Conforms to 91/155/EEC - 2001/58/EC - United Kingdom (UK)

SAFETY DATA SHEET

DREWPLEX OX
1. Identification of the substance/preparation and of the company/undertaking
Product name : DREWPLEX OX
Material Uses : Industrial applications: Corrosion inhibitor for steamgenerating systems,
oxygen scavenger and metal passivator.

Manufacturer / Supplier :
Drew Marine Drew Marine
Ashland Specialty Chemical Company Ashland Specialty Chemical Company
Malledijk 20 One Drew Plaza
3208 LA Spijkenisse Boonton, NJ 07005
Netherlands United States
Tel. No.: Tel. No.:
+31 181 457 070 +1 (973) 263 7600
Fax: Fax:
+31 181 625 792 +1 (973) 263 4491
Emergency telephone number
(Germany) : +49 621 60-43333
Fax:
(Germany) : +49 621 60-92664

2. Composition/information on ingredients
Substance/Preparation : Preparation
Chemical characterization : Slightly alkaline solution containing: N,N-Diethylhydroxylamine

Chemical name* CAS No. % EC Number Classification

N,N-Diethylhydroxylamine 3710-84-7 10-20 223-055-4 R10
Xn; R20/21
Xi; R36
1,2,3-Trihydroxybenzene 87-66-1 0.5-1 201-762-9 Muta. Cat. 3; R68
Xn; R20/21/22
R52/53
See Section 16 for the full text of the R Phrases declared above

* Occupational Exposure Limit(s), if available, are listed in Section 8

3. Hazards identification
The preparation is not classified as dangerous according to Directive 1999/45/EC and its amendments.
Classification :
This product is not classified according to the EU regulations.
Effects and symptoms
Inhalation : Inhalation of the spray mist may produce severe irritation of respiratory tract,
characterized by coughing, choking or shortness of breath. Overexposure by
inhalation may cause respiratory irritation.
Ingestion : Irritating to mouth, throat and stomach.
Skin contact : Slightly irritating to the skin.
Eye Contact : May cause eye irritation.

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4. First-aid measures
First-Aid measures
Inhalation : If inhaled, remove to fresh air. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen. Obtain medical attention.
Ingestion : Do NOT induce vomiting unless directed to do so by medical personnel.
Never give anything by mouth to an unconscious person. Loosen tight clothing
such as a collar, tie, belt or waistband. Get medical attention if symptoms
appear.
Skin contact : In case of contact, immediately flush skin with plenty of water. Remove
contaminated clothing and shoes. Cold water may be used. Wash clothing
before reuse. Clean shoes thoroughly before reuse. Obtain medical attention.
Eye Contact : Check for and remove any contact lenses. In case of contact, immediately
flush eyes with a copious amount of water for at least 15 minutes. Cold water
may be used. Obtain medical attention.

5. Fire-fighting measures
Extinguishing Media
Suitable : Not applicable.
Hazardous thermal (de)composition : These products are carbon oxides (CO, CO2) and water, nitrogen oxides (NO,
products NO2...).
Protection of fire-fighters : Fire fighters should wear self-contained positive pressure breathing apparatus
(SCBA) and full turnout gear.

6. Accidental release measures

Personal Precautions : Splash goggles. Full suit. Vapour respirator. Boots. Gloves. A self-contained
breathing apparatus should be used to avoid inhalation of the product.
Suggested protective clothing might not be sufficient; consult a specialist
BEFORE handling this product.
Environmental precautions and : Stop leak if without risk. Absorb with dry earth, sand or other noncombustible
cleanup methods material. Use water spray curtain to divert vapour drift. Prevent entry into
sewers, basements or confined areas; dike if needed. Call for assistance on
disposal. Neutralize the residue with a dilute solution of acetic acid.
Note: See section 8 for personal protective equipment and section 13 for waste disposal.

7. Handling and storage

Handling : Keep locked up. Keep container dry. Keep away from heat. Keep away from
sources of ignition. Do not ingest. Do not breathe gas/fumes/vapour/spray.
Wear suitable protective clothing. If ingested, seek medical advice
immediately and show the container or the label.
Storage : Keep container tightly closed. Keep container in a cool, well-ventilated area.
Packaging materials
Recommended use : Use original container.

8. Exposure controls/personal protection

Engineering measures : Provide exhaust ventilation or other engineering controls to keep the airborne
concentrations of vapours below their respective occupational exposure limits.
Ensure that eyewash stations and safety showers are close to the workstation
location.
Hygiene measures : Wash hands, forearms, and face thoroughly after handling compounds and
before eating, smoking, using lavatory, and at the end of day.

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Respiratory system : Wear appropriate respirator when ventilation is inadequate. Vapour respirator.

Skin and body : Full suit.

