II PUC Chemistry Passing Package

Dr.
Irfan Ahamed Shaikh

Lecturer in Chemistry
AL-FARAAN PU College of Science
Kalaburagi
Mobile: 8749027777
CONTENT
Unit No. CHAPTERS Page No.

1 THE SOLID STATE 1– 3
2 SOLUTIONS 4
3 ELECTROCHEMISTRY 5–6
4 CHEMICAL KINETICS 7–9
5 SURFACE CHEMISTRY 10
GENERAL PRINCIPLES AND PROCESS OF
6 11 – 12
ISOLATION OF ELEMENTS
7 THE p-BLOCK ELEMENTS 13 – 14
8 THE d AND f-BLOCK ELEMENTS 15
9 COORDINATION COMPOUNDS 16 – 18
10 HALOALKANES AND HALOARENES 19 – 20
11 ALCOHOLS, PHENOLS AND ETHERS 21 – 22
12 ALDEHYDES, KETONES AND CARBOXYLIC ACIDS 23 – 24
13 ORGANIC COMPOUNDS CONTAINING NITROGEN 24
14 BIOMOLECULES 25 – 26
15 POLYMERS 26 – 27
16 CHEMISTRY IN EVERYDAY LIFE 28

Chapter-1: The Solid State
1. Give any two differences between Crystalline and Amorphous solids.

Crystalline solids Amorphous solids
Definite geometrical shape Irregular shape
Sharp melting points Range of melting points
Anisotropic in nature Isotropic in nature
2. Calculate the number of particles per unit cell of simple cubic.

The particles are present only at eight corners of the cube.
From each corner, contribution per unit cell is 1 x8=1
8
Therefore, number of particles per unit cell = 1
3. Calculate the number of particles per unit cell of Body-Centred Cubic (BCC).
The particles are present at eight corners and at body centre.
8
The particle present at body centre of the cube = 1 =1

1
Therefore, number of particles per unit cell = 1 + 1 = 2
4. Calculate the number of particles per unit cell of Face-Centred Cubic (FCC).
The particles are present at eight corners and at the centre of six faces.
8
From each face, contribution per unit cell is 1 x6=3

2
Therefore, number of particles per unit cell = 1 + 3 = 4
5. Calculate the packing efficiency in simple cubic (sc) lattice

Let the edge length of the unit cell be ‘a’ and radius of particle be ‘r’.
Then, a = 2r
Volume of particle = 4 𝜋𝑟3
3
Volume of the unit cell = a3 = (2r) 3 = 8r3

𝑉𝑜𝑙𝑢𝑚𝑒 𝑜𝑐𝑐𝑢𝑝𝑖𝑒𝑑 𝑏𝑦 𝑡ℎ𝑒 𝑝𝑎𝑟𝑡𝑖𝑐𝑙𝑒𝑠
Packing efficiency = x 100
𝑣𝑜𝑙𝑢𝑚𝑒 𝑜𝑓 𝑡ℎ𝑒 𝑢𝑛𝑖𝑡 𝑐𝑒𝑙𝑙
4
𝜋𝑟3
= 3 x 100
8𝑟3
Packing efficiency = 52 %
Page 1
6. Calculate the packing efficiency in cubic close packed (ccp) / face-centred cubic (fcc)
From Δ ABC
AC2 = AB2 + BC2
b2 = a2 + a2 = 2a2
b = √2𝑎 But, b = 4r
Therefore, 4r = √2 𝑎
4𝑟
a= = 2√2𝑟
√2
Volume of the unit cell = a3 = (2√2𝑟) 3

Volume of particles = 4 x 4 𝜋𝑟3 = 16 𝜋𝑟3
3 3
𝑉𝑜𝑙𝑢𝑚𝑒 𝑜𝑐𝑐𝑢𝑝𝑖𝑒𝑑 𝑏𝑦 𝑡ℎ𝑒 𝑝𝑎𝑟𝑡𝑖𝑐𝑙𝑒𝑠
Packing efficiency = x 100 %
𝑣𝑜𝑙𝑢𝑚𝑒 𝑜𝑓 𝑡ℎ𝑒 𝑢𝑛𝑖𝑡 𝑐𝑒𝑙𝑙
16 3
𝜋𝑟
3
= x 100 %
( 2√2𝑟)3
7. Calculate the packing efficiency in body-centred cubic (bcc)

From Δ EFD
FD2 = EF2 + ED2
b2 = a2 + a2 = 2a2
Now in Δ AFD
AF2 = AD2 + FD2
c2 = a2 + b2 = a2 + 2a2 = 3a2
c = √3 a , But c = 4r
4𝑟
Therefore, 4r = √3𝑎 then a =
√3
Volume of the unit cell = a3 = (4r /√3)3
Volume of particles = 2 x 4 𝜋𝑟3 = 8 𝜋𝑟3

3 3
Volume occupied by the particles
Packing efficiency = x 100 %
Volume of the unit cell
8
πr3
= 3 𝟑 x 100 %
(4r/√3 )
Page 2
8. Give any two differences between Schottky and Frenkel defect
Schottky defects Frenkel defect
Missing of equal number of cations and anions Displacement of cation from their lattice sites
from their lattice sites is called Schottky defect. into the interstitial site is called Frenkel defect.
It decreases density of the crystal No change in the density of crystal
Ex : AgBr Ex : AgBr
Note : AgBr shows both Schottky and Frenkel defects.
9. Sodium metal crystallises in a BCC structure. Its unit cell edge length is 420 pm.
Calculate its density. (Atomic mass of sodium = 23 𝝁, NA = 6.022x1023 mol-1)
Z X M
d=
𝑁𝐴 X 𝑎3
2 𝑋 23
=
6.022 𝑋 1023 𝑋 (420)3
46
=
6.022 𝑋 1023 (4.20)3 𝑋 10−24
d = 1.031 g 𝑐𝑚−3
10. What are paramagnetic substances? Give an example.

