5) C +1/6 Mn is not to exceed 0,40%.
(6) Max. 0,23% for sections.
(7) When Grade B steel is impact tested, the minimum manganese content may be reduced to 0,60%.
(8) Al is required for thickness greater than 25 mm.
(9) The total aluminum content may be determined instead of acid soluble content. In such cases the total aluminum content is to
be not less than 0,020%. Other suitable grain refining elements may be used subject to the special approval of the Society.
2.3.3 Rolling practice ASTM A 578) and an examination level accepted by the
Where CR (NR) and TM with or without AcC are applied, Society.
the programmed rolling schedules are to be submitted to
the Society at the time of the approval and are to be made 2.3.6 Rectification of surface defects by grinding
available when required by the attending Surveyor. On the Surface defects may be removed by grinding as indicated in
manufacturer’s responsibility, the programmed rolling [1.6.1] provided that:
schedules are to be adhered to during the rolling operation
a) the nominal thickness will not be reduced by more than
(as per [1.3.2]). To this effect, the actual rolling records are
7% or 3 mm, whichever is the lesser
to be reviewed by the manufacturer and, occasionally, by
the Surveyor. b) each single ground area does not exceed 0,25 m 2
When deviation from the programmed rolling schedules c) the total area of local grinding does not exceed 2% of
occurs, the manufacturer is to take further measures, to the the total surface of the plate.
Surveyor’s satisfaction, in accordance with [1.3.2].
Adjacent repairs located at a distance less than their mean
2.3.4 Tolerances on dimensions width are considered as forming a single ground area.
For plates and wide flats with thicknesses of 5mm and over, In the case of ground areas lying opposite each other on
an under thickness tolerance of 0,3 mm is permitted. both surfaces of the plate, the resulting thickness is to satisfy
For sections and bars, the under thickness tolerance is to be in any place the values indicated in item a).
in accordance with the requirements of a recognised inter-
2.3.7 Rectification of surface defects by welding
national or national standard.
Surface defects of products which cannot be removed as
Measurements are to be made as indicated in [1.5.2].
stated in [2.3.6] may be repaired by chipping or grinding
2.3.5 Non-destructive examinations followed by welding subject to the Surveyor’s agreement
and witnessing when requested, provided that:
Ultrasonic testing of plates intended for offshore structural
applications of first and special category as defined in the a) after removal of defects and before welding, the thick-
Society’s Offshore Rules is required and is to be performed ness of the piece is in no place reduced by more than
in accordance with a recognised standard (e.g. EN 10160 or 20% with respect to the nominal thickness
b) repair is carried out by an approved procedure and by At the time of the approval of higher strength steels, an
qualified welders using approved low hydrogen elec- upper limit for carbon equivalent CEQ on the ladle analysis
trodes and the excess weld thickness is subsequently may be specified.
ground smooth to the surface level Unless otherwise agreed, the value of CEQ is calculated by
2
c) no single welded area exceeds 0,125 m and the sum of the following formula:
all welded areas does not exceed 2% of the total surface Mn Cr + M o + V Ni + Cu
area of the plate C E Q = C + --------- + -------------------------------- + --------------------- %
6 5 15
d) after the final grinding the piece is normalised or stress- For steel produced by thermo-mechanical rolling, CEQ is to
relieved, where required by the Surveyor. For plates to comply with the requirements of Tab 3.
be supplied in normalised condition, a new normalising As an alternative to CEQ, at the discretion of the Society, the
heat treatment is required as a rule, except for repairs of cold cracking susceptibility Pcm may be used for evaluating
negligible size, when the piece had already been nor- the weldability.
malised before repair; for products obtained by thermo-
mechanical rolling processes, the conditions stated at Pcm is given by the following formula and an upper limit
the approval of the rolling process apply may be agreed at the time of the approval of the steel:
S i Mn Cu N i Cr Mo V
e) the repaired plates are presented to the Surveyor for Pc m = C + ------ + --------- + ------- + ------ + ------ + --------- + ------ + 5B %
30 20 20 60 20 15 10
acceptance; in addition to the visual inspection the Sur-
veyor may require the soundness to be verified by ultra- When a limit of CEQ and Pcm is required, the relevant val-
sonic, magnetic particle or dye penetrant methods, as ues are to be stated by the Manufacturer and included in
appropriate. the testing documentation for each cast.
