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Conforms to 91/155/EEC - 2001/58/EC - United Kingdom (UK)

SAFETY DATA SHEET


DEWT-NC Reagent No.2
1. Identification of the substance/preparation and of the company/undertaking
Product name : DEWT-NC Reagent No.2
Material Uses : Industrial applications: Analytical reagent.

Manufacturer / Supplier :
Drew Marine Drew Marine
Ashland Specialty Chemical Company Ashland Specialty Chemical Company
Malledijk 20 One Drew Plaza
3208 LA Spijkenisse Boonton, NJ 07005
Netherlands United States
Tel. No.: Tel. No.:
+31 181 457 070 +1 (973) 263 7600
Fax: Fax:
+31 181 625 792 +1 (973) 263 4491
Emergency telephone number
(Germany) : +49 621 60-43333
Fax:
(Germany) : +49 621 60-92664

2. Composition/information on ingredients
Substance/Preparation : Preparation

Chemical name* CAS No. % EC Number Classification


Potassium permanganate 7722-64-7 5-10 231-760-3 O; R8
Xn; R22
N; R50/53
See Section 16 for the full text of the R Phrases declared above

* Occupational Exposure Limit(s), if available, are listed in Section 8

3. Hazards identification
The preparation is classified as dangerous according to Directive 1999/45/EC and its amendments.
Classification : Dangerous for the environment
R51/53- Toxic to aquatic organisms, may cause long-term adverse effects in
the aquatic environment.
Effects and symptoms
Skin contact : Hazardous in case of skin contact (irritant). Skin inflammation is
characterized by itching, scaling, reddening, or, occasionally, blistering.
Eye Contact : Hazardous in case of eye contact (irritant).
Target Organs : Contains material which causes damage to the following organs: skin, eyes,
stomach.

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DEWT-NC Reagent No.2

4. First-aid measures
First-Aid measures
Inhalation : If inhaled, remove to fresh air. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen. Obtain medical attention.
Ingestion : Do NOT induce vomiting unless directed to do so by medical personnel.
Never give anything by mouth to an unconscious person. Loosen tight clothing
such as a collar, tie, belt or waistband. Get medical attention if symptoms
appear.
Skin contact : In case of contact, immediately flush skin with plenty of water. Cover the
irritated skin with an emollient. Remove contaminated clothing and shoes.
Cold water may be used. Wash clothing before reuse. Clean shoes
thoroughly before reuse. Obtain medical attention.
Eye Contact : Check for and remove any contact lenses. In case of contact, immediately
flush eyes with a copious amount of water for at least 15 minutes. Cold water
may be used. Obtain medical attention.

5. Fire-fighting measures
Extinguishing Media
Suitable : Not applicable.
Unusual fire/explosion Hazards : In a fire, the following can be released: Oxygen
Hazardous thermal (de)composition : These products are halogenated compounds. Some metallic oxides.
products
Protection of fire-fighters : Fire fighters should wear self-contained positive pressure breathing apparatus
(SCBA) and full turnout gear.

6. Accidental release measures


Personal Precautions : Splash goggles. Full suit. Dust respirator. Boots. Gloves. A self-contained
breathing apparatus should be used to avoid inhalation of the product.
Environmental precautions and : Use a shovel to put the material into a convenient waste disposal container.
cleanup methods Finish cleaning by spreading water on the contaminated surface and allow to
evacuate through the sanitary system.
Note: See section 8 for personal protective equipment and section 13 for waste disposal.

7. Handling and storage


Handling : Do not breathe dust. Wear suitable protective clothing. If ingested, seek
medical advice immediately and show the container or the label. Avoid
contact with skin and eyes. Keep away from incompatibles such as reducing
agents. Use only in accordance with Drew Test Procedures.
Storage : Keep container tightly closed. Keep container in a cool, well-ventilated area.
Packaging materials
Recommended use : Use original container.

8. Exposure controls/personal protection


Engineering measures : Use process enclosures, local exhaust ventilation, or other engineering
controls to keep airborne levels below recommended exposure limits. If user
operations generate dust, fume or mist, use ventilation to keep exposure to
airborne contaminants below the exposure limit.
Hygiene measures : Wash hands after handling compounds and before eating, smoking, using
lavatory, and at the end of day.