Substances which are weakly attracted by a magnetic field are called paramagnetic substances.
Ex : O2
11. What are ferromagnetic substances? Give an example.

Substances which are strongly attracted by a magnetic field and they can be permanently magnetized are
called ferromagnetic substances.
Ex : Iron
Dr. Irfan Ahamed Shaikh, Lecturer in Chemistry Mobile: 8749027777 Page 3

Chapter–2: Solutions
1. State Henry’s law. Write its mathematical form.

‘At constant temperature, the solubility of a gas in liquid is directly proportional to the partial pressure of
the gas present above the surface of the solution’.
P = KH Xg
Where; KH Henry’s constant
Xg Mole fraction of the gas in solution.
2. What is the effect of temperature and pressure on the solubility of gases in liquids?
Solubility of gases in liquids,
✓ Decreases with temperature
✓ Increases with pressure.
3. State Raoult’s law for liquid mixtures.

‘For a solution of volatile liquids, the partial vapour pressure of a component at a given temperature is
directly proportional to mole fraction of that component in the solution.’
4. Give any two differences between Ideal and Non – Ideal solutions.
Ideal Solutions Non – Ideal Solutions

Solutions which obey Raoult’s law are Solutions which does not obey Raoult’s law
called ideal solutions. are called non – ideal solutions.
Ex : n-hexane and n-heptane Ex : Phenol and Aniline
ΔV = 0 ΔV ≠ 0
ΔH = 0 ΔH ≠ 0
5. What is reverse osmosis? Mention its one practical utility(use).

The process of reversing the direction of osmosis by applying the pressure higher than the osmatic
pressure to the solution of higher concentration is called reverse osmosis.
Used in desalination of sea water.

Chapter–3: Electrochemistry
1. State Faraday’s first law and Faraday's second law of electrolysis.

First law :
It states that ‘The amount of substance deposited on cathode is directly proportional to quantity of electric
current supplied’.
W=ZxIxt
Where; Z is called Electro-chemical equivalent
Second law :
It states that the ‘The amounts of different substances liberated by the same quantity of electricity passing
through the electrolytic solution are proportional to their chemical equivalent weights’.
2. Explain the construction and working of Standard Hydrogen Electrode (SHE).

Construction :
It consists of a platinum foil fitted into a glass tube containing mercury.
The inner glass tube is enclosed in an outer jar that contains an inlet at the top to pass hydrogen gas.
The whole apparatus is placed in 1M HCl solution.
Working:
Hydrogen gas passed is adsorbed on platinum surface.
At Anode :
1
H2(g) → H+(aq) + e-
2
At Cathode :
1
H+(aq) + e- → H2(g)
2
Representation of SHE is Pt(s) / H2(g, 1 bar) || H+(aq, 1M)

Emf of SHE is 0.0 V
3. What is a Primary and Secondary cell? Give an example.

A primary cell is one where the reaction occurs only once and after use over a period of time battery
becomes dead.
Ex : Dry cell
A secondary cell is one where after use it can be recharged by passing current through it in the opposite
direction.
Ex : Lead storage cell

4. State Kohlrausch law.
It states that ‘Limiting molar conductivity of an electrolyte can be represented as the sum of the individual
contributions of the cation and anion of the electrolyte’.
5. Write Nernst equation for Daniel cell. Explain the terms?

EMn+ / M = E0 𝑅𝑇 [𝑀]
Mn+ / M – ln 𝑛+
𝑛𝐹 [𝑀 ]
Where; E0Mn+/M standard electrode potential

n number of electrons transferred during the reaction.
R gas constant
T Temperature in kelvin
F Faraday’s constant
[Mn+] concentration of species
6. Write the equations of anodic and cathodic reactions occur during rusting of iron.
At Anode :
2Fe (s) → 2Fe2+(aq) + 4e-
At Cathode :
O2(g) + 4H+(aq) + 4e- → 2H2O (l)
7. Write the equations of anodic and cathodic reactions of Hydrogen-Oxygen fuel cell.
At Anode :
2H2(g) + 4OH-(aq) → 4H2O (l) + 4e-
At Cathode:
O2(g) + 2H2O (l) + 4e- → 4OH-(aq)

Chapter–4: Chemical Kinetics
1. What is a Pseudo first order reaction? Give an example.