2.4.1 The products are to be supplied in the condition indi- Carbon equivalent
cated in Tab 5 and Tab 6 for normal strength steels and Tab Steel grade CEQ max. (%) (1)
9 and Tab 10 for higher strength steels.
t ≤ 50 50 < t ≤ 100
The definition of the supply conditions is given in [1.7.3].
AH32, DH32, EH32, FH32 0,36 0,38
AH36, DH36, EH36, FH36 0,38 0,40
2.5 Chemical composition AH40, DH40, EH40, FH40 0,40 0,42
t = thickness (mm)
2.5.1 General
(1) More stringent carbon equivalent limits may be agreed
The chemical composition is determined by the Manufac-
between the Manufacturer and the shipbuilder in indi-
turer on ladle samples (see Ch 1, Sec 1, [2.2.1]).
vidual cases.
Table 5 : Normal strength plates and wide flats - Condition of supply and number of impact tests
Table 6 : Normal strength sections and bars - Condition of supply and number of impact tests
Yield stress Tensile Elong. A5 Average impact energy (J) min. for thickness t (mm)
Steel grade ReH strength Rm (%) min. Test temp. t ≤ 50 50 < t ≤ 70 70 < t ≤ 100
(N/mm²) min. (N/mm²) (1) (°C) KVL KVT KVL KVT KVL KVT
AH32 315 440/570 22 0 31 22 38 26 46 31
DH32 − 20 31 22 38 26 46 31
EH32 − 40 31 22 38 26 46 31
FH32 − 60 31 22 38 26 46 31
AH36 355 490/630 21 0 34 24 41 27 50 34
DH36 − 20 34 24 41 27 50 34
EH36 − 40 34 24 41 27 50 34
FH36 − 60 34 24 41 27 50 34
AH40 390 510/660 20 0 39 26 46 31 55 37
DH40 − 20 39 26 46 31 55 37
EH40 − 40 39 26 46 31 55 37
FH40 − 60 39 26 46 31 55 37
(1) For full thickness flat tensile test specimens with a width of 25 mm and a gauge length of 200 mm, the elongation is to comply
with the minimum values given in Tab 8.
Strength grade t≤5 5 < t ≤ 10 10 < t ≤ 15 15 < t ≤ 20 20 < t ≤ 25 25 < t ≤ 30 30 < t ≤ 40 40 < t ≤ 50
32 14 16 17 18 19 20 21 22
36 13 15 16 17 18 19 20 21
40 12 14 15 16 17 18 19 20
Table 9 : Higher strength plates and wide flats - Condition of supply and number of impact tests
Table 10 : Higher strength sections and bars - Condition of supply and number of impact tests
b) except for grade A, for products supplied subject to spe- 3.3 Manufacture
cial approval in the as rolled condition (AR*), and for
products with thickness higher than 50 mm supplied in 3.3.1 Approval
the controlled rolled condition (NR), the mass of the The Manufacturers are to be approved by the Society and
batches for the purpose of impact tests is to be 25 t, or a the relevant requirements of [1.2] apply.
fraction thereof
3.3.2 Deoxidation process
c) one set of three impact test specimens is required for: The steel is to be fully killed and fine grain treated.
• each piece for grades E and F in all strengths
3.3.3 Dimensional tolerances and surface conditions
• each batch of 25 t or fraction thereof of sections of
Unless otherwise agreed or specially required, for under
grades E and F in all strengths
thickness tolerances, surface condition and rectification of
d) when, subject to special approval, sections of steel surface defects, the requirements depend on the applications
grades E and F in all strengths other than 40 are supplied and are indicated in [2.3.4], [2.3.6] and [2.3.7] for structural
in the as rolled (AR*) or controlled rolled (NR*) condi- applications, in [4.3.4], [4.3.5] and [4.3.6] for applications
tion, the mass of the batches for the purpose of impact under pressure and in [6.3.3] for parts of machinery.
tests is to be 15 t, or a fraction thereof.
