Conforms to 91/155/EEC - 2001/58/EC - United Kingdom (UK)

SAFETY DATA SHEET

DREW PL
1. Identification of the substance/preparation and of the company/undertaking
Product name : DREW PL
Material Uses : Industrial applications: Passivating Liquid

Manufacturer / Supplier :
Drew Marine Drew Marine
Ashland Specialty Chemical Company Ashland Specialty Chemical Company
Malledijk 20 One Drew Plaza
3208 LA Spijkenisse Boonton, NJ 07005
Netherlands United States
Tel. No.: Tel. No.:
+31 181 457 070 +1 (973) 263 7600
Fax: Fax:
+31 181 625 792 +1 (973) 263 4491
Emergency telephone number
(Germany) : +49 621 60-43333
Fax:
(Germany) : +49 621 60-92664

2. Composition/information on ingredients
Substance/Preparation : Preparation

Chemical name* CAS No. % EC Number Classification

Nitric acid 7697-37-2 50-60 231-714-2 O; R8
C; R35
See Section 16 for the full text of the R Phrases declared above

* Occupational Exposure Limit(s), if available, are listed in Section 8

3. Hazards identification
The preparation is classified as dangerous according to Directive 1999/45/EC and its amendments.
Classification : Corrosive
R35- Causes severe burns.
Effects and symptoms
Inhalation : Inhalation of the spray mist may produce severe irritation of respiratory tract,
characterized by coughing, choking or shortness of breath. Overexposure by
inhalation may cause respiratory irritation.
Ingestion : May be fatal if swallowed. May cause burns to mouth, throat and stomach.
Skin contact : Corrosive to skin on contact. Skin contact may produce burns.
Eye Contact : Corrosive to eyes.
Target Organs : Contains material which causes damage to the following organs: lungs,
mucous membranes, upper respiratory tract, skin, eye, lens or cornea, teeth.

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4. First-aid measures
First-Aid measures
Inhalation : If inhaled, remove to fresh air. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen. Obtain medical attention immediately.
Ingestion : Do NOT induce vomiting unless directed to do so by medical personnel.
Never give anything by mouth to an unconscious person. If large quantities of
this material are swallowed, call a physician immediately. Loosen tight clothing
such as a collar, tie, belt or waistband.
Skin contact : In case of contact, immediately flush skin copiously with water for at least 15
minutes while removing contaminated clothing and shoes. Cold water may be
used. Wash clothing before reuse. Clean shoes thoroughly before reuse.
Obtain medical attention immediately.
Eye Contact : Check for and remove any contact lenses. In case of contact, immediately
flush eyes with a copious amount of water for at least 15 minutes. Cold water
may be used. Obtain medical attention immediately.

5. Fire-fighting measures
Extinguishing Media
Suitable : Not applicable.
Unusual fire/explosion Hazards : Aqueous solutions are nonflammable. Contact with combustible material may
cause fire. Decomposes on heating. In a fire, the following can be released:
nitrogen oxides (NO, NO2...)
Hazardous thermal (de)composition : These products are nitrogen oxides (NO, NO2...).
products
Protection of fire-fighters : Fire fighters should wear self-contained positive pressure breathing apparatus
(SCBA) and full turnout gear.

6. Accidental release measures

Personal Precautions : Splash goggles. Full suit. Boots. Gloves. Suggested protective clothing
might not be sufficient; consult a specialist BEFORE handling this product.
Environmental precautions and : Stop leak if without risk. Absorb with dry earth, sand or other noncombustible
cleanup methods material. Use water spray curtain to divert vapour drift. Prevent entry into
sewers, basements or confined areas; dike if needed. Call for assistance on
disposal. Neutralize the residue with a dilute solution of sodium
carbonate.
Note: See section 8 for personal protective equipment and section 13 for waste disposal.

7. Handling and storage

Handling : Keep container dry. Do not breathe gas/fumes/vapour/spray. Wear suitable
protective clothing. If ingested, seek medical advice immediately and show
the container or the label. Keep away from incompatibles such as reducing
agents, combustible materials, organic materials, metals, alkalis, moisture.

May corrode metallic surfaces. Store in a metallic or coated fibreboard drum

using a strong polyethylene inner package.
Storage : Keep container tightly closed. Keep container in a cool, well-ventilated area.
Packaging materials
Recommended use : Use original container.

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8. Exposure controls/personal protection

Engineering measures : Provide exhaust ventilation or other engineering controls to keep the airborne
concentrations of vapours below their respective occupational exposure limits.
Hygiene measures : Wash hands after handling compounds and before eating, smoking, using
lavatory, and at the end of day.
Occupational Exposure Limits

Ingredient Name Occupational Exposure Limits

Nitric acid EH40-OES (United Kingdom (UK), 2000).
STEL: 10 mg/m3
STEL: 4 ppm
TWA: 5.2 mg/m3
TWA: 2 ppm

Respiratory system : Wear appropriate respirator when ventilation is inadequate.