The reaction where order is one but molecularity is two or more is called pseudo first order reaction.
Ex : Acid hydrolysis of methyl acetate
2. Give any two differences between order and molecularity
Order Molecularity
It is the sum of the powers of the concentration It is the number of reacting species involved
terms in the rate law expression. in an elementary reaction.
Experimental quantity Theoretical quantity
3. Derive an integrated rate equation for the rate constant of a zero order reaction.
Consider a zero order reaction

R →−−→ P
d[R]
− = K [R]0
dt
d[R] = − K dt (∵ [R]0 = 1)
On integration we get,
[R] = −Kt + I----------------- (1)
Where ‘I’ is integration constant.
When, t = 0 then [R] = [R]0
Therefore [R]0 = −K x 0 + I
Then I = [R]0
equation (1) becomes
[R] = −Kt + [R]o
Kt = [R]o – [R]
[R]o – [R]
K =
t

4. Derive an integrated rate equation for the rate constant of a first order reaction.
Consider a first order reaction
R →−−−→ P
d[R]
− = K [R]1
dt
d[R]
= − K dt
[R]
On integration we get,
ln [R] = - Kt + I ------------------ (1)
When t = 0 then, [R] = [R]0
ln[R]0 = −K x 0 + I
Then I = − ln[R]0
equation (1) becomes
ln [R] = - Kt + ln[R]0
Kt = ln[R]0 – ln[R]
Then, Kt = ln [𝑅]0
[R]
2.303 [𝑅]0
K= log
t [R]
5. Show that for a zero order reaction half -life period is directly proportional to initial
concentration of the reactant.
[R]o – [R]
We know that, K=
t
1
When, t = t1/2 then [R] = [R]0
2
1 1
[𝑅]0– [𝑅]0 [𝑅]0
K= 2 = 2
t1/2 t1/2
[𝑅]0
K= 2 t1/2
OR
[𝑅]0
t1/2 =
2K
Therefore, for a zero order reaction t1/2 α [R]0

6. Show that for a first order reaction half- life is independent of the initial concentration of the
reactant.
[𝑅]0
We know that, K= 2.303 log
t [R]
1
When, t = t1/2 then [R] = [R]0
2
2.303 [𝑅]0
K= 𝑡1/2
log
[𝑅]0/2
K= 2.303 log 2
𝑡1/2
2.303 X 0.3010 0.693

K= 𝑡1/2
= 𝑡1/2
0.693
t1/2 =
K
Therefore, for a first order reaction t1/2 is independent of initial concentration.
7. Explain the effect of catalyst on the activation energy of a reaction with graph.
The effect is explained by intermediate complex formation theory.
According to this theory, a catalyst combines with the reactants to form an intermediate complex which
is decomposes to products.
A positive catalyst increases the rate of reaction by providing an alternative pathway with lower activation
energy.
𝗍
↑ without catalyst
Potential with catalyst
Energy Ea Ea
Reactants
Products
→
Reaction coordinate →

Chapter-5: Surface Chemistry
1. Write the differences between Physisorption and Chemisorption.
Physical adsorption (Physisorption) Chemical adsorption (Chemisorption)

Low heat of adsorption High heat of adsorption
Reversible Irreversible
Multi molecular layers Mono molecular layer
2. What are Homogeneous and Heterogeneous catalysis? Give an example for each.
Homogeneous catalysis :
The process in which both reactants and the catalyst are present in the same phase.
𝐻𝐶𝑙(l)
Ex : CH3COOCH3(l) + H2O(l) →−−−−−→ CH3COOH(aq) + CH3OH(aq)
Heterogeneous catalysis :
The process in which the reactants and the catalyst are in different phases.
𝐹𝑒(𝑠)
Ex : N2(g) + 3H2(g) →−−−−−−→ 2NH3(g)
3. Write the differences between Lyophilic and Lyophobic colloids.
Lyophilic colloids Lyophobic colloids

The colloids in which there is a strong affinity The colloids in which there is no affinity
between dispersed phase and dispersion medium between dispersed phase and dispersion
is called lyophilic colloids. medium is called lyophobic colloids.
Ex : Starch sol Ex : Gold sol
More stable Less stable
Reversible in nature Irreversible in nature
4. What is Brownian movement? Give reason for that.

The zig-zag movement of colloidal particles in the colloidal solution is called Brownian movement.
It is due to bombardment of particles by the molecules of dispersion medium.
5. State Hardy-Schulze rule.

It states that ‘Greater the value of the flocculating ion added, the greater is its power to cause
precipitation’.

Chapter–6: General principles and process of isolation of elements
1. How is pure alumina is obtained from bauxite by leaching process?

Al2O3 is treated with NaOH gives sodium aluminate leaving the impurities behind.
Al2O3(s) + 2NaOH(aq) + 3H2O(l) →−−−→ 2Na[Al (OH) 4](aq)
The solution is neutralized by passing CO2 gas
2Na[Al (OH) 4](aq) + 2CO2(g) →−−−→ Al2O3.xH2O (s) + 2NaHCO3(aq)
Hydrated alumina is filtered, dried to give back pure Al2O3.
Al2O3.xH2O(s) →−−→ Al2O3(s) + xH2O(g)
2. Explain Zone refining.