Repair by welding is to be specially approved.
Random checks of the impact values may be required at the
discretion of the Surveyor. 3.3.4 Non-destructive examination
For specific applications, ultrasonic examination in accord-
ance with recognised standards may be required.
3 High strength quenched and tem-
Ultrasonic testing of plates intended for offshore structural
pered steels applications of first and special category as defined in the
Society’s Offshore Rules is required and is to be performed
3.1 Scope in accordance with a recognised standard (e.g. EN 10160 or
ASTM A 578) and an examination level accepted by the
3.1.1 The requirements of this Article apply to weldable Society.
ferritic high strength quenched and tempered steel plates
and wide flats with thickness up to 70 mm. 3.4 Condition of supply
These requirements may also be applied to products with
thickness above 70 mm and to other product forms, such as 3.4.1 The products are to be supplied in the quenched and
sections and tubulars, subject to special agreement with the tempered condition.
Society. However, thermo-mechanical rolling may be also permitted
subject to special approval for thicknesses up to 50 mm, for
3.2 Steel grades steels up to grade 550.
For the definition of rolling procedures, see [1.7.3].
3.2.1 The requirements apply to carbon-manganese and
low alloyed steels. 3.5 Chemical composition
The steels are classed into six groups indicated by minimum
yield strength levels ReH (N/mm2) 420, 460, 500, 550, 620 3.5.1 The chemical composition on ladle analysis is to
and 690. comply with the requirements specified in Tab 11 and in
the approved specification.
Each group is further subdivided into four grades A, D, E
The approved specification is also to include the alloying
and F based on the impact test temperature. and grain refining elements and the maximum Pcm value
The letters A, D, E and F mean impact test at 0, −20, −40 (cold cracking susceptibility index), agreed during the initial
and −60°C, respectively. approval tests of the steel.
The Pcm value is to be calculated from the ladle analysis in The alloying and grain refining elements and Pcm value, as
accordance with the following formula: applicable, are to be stated by the steelmaker and included
in the testing documentation for each cast.
S i Mn Cu N i Cr Mo V
Pcm = C + ------ + --------- + ------- + ------ + ------ + --------- + ------ + 5B %
30 20 20 60 20 15 10
3.6 Mechanical properties
3.6.1 The mechanical properties are specified in Tab 12.
Table 13 : Minimum elongation values for flat specimens 25 mm width and 200 mm gauge length
Thickness t (mm)
Strength level
t ≤ 10 10 < t ≤ 15 15 < t ≤ 20 20 < t ≤ 25 25 < t ≤ 40 40 < t ≤ 50 50 < t ≤ 70
420 11 13 14 15 16 17 18
460 11 12 13 14 15 15 17
500 10 11 12 13 14 15 16
550 10 11 12 13 14 15 16
620 9 11 12 12 13 14 15
690 9 10 11 11 12 13 14
3.7 Mechanical tests 4.1.2 Special requirements may be specified in the case of
applications intended for dangerous substances or particu-
3.7.1 General larly severe service conditions.
Samples for tests are to be cut from the products in the final
supply condition. The tests are to be carried out on each 4.1.3 In the case of applications involving the storage and
rolled unit as heat treated. transport of liquefied gases, the relevant requirements of the
Society’s Rules for the Classification of Steel Ships apply.
The definition of rolled unit is given in Ch 1, Sec 1, [3.3.3].
For continuously heat treated products, special sampling 4.2 Steel grades
procedures may be agreed at the Society’s discretion.
4.2.1 The requirements apply to carbon and carbon man-
3.7.2 Sampling
ganese steels and low alloy steels (Mo and Cr-Mo steels).
