GenChem 1 Module 3 Q4
GenChem 1 Module 3 Q4
GenChem 1 Module 3 Q4
Senior High
High School
School
General
Chemistry 1
Quarter 4 - Module 3
Organic Compounds
About 200 years ago, it is believed that organic compounds needed a ‘life force’
to be produced. Other compounds like rock that were from nonliving things were
referred to as inorganic. The synthesis of urea (an organic compound) from amonium
cyanate (an inorganic compound) as an experiment of Friedrich Wöhler in 1828
dispelled the belief that organic compounds could only be formed by nature. The range
of application of organic compounds includes, but is not limited to petrochemicals,
food, pharmaceuticals, explosives, fragrances, paints and cosmetics.
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How to Learn from this Module
To achieve the objectives cited above, you are to do the following:
• Take your time reading the lessons carefully.
• Follow the directions and/or instructions in the activities and exercises
diligently.
• Answer all the given tests and exercises.
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What I Know
2. What products are obtained with CH4(g) burns completely in an excess of oxygen?
A. CO2 C. Hydrogen gas
B. CO2 and H2O D. Explosion
7. The reaction of water with alkene to produce an alcohol is a/an ______ reaction.
A. Addition C. Combustion
B. Condensation D. Saponification
8. The organic starting materials for the preparation of an ester could be_________
A. a ketone and alcohol C. an acid and alcohol
B. water and oxygen D. alkane and aldehyde
10. This type of isomerism occurs when different compounds are formed due to the
different arrangements of their atoms leading to different functional groups.
A. chain C. positional
B. functional D. geometric
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Hydrocarbons and Functional
1 Groups
What’s New
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What Is It
From the discussion on the bonding models in the previous module, it can be
seen that carbon has a unique nature. Carbon completes its octet by sharing electrons
with other carbon atoms forming single, double, and triple bonds. It also readily forms
bonds with atoms of other elements like H, O, N, and the halogens. Carbon can form
millions of different compounds and can form more compounds than any other element
in the periodic table.
HYDROCARBONS
ALIPHATIC AROMATIC
a. Alkanes- are aliphatic, saturated hydrocarbons and has only single carbon-
carbon bonds in the molecule. They are referred to as saturated
hydrocarbons because they hold the maximum number of hydrogen atoms
that can bond to the carbon atoms present. Some alkanes are gases and
are used directly as fuels. Saturated hydrocarbons that forms a single ring
are called cycloalkanes. Alkanes are nonpolar, not very reactive, insoluble
in water and have little biological activity. They are all colorless and
odorless.
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b. Alkenes- also called as olefins. These are unsaturated hydrocarbons that
contain at least one carbon-carbon double bond. They are all colorless and
odorless in nature except ethene. They are insoluble in water due to their
nonpolar feature but are more reactive than alkanes.
A group of atoms that is mainly responsible for the chemical behavior of the
parent molecule is called functional group. Organic compounds may also be classified
according to the functional groups they contain. Compounds with the same functional
groups undergo like reactions.
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b. Ethers- (R-O-R’; R, R’=hydrocarbon)
d. Carboxylic acids- ( )
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Figure 8. Some common carboxylic acids
e. Esters- ( )
f. Amines – ( )
Amines are organic bases having the general formula R 3N, where R
may be Hydrogen or a hydrocarbon group. When amines are allowed to
react with acids, they form colourless and odourless salts. When all Rs are
hydrogens, the resulting compound is ammonia, NH3.
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What’s More
Activity 2: Identification
Directions: Identify the functional group each compound represents. If the compound
represents two or more functional groups, list all groups being represented. If the
compound is a hydrocarbon, write the specific type of hydrocarbon class it belongs.
Write your answer on the space provided below each item.
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Structural Isomerism and
2 Organic Reactions
What’s In
What’s New
1.
2. .
3.
4.
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What Is It
I. Structural Isomerism
When two or more organic compounds have the same molecular formula but
different properties due to their difference in arrangement of atoms along the carbon,
they are called structural isomers. There are six forms of structural isomerism and
the most common are chain, positional and functional isomerism.
STRUCTURAL ISOMERISM
a. Chain Isomerism
Chain isomers are organic compounds with the same formula, but the
arrangements of their carbon skeleton are different.
FORMULA: C4H10
b. Positional Isomerism
Positional isomerism occurs when the same functional groups are
attached to different positions on a carbon chain.