Principle : Impurities are more soluble in the molten state than in the solid state.
A moving electrical coil is fixed at one end of a impure metal rod.
On heating, pure metal solidifies while impurities pass into the molten zone.
The process is repeated for several times.
This method is used to get ultra-pure metals for producing semiconductors like germanium and silicon.
Recrystallized zone
Electric Coil Impurities
3. Explain Mond’s process for refining of nickel.

The crude metal is heated with carbon monoxide gives tetra carbonyl.
On heating tetra carbonyl gives metal.
350 𝐾
Ni + 4CO →−−−−−−−→ Ni(CO)4
450 𝐾
Ni (CO)4 →−−−−−−−→ Ni + 4CO
4. Explain Van Arkel method for refining of Zirconium or Titanium.

The crude metal is heated with iodine, gives tetra iodides.
On heating tetra iodides gives metal.
850 𝐾
Zr + 2I2 →−−−−−−−→ ZrI4
200 𝐾
ZrI4 →−−−−−→ Zr + 2I2
Metals used in space technology purified by this method.

5. Write down the reactions taking place in different zones in the Blast furnace during the
extraction of iron.
Combustion zone :
At the bottom of the furnace carbon burns with hot air gives CO2.
CO2 moves upwards meets more carbon gives carbon monoxide.
C + O2 →−−−→ CO2
C + CO2 →−−→ 2CO
Reduction zone :
At the top of the furnace CO reduces iron oxide to iron
Fe2O3 + 3CO →−−−→ 2Fe + 3CO2
Slag zone :
Limestone decomposed to CaO, which is combined with SiO2 form a slag.
CaCO3 →−−→ CaO + CO2
CaO + SiO2 →−−−→ CaSiO3
6. Draw labelled diagram of Hall – Heroult Electrolytic cell for the extraction of aluminium.
Write anode and cathode reactions.
Purified Al2O3 (bauxite) is mixed with Na3AlF6, which lowers the melting point and increases the
conductivity of the melt.
Anode :
Graphite rod
C(s) + O2-(melt) →−−→ CO (g) + 2e-
C(s) + 2O2-(melt) →−→ CO2(g) + 4e-
Cathode :
Steel vessel with carbon lining
Al3+(melt) + 3e- →−−→ Al
Overall reaction is
2Al2O3 + 3C →−−−→ 4Al + 3CO2
7. Write the composition of copper matte.

Cu2S + FeS

Chapter–7: The p – block elements
1. For the manufacture of Ammonia by Haber’s process, write the flow chart and chemical
equations with optimum conditions.
N2 and H2 combined in the ratio of 1:3, gives ammonia
N2(g) + 3H2(g) 2NH3(g)
According to Le Chatelier’s principle, the optimum conditions to get a good yield of ammonia are,
Optimum temperature of 700 K
High pressure of 200 atm
In presence of iron oxide as catalyst
2. Write the balanced chemical equations with conditions involved in the manufacture of
Nitric acid by Ostwald’s process.
Ammonia is oxidized by air in the presence of Pt – Rh gauze catalyst at 500 K, gives nitric oxide.
𝑃𝑡 − 𝑅ℎ 𝐶𝑎𝑡𝑎𝑙𝑦𝑠𝑡
4NH3 (g) + 5O2 (g) →−−−−−−−−−−−−−−−→ 4NO (g) + 6H2O (g)
The nitric oxide is oxidised by air, it gives nitrogen dioxide
2NO (g) + O2 (g) →−−−→ 2NO2 (g)
Nitrogen dioxide so formed, dissolves in water it gives nitric acid.
3NO2 (g) + H2O (l) →−−→ 2HNO3 (aq) + NO (g)
NO thus formed is recycled.
3. In the manufacture of sulphuric acid by contact process write reactions and optimum
conditions?
• Burning of sulphur in air gives sulphur dioxide
S + O2 →−−→ SO2
• Sulphur dioxide oxidised to sulphur trioxide with air
𝑉2 𝑂5
2SO2 + O2 →−−−→ 2SO3

According to Le Chatelier’s principle, the optimum conditions to get a good yield of SO3 are,
Optimum temperature of 720 K
High pressure of 2 bar
In presence of V2O5 as catalyst.
• Absorption of SO3 in H2SO4 gives oleum. (Fuming sulphuric acid is called oleum)
SO3 + H2SO4 →−−−→ H2S2O7
• Oleum with water gives sulphuric acid.
H2S2O7 + H2O →−−→ 2H2SO4
4. For Noble gases

(a) Name the noble gas obtained as decay product of 226Ra.
(b) Name the noble gas used in the treatment of cancer.
(c) Which noble gas is most abundant in atmospheric dry air?
(d) Mention the main commercial source of helium.
(e) Give reason for chemical inertness
(a) Radon
(b) Radon
(c) Argon
(d) Natural gas
(e) It is due to octet configuration and high ionisation energy.
5. What are inter halogen compounds? Give an example.

The compounds obtained when two different halogens react with each other are called inter halogen
compounds.
Ex : ClF
6. Give reason : Inter halogen compounds are more reactive than halogens (except fluorine).
This is because X – X1 bond in inter halogens is weaker than X – X bond in halogens except F – F bond.