In the case of plates and flats having width ≥ 600 mm, the
tensile test and impact test specimens are to be taken in the 4.2.2 Carbon and carbon manganese steels are classed into
transverse direction. four groups indicated by the minimum ultimate tensile
In other cases the specimens are to be taken in the longitu- strength Rm ( N/mm2): 360, 410, 460 and 510.
dinal direction, unless otherwise required by or agreed with Each group may be further subdivided into grades HA, HB
the Society. and HD, as appropriate, based on the quality level and
impact properties.
3.7.3 Number of tests
The letters HA, HB and HD mean impact properties at
The following test specimens are to be taken from each
+20°C, 0°C and −20°C, respectively.
sample:
a) 1 tensile test specimen, 4.2.3 Low alloy steels are designated according to the
b) 1 set of 3 Charpy V-notch impact test specimens. chemical composition into the grades 0,3Mo - 1Cr0,5Mo -
2,25Cr1Mo.
4 Steels for boilers and pressure ves- Two types of 2,25Cr1Mo steel are specified in relation to
the heat treatment and consequent mechanical properties.
sels
The figures mean the nominal percentage content of the
main alloying elements.
4.1 Scope
4.1.1 The requirements of this Article apply to weldable 4.3 Manufacture
ferritic steel products (plates, flats, sections and bars)
4.3.1 Approval
intended for boilers and pressure vessels.
Unless otherwise agreed by the Society, the Manufacturers
Provision is made for products with thickness up to 60 mm
are to be approved and the relevant requirements of [1.2]
and impact properties at a temperature not lower than −
apply.
20°C.
These requirements may also be applied to products with 4.3.2 Deoxidation process
thickness above 60 mm subject to agreement with the Soci- The method of deoxidation is specified in Tab 14 and Tab
ety. 15.
4.3.3 Rolling practice ance and the relevant conditions are subject to special con-
Where CR (NR) are applied, the programmed rolling sched- sideration by the Society.
ules are to be submitted to the Society at the time of the
approval and are to be made available when required by 4.3.6 Rectification of surface defects by welding
the attending Surveyor. On the manufacturer’s responsibil- Defects which cannot be removed by grinding may gener-
ity, the programmed rolling schedules are to be adhered to ally be repaired by welding under the conditions given in
during the rolling operation (as per [1.3.2]). To this effect, [1.6.2], except that suitable heat treatment and non-
the actual rolling records are to be reviewed by the manu- destructive examination are always required after repair.
facturer and, occasionally, by the Surveyor.
The purchaser is to be informed as to the extent and posi-
When deviation from the programmed rolling schedules tion of the repairs carried out on the individual plates.
occurs, the manufacturer is to take further measures, to the
Surveyor’s satisfaction, in accordance with [1.3.2].
4.4 Condition of supply
4.3.4 Dimensional tolerances
Minus tolerances on the thickness are not normally permit- 4.4.1 The products are to be supplied in the conditions
ted. indicated in Tab 16 for carbon and carbon manganese
steels and Tab 17 for low alloy steels.
4.3.5 Rectification of surface defects by grinding
Surface defects may generally be removed by grinding as 4.4.2 The products to be processed after supply by hot
indicated in [1.6.1], provided that the thickness, after grind- forming may also be supplied, where agreed, in the as
ing, is not less than the nominal thickness. rolled condition.
However the extent of repairs is to be agreed with the Sur- In such cases heat treatment is to be carried out after hot
veyor. Where the thickness is reduced below the nominal forming and provision for the mechanical tests indicated in
thickness given in the approved plans, the possible accept- [4.8.4] is to be made.
Yield stress ReH (N/mm2) min. Tensile Average impact energy (J)
Heat min.
