C Sol Ch-08 The Solid State
C Sol Ch-08 The Solid State
C Sol Ch-08 The Solid State
2 rx ry 2a
2rx a 2a
2rx a
2 –1
rx = 0.207 a
3 vol. of x vol. of y
Packing fraction = vol. of unit cell
4 4
3 rx3 ry3
3 3
a3
4
4 (0.207a)3 (0.5a)3
3
a3
0.63
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CHEMISTRY ARCHIVE - JEE (Advanced) (Solutions)
5. Answer (B)
Atom X occupies FCC lattice sites as well as alternate tetrahedral voids of FCC.
Hence
1 1
Atom X in a unit cell (FCC lattice sites) = 8 6 4
8 2
1
Atom X in a unit cell (in T.V.) = 8 4
2
1
For relation between a and r, since T.V. forms at th of body diagonal,
4
a 3
2r
4
8r
a=
3
4 3 4
8 r 8 r3
3 100 3 100 35%
Packing efficiency =
a3 8r
3
3
6. Answer (B, C)
ASchottky defect are favoured by small difference in sizes of cation and anion.
BIn Frenkel defect cations are dislocated therefore. (True)
CElectron trapped in lattice are called F-centre. (True)
DSchottky defect decrease density.
7. Answer (A)
The formula will be MgAl2O4
Total tetrahedral voids = 8
Total octahedral voids = 4
1
as only one Mg atom is present hence, n =
8
2 1
as there are two Al atoms are present hence, m = =
4 2
1 1
m, n = ,
2 8
8. Answer (B, C, D)
In CCP, the coordination number for atom in top-most layer is 9.
9. Answer (A, C)
1
Contribution of M = 2 1
2
1
Contribution of X = 4 1
4
Formula = MX
a2 a 2 3 3
Distance between M and X = a a = 0.866 a
4 2 4 2
Both cation and anion have same co-ordination number, i.e., 8.
Assuming, anions are in contact, the ratio of ionic radii of cation M to anion X is 0.732, the minimum radius
ratio for a cubical void.
10. Answer (B)
1 1
The number of effective atom in a unit cell = 12 2 3 1 = 6
6 2 no of atoms in
corner Face hexagonal primitive
11. Answer (A) Centre unit cell
3 2 2
= 6 a 4r
4 3
3 2
= 6 2r 2 4r = 24 2 r 3
4 3
4 3
6
r
3
Packing fraction =
Base area Height
4 3
6 r
3
= = 0.74
6 3 a 2 4r 2
4 3
4 3
Volume of 1 Ag atom = r
3
4 3 108
r cm3
3 6.023 1023 10.5
r = 1.6 × 10–8 cm
r = 1.6 × 10–10 m
10 –12
n
3.14 (1.6 10 –10 )2
10 107
n
8
n = 1.25 × 107
The value of x = 7
15. Answer (8)
Truncated octahedron contain 14 faces out of that eight are hexagonal and six are square.
16. Answer (2)
a = 4 10–8 cm (a = edge length)
d = 8 g cm–3 (density)
ZM
d M = molecular mass (g/mol)
NA a3