Chapter–8: d and f- block Elements
1. Give reason : The electronic configuration of chromium is [Ar] 3d5 4s1 but not [Ar] 3d4 4s2,
similarly for copper is [Ar] 3d10 4s1 but not [Ar] 3d9 4s2.
This is because, half -filled and completely filled orbitals are more stable.
2. Transition metals and many of their compounds acts as good catalyst. Explain
Most of the transition elements and their compounds are acts as good catalysts.
The catalytic properties is due to,
✓ Variable oxidation states.
✓ Large surface area in the finely divided state.
Ex : Iron is used as a catalyst in Haber’s process.
3. What are interstitial compounds?

The compounds obtained, when small atoms like H or C are trapped inside the crystal lattices of metals
are called interstitial compounds.
4. Explain the manufacture of potassium dichromate (K2Cr2O7) from chromite ore (FeCr2O4)
Chromite ore is mixed with soda ash and burnt in excess of air gives sodium chromate.
4FeCr2O4 + 8Na2CO3 + 7O2 8Na2CrO4 + 2Fe2O3 + 8CO2
Sodium chromate is treated with acid gives sodium dichromate.
2Na2CrO4 + 2H+ Na2Cr2O7 + 2Na+ + H2O
Sodium dichromate is treated with potassium chloride gives potassium dichromate.
Na2Cr2O7 + 2KCl K2Cr2O7 + 2NaCl
5. How is Potassium permanganate (KMnO4) is prepared from MnO2. Write equations.

When MnO2 is fused with KOH gives potassium manganite.
2MnO2 + 4KOH + O2 2K2MnO4 + 2H2O
Potassium manganite in acidic medium gives potassium permanganate.
3K2MnO4 + 4H+ 2KMnO4 + MnO2 + 2H2O + 4K+
6. What is Lanthanide contraction? Mention one of its consequence and cause for it.
The gradual decrease in atomic and ionic radii from lanthanum to lutetium is called lanthanide contraction.
Consequence : Almost identical radii of Zr and Hf.
Cause: It is due to imperfect shielding of 4f electrons.

Chapter–9: Coordination Compounds
1. Write the postulates of Werner’s theory.

Postulates
❖ The central metal show two types of valences, namely primary and secondary valency.
❖ Primary valences are ionisable and are satisfied by negative ions.
❖ Secondary valences are non-ionisable and are satisfied by neutral molecules or negative ions.
2. Using Valence bond theory account for the geometry and magnetic property of [CoF6]3-.
In [CoF6]3- the cobalt ion is in +3 oxidation state.
For Co3+ the electronic configuration is [Ar] 3d6 4s0
[Ar]
3d 4s 4p 4d
Fluoride is a weak ligand, hence no pairing of electrons takes place in d-orbitals.
Hybridization takes place gives six vacant sp3d2 hybridized orbitals.
Six pairs of electrons, from six fluoride ligands occupy hybrid orbitals.
[Ar]
3d sp3d2
Due to presence of unpaired electrons, the complex is paramagnetic.
It has octahedral geometry.
3. Using Valence bond theory account for the geometry and magnetic property of [Co(NH3)6]3+.
In [Co(NH3)6]3+ the cobalt ion is in +3 oxidation state.
For Co3+ the electronic configuration is [Ar] 3d6 4s0
[Ar]
3d 4s 4p
NH3 is a strong ligand, hence pairing of electrons takes place in d-orbitals.
Hybridization takes place gives six vacant d2sp3 hybridized orbitals.

Six pairs of electrons from six NH3 ligands, occupy hybrid orbitals.
[Ar]
3d d2sp3
Due to absence of unpaired electrons, the complex is diamagnetic.
It has octahedral geometry.
4. Using Valence bond theory account for the geometry and magnetic property of [NiCl4]2-.
In [NiCl4]2- the nickel ion is in +2 oxidation state.
For Ni2+ the electronic configuration is [Ar] 3d8 4s0
[Ar]
3d 4s 4p
Chloride is a weak ligand, hence no pairing of electrons takes place in d-orbitals.
Hybridization takes place gives four vacant sp3 hybridized orbitals.
Four pairs of electrons, from four chloride ligands occupy hybrid orbitals.
[Ar]
3d sp3
Due to presence of unpaired electrons, the complex is paramagnetic.
It has tetrahedral geometry.
5. Using Valence bond theory account for the geometry and magnetic property of [Ni(CN)4]2-.
In [Ni(CN)4]2- the nickel ion is in +2 oxidation state
For Ni2+ the electronic configuration is [Ar] 3d8 4s0
[Ar]
3d 4s 4p
Cyanide is a strong ligand, hence pairing of electrons takes place in d-orbitals.
Hybridization takes place gives four vacant dsp2 hybridized orbitals.

Four pairs of electrons, from four cyanide ligands occupy hybrid orbitals.
[Ar]
3d dsp2 4p
Due to absence of unpaired electrons, the complex is diamagnetic.
It has square planar geometry.
6. What are Homoleptic and Heteroleptic complexes? Give an example.

Complexes in which a metal is bound to only one kind of ligands are called homoleptic complexes.
Ex : Ni(CO)4
Complexes in which a metal is bound to more than one kind of ligands are called heteroleptic complexes.
Ex : [CoCl3(NH3)3]
7. What are linkage and ionization isomerism? Give an example.

