SAFETY DATA SHEET

COOLTECH CT3050
Page: 1
Compilation date: 27/08/2014
Revision date: 01/01/2022
Revision No: 2.1

Section 1: Identification of the substance/mixture and of the company/undertaking

1.1. Product identifier

Product name: COOLTECH CT3050

Product code: C3050

1.2. Relevant identified uses of the substance or mixture and uses advised against

Use of substance / mixture: PC37: Water treatment chemicals.

1.3. Details of the supplier of the safety data sheet

Company name: CoolTech Water Treatment LLC

P.O. Box 29478

Abu Dhabi
United Arab Emirates
Tel: +971 2 550 1182
Fax: +971 2 550 4878
Email: [email protected]

1.4. Emergency telephone number

Emergency tel: +971 2 550 1182

(office hours only)

Section 2: Hazards identification

2.1. Classification of the substance or mixture

Classification under CLP: Aquatic Chronic 2: H411; Skin Corr. 1B: H314; Skin Sens. 1: H317
Most important adverse effects: Causes severe skin burns and eye damage. May cause an allergic skin reaction.

Toxic to aquatic life with long lasting effects.

2.2. Label elements

Label elements:
Hazard statements: H314: Causes severe skin burns and eye damage.

H317: May cause an allergic skin reaction.

H411: Toxic to aquatic life with long lasting effects.
Hazard pictograms: GHS05: Corrosion

GHS07: Exclamation mark

GHS09: Environmental

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Signal words: Danger
Precautionary statements: P260: Do not breathe mist/spray.

P280: Wear protective gloves/protective clothing/eye protection/face protection.

P301+P330+P331: IF SWALLOWED: Rinse mouth. Do NOT induce vomiting
P302+P352: IF ON SKIN: Wash with plenty of water.
P303+P361+P353: IF ON SKIN (or hair): Take off immediately all contaminated
clothing. Rinse skin with water .
P304+P340: IF INHALED: Remove person to fresh air and keep comfortable for
breathing.
P264: Wash exposed skin thoroughly after handling.
P272: Contaminated work clothing should not be allowed out of the workplace.
P273: Avoid release to the environment.
P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do. Continue rinsing.
P310: Immediately call POISON CENTER/doctor.
P321: Specific treatment (see instructions on this label)
P333+P313: If skin irritation or rash occurs: Get medical advice/attention.
P363: Wash contaminated clothing before reuse.
P391: Collect spillage.
P405: Store locked up.
P410: Protect from sunlight.
P411: Store at temperatures not exceeding 40.
P501: Dispose of contents to hazardous or special waste collection point.

2.3. Other hazards

PBT: This product is not identified as a PBT/vPvB substance.

Section 3: Composition/information on ingredients

3.2. Mixtures

ORTHOPHOSPHORIC ACID

231-633-2 7664-38-2 - Skin Corr. 1B: H314 2.5-5%

ZINC CHLORIDE

231-592-0 7646-85-7 - Acute Tox. 4: H302; Skin Corr. 1B: H314; 2.5-5%
Aquatic Chronic 1: H410; Aquatic Acute
1: H400

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2-PHOSPHONOBUTANE-1,2,4-TRICARBOXYLIC ACID - REACH registered number(s): 01-21-19436643-39-0003

253-733-5 37971-36-1 - Acute Tox. 4: H312; Eye Irrit. 2: H319 1.0-2.5%

BENZOTRIAZOLE - REACH registered number(s): 17-21-19898858-06-0000

202-394-1 95-14-7 - Aquatic Acute 1: H400; Aquatic Chronic 0.5-1.0%

1: H410; Skin Irrit. 2: H315; Skin Sens. 1:
H317

Section 4: First aid measures

4.1. Description of first aid measures

Skin contact: Remove all contaminated clothes and footwear immediately unless stuck to

skin. Drench the affected skin with running water for 10 minutes or longer if
substance is still on skin. Transfer to hospital if there are burns or symptoms of
poisoning.
Eye contact: Bathe the eye with running water for 15 minutes. Transfer to hospital for

specialist examination.
Ingestion: Wash out mouth with water. Do not induce vomiting. Give 1 cup of water to drink

every 10 minutes. If unconscious, check for breathing and apply artificial

respiration if necessary. If unconscious and breathing is OK, place in the recovery
position. Transfer to hospital as soon as possible.
Inhalation: Remove casualty from exposure ensuring one's own safety whilst doing so. If

unconscious and breathing is OK, place in the recovery position. If conscious,

ensure the casualty sits or lies down. If breathing becomes bubbly, have the
casualty sit and provide oxygen if available. Transfer to hospital as soon as
possible.

