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    Catalytic Oxidation Techology - Sud Chemie (Very Good)

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    The document discusses catalytic oxidation technology for air pollution control presented by Sud Chemie India. It provides an overview of Sud Chemie India, including that it is a 50:50 joint venture with Clariant established in 1969. It then discusses domestic customers, air pollutants and their effects, emission sources, the development of air pollution regulations, emission regulation limits for various industries, catalytic oxidation technology and process, applications, and examples of chemical off-gas treatment using catalytic oxidation.

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    Catalytic Oxidation Techology - Sud Chemie (Very Good)

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    daraj daraj
    51 views25 pages
    The document discusses catalytic oxidation technology for air pollution control presented by Sud Chemie India. It provides an overview of Sud Chemie India, including that it is a 50:50 joint venture with Clariant established in 1969. It then discusses domestic customers, air pollutants and their effects, emission sources, the development of air pollution regulations, emission regulation limits for various industries, catalytic oxidation technology and process, applications, and examples of chemical off-gas treatment using catalytic oxidation.

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    The document discusses catalytic oxidation technology for air pollution control presented by Sud Chemie India. It provides an overview of Sud Chemie India, including that it is a 50:50 joint venture with Clariant established in 1969. It then discusses domestic customers, air pollutants and their effects, emission sources, the development of air pollution regulations, emission regulation limits for various industries, catalytic oxidation technology and process, applications, and examples of chemical off-gas treatment using catalytic oxidation.

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    51 views25 pages

    Catalytic Oxidation Techology - Sud Chemie (Very Good)

    Uploaded by

    daraj daraj
    The document discusses catalytic oxidation technology for air pollution control presented by Sud Chemie India. It provides an overview of Sud Chemie India, including that it is a 50:50 joint venture with Clariant established in 1969. It then discusses domestic customers, air pollutants and their effects, emission sources, the development of air pollution regulations, emission regulation limits for various industries, catalytic oxidation technology and process, applications, and examples of chemical off-gas treatment using catalytic oxidation.

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    of 25

    Catalysis & Energy

    Air Purification

    Catalytic Oxidation Technology


    for Air Pollution Control
    Presentation for GC&E Seminar, Hyderabad
    28 April 2015

    Page 1
    Sud Chemie India Fact File
    • Private Limited Company
    • 50:50 JV with Clariant
    • Established in 1969
    • Managing Director: Ms Arshia Lalljee
    • Products
    – Industrial catalysts
    – Zeolites
    – Environmental catalysts
    • Work force: 400
    • ISO 9001/14001/OHSAS 18001/ TS
    16949 certified

    Presentation for GC&E Seminar, Hyderabad Page 2


    Domestic Customers…

    FERTILIZER/SYNGAS/STEEL AUTOMOTIVE REFINERY/PETROCHEMICAL

    Many more…….
    Presentation for GC&E Seminar, Hyderabad Page 3
    Air Pollution & Regulatory standards

    Presentation for GC&E Seminar, Hyderabad Page 4


    Air Pollutants & Its Effects

    >2 Billion pounds of pollutants are being released every year to atmosphere
    Presentation for GC&E Seminar, Hyderabad Page 5
    Emission Sources

    Emission Sources

    Fuel Combustion Industrial process Solid Waste


    Transportation Miscellaneous
    in stationary losses disposal

    Motor Vehicles Residential Onsite & Municipal


    Chemical Process Forest Fires
    Off-Highway Fuel Industrial waste incineration
    Food & Agricultural Structural Fires
    Usage Power plants Open Burning
    Metallurgical Coal refuse
    Aircrafts burning
    Mineral Product
    Trains Agricultural
    Petroleum refining
    Ships burning
    Pharma &
    Volcano eruption
    Healthcare

    Presentation for GC&E Seminar, Hyderabad Page 6


    Development of Air Pollution Regulations

    Major drivers:
    1. Protection of human health,
    2. Protection of assets,
    3. Protection of ozone layer / Climate

