Conforms to 91/155/EEC - 2001/58/EC - United Kingdom (UK)

SAFETY DATA SHEET

PRODUCT FORMULA No. 3
1. Identification of the substance/preparation and of the company/undertaking
Product name : PRODUCT FORMULA No. 3
Material Uses : Industrial applications: Cleaner for removal of vegetable or animal oil from
soiled surfaces.

Manufacturer / Supplier :
Drew Marine Drew Marine
Ashland Specialty Chemical Company Ashland Specialty Chemical Company
Malledijk 20 One Drew Plaza
3208 LA Spijkenisse Boonton, NJ 07005
Netherlands United States
Tel. No.: Tel. No.:
+31 181 457 070 +1 (973) 263 7600
Fax: Fax:
+31 181 625 792 +1 (973) 263 4491
Emergency telephone number
(Germany) : +49 621 60-43333
Fax:
(Germany) : +49 621 60-92664

2. Composition/information on ingredients
Substance/Preparation : Preparation

Chemical name* CAS No. % EC Number Classification

Ethoxylated isononyl phenol 37205-87-1 5-10 Xi; R36/38
R53
2-Butoxyethanol 111-76-2 1-5 203-905-0 Xn; R20/21/22
Xi; R36/38
Nitrilo-triacetic acid (Sodium salt) 5064-31-3 1-5 225-768-6 Xn; R22
See Section 16 for the full text of the R Phrases declared above

* Occupational Exposure Limit(s), if available, are listed in Section 8

3. Hazards identification
The preparation is not classified as dangerous according to Directive 1999/45/EC and its amendments.
Classification :
This product is not classified according to the EU regulations.
Effects and symptoms
Inhalation : Inhalation causes headaches, dizziness, drowsiness, and nausea, and may
lead to unconsciousness.
Ingestion : Irritating to mouth, throat and stomach.
Skin contact : Slightly hazardous in case of skin contact (irritant). Skin inflammation is
characterized by itching, scaling, reddening, or, occasionally, blistering.
Repeated or prolonged exposure to the substance can produce damage to
liver and kidneys.
Eye Contact : Slightly hazardous in case of eye contact (irritant).
Target Organs : Contains material which causes damage to the following organs: blood,
kidneys, liver, lymphatic system, upper respiratory tract, skin, central nervous
system (CNS), eye, lens or cornea.

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4. First-aid measures
First-Aid measures
Inhalation : If inhaled, remove to fresh air. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen. Obtain medical attention.
Ingestion : Do NOT induce vomiting unless directed to do so by medical personnel.
Never give anything by mouth to an unconscious person. If large quantities of
this material are swallowed, call a physician immediately. Loosen tight clothing
such as a collar, tie, belt or waistband.
Skin contact : Wash contaminated skin with soap and water. Cold water may be used.
Wash clothing before reuse. Clean shoes thoroughly before reuse. Obtain
medical attention immediately.
Eye Contact : Check for and remove any contact lenses. In case of contact, immediately
flush eyes with a copious amount of water for at least 15 minutes. Cold water
may be used. Get medical attention if irritation occurs.

5. Fire-fighting measures
Extinguishing Media
Suitable : Not applicable.
Hazardous thermal (de)composition : These products are carbon oxides (CO, CO2) and water, nitrogen oxides (NO,
products NO2...). Some metallic oxides.
Protection of fire-fighters : Fire fighters should wear self-contained positive pressure breathing apparatus
(SCBA) and full turnout gear.

6. Accidental release measures

Personal Precautions : Splash goggles. Full suit. Boots. Gloves. Suggested protective clothing
might not be sufficient; consult a specialist BEFORE handling this product.
Environmental precautions and : Stop leak if without risk. Use water spray to reduce vapours. Prevent entry
cleanup methods into sewers, basements or confined areas; dike if needed. Neutralize the
residue with a dilute solution of sodium carbonate.Finish cleaning by
spreading water on the contaminated surface and allow to evacuate through
the sanitary system.
Note: See section 8 for personal protective equipment and section 13 for waste disposal.

7. Handling and storage

Handling : Do not breathe gas/fumes/vapour/spray. Avoid contact with skin and eyes.
Wear suitable protective clothing. If ingested, seek medical advice
immediately and show the container or the label. Keep away from
incompatibles such as oxidizing agents, acids.
Storage : Keep container tightly closed. Keep container in a cool, well-ventilated area.
Packaging materials
Recommended use : Use original container.