4.2. Most important symptoms and effects, both acute and delayed

Skin contact: Blistering may occur. Progressive ulceration will occur if treatment is not

immediate.
Eye contact: Corneal burns may occur. May cause permanent damage.
Ingestion: Corrosive burns may appear around the lips. Blood may be vomited. There may be

bleeding from the mouth or nose.

Inhalation: There may be shortness of breath with a burning sensation in the throat.

Exposure may cause coughing or wheezing.

Delayed / immediate effects: Immediate effects can be expected after short-term exposure.

4.3. Indication of any immediate medical attention and special treatment needed

Immediate / special treatment: Eye bathing equipment should be available on the premises.

Section 5: Fire-fighting measures

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5.1. Extinguishing media

Extinguishing media: Suitable extinguishing media for the surrounding fire should be used. Use water

spray to cool containers.

5.2. Special hazards arising from the substance or mixture

Exposure hazards: Corrosive. In combustion emits toxic fumes.

5.3. Advice for fire-fighters

Advice for fire-fighters: Wear self-contained breathing apparatus. Wear protective clothing to prevent

contact with skin and eyes.

Section 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures

Personal precautions: Notify the police and fire brigade immediately. If outside keep bystanders

upwind and away from danger point. Mark out the contaminated area with signs
and prevent access to unauthorised personnel. Do not attempt to take action
without suitable protective clothing - see section 8 of SDS. Turn leaking
containers leak-side up to prevent the escape of liquid. Refer to section 8 of SDS
for personal protection details.

6.2. Environmental precautions

Environmental precautions: Do not discharge into drains or rivers. Contain the spillage using bunding.

6.3. Methods and material for containment and cleaning up

Clean-up procedures: Clean-up should be dealt with only by qualified personnel familiar with the

specific substance. Absorb into dry earth or sand. Transfer to a closable, labelled
salvage container for disposal by an appropriate method.

6.4. Reference to other sections

Reference to other sections: Refer to section 8 of SDS.

Section 7: Handling and storage

7.1. Precautions for safe handling

Handling requirements: Avoid direct contact with the substance. Ensure there is sufficient ventilation of

the area. Do not handle in a confined space. Avoid the formation or spread of
mists in the air.

7.2. Conditions for safe storage, including any incompatibilities

Storage conditions: Store in a cool, well ventilated area. Keep container tightly closed. The floor of

the storage room must be impermeable to prevent the escape of liquids.

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7.3. Specific end use(s)

Specific end use(s): No data available.

Section 8: Exposure controls/personal protection

8.1. Control parameters

Hazardous ingredients:

ORTHOPHOSPHORIC ACID...100%

Workplace exposure limits: Respirable dust

State 8 hour TWA 15 min. STEL 8 hour TWA 15 min. STEL

UK 1 mg/m3 2 mg/m3 - -

ZINC CHLORIDE

UK 1 mg/m3 2 mg/m3 - -

DNEL/PNEC Values

DNEL / PNEC No data available.

8.2. Exposure controls

Engineering measures: Ensure there is sufficient ventilation of the area. The floor of the storage room

must be impermeable to prevent the escape of liquids.

Respiratory protection: Self-contained breathing apparatus must be available in case of emergency.
Hand protection: Impermeable gloves.
Eye protection: Tightly fitting safety goggles. Ensure eye bath is to hand.
Skin protection: Impermeable protective clothing.

Section 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties

State: Liquid
Colour: Colourless to pale yellow
Odour: Characteristic odour

Evaporation rate: Slow

Oxidising: Non-oxidising (by EC criteria)
Solubility in water: Soluble
Viscosity: Non-viscous
Boiling point/range°C: >35 Melting point/range°C: No data available.
Flammability limits %: lower: Not applicable. upper: Not applicable.
Flash point°C: >93 Part.coeff. n-octanol/water: No data available.
Autoflammability°C: Not applicable. Vapour pressure: No data available.
Relative density: 1.106 pH: <2
VOC g/l: Nil
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9.2. Other information

Other information: No data available.

Section 10: Stability and reactivity

10.1. Reactivity

Reactivity: Stable under recommended transport or storage conditions.

10.2. Chemical stability

Chemical stability: Stable under normal conditions.