FORMULA: C4H8
FORMULA: C3H7OH
FORMULA: C2H6O
FORMULA: C3H6O
FORMULA: C2H4O2
a. Combustion Reactions
When a substance reacts with oxygen gas, releasing energy in the form
of light and heat, a combustion reaction occurs. This type reaction must involve
O2 or oxygen gas as one reactant. One of the most notable combustion
reactions is the combustion of organic fuels. Fuels rapidly react with oxygen to
produce energy. These fuels include: coal, high molecular weight
hydrocarbons, methane, propane, and butane.
1.
b. Addition Reactions
2. 3.
4.
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c. Condensation Reactions
6.
ketone aldehyde
5.
d. Saponification Reactions
Saponification reaction takes place when a fat, oil or lipid is cleaved and
converted into soap and alcohol by the action of heat and with the presence of
water and a base. Fats are typically in the form of esters. When esters undergo
saponification, carboxylate (soap) and an alcohol (glycerol) functional groups
are produced.
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III. Preparation of Selected Organic Compounds
1. Preparation of Alkanes
2. Preparation of Alkenes
acid
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3. Preparation of Alcohols
acid
4. Preparation of Esters
Heat,acid
Strong
oxidizing
agent
Heat
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What’s More (A)
1. 3.
2. 4.
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What I Have Learned
1. Structural isomers have the same molecular formula but have different
properties. How is this possible?
2. How are positional and functional isomerism different from each other?
3. Ethanol and dimethyl ether have the same molecular formula C2H6O.
Ethanol is liquid at room temperature while dimethyl ether is gas. How is this
possible?
4. Why are short-chain alkanes like methane and butane serve as good fuels?
1.
2.
3.
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What I Can Do (B)
Directions: The goal is to convince an investor to invest in your company so that you
can build a factory to make ester compounds. For example, you could make hexyl
pentanoate, and sell it for use in perfumes and make the investor money. You must
come up with a compound that you can make and sell. You can use your textbooks
and the internet as resources. You can also access the link:
https://jameskennedymonash.wordpress.com/2013/12/13/infographic-table-of-esters-
and-their-smells/ to look at an infographic of the ester compounds responsible for the
smell of different fruits, perfumes and flowers. At the end of your research, you must
have the compound table filled out.
Ester How to
Compound Structure prepare the Properties Uses
Name compound?
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SUMMARY
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Assessment: (Post-Test)
Multiple Choice. Answer the questions that follow. Choose the best answer
among the given choices for each item.
1. Which of the following compounds is a functional group isomer of C 2H5OH, ethanol (ethyl
alcohol)?
A. ethanal, CH3CHO C. acetic acid, CH3COOH
B. dimethyl ether, (CH3)2O D. diethyl ether, (C2H5)2O
3. The reaction of water with alkene to produce an alcohol is a/an ______ reaction.
A. Saponification C. Combustion
B. Condensation D. Addition
4. The organic starting materials for the preparation of an ester could be_________
A. an acid and alcohol C. a ketone and alcohol
B. water and oxygen D. alkane and aldehyde
A. ester C. alcohol
B. aldehyde D. alkyne
A. chain C. positional
B. functional D. geometric
A. chain C. positional
B. functional D. geometric
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Key to Answers
Lesson 1:
Activity 1 Activity 2
1. A 6. B 1. ketone 6. alkyne
2. G 7. C 2. carboxylic acid 7. Amine,
carboxylic acid
3. F 8. H
3. aldehyde 8. alkane
4. D
4. ester 9. Ester, alcohol
5. E
5. amine
Lesson 2:
Activity 1 Activity 2.1 Activity 2.2
1. isomers 1. chain 1. combustion 5. condensation
2. chain
2. clones 2. addition
3. isomers 3. position 3. condensation
4. isomers 4. functional 4. saponification
Activity 3.
1. They have different structures which affect their properties.
2. Functional isomerism leads to a production of a new functional group while
position isomerism produces same class of compound.
3. They are functional isomers, hence the difference in their boiling points and
volatility.
4. Short chain alkanes burn completely in a good supply of oxygen.
5. Yes. The compound is an ester
6. Hydration of an alkene
7. Dehydration of an alkene
8. Esterification or condensation reaction of alcohol and carboxylic acid
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