Exercise 2 Nuclear Reaction - Lucas Damien F. Mancera

Download as pdf or txt
Download as pdf or txt
You are on page 1of 6

Exercise 2: Nuclear Reactions, Binding Energy and Rate of Decay

Name: Lucas Damien F. Mancera Group No: ???

Course/Section: B11 Instructor: Cathedrine Aurin

Exercise 2
NUCLEAR REACTIONS, BINDING ENERGY AND RATE OF DECAY

OBJECTIVES

Upon completion of the experiment, the student should be able to:


1. Identify the missing species to balance nuclear reactions;
2. Determine the binding energy of a nuclear species;
3. Determine the amount of energy released in a nuclear fission;
4. Calculate the amount of species left after a specified time of nuclear reaction; and
5. Determine the half-life of a nuclear species.

Direction: Answer the following questions. Show complete solution, whenever applicable.
A. Nuclear Reactions
Balance the following nuclear reactions by filling out the missing species or predicting the
products.

1. 1
1𝐻 + 31𝐻 → 𝟒𝟐𝑯𝒆
2. 239
94𝑃𝑢 → 42𝐻𝑒 + 𝟐𝟑𝟓
𝟗𝟐𝑼
239 𝟐𝟒𝟐
3. 92𝑈 + 42𝐻𝑒 → 𝟗𝟒𝑷𝒖 + 10𝑛
𝟐𝟏𝟐
4. 𝟖𝟑𝑩𝒊 → 42𝐻𝑒 + 208
81𝑇𝑙
37 𝟑𝟕
5. 19𝐾 → 𝟏𝟖𝑨𝒓 + +10𝑒
6. 226
88𝑅𝑎 → 42𝐻𝑒 + 𝟐𝟐𝟒
𝟖𝟔𝑹𝒏

7. 9
4𝐵𝑒 + 11𝐻 → 𝟔𝟑𝑳𝒊 + 42𝐻𝑒
254
8. 𝐸𝑠 + 4𝐻𝑒 → 𝟐𝟖𝟔
𝟏𝟎𝟏𝑴𝒅 + 2 𝟎1𝑛
𝑒𝑙𝑒𝑐𝑡𝑟𝑜𝑛 𝑐𝑎𝑝𝑡𝑢𝑟𝑒
222 𝟐𝟐𝟐
9. 𝟖𝟔𝑅𝑛 → 𝟖𝟓𝑨𝒕 + 𝒙 − 𝒓𝒂𝒚
𝑎𝑙𝑝ℎ𝑎 𝑒𝑚𝑖𝑠𝑠𝑖𝑜𝑛
10. 222
𝟖𝟔𝑅𝑛 →
𝟐𝟏𝟖
𝟖𝟒𝑷𝒐 + 𝟒𝟐𝑯𝒆

CHM031L. Chemistry for Engineers Laboratory Page E2-1


No part of this laboratory manual may be reproduced without the written permission of the College of Arts and
Science, Malayan Colleges Laguna.
Exercise 2: Nuclear Reactions, Binding Energy and Rate of Decay

B. Binding energy

1. Determine the binding energy per nucleon (ΔE/A) for Osmium-190.

mass of 190Os = 189.95863 amu


mass of neutron = 1.008664 amu
mass of proton = 1.007276 amu

Protons of Os (Osmium) = 76
Neutrons of Os (Osmium) = 114

Protons = (76)(1.007276 amu) = 76.552976 amu


Neutrons = (114)(1.008664) = 114.987696 amu

Mass of free Nucleons = 191.540672 amu

𝑚𝑎𝑠𝑠 𝑜𝑓 𝑂𝑠𝑚𝑖𝑢𝑚 − 190 = 189.95863 𝑎𝑚𝑢


𝑇𝑜𝑡𝑎𝑙 𝑚𝑎𝑠𝑠 𝑜𝑓 𝑓𝑟𝑒𝑒 𝑛𝑢𝑐𝑙𝑒𝑜𝑛𝑠 = 191.540672 𝑎𝑚𝑢

∆𝑚 = 𝑚𝑎𝑠𝑠 𝑜𝑓 𝑛𝑢𝑐𝑙𝑖𝑑𝑒 − 𝑡𝑜𝑡𝑎𝑙 𝑚𝑎𝑠𝑠 𝑜𝑓 𝑓𝑟𝑒𝑒 𝑛𝑢𝑐𝑙𝑒𝑜𝑛𝑠

∆𝑚 = 189.95863 − 191.540672
∆𝒎 = −𝟏. 𝟓𝟖𝟐𝟎𝟒𝟐 𝒂𝒎𝒖

𝐸 = ∆𝑚𝑐 2
3.5𝑥108 𝑚
Speed of light =
𝑠
Kilogram converter = 6.0221418𝑥1026 𝑎𝑚𝑢
2
1 𝑘𝑔 3.0𝑥108 𝑚 1𝐽
𝐸 = (−1.5820424) ( ) ( ) ( )
6.0221418𝑥1026 𝑠 𝑚2
1 𝑘𝑔 2
𝑠
𝑬 = −𝟐. 𝟑𝟔𝟒𝟑𝟑𝟕𝟖𝟖𝒙𝟏𝟎−𝟏𝟎 𝑱