10.3. Possibility of hazardous reactions

Hazardous reactions: Hazardous reactions will not occur under normal transport or storage conditions.

Decomposition may occur on exposure to conditions or materials listed below.

10.4. Conditions to avoid

Conditions to avoid: Heat.

10.5. Incompatible materials

Materials to avoid: Strong oxidising agents. Strong acids.

10.6. Hazardous decomposition products

Haz. decomp. products: In combustion emits toxic fumes.

Section 11: Toxicological information

11.1. Information on toxicological effects

Hazardous ingredients:

ORTHOPHOSPHORIC ACID...100%

ORL RAT LD50 1530 mg/kg

ZINC CHLORIDE

IVN RAT LD50 3690 µg/kg

ORL MUS LD50 329 mg/kg
ORL RAT LD50 350 mg/kg

2-PHOSPHONOBUTANE-1,2,4-TRICARBOXYLIC ACID

ORAL RAT LD50 5000 mg/kg

Relevant hazards for product:

Hazard Route Basis

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Skin corrosion/irritation DRM Hazardous: calculated

Serious eye damage/irritation OPT Hazardous: calculated
Respiratory/skin sensitisation DRM Hazardous: calculated

Symptoms / routes of exposure

Skin contact: Blistering may occur. Progressive ulceration will occur if treatment is not

immediate.
Eye contact: Corneal burns may occur. May cause permanent damage.
Ingestion: Corrosive burns may appear around the lips. Blood may be vomited. There may be

bleeding from the mouth or nose.

Inhalation: There may be shortness of breath with a burning sensation in the throat.

Exposure may cause coughing or wheezing.

Delayed / immediate effects: Immediate effects can be expected after short-term exposure.

Section 12: Ecological information

12.1. Toxicity

Hazardous ingredients:

2-PHOSPHONOBUTANE-1,2,4-TRICARBOXYLIC ACID

ALGAE 72H EC50 72 mg/l

DAPHNIA 48H EC50 265 mg/l
FISH LC50 3440 mg/l

12.2. Persistence and degradability

Persistence and degradability: Biodegradable.

12.3. Bioaccumulative potential

Bioaccumulative potential: No bioaccumulation potential.

12.4. Mobility in soil

Mobility: Readily absorbed into soil.

12.5. Results of PBT and vPvB assessment

PBT identification: This product is not identified as a PBT/vPvB substance.

12.6. Other adverse effects

Other adverse effects: Negligible ecotoxicity.

Section 13: Disposal considerations

13.1. Waste treatment methods

Disposal operations: Transfer to a suitable container and arrange for collection by specialised

disposal company.

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NB: The user's attention is drawn to the possible existence of regional or national

regulations regarding disposal.

Section 14: Transport information

14.1. UN number

UN number: UN1760

14.2. UN proper shipping name

Shipping name: CORROSIVE LIQUID, N.O.S.

14.3. Transport hazard class(es)

Transport class: 8

14.4. Packing group

Packing group: III

14.5. Environmental hazards

Environmentally hazardous: Yes Marine pollutant: No

14.6. Special precautions for user

Special precautions: No special precautions.

Tunnel code: E
Transport category: 3

Section 15: Regulatory information

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture

Specific regulations: Regulation EC 1907/06, SVHC content none, Substances subject to authorisations:

none; Substances subject to restriction on use: none.

15.2. Chemical Safety Assessment

Chemical safety assessment: A chemical safety assessment has not been carried out for the substance or the

mixture by the supplier.

Section 16: Other information

Other information

Other information: Hazard Category: D - Acidic. Do not store with Category B (Alkaline), C (Highly

Alkaline) or O (Oxidising) products or materials.

This safety data sheet is prepared in accordance with Commission Regulation
(EU) No 2015/830.
* indicates text in the SDS which has changed since the last revision.
Phrases used in s.2 and s.3: H302: Harmful if swallowed.

H312: Harmful in contact with skin.

H314: Causes severe skin burns and eye damage.

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H315: Causes skin irritation.

H317: May cause an allergic skin reaction.
H319: Causes serious eye irritation.
H400: Very toxic to aquatic life.
H410: Very toxic to aquatic life with long lasting effects.
H411: Toxic to aquatic life with long lasting effects.
Legal disclaimer: The above information is believed to be correct but does not purport to be all

inclusive and shall be used only as a guide. This company shall not be held
liable for any damage resulting from handling or from contact with the above
product.

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