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DEWT-NC Reagent No.2

Respiratory system : Dust respirator.

Skin and body : Lab coat.


Hands : Impervious gloves.
Eyes : Splash goggles.

9. Physical and chemical properties


Physical state : Solid. ((powder))
Colour : Violet.
Odour : Not available.
Boiling point : Decomposition Temperature: 240°C (464°F)
Melting point : Decomposition Temperature: 240°C (464°F)
Density : 2.3 g/cm3
Solubility : Easily soluble in cold water.
pH : Not available.
Flash point : Not applicable.

10. Stability and reactivity


Stability : The product is stable.
Materials to avoid : Reactive with reducing agents.
Extremely reactive; reacts readily with water, ammonia, halogens, oxygen and
most acids. Can undergo an exothermic reaction with aluminium. Reacts
violently with: Hydrogen peroxide. Incompatible with magnesium, zinc,
sodium, potassium and aluminium. Contact with combustible material may
cause fire. Contact with hydrochloric acid liberates toxic gas: Chlorine.
Hazardous decomposition products : These products are halogenated compounds. Some metallic oxides.

11. Toxicological information


Acute toxicity
Ingredient Name Test Result Route Species
Potassium permanganate LD50 1090 mg/kg Oral Rat
LD50 1151 mg/kg Oral Guinea pig
LD50 2157 mg/kg Oral Mouse
LDLo 600 mg/kg Oral Rabbit
LDLo 100 mg/kg Oral woman
LDLo 143 mg/kg Oral human

Chronic toxicity : Repeated or prolonged exposure is not known to aggravate medical condition.
Skin irritation : Hazardous in case of skin contact (irritant).
Eye irritation : Hazardous in case of eye contact (irritant).
Carcinogenic effects : Not available.

Mutagenic Effects : Not available.


Reproduction toxicity : Not available.

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DEWT-NC Reagent No.2

12. Ecological information

Persistence/degradability : Not available.

13. Disposal considerations


Methods of disposal ; Waste of : Waste must be disposed of in accordance with federal, state and local
residues ; Contaminated packaging environmental control regulations.

European Waste Catalogue (EWC) : 16 05 02


Hazardous Waste : The classification of the product may meet the criteria for a hazardous waste.
Additional Information : 16 05 02 other waste containing inorganic chemicals, e.g. lab chemicals not
otherwise specified, fire extinguishing powders

14. Transport information


International transport regulations
Land - Road/Railway
UN number : Not regulated.
Proper shipping name : -
ADR/RID Class : -
Other information : Remarks
Not controlled under ADR (Europe).
Sea
UN number : Not regulated.
Proper shipping name : -
IMDG Class : -
Other information : Remarks
Not controlled under IMDG.

15. Regulatory information


EU Regulations
Hazard symbol(s) :

Dangerous for the environment


Risk Phrases : R51/53- Toxic to aquatic organisms, may cause long-term adverse effects in
the aquatic environment.
Safety Phrases : S56- Dispose of this material and its container at hazardous or special waste
collection point.
Product Use : Classification and labelling have been performed according to EU directives
67/548/EEC, 88/379/EEC, including amendments and the intended use.
- Industrial applications.

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DEWT-NC Reagent No.2

16. Other information


Full text of R-Phrases with no. : R8- Contact with combustible material may cause fire.
appearing in Section 2 - United R22- Harmful if swallowed.
Kingdom (UK) R50/53- Very toxic to aquatic organisms, may cause long-term adverse effects
in the aquatic environment.
Text of classifications appearing in : O - Oxidizing
Section 2 - United Kingdom (UK) Xn - Harmful
N - Dangerous for the environment.
HISTORY
Date of printing : 10/22/2002.
Date of issue : 7/18/2002.
Version : 2.07
DEWT® is a registered trademark of Ashland Inc.
Notice to Reader
To the best of our knowledge, the information contained herein is accurate. However, neither the above named supplier nor
any of its subsidiaries assumes any liability whatsoever for the accuracy or completeness of the information contained
herein.
Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown
hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these
are the only hazards that exist.
Date of issue Version
7/18/2002. 2.07 Page: 5/5

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