Linkage isomers have same molecular formula but the same ligand linked to central metal with different
donor atom.
Ex : [Co(NH3)5(NO2)]Cl2 and [Co(NH3)5(ONO)]Cl2
Ionization isomers have same molecular formula but give different ions on ionization in solution.
Ex : [Co(NH3)5(SO4)]Br and [Co(NH3)5Br] SO4

Chapter-10: Haloalkanes and haloarenes
1. Explain SN1 mechanism for the conversion of tertiary butyl bromide to tertiary butyl
alcohol.
When tertiary butyl bromide is heated with aqueous potassium hydroxide, tertiary butyl alcohol is formed.
(CH3)3C-Br + KOH (CH3)3C-OH + KBr
Mechanism :
Step 1: Tertiary butyl bromide undergoes slow ionization gives carbocation.
CH3 CH3
CH3-C-Br CH3-C + + Br -
CH3 CH3
This is a slow step and hence it is a rate determining step.
Step 2: The nucleophile OH- attack carbocation and gives tertiary butyl alcohol.
CH3 CH3
CH3-C + + OH- CH3-C-OH
CH3 CH3
Rate of reaction depends only on concentration of alkyl halide, hence it is a 1st order reaction.
2. Explain SN2 mechanism for the conversion of methyl chloride to methyl alcohol.
When methyl chloride is heated with aqueous potassium hydroxide methyl alcohol is formed.
CH3 -Cl + KOH CH3 -OH + KCl
Mechanism :
The nucleophile OH- attacks the carbon atom from the side opposite to the chlorine.
The formation of C-OH and the cleavage of C-Cl bond takes place simultaneously.
Finally Cl- gets detached to give methyl alcohol.
It involves only one step hence this is the rate determining step.
Rate depends on both concentration of nucleophile and alkyl halide, hence it is a second order reaction.
3. What are Freon’s? Give an example.

The chlorofluoro compounds of methane and ethane are called Freon’s.
Ex : Freon 12

4. Explain Finkelstein and Swart’s reactions with equation.
When alkyl chlorides are heated with sodium iodide in acetone, gives alkyl iodides. This reaction is called
Finkelstein reaction.
𝐴𝑐𝑒𝑡𝑜𝑛𝑒
CH3Cl + NaI →−−−−−−−→ CH3I + NaI
Methyl Methyl
chloride iodide
When alkyl chlorides are heated with silver fluorides, gives alkyl fluorides. This reaction is called Swarts
reaction.
CH3Cl + AgF →−−−→ CH3F + AgCl
Methyl Methyl
chloride fluoride
5. Explain Fittig and Wurtz-Fittig reaction with equation.

When two molecules of aryl halides are coupled in presence of sodium metal in dry ether, gives biphenyl.
This reaction is called Fittig reaction.
When aryl halide coupling with alkyl halide in presence of sodium metal in dry ether, gives alkylarene.
This reaction is called Wurtz-Fittig reaction.

Chapter-11: Alcohols, Phenols and Ethers
1. Explain the preparation of phenol from Cumene.

When Cumene is oxidised in presence of air gives Cumene hydroperoxide.
Cumene hydroperoxide on acidification gives phenol and acetone.
2. Write the mechanism of acid catalysed dehydration of ethanol to ethene.

Step1: Protonation of alcohol yields protonated alcohol.
Step2: Protonated alcohol loses water molecule to form ethyl carbocation.
Step3: Ethyl carbocation loses a proton to form ethene.
3. Explain Reimer-Tieman reaction.

When phenol is heated with sodium hydroxide and CHCl3, sodium salt of Salicylaldehyde is obtained,
which on acidified with HCl gives Salicylaldehyde.

4. Explain Kolbe’s reaction.
When phenol is heated with NaOH gives sodium phenate and then CO2 is passed through it and
followed by acidification gives salicylic acid.
5. What is Lucas reagent?

A solution of anhydrous zinc chloride in concentrated HCl is called Lucas reagent.
6. How is phenol reacts with bromine water. Write equation.

When phenol is treated with bromine water, a white precipitate of 2, 4, 6-tribromophenol is formed.
7. Explain Williamson’s ether synthesis.

When alkyl halide is heated with sodium alkoxides, gives ether. This reaction is called Williamson’s
ether synthesis.
Ex : CH3Br + NaOC2H5 CH3-O-CH2-CH3 + NaBr
Methyl Sodium Ethyl methyl
bromide ethoxide ether

Chapter-12: Aldehydes, Ketones and Carboxylic acids
1. Explain Rosenmund’s reduction in the preparations of aldehydes.

When acid chlorides heated with H2 in the presence of palladium catalyst gives aldehydes. This reaction
is called Rosenmund reduction.
COCl CHO
Pd-BaSO4,quinoline
+ H2 + HCl
Benzoyl chloride Benzaldehyde
2. Explain Gatterman-Koch reaction in the preparations of aldehydes.

When toluene is heated with a mixture of carbon monoxide and hydrogen chloride in presence of
anhydrous AlCl3 catalyst, gives benzaldehyde. This reaction is called Gatterman-Koch reaction.
3. Explain Clemmensen reduction with an example.