    Started in 1979: Convention on Long-


    Range Trans-Boundary Air Pollution

    Most popular: UNFCCC “Framework


    Convention on Climate Change” incl.
    Kyoto Protocol

    Presentation for GC&E Seminar, Hyderabad Page 7


    Emission Regulation
    Actual limit depend on Industry, Plant, Feedstock & Age of Plant
    T. Dioxins &
    Industries SOx NOx PM CO VOC/TOC NH3
    Furan

    ng
    mg / Nm³
    TEQ/Nm3

    Pesticides 200 20-50 100 20 30 0.1-0.2

    Pharma-
    Incinerator 200 50 100 20 0.1
    (Bulk Drugs)

    Dyes & Dyes


    200 50 100 20 30 0.1
    Intermediate

    Waste
    200 400 50 50 - 100 20 0.1
    Incinerators

    Petro-
    50 – 1700 250 – 450 10 – 100 100 – 200 0.1 - 150
    chemicals

    And many more like Heavy Metals, H2S or Organic Particulates etc.
    Presentation for GC&E Seminar, Hyderabad Page 8
    Catalytic Oxidation Technology

    Presentation for GC&E Seminar, Hyderabad Page 9


    Catalytic Oxidation
    • Total oxidation of volatile organic compounds and
    carbon monoxide…
    CxHy + (x + y)/4 O2 → x CO2 + y/2 H2O
    CO + ½ O2 → CO2
    NH3 + O2 → N2 + H2O
    • Catalyst selection based on avoiding undesirable
    reactions such as
    - Polymerization
    - Partial conversion of HC to CO
    - NH3 oxidation to Nox

    Presentation for GC&E Seminar, Hyderabad Page 10


    Catalytic Oxidation – Design considerations
    • Systems are designed based on
    - Inlet concentration
    - Conversion requirements
    - Temperature limitations
    - Space velocity
    - Pressure drop
    - Durability
    - Safety

    Presentation for GC&E Seminar, Hyderabad Page 11


    Catalytic Oxidation steps
    • Diffusion of the reactants from the bulk phase to the
    catalyst
    • Diffusion of the reactants to active sites
    • Adsorption of the reactants at the active sites
    • Electron transfer process at the active sites
    • Desorption of the reaction products at the active sites
    • Diffusion of the reaction products to the catalyst
    surface
    • Diffusion of the reaction products to the bulk phase

    Presentation for IICHE, Ankleshwar Page 12


    Schematic of Coated Catalyst Monolith

    Precious Metal Particle

    Washcoat Layer

    Cell Wall
    Presentation for GC&E Seminar, Hyderabad Page 13
    Applications for Oxidation Processes

     Commercial Printing
     Flexible Packaging
     Wood Products
     Wood burning Appliances
     Pharmaceuticals
     Metal Decorating
     Converting / Coating
     Painting/Finishing
     Automotive Parts
     Baking/Food Processes
     Chemical Processing
    Presentation for GC&E Seminar, Hyderabad Page 14
    Chemical Off-Gas Application
    VOCs (Volatile Organic Compounds):  Acrylic Acid (AA)
    Alcohols, ethers, aromatics,  Polyethylene Terephthalate (PET)
    Ketones, acetates, acids,  Phthalic Anhydride (PA)
    Alkanes, Etc.
    Carbon  Acrylonitrile (AN)
    Monoxide  Phenol/Acetone
     Maleic Anhydride (MA)
     Methyl Methacrylate (MMA)
    OXIDATION
     Formaldehyde (FA)
     Urea Production (H2 removal in
    CO2)
     Purified Terephthalic Acid (PTA)
     CO2 Purification
     PO/SM – Propylene oxide/Styrene
    monomer
     Cyclohexanone
    Several hundred installations for this processes worldwide
    Presentation for GC&E Seminar, Hyderabad Page 15
    Typical List of pollutants for catalytic oxidation
    VOCs
    Alkanes Methane, Propane, Butane, Hexane, Heptane, Cyclopentane,
    Cyclohexane
    Hydrocarbon Alkenes Ethylene, Propene, Cyclohexene
    Aromatics Benzene, Toluene, Xylene, Methyl-subtituted aromatic,
    Phenanthrene