6.022𝑥1023
𝐸( )
1
6.022𝑥1023
(−2.364337884𝑥10−10 ) ( )
1
= −1.42380427𝑥1014 𝐽

Total Nucleon = 190


CHM031L. Chemistry for Engineers Laboratory Page E2-2
No part of this laboratory manual may be reproduced without the written permission of the College of Arts and
Science, Malayan Colleges Laguna.
Exercise 2: Nuclear Reactions, Binding Energy and Rate of Decay

𝑐𝑎𝑙𝑐𝑢𝑙𝑎𝑡𝑒𝑑 𝑒𝑛𝑒𝑟𝑔𝑦 𝐽
( )
𝑡𝑜𝑡𝑎𝑙 𝑛𝑢𝑚𝑏𝑒𝑟 𝑜𝑓 𝑛𝑢𝑐𝑙𝑒𝑜𝑛𝑠
−2.364337884𝑥10−10 𝐽
( )
190 𝑛𝑢𝑐𝑙𝑒𝑜𝑛𝑠
𝑱
𝑭𝒊𝒏𝒂𝒍 𝑨𝒏𝒔𝒘𝒆𝒓 = −𝟏. 𝟐𝟒𝟒𝟑𝟖𝟖𝟑𝟔𝒙𝟏𝟎−𝟏𝟐
𝒏𝒖𝒄𝒍𝒆𝒐𝒏

2. Calculate the amount of energy released (in kJ) 235U undergoes fission to form Te-137 and
Zr-96 (Given: m(235U) = 235.043915 amu; m(1n) = 1.008664 amu; m(137Te) = 136.925449
amu; m(96Zr) = 95.908286 amu)
Note: Fission occurred because of the collision of 235U with a neutron.

∆m = mass of the products-mass of the reactant


∆𝑚 = [136.925449 𝑎𝑚𝑢 + 95.908286 𝑎𝑚𝑢 + 3(1.008664 𝑎𝑚𝑢 )]
− (235.043915 𝑎𝑚𝑢 + 1.008664 𝑎𝑚𝑢)
∆𝑚 = −𝟎. 𝟏𝟗𝟐𝟖𝟓𝟐 𝒂𝒎𝒖
𝐸 = 𝑚𝑐 2
1𝑘𝑔
𝐸 = −0.192852 𝑎𝑚𝑢 ( × 1026 𝑎𝑚𝑢)
6.0221418
𝐸 = −3.202382249 × 1028 𝑘𝑔
1𝐽
𝐸 = −3.202382249 × 1028 𝑘𝑔(3.0 × 108 𝑚⁄𝑠)2 ( 2 )
1𝑘𝑔 𝑚 ⁄ 2
𝑠
= −𝟐. 𝟖𝟖𝟐𝟏𝟒𝟒𝟎𝟐𝟒 × 𝟏𝟎−𝟏𝟏 𝑱
1𝑘𝐽
𝐸 = −2.882144024 × 10−11 𝐽 ( )
1000𝐽
= −𝟐. 𝟖𝟖𝟐𝟏𝟒𝟒𝟎𝟐𝟒 × 𝟏𝟎−𝟏𝟒 𝒌𝑱

CHM031L. Chemistry for Engineers Laboratory Page E2-3


No part of this laboratory manual may be reproduced without the written permission of the College of Arts and
Science, Malayan Colleges Laguna.
Exercise 2: Nuclear Reactions, Binding Energy and Rate of Decay

3. How much energy is released in the decay of 23892U into 23490Th and an alpha particle?
Mass of 23892U = 238.0508 amu
Mass of 23490Th = 234.0426 amu
Mass of 42α = 4.0026 amu

∆m = mass of the product – mass of the reactant


∆𝑚 = 238.0508 𝑎𝑚𝑢 − (234.0426 𝑎𝑚𝑢 + 4.0026 𝑎𝑚𝑢)
∆𝑚 = 5.6 × 10−3 𝑎𝑚𝑢
𝐸 = 𝑚𝑐 2
𝐸 = (5.6 × 10−3 𝑎𝑚𝑢)(931)
𝑬 = 𝟓. 𝟐𝟏𝟑𝟔 𝑴𝒆𝒗

C. Rate of Decay

1. Cobalt-60, with a half-life of 5 years, is used in cancer radiation treatments. If a hospital


purchases a supply of 30.0 g, how much would be left after 15 years?