Steel for thickness (mm) strength Elong. A5
treatment Rm
grade (%) min. Test temp
(1) t ≤ 16 16 < t ≤ 40 40 < t ≤ 60 KVT KVL
(N/mm2) (°C)
360HA 215 205 195 360 - 480 25 + 20 27 41
360HB N or NR 235 225 215 0
360HD − 20
410HA 245 235 225 410 - 530 23 + 20
410HB N or NR 265 255 245 0
410HD − 20
460HB 285 270 260 460 - 580 22 0
N or NR
460HD 295 285 280 − 20
510HB 345 335 325 510 - 630 21 0
N or NR
510HD 355 345 335 − 20
(1) N : Normalising - NR : Normalising Rolling. As an alternative to normalising, the as rolled condition may be accepted for sec-
tions, subject to approval of individual steelmakers.
Average impact
Heat Yield stress ReH (N/mm2) Tensile Elongation A5 (%) min.
energy (J) min.
Steel grade treatment min. for thickness (mm) strength Rm for thickness (mm)
at + 20°C
(1) (N/mm2)
t ≤ 16 16 < t ≤ 40 40 < t ≤ 60 t ≤ 40 40 < t ≤ 60 KVT
0,3Mo N 275 270 260 430 - 600 24 23 31
1Cr 0,5Mo N+T 300 295 295 450 - 610 20 19
2,25Cr 0,5Mo N+T 295 285 275 520 - 670 18 18
N+T or Q+T 310 310 310 470 - 620
(1) N = Normalising; T = Tempering; Q = Quenching
4.5 Chemical composition The above values are for design purposes only. Their verifi-
cation is in general not required during the testing, unless
4.5.1 The chemical composition on ladle analysis is to figures higher than those shown in the above Tables but in
comply with the requirements specified in Tab 14 for car- accordance with recognised standards are proposed by the
bon and carbon manganese steels and Tab 15 for low alloy steel Manufacturer.
steels and/or in the approved specification.
In such cases, the verification is required and the proce-
The approved specification is also to include the alloying dures detailed in [4.7.2] and [4.7.3] are to be followed.
and grain refining elements (not specified in the above-
mentioned Tables). 4.7.2 When Rp0,2 is required to be verified, at least one ten-
sile test for each cast is to be carried out at the agreed tem-
The relevant elements as applicable are to be stated by the perature.
steelmaker and included in the testing documentation for
each cast. The sample is to be cut from the thickest plate of the cast
and, if applicable, at the end of the plate that has shown the
For C and C-Mn steels, an upper limit for carbon equivalent lowest figures in the tensile test at ambient temperature.
CEQ on the ladle analysis may be specified at the time of
approval of the individual steels. The sample is to be taken halfway between the edge and the
axis of the piece, and the axis of the test specimen is to be
Unless otherwise agreed, the value of CEQ is calculated by located at one quarter of the thickness from one of the
the following formula: rolled surfaces.
4.7.1 The values for the yield stress or 0,2% proof stress 4.7.4 For design purposes only, the estimated values of the
(Rp0,2) at temperatures of 100°C and higher are given in Tab stress to rupture in 100000 hours are given in Tab 19 for
18. groups of steels.
4.8.1 General The following test specimens are to be taken from each
Unlesss otherwise agreed (see [4.8.6]), samples for tests are sample:
to be cut from the products in the final supply conditions.
a) 1 tensile test specimen (2 tests in the case of bars
4.8.2 Samples from plates and wide flats intended for tie rods)
One sample is to be taken from one end of each rolled unit b) 1 set of 3 Charpy V-notch impact test specimens (only
when the mass and the length do not exceed 5t and 15m, for grades HB and HD unless otherwise specified)
respectively.
When either of these limits is exceeded, samples are to be c) 1 tensile test specimen at elevated temperature, for each
cut at both ends of each rolled unit. cast, when required.
The definition of rolled unit is given in Ch 1, Sec 1, [3.3.3].
4.8.6 Material to be hot worked
4.8.3 Samples from sections and bars
When for material to be hot worked after delivery, it is
One sample is to be taken from each batch homogeneous
agreed that the heat treatment required will be carried out
for cast, section size and condition of supply. Each batch is
by the purchaser, the samples are to be submitted by the
to contain not more than 50 pieces and its total mass is not
steelmaker to such treatment before the cutting of test spec-
to exceed 10 t.
imens.