    Halogenated H/C Methyl Bromide, MDC, Chlorobenzene, Tricholoethylene,

    Alcohols Methanol, Ethanol, Propanol, Butanol


    Ketones Acetone, MEK,
    Oxygenated VOC
    Aldehydes Formaldehyde, Acetaldehyde,
    Esters Ethyl Acetate, Butyl Acetate, MethylMethacrylate
    Diethyl amine, Thiophene, Gasoline Vapor, Pyridine & Pyridine
    Other VOCs derivates, Mercaptans, Dimethyl Disulphide
    Dioxins & Furans
    NON-VOCs
    Ammonia, CO, NOx, N2O,

    Presentation for GC&E Seminar, Hyderabad Page 16


    Various Products

    Presentation for GC&E Seminar, Hyderabad Page 17


    Advantages of Catalytic Oxidation
    • Lower operating temperature ~ Lower Energy ~ REDUCED COSTS
    • High destruction efficiency (>99%)
    • Low secondary pollutants,
    • Less severe MOC, hence lower equipment costs
    • High selectivity
    • Ease of Operation.
    • Less Space Requirement.
    Temperatures (⁰C) for 99% Destruction Efficiency
    VOC Catalytic Thermal
    Alcohols ~250 ~690
    Aldehyde ~300 ~775
    Ester ~325 ~750
    Aromatics ~250 ~845
    Alkanes ~425 ~750

    Presentation for GC&E Seminar, Hyderabad Page 18


    Need Paradigm Shift – Process Emission
    Fuel
    Stream 1

    Stream 2
    Thermal Oxidizer/ Scrubber
    To Atm
    Incinerator (Optional)
    Stream 3

    Stream 4 Conventional Treatment Philosophy


    Stream
    Segregation &
    Divert to
    Catalytic Unit
    Stream 1 – Air + VOC + NH3
    Stream 2 – Air + Halogenated H/C + CO + CO2 + NOx
    Stream 3 – Air + metal halide + PM
    Stream 4 - Air + Complex hydrocarbons

    Presentation for GC&E Seminar, Hyderabad Page 19


    Different Areas of Application

    Municipal /Waste
    Dioxins
    incinerator

    Condenser Fugitive Emission To Atm

    Scrubber Outlet
    Catalytic
    Incinerator
    Vacuum Pump outlet

    Storage tank vents

    Drying chamber vents

    Presentation for GC&E Seminar, Hyderabad Page 20


    Catalytic Vs Thermal Oxidation
    Off Gas Flow – 20000 scfm Temp – 40 ⁰C

    VOC – 18.14 kg/hr, Pressure – Ambient

    LHV – 40,705 KJ/kg


    Regenerative Thermal Regenerative Catalytic
    Operating Parameters/Technology Oxidizer Oxidizer
    RTO RCO
    Working Temp, ⁰C 760 371

    System Pressure Drop, inch wc 12 8

    Thermal Energy Recovery


    95% 92%

    Fuel consumption, mmbtu/hr 0.81 0.39

    Fan power, HP 58 39

    Presentation for GC&E Seminar, Hyderabad Page 21


    Typical Catalytic Incineration System

    To Atmosphere
    Sud Chemie Catalyst

    Catalytic
    Pre- Thermic Fluid Heater/ Combustion By-Pass to Atm
    Direct Fired Heater Reactor (CCR)
    Off Gas In Heater

    Confidential Page 22
    Sud Chemie Standard Catalysts and applications
    Catalyst Application Remarks
    EnviCat ® 15200 CH VOC Oxygenated
    hydrocarbons
    EnviCat ® 2003 CH VOC, CO

    EnviCat ® 2060 CH VOC, NH3

    EnviCat ® 5006 VOC

    EnviCat ® 5028 VOC Alkanes

    EnviCat ® 15700 NOx SCR

    EnviCat ® 2311 De Oxo CO2 purification

    EnviCat ® 3363 Ozone

    And many more custom catalysts

    Presentation for GC&E Seminar, Hyderabad Page 23


    SÜD-CHEMIE Offers

    – Wide range of Environmental Catalysts for Off-Gas treatment.

    – State-Of-Art Facility in India and World Wide

    – Customized solutions and after sales services

    – Complete turnkey solutions with its engineering partner

    – Technical support, feasibility study

    Presentation for GC&E Seminar, Hyderabad Page 24


    THANK YOU

    Presentation for GC&E Seminar, Hyderabad Page 25

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