8. Exposure controls/personal protection

Engineering measures : Provide exhaust ventilation or other engineering controls to keep the airborne
concentrations of vapours below their respective occupational exposure limits.
Hygiene measures : Wash hands, forearms, and face thoroughly after handling compounds and
before eating, smoking, using lavatory, and at the end of day.
Occupational Exposure Limits

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Ingredient Name Occupational Exposure Limits

2-Butoxyethanol EH40-OES (United Kingdom (UK), 2001). skin Notes:
OES
TWA: 123 mg/m3
TWA: 25 ppm

Respiratory system : Wear appropriate respirator when ventilation is inadequate. Vapour

respirator. (as filter A)

Skin and body : Overalls buttoned to the neck and wrist. Lab coat.
Hands : Impervious gloves.
Eyes : Safety glasses.

9. Physical and chemical properties

Physical state : Liquid.
Colour : Colourless.
Odour : Characteristic.
Boiling point : 100°C (212°F)
Melting point : -3°C (27°F)
Density : 1.03 g/cm3 (20°C / 68°F)
Vapour density : The highest known value is 4.07 (Air = 1) (2-Butoxyethanol).
Vapour pressure : The highest known value is 2.33 kPa (17.5 mmHg) (at 20°C) (Water).
Evaporation Rate : <1 compared to Ether (anhydrous).

Solubility : Easily soluble in cold water.

pH : Acidic.
Flash point : Not applicable.

10. Stability and reactivity

Stability : The product is stable.
Materials to avoid : Reactive with oxidizing agents, acids.
Hazardous decomposition products : These products are carbon oxides (CO, CO2) and water, nitrogen oxides (NO,
NO2...). Some metallic oxides.

11. Toxicological information

Acute toxicity
Ingredient Name Test Result Route Species
Ethoxylated isononyl phenol LD50 5600 mg/kg Oral Rat
LD50 5800 mg/kg Oral Rat
LD50 4700 mg/kg Oral Mouse
2-Butoxyethanol LD50 470 mg/kg Oral Rat
LD50 300 mg/kg Oral Rabbit
LD50 1200 mg/kg Oral Guinea pig
LD50 220 mg/kg Dermal Rabbit
Nitrilo-triacetic acid (Sodium salt) LD50 1100 mg/kg Oral Rat
LD50 681 mg/kg Oral Mouse
LD50 750 mg/kg Oral Monkey

Chronic toxicity : Repeated exposure to an highly toxic material may produce general
deterioration of health by an accumulation in one or many human organs.
Skin irritation : Slightly hazardous in case of skin contact (irritant).

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Eye irritation : Slightly hazardous in case of eye contact (irritant).

Carcinogenic effects : Not available.

Mutagenic Effects : Not available.

Reproduction toxicity : Not available.
Additional Information :

12. Ecological information

Ecotoxicity Data
Ingredient Name Species Period Result
Ethoxylated isononyl phenol Fish (LC50) 96 hours 7.2 mg/l
Daphnia (EC50) 48 hours 15 mg/l
Algae (IC50) 72 hours 30 mg/l
Persistence/degradability : Not available.

13. Disposal considerations

Methods of disposal ; Waste of : Waste must be disposed of in accordance with federal, state and local
residues ; Contaminated packaging environmental control regulations.

European Waste Catalogue (EWC) : 16 05 03

Hazardous Waste : To present knowledge of the supplier, this product is not regarded as
hazardous waste as defined by EU Directive 91/689/EC.
Additional Information : 16 05 03 other waste containing organic chemicals, e.g. lab chemicals not
otherwise specified

14. Transport information

International transport regulations
Land - Road/Railway
UN number : Not regulated.
Proper shipping name : -
ADR/RID Class : -
Other information : Remarks
Not controlled under ADR (Europe).
Sea
UN number : Not regulated.
Proper shipping name : -
IMDG Class : -
Other information : Remarks
Not controlled under IMDG.

15. Regulatory information

EU Regulations
Risk Phrases : This product is not classified according to the EU regulations.
Product Use : Classification and labelling have been performed according to EU directives
67/548/EEC, 88/379/EEC, including amendments and the intended use.
- Industrial applications.

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16. Other information

Full text of R-Phrases with no. : R20/21/22- Harmful by inhalation, in contact with skin and if swallowed.
appearing in Section 2 - United R22- Harmful if swallowed.
Kingdom (UK) R36/38- Irritating to eyes and skin.
R53- May cause long-term adverse effects in the aquatic environment.
Text of classifications appearing in : Xn - Harmful
Section 2 - United Kingdom (UK) Xi - Irritant
HISTORY
Date of printing : 10/17/2002.
Date of issue : 10/16/2002.
Version : 3
PRODUCT FORMULA No. 3 is a trademark of Ashland Inc.
Notice to Reader
To the best of our knowledge, the information contained herein is accurate. However, neither the above named supplier nor
any of its subsidiaries assumes any liability whatsoever for the accuracy or completeness of the information contained
herein.
Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown
hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these
are the only hazards that exist.
Date of issue Version
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