4.8.4 Sampling of test specimens
In particular cases (when the material is submitted to cold
In the case of plates and wide flats having width ≥ 600mm,
or hot working during fabrication), tests additional to the
the tensile test and impact test specimens are to be taken in
routine testing may be required on samples in the final con-
the transverse direction.
dition of the material after fabrication.
In other cases the specimens are to be taken in the longitu-
dinal direction, unless otherwise required by or agreed with These may also include tests on material submitted to artifi-
the Society. cial aging treatment as indicated in Ch 1, Sec 2, [8.1.1].
Steel grade
Temperature (°C)
360 - 410 460 - 510 0,3Mo 1Cr 0,5Mo 2,25Cr 1Mo
380 170 225
390 155 200
400 140 175
410 125 155
420 110 135
430 100 115
440 90 100
450 75 85 235 285 220
460 (60) (70) 205 250 205
470 (50) (60) 175 220 185
480 (40) (55) 145 190 170
490 (45) 120 160 150
500 (40) 100 135 135
510 80 120 120
520 65 95 105
530 50 80 90
540 60 75
550 50 65
560 40 55
570 30 50
580 45
590 (40)
600 (35)
Note 1: The values shown are estimated average values; the lower limit of the range is approximately 20% less than the average
value. The values in brackets for some higher temperatures indicate that the steel is not suitable for continuous use at such tempera-
tures.
5 Ferritic steels for low temperature 5.1.3 In case of applications involving the storage and
transport of liquefied gases, the appropriate requirements of
service the Society’s Rules for the Classification of Steel Ships also
apply.
5.1 Scope
5.2 Steel grades
5.1.1 The requirement of this Article apply to ferritic steel
5.2.1 The requirements apply to carbon, carbon manga-
products (plates, flats, sections and bars) intended for cargo
nese and Ni alloy steels.
tanks, storage tanks, process pressure vessels and systems
for liquefied gases and other pressure vessels in general, 5.2.2 The carbon and carbon manganese steels are classed
when impact properties at temperature lower than −20°C into four groups indicated by the minimum ultimate tensile
are required. strength Rm (N/mm2): 410, 460, 510 and 550.
Provision is made for products with thickness up to 60mm. Each group is further subdivided into two grades, LE and LF,
based on the quality level and impact properties.
The extension to higher thicknesses and relevant conditions
The letters LE and LF mean impact properties at −40 and −
are subject to agreement with the Society.
60°C, respectively.
5.1.2 Special requirements may be specified in the case of 5.2.3 Ni alloy steels are designated according to the chem-
applications intended for dangerous substances or particu- ical composition into the grades: 1,5Ni - 3,5Ni - 5Ni - 9Ni.
larly severe service conditions. The figures mean the Ni nominal percentage content.
5.3 Manufacture In such cases heat treatment is to be carried out after form-
ing and provision for the mechanical tests indicated in
5.3.1 Approval [4.8.6] is to be made.
The Manufacturers are to be approved by the Society (see
[1.2]).
5.5 Chemical composition
5.3.2 Deoxidation process
The steel is to be killed and fine grained. 5.5.1 The chemical composition on ladle analysis is to
comply with the requirements specified in Tab 20 and Tab
5.3.3 Dimensional tolerances 21 and/or in the approved specification.
For pressure vessels, minus tolerances on thickness are not
The approved specification is also to include the alloying
normally permitted.
and grain refining elements (not specified in Tab 20).
5.3.4 Surface conditions
The content of the above elements, as applicable, is to be
For repairs, the provisions of [4.3.5] and [4.3.6] apply. stated by the steelmaker for each heat and included in the
Repairs by welding are not normally allowed on 5% or 9% testing documentation.
nickel steels.
For C and C-Mn steels, an upper limit for carbon equivalent
CEQ on the ladle analysis may be specified at the time of
5.4 Condition of supply
approval of the individual steels.