The reduction of aldehydes with zinc amalgam and concentrated HCl to corresponding hydrocarbon is
called Clemmensen reduction.
𝑍𝑛−𝐻𝑔
CH3CHO + 4[H] →−−−−−−→ CH4 + H2O
4. What is a Cannizzaro’s reaction explain with an example.

Aldehydes do not containing α-hydrogen atoms are reacted with strong alkali gives alcohol and salt of
carboxylic acid. This reaction is called Cannizzaro’s reaction.
2HCHO + NaOH HCOONa + CH3OH
Formaldehyde Sodium formate Methanol
5. Explain Decarboxylation reaction with an example.

The process of removal of CO2 from sodium salt of carboxylic acids using dry soda lime (NaOH +
CaO) is called decarboxylation.
𝑁𝑎𝑂𝐻 + 𝐶𝑎𝑂
CH3COONa →−−−−−−−−−→ CH4 + Na2CO3
Sodium acetate Methane

6. Explain the mechanism of addition of HCN to a carbonyl group in presence of a base.
Aldehydes and ketones react with hydrogen cyanide to give cyanohydrine.
This reaction is very slow. Therefore, it is catalysed by a base and the generated cyanide ions (CN-) is a
stronger nucleophile which readily adds to carbonyl compounds to yield corresponding cyanohydrin.
Chapter-13: Organic Compounds Containing Nitrogen
1. How is primary amine is prepared by Hoffmann bromamide degradation reaction? Write

equation.
The acid amides on reaction with Br2 in presence of NaOH, gives primary amine is called Hoffmann
bromamide reaction.
C6H5CONH2 + Br2 + 4NaOH C6H5NH2 + Na2CO3 + 2NaBr + 2H2O
Benzamide Aniline
2. Explain Carbylamine reaction.

When primary amines are heated with chloroform and KOH carbylamines are formed. This reaction is
called Carbylamine reaction.
This is used as a test for primary amines.
CH3NH2 + CHCl3 + 3KOH CH3NC + 3KCl + 3H2O
Methyl amine Methyl isocyanide

Chapter-14: Biomolecules
1. Write Haworth structure of glucose and maltose.
Glucose
Maltose
2. What are essential and non-essential amino acids? Give an example.

Amino acids that are not synthesised in the body and must be supplied through diet are called essential
amino acids.
Ex : Lysine
Amino acids that are synthesised in the body are called non-essential amino acids.
Ex : Glycine
3. Answer the following questions.

Reducing sugar Glucose
Non-reducing sugar Sucrose
Nitrogen base present only in DNA Thymine
Nitrogen base present only in RNA Uracil
Water soluble component of starch Amylose
Water insoluble component of starch Amylopectin
Water soluble vitamin Vitamin C

Fat soluble vitamin Vitamin D
Deficiency of vitamin A Night blindness
Deficiency of vitamin C (Ascorbic acid) Scurvy
Deficiency of vitamin D Rickets

Deficiency of vitamin B12 Pernicious anaemia
Hormone maintains blood sugar level Insulin
4. What are fibrous and globular proteins? Give an example.

Long polypeptide chains arranged parallel to each other and held together by disulphide and hydrogen
bonds are called fibrous proteins.
Ex : Keratin (present in hair)
In globular proteins polypeptide chains are coiled around, giving a spherical shape.
Ex : Egg albumin
Chapter-15: Polymers
1. Name the monomer present in the following polymer

Polymer Monomer unit
Poly vinyl chloride (PVC) Vinyl chloride
Polythene Ethene
Nylon 6,6 Hexamethylene diamine + adipic acid
Nylon-6 Caprolactum
Neoprene Chloroprene
Natural rubber Cis-isoprene
(IUPAC Name is 2-methyl buta-1,3-diene)
2. Explain the preparation of Buna-N.

Buna-N is obtained by the copolymerisation of 1,3-butadiene and acrylonitrile in the presence of a
peroxide catalyst .
CN CN
𝑁𝑎
nCH2=CH-CH=CH2 + nCH2=CH →−−−−−−−→ [CH2-CH=CH-CH2-CH2-CH ]n
1,3-butadiene Acrylonitrile Buna-N

3. Explain the preparation of Buna-S:
Buna-S is obtained by the co-polymerisation of 1,3-butadine and styrene.
C6H5
𝑁𝑎
nCH2=CH-CH=CH2 + nC6H5CH=CH2 →−−−−−−−→ [CH2-CH=CH-CH2-CH2-CH ]n
1,3-butadiene Styrene Buna-S
4. Explain preparation of Neoprene.

Neoprene are Polychloroprene is formed by the free radical polymerisation of chloroprene.
5. Explain Vulcanisation of rubber.

The process of heating natural rubber with sulphur, to improve the physical properties rubber is called
vulcanisation of rubber.
✓ During vulcanisation, sulphur forms bridges between different chains.
✓ Vulcanized rubber is hard, non-sticky and has high tensile strength.
✓ It is used for making rubber bands, gloves and tyres.
6. What are biodegradable and non-biodegradable polymers? Give an example for each.
Polymers which undergo natural break down into raw materials of nature and disappear into nature are
called biodegradable polymers.
Ex : PHBV
Polymers which cannot undergo natural break down or break down over a long period of time are called
non-biodegradable polymers.
Ex : Polythene
7. What are addition and condensation polymers? Give an example.