Skin and body : Full suit.

Hands : Impervious gloves.
Eyes : Face shield.

9. Physical and chemical properties

Physical state : Liquid.
Colour : Colourless.
Odour : Pungent. Suffocating.
Boiling point : 122°C (252°F)
Melting point : -41°C (-42°F)
Density : 1.37 g/cm3 (20°C / 68°F)
Vapour density : 2.2 (Air = 1)
Vapour pressure : 6.53 to 7.33 kPa (49 to 55 mmHg) (at 20°C)
Evaporation Rate : <1 compared to Ether (anhydrous).

Solubility : Easily soluble in cold water.

pH : 1 [Acidic.]
Flash point : Not applicable.

10. Stability and reactivity

Stability : The product is stable.
Conditions to Avoid : Decomposes on heating. Sensitive to light.
Materials to avoid : Extremely reactive or incompatible with combustible materials, organic
materials, metals, alkalis.
Reactive with reducing agents.
Will react with water or steam to produce heat and toxic fumes. Mixing with
small amounts of water may cause violent splattering.
Hazardous decomposition products : These products are nitrogen oxides (NO, NO2...).

Remarks : Powerful oxidizing agent; may ignite oxidizable materials. Emits toxic fumes
when heated to decomposition. May develop pressure; vent periodical
Flammable hydrogen gas may be produced on prolonged contact with metals
such as aluminium, tin, lead and zinc.

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11. Toxicological information

Acute toxicity
Ingredient Name Test Result Route Species
Nitric acid LDLo 430 mg/kg Oral human

Chronic toxicity : Repeated or prolonged contact with spray mist may produce chronic eye
irritation and severe skin irritation. Repeated or prolonged exposure to spray
mist may produce respiratory tract irritation, leading to frequent attacks of
bronchial infection.
Skin irritation : Extremely hazardous in case of skin contact (corrosive).
Eye irritation : Extremely hazardous in case of eye contact (corrosive).
Carcinogenic effects : Not available.

Mutagenic Effects : Not available.

Reproduction toxicity : Not available.

12. Ecological information

Persistence/degradability : Not available.

13. Disposal considerations

Methods of disposal ; Waste of : Waste must be disposed of in accordance with federal, state and local
residues ; Contaminated packaging environmental control regulations.

European Waste Catalogue (EWC) : 06 01 05

Hazardous Waste : The classification of the product may meet the criteria for a hazardous waste.
Additional Information : 06 01 05 nitric acid and nitrous acid

14. Transport information

International transport regulations
Land - Road/Railway
UN number : 2031
Proper shipping name : NITRIC ACID
ADR/RID Class : 8
Packing group : II
ADR/RID label :

Other information : Hazard identification number

80
Sea
UN number : 2031
Proper shipping name : NITRIC ACID
IMDG Class : 8
Packing group : II

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IMDG label :

Other information : Emergency Schedules (EmS)

8-03

15. Regulatory information

EU Regulations
Hazard symbol(s) :

Corrosive
Risk Phrases : R35- Causes severe burns.
Safety Phrases : S23- Do not breathe fumes / vapour / spray.
S26- In case of contact with eyes, rinse immediately with plenty of water and
seek medical advice.
S36/37/39- Wear suitable protective clothing, gloves and eye/face protection.
S38- In case of insufficient ventilation, wear suitable respiratory equipment.
S45- In case of accident or if you feel unwell, seek medical advice
immediately (show the label where possible).
Contains : Nitric acid 231-714-2
Product Use : Classification and labelling have been performed according to EU directives
67/548/EEC, 88/379/EEC, including amendments and the intended use.
- Industrial applications, Used by Spraying.

16. Other information

Full text of R-Phrases with no. : R8- Contact with combustible material may cause fire.
appearing in Section 2 - United R35- Causes severe burns.
Kingdom (UK)
Text of classifications appearing in : O - Oxidizing
Section 2 - United Kingdom (UK) C - Corrosive
HISTORY
Date of printing : 10/17/2002.
Date of issue : 10/16/2002.
Version : 3
DREW® is a registered trademark of Ashland Inc. DREW™ CTC is a trademark of Ashland
Inc.
Notice to Reader
To the best of our knowledge, the information contained herein is accurate. However, neither the above named supplier nor
any of its subsidiaries assumes any liability whatsoever for the accuracy or completeness of the information contained
herein.
Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown
hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these
are the only hazards that exist.
Date of issue Version
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