5.4.1 Unless otherwise accepted by the Society, carbon
Unless otherwise agreed, the value of CEQ is calculated by
and carbon manganese products are to be supplied in nor-
the following formula:
malised (N) condition.
Nickel steel products are to be supplied in the conditions Mn Cr + Mo + V Ni + Cu
C E Q = C + --------- + -------------------------------- + --------------------- %
indicated in Tab 23. 6 5 15
5.4.2 The products to be processed after supply by hot Unless otherwise agreed, when a limit for CEQ is required
working may also be supplied, where agreed, in the as the relevant values are to be stated by the steelmaker and
rolled condition. included in the testing documentation for each cast.
5.7.3 Sections and bars In the case of applications in low or high temperature pres-
One sample is to be taken from each batch homogeneous sure systems, reference is to be made to the applicable
for heat, section size and condition of supply. requirements of Articles [5] and [4] respectively.
Each batch is to contain not more than 50 pieces and its
6.1.2 The products are grouped as follows, depending on
total mass is not to exceed 10 t.
the application:
5.7.4 Sampling a) structural parts of deck equipment
In the case of plates and wide flats having width ≥ 600mm,
the tensile test and impact test specimens are to be taken in b) welded machinery structures such as bedplates, crank-
the transverse direction. cases, frame entablatures or similar items
In other cases the specimens are to be taken in the longitu- c) rolled products, such as bars for small shafts, pins, bolts
dinal direction, unless otherwise required by or agreed with or similar items, when, in the limit of diameters of
the Society. 250mm, they are accepted in lieu of forgings.
Steel Heat treatment Yield stress ReH Tensile strength Elongation A5 Average impact energy (J) min.
grade (1) (N/mm2)min. Rm (N/mm2) (%) min. Temp (°C) KVT KVL
1,5 Ni N+T or Q+T 275 490 - 640 22 − 80 27 41
3,5 Ni N+T or Q+T 285 450 - 610 21 − 95 27 41
5,0 Ni N+T or Q+T 390 540 - 740 21 − 110 27 41
9,0 Ni N+N+T or Q+T 490 640 - 790 18 − 196 27 41
(1) N=normalising T= tempering Q = quenching
Surface defects which cannot be removed by grinding may 7.5 Chemical composition
be generally repaired under the conditions given in [2.3.7],
as applicable. 7.5.1 The chemical composition on ladle analysis is to
comply with the requirements specified in Tab 25.
7.4 Condition of supply
7.6 Mechanical properties
7.4.1 All materials are to be supplied in the solution treated
condition. 7.6.1 The mechanical properties are specified in Tab 26.
AISI grade Yield strength (N/mm2) min. (1) Tensile strength Rm A5 (%) Average impact energy (J) min.
designation Rp0,2 Rp1,0 (N/mm2) min. KVL KVT
Austenitic at −196°C at −196°C
304 L 175 215 470 - 670 45 41 27
304LN 270 310 570 - 790 40
316L 195 235 490 - 690 45
316LN 300 340 ≥ 590 45
317L 195 235 490 - 690 40
317LN 300 340 ≥ 590 45
321 205 245 500 - 750 40
347 205 245 500 - 750 40
Duplex austenitic-ferritic at −20°C at −20°C
UNS S31803 ≥ 470 660 - 800 25 41 27
UNS S32550 ≥ 490 690 - 890 25
UNS S32750 ≥ 530 730 - 930 25
(1) The yield strength Rp0,2 is in general to be determined
7.10.3 When the reduction in area is between 25 and 35 8.6.1 The mechanical properties of the backing material
per cent, additional metallographic examination or other are to comply with the requirements given in Article [4].
evidence is required to show that no significant amount of The check of the mechanical properties of the cladding
any detrimental phase, such as sigma, is present. material is not required.