The polymers formed by repeated addition of monomer molecules possessing double or triple bonds are
called addition polymers.
Ex : Polythene
The polymers formed by repeated condensation reaction between two different bi-functional monomeric
units are called condensation polymers.
Ex : Nylon 6,6

Chapter-16: Chemistry in everyday life
1. What are food preservatives? Give an example.

Food preservatives are chemicals that prevents food from spoilage due to microbial growth.
Ex : Table salt
2. What are antioxidants? Give an example.

The chemical substances which prevent oxidation and subsequent spoilage of the food are called
antioxidants.
Ex : Butylated hydroxyl toluene (BHT)
3. What are antifertility drugs? Give an example.

The chemical compounds which prevents the pregnancy in women are called antifertility drugs.
Ex : Norethindrone
4. What are tranquilizers? Give an example.

Tranquilizers are drugs used for the treatment of stress and mental disorders.
Ex : Equanil
5. What are anionic detergents? Give an example.

Sodium salts of sulphonated long chain hydrocarbons are called anionic detergents.
Ex : Sodium lauryl sulphate
6. Give an example for each of the following.

Artificial sweetening agent : Saccharin
Antiseptic : Dettol
Non-narcotic analgesic : Aspirin

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Dr.

Irfan Ahamed Shaikh

Unit No. CHAPTERS Page No.

4 CHEMICAL KINETICS 7–9

8 THE d AND f-BLOCK ELEMENTS 15

10 HALOALKANES AND HALOARENES 19 – 20

11 ALCOHOLS, PHENOLS AND ETHERS 21 – 22

12 ALDEHYDES, KETONES AND CARBOXYLIC ACIDS 23 – 24

13 ORGANIC COMPOUNDS CONTAINING NITROGEN 24

16 CHEMISTRY IN EVERYDAY LIFE 28

1. Give any two differences between Crystalline and Amorphous solids.

2. Calculate the number of particles per unit cell of simple cubic.

Therefore, number of particles per unit cell = 1

The particle present at body centre of the cube = 1 =1

Therefore, number of particles per unit cell = 1 + 1 = 2

From each face, contribution per unit cell is 1 x6=3

Therefore, number of particles per unit cell = 1 + 3 = 4

5. Calculate the packing efficiency in simple cubic (sc) lattice

Volume of the unit cell = a3 = (2r) 3 = 8r3

Volume of the unit cell = a3 = (2√2𝑟) 3

7. Calculate the packing efficiency in body-centred cubic (bcc)

Volume of the unit cell = a3 = (4r /√3)3

Volume of particles = 2 x 4 𝜋𝑟3 = 8 𝜋𝑟3

Note : AgBr shows both Schottky and Frenkel defects.

10. What are paramagnetic substances? Give an example.

11. What are ferromagnetic substances? Give an example.

Dr. Irfan Ahamed Shaikh, Lecturer in Chemistry Mobile: 8749027777 Page 3

1. State Henry’s law. Write its mathematical form.

3. State Raoult’s law for liquid mixtures.

Ideal Solutions Non – Ideal Solutions

5. What is reverse osmosis? Mention its one practical utility(use).

Dr. Irfan Ahamed Shaikh, Lecturer in Chemistry Mobile: 8749027777 Page 4

1. State Faraday’s first law and Faraday's second law of electrolysis.

2. Explain the construction and working of Standard Hydrogen Electrode (SHE).

Representation of SHE is Pt(s) / H2(g, 1 bar) || H+(aq, 1M)

3. What is a Primary and Secondary cell? Give an example.

Dr. Irfan Ahamed Shaikh, Lecturer in Chemistry Mobile: 8749027777 Page 5

5. Write Nernst equation for Daniel cell. Explain the terms?

Where; E0Mn+/M standard electrode potential

Dr. Irfan Ahamed Shaikh, Lecturer in Chemistry Mobile: 8749027777 Page 6

1. What is a Pseudo first order reaction? Give an example.

2. Give any two differences between order and molecularity

Consider a zero order reaction

[R] = −Kt + I----------------- (1)

Where ‘I’ is integration constant.

When, t = 0 then [R] = [R]0

equation (1) becomes

[R] = −Kt + [R]o

Dr. Irfan Ahamed Shaikh, Lecturer in Chemistry Mobile: 8749027777 Page 7

ln [R] = - Kt + I ------------------ (1)

When t = 0 then, [R] = [R]0

equation (1) becomes

Therefore, for a zero order reaction t1/2 α [R]0

Dr. Irfan Ahamed Shaikh, Lecturer in Chemistry Mobile: 8749027777 Page 8

2.303 X 0.3010 0.693

Therefore, for a first order reaction t1/2 is independent of initial concentration.

Dr. Irfan Ahamed Shaikh, Lecturer in Chemistry Mobile: 8749027777 Page 9

1. Write the differences between Physisorption and Chemisorption.

Physical adsorption (Physisorption) Chemical adsorption (Chemisorption)