𝑡1 𝑙𝑛2 𝑙𝑛2
2= 𝐾 →𝐾= 1
𝑡2

𝑲 = 𝟎. 𝟏𝟑𝟖𝟔𝟐𝟗𝟒𝟑𝟔𝟏/𝒚𝒓
𝑁𝑡
ln ( ) = −𝐾𝑡
𝑁0
𝑁𝑡 0.18362943861
ln ( ) = −( )(15 𝑦𝑟𝑠)
30.0𝑔 𝑦𝑟𝑠

𝑵𝒕 = 𝟑. 𝟕𝟓𝒈

CHM031L. Chemistry for Engineers Laboratory Page E2-4


No part of this laboratory manual may be reproduced without the written permission of the College of Arts and
Science, Malayan Colleges Laguna.
Exercise 2: Nuclear Reactions, Binding Energy and Rate of Decay

2. The half-life of plutonium-239 is 24,110 years. If an original sample is 100. grams, how
much plutonium-239 remains after 96,440 years?

𝑡1 𝑙𝑛2 𝑙𝑛2
= →𝐾=
2 𝐾 𝑡1
2

𝑙𝑛2
=
24110 𝑦𝑒𝑎𝑟𝑠

𝟐. 𝟖𝟕𝟒𝟗𝟑𝟔𝟒𝟔𝒙𝟏𝟎−𝟓
𝐾=
𝒚𝒓
𝑁𝑡
ln ( ) = 𝑘𝑡
𝑁0
𝑁𝑡
ln ( )
100 𝑔

2.87493646𝑥10−5
= −( )(96440 𝑦𝑟𝑠)
𝑦𝑟

𝑁𝑡 = 𝟔. 𝟐𝟓 𝒈

3. Iodine-131 is used in the treatment of thyroid disease. What is the half-life of iodine-131
if a 160-mg sample became 5 mg after 40 days?

𝑁𝑡
ln ( ) = −𝑘𝑡
𝑁𝑜
5𝑚𝑔
ln ( ) = −𝑘(40 𝑑𝑎𝑦𝑠)
160𝑚𝑔

5𝑚𝑔
ln(160𝑚𝑔)
𝑘=
−(40 𝑑𝑎𝑦𝑠)

𝑲 = 𝟎. 𝟎𝟖𝟔𝟔𝟒𝟑𝟑𝟗𝟕𝟓𝟕 𝒅𝒂𝒚−𝟏
𝑙𝑛2
𝑡1 =
2 𝑘

𝑙𝑛2
𝑡1 =
2 0.866433975 𝑑𝑎𝑦 −1

𝑡1 = 𝟖. 𝟎𝟎 𝒅𝒂𝒚𝒔
2
CHM031L. Chemistry for Engineers Laboratory Page E2-5
No part of this laboratory manual may be reproduced without the written permission of the College of Arts and
Science, Malayan Colleges Laguna.
Exercise 2: Nuclear Reactions, Binding Energy and Rate of Decay

4. Carbon-14 has a half-life of 5715 years. It is used to determine the age of ancient objects.
If a sample today contains 0.060 mg of carbon-14, how much carbon-14 just have been
present in the sample 11,430 years ago?

𝑡1 𝑙𝑛2 𝑙𝑛2
= →𝐾=
2 𝐾 𝑡1
2
𝑙𝑛2
=
5715 𝑦𝑒𝑎𝑟𝑠

𝟏. 𝟐𝟏𝟐𝟖𝟓𝟓𝟗𝟓𝟗𝒙𝟏𝟎−𝟒
𝐾=
𝒚𝒆𝒂𝒓
𝑁𝑡
ln ( ) = 𝑘𝑡
𝑁0
0.060 𝑚𝑔
ln ( )
𝑁0
1.21285595𝑥10−4
= −( )(11430 𝑦𝑒𝑎𝑟𝑠)
𝑦𝑒𝑎𝑟
𝑁𝑡 = 𝟎. 𝟐𝟒 𝒎𝒈

CHM031L. Chemistry for Engineers Laboratory Page E2-6


No part of this laboratory manual may be reproduced without the written permission of the College of Arts and
Science, Malayan Colleges Laguna.

You might also like