8.7.1 Batch composition 8.9.1 Ultrasonic inspection of the adhesion of the cladding
The batch is to be composed of plates having the same is generally to be performed on plates with an overall thick-
overall thickness, cladding thickness and cast of backing ness (backing + cladding) equal to or greater than 10mm.
steel, and mass not exceeding 20 t. For overall thickness less than 10mm, the ultrasonic inspec-
tion procedure is to be defined in agreement with the Soci-
8.7.2 Number of tests ety.
The following tests are to be performed:
• 1 tensile test on the full clad plate 8.9.2 The ultrasonic inspection is to be performed with the
following procedures:
• 2 bend tests on the the full clad plate
• peripheral inspection of a strip of 50mm in width on all
• 1 series of impact tests on the backing steel
the plate edges
• 1 shear test on the cladding.
• continuous inspection according to a grid with square
8.7.3 Tensile test meshes, 200 mm long and parallel to the plate edges.
During the tensile test of the full clad plate, the strength is to
Random checks may be required by the Surveyor.
be not less than the value given by the following formula:
Rb ⋅ tb + Rc ⋅ tc 8.9.3 The reflection technique is used, with a normal probe
R = ---------------------------------
-
t having a diameter ranging from 20 to 35 mm and a fre-
where: quency from 3 to 5 Mhz.
Rb : Nominal minimum ReH or Rm of backing mate- 8.9.4 Unless otherwise agreed with the Society, non-adhe-
rial sion areas which do not exceed (50 mm x 50 mm) are toler-
Rc : Nominal minimum ReH or Rm of cladding mate- ated without repair, provided that they are at least 500 mm
rial apart.
tb : Nominal thickness of backing material
tc : Nominal thickness of cladding material 8.10 Surface defects and repairs
t : Nominal thickness of the full clad plate.
8.10.1 Surface defects may be accepted by the Surveyor
If the values resulting from the tensile test yield stress, ulti- when they are not detrimental to the proper use of the prod-
mate tensile strength) are lower than those given by the uct and its corrosion resistance.
above formula, one additional test is to be performed after
removal of the cladding material. 8.10.2 All the surface defects are to be ground so as to
During the tests the requirements for the backing material restore the surface continuity. Nevertheless, such repair by
are to be satisfied. grinding is admitted only if the remaining thickness of the
cladding is at least equal to its guaranteed nominal thick-
The value of elongation specified for the backing material
ness.
applies also to the full clad plate.
8.7.4 Bend tests 8.10.3 In cases where, after grinding, the cladding thick-
ness is less than the guaranteed nominal thickness, the
The bending conditions (mandrel diameter in general 3
repair is carried out by welding. The filler metal is to be of
times the plate thickness) are those required for the backing
the same grade as the cladding and the repair procedure is
steel grade. One bend test is carried out with the cladding
to be defined in agreement with the Surveyor and prelimi-
metal on the tensioned side (outer side of bend) and another
narily approved.
with the cladding metal on the compressed side (inner side
of bend). In the latter test, separations of the cladding not
8.10.4 If, after grinding of the defect, the remaining thick-
exceeding 25% of the bent portion are admitted.
ness of the cladding is less than half of the guaranteed nom-
8.7.5 Shear test inal thickness, it is necessary to replace the cladding by
tapering and to rebuild the whole of the cladding by weld-
The shear test is carried out in accordance with ASTM A
ing. Such repair is to be carried out in agreement with the
264. The shear strength is to be at least 140 N/mm2.
Surveyor and preliminarily approved.
The conditions for approval are indicated in the document Central line of product
NR480 “Approval of the manufacturing process of metallic Test
specimens
materials”.
9.9 Re-test
Parallel length > 2d
9.9.1 Three additional test specimens taken from the
remaining test sample can be prepared and tested in three
Figure 8 : Welded test specimen cases shown in Fig 9. The average of all six tensile tests is to
be greater than the required minimum average with no
more than two results below the minimum average.
d In the case of failure after retest, either the batch repre-
sented by the piece is rejected or each piece within the
Plate thickness batch is required to be tested.
Parallel length > t + 4mm
Minimum
Average
Minimum
Individual