Hands : Impervious gloves.
Eyes : Face shield.

9. Physical and chemical properties

Physical state : Liquid.
Colour : Colourless to light yellow.
Odour : Characteristic.
Boiling point : >100°C (212°F)
Melting point : -4 to -2°C (25 to 28°F)
Density : 1 g/cm3
Vapour pressure : The highest known value is 4.27 kPa (32 mmHg) (at 20°C)
(N,N-Diethylhydroxylamine).
Evaporation Rate : 0.36 (Water) compared to n-Butyl acetate

Solubility : Easily soluble in cold water.

pH : Basic.
Flash point : Not applicable.

10. Stability and reactivity

Stability : The product is stable.
Conditions to Avoid : Exposure to heat . Do not use sodium nitrite or other nitrosating agents
together with this product. Suspected cancer-causing nitrosamines could be
formed.
Materials to avoid : Slightly reactive to reactive with oxidizing agents.
Incompatible with magnesium, zinc, sodium, potassium and aluminium.
Incompatible with copper alloys. Avoid contact with organic materials.
Hazardous decomposition products : These products are carbon oxides (CO, CO2) and water, nitrogen oxides (NO,
NO2...).

11. Toxicological information

Acute toxicity
Ingredient Name Test Result Route Species
N,N-Diethylhydroxylamine LD50 2190 mg/kg Oral Rat
LD50 1300 mg/kg Dermal Rabbit
LDLo 1600 mg/kg Oral Rat
LDLo 100 mg/kg Dermal Rat
LC50 11.7 mg/l (4 Inhalation Rat
hours)
1,2,3-Trihydroxybenzene LD50 1600 mg/kg Oral Rabbit
LD50 300 mg/kg Oral Mouse
LD50 789 mg/kg Oral Rat
LDLo 25 mg/kg Oral Dog
LDLo 28 mg/kg Oral Human/30 min

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Chronic toxicity : Repeated or prolonged contact with spray mist may produce chronic eye
irritation and severe skin irritation. Repeated or prolonged exposure to spray
mist may produce respiratory tract irritation, leading to frequent attacks of
bronchial infection. Repeated exposure to an highly toxic material may
produce general deterioration of health by an accumulation in one or many
human organs.
Local effects
Specific effects
Carcinogenic effects : Not available.

Mutagenic Effects : Classified 3 by European Union [1,2,3-Trihydroxybenzene].

Reproduction toxicity : Not available.

12. Ecological information

Ecotoxicity Data
Ingredient Name Species Period Result
N,N-Diethylhydroxylamine Fish (LC50) 96 hours 100 to 130 mg/l
Daphnia (EC50) 48 hours 150 to 180 mg/l
Persistence/degradability : The BOD is 49000 mg/l [5 day(s)] at 5%. The COD is 200000 mg/l[ day(s)] at
5%.

13. Disposal considerations

Methods of disposal ; Waste of : Waste must be disposed of in accordance with federal, state and local
residues ; Contaminated packaging environmental control regulations.

European Waste Catalogue (EWC) : 06 02 00

Hazardous Waste : The classification of the product may meet the criteria for a hazardous waste.
Additional Information : 06 02 00 waste alkaline solutions

14. Transport information

International transport regulations
Land - Road/Railway
UN number : 2735
Proper shipping name : AMINES, LIQUID, CORROSIVE, N.O.S. (N,N-Diethylhydroxylamine)
ADR/RID Class : 8
Packing group : III
ADR/RID label :

Other information : Hazard identification number

80
Sea
UN number : 2735
Proper shipping name : AMINES, LIQUID, CORROSIVE, N.O.S. (N,N-Diethylhydroxylamine)
IMDG Class : 8
Packing group : III

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IMDG label :

Other information : Emergency Schedules (EmS)

8-05

15. Regulatory information

EU Regulations
Risk Phrases : This product is not classified according to the EU regulations.
Product Use : Classification and labelling have been performed according to EU directives
67/548/EEC, 88/379/EEC, including amendments and the intended use.
- Industrial applications.

16. Other information

Full text of R-Phrases with no. : R10- Flammable.
appearing in Section 2 - United R20/21- Harmful by inhalation and in contact with skin.
Kingdom (UK) R36- Irritating to eyes.
Text of classifications appearing in : Xn - Harmful
Section 2 - United Kingdom (UK) Xi - Irritant
HISTORY
Date of printing : 10/17/2002.
Date of issue : 10/16/2002.
Version : 3
DREWPLEX® is a registered trademark of Ashland Inc.
Notice to Reader
To the best of our knowledge, the information contained herein is accurate. However, neither the above named supplier nor
any of its subsidiaries assumes any liability whatsoever for the accuracy or completeness of the information contained
herein.
Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown
hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these
are the only hazards that exist.
Date of issue Version
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