Chemistry Poll 17

Answer keys : NCERT Booster Programme for NEET-2022_Chemistry_Poll-17
You scored 0 of 4
Question : 1 skipped
If enthalpy change for reaction, N2(g) + 3H2(g) → 2NH3(g) is – 91.8 kJ mol–1 then enthalpy change for 2N2(g) + 6H2 → 4NH3(g) will be
Options:
– 91.8 kJ mol–1
+ 91.8 kJ mol–1
– 183.6 kJ mol–1
183.6 kJ mol–1
Solution :
Answer (3)
(Reference NCERT Page No. -175)
/
You scored 0 of 4
If ΔHf(CO2) = – x1 kJ mol–1 and ΔHf(CO(g)) = – x2 kJ mol–1 then ΔH (in kJ mol–1) for reaction, CO(g)+ will be
Options:
– (x1 + x2)
(x1 – x2)
(x2 – x1)
(x1 + x2)
Solution :
Answer (3)
/
You scored 0 of 4
Enthalpy of atomization for H2(g) is equal to
Options:
BE(H–H)
2 × BE (H–H)
ΔHVap (H2) + BE(H–H)
Solution :
Answer (1)
You scored 0 of 4
If Bond energies of successive breakage of C–H bonds respectively are 427, 439, 452 and 347 kJ/mol then mean bond enthalpy of C–H bond will be
Options:
452 kJ mol–1
1665 kJ mol–1
347 kJ mol–1
416.25 kJ mol–1
Solution :
Answer (4)
/
You scored 0 of 4
Select the correct order of mean multiple bond enthalpies (in kJ mol–1) at 298 K
Options:
N=N>C=C>O=O
N=N>O=O>C=C
C=C>O=O>N=N
C=C>N=N>O=O
Solution :
Answer (3)
/
You scored 0 of 4
During the calculation of Lattice enthalpy of NaCl by using Born-Haber cycle, which type of energy exchange is not involved?
(a) Bond enthalpy of Cl2
(b) Enthalpy of atomisation of sodium atom
(c) Enthalpy of vapourization of Cl2
(d) Enthalpy of formation of NaCl
(e) Ionization enthalpy of Cl2
Options:
a and b only
b and c only
b, c and e only
c and e only
Solution :
Answer (4)
/
You scored 0 of 4
In which of the following entropy increases?
Options:
A liquid crystallizes into a solid
Temperature of gas decreases from 500K to 400 K
Polymerisation of ethylene molecules
2NaHCO3(s)→ Na2CO3(s) + CO2(g) + H2O(g)
Solution :
Answer (4)
You scored 0 of 4
Third law of thermodynamics is related with
Options:
Mass conservation in nuclear reactions
Internal energy conservation
Entropy change of a process during freezing
Entropy of any pure crystalline substance at absolute zero temperature
Solution :
Answer (4)
/
You scored 0 of 4
Select the correct statement(s)
(a) TΔSsys is the energy which is not available to do useful work
(b) ΔG term measures the net energy available to do useful work
(c) If TΔSsys – ΔHsys > 0 then process will be spontaneous
Options:
a and b only
a and c only
a only
a, b and c
Solution :
Answer (4)
/
You scored 0 of 4
Select the incorrect thermodynamic relations among the following
Options:
ΔG = ΔG° + RTlnQ
ΔG° = – RTlnKp
ΔG = RTln
ΔH° –TΔS° = – RTlnKC
Solution :
Answer (3)
/
You scored 0 of 4
The value of equilibrium constant for the given reaction at 300K will be
2NH3(g) + CO2(g) NH2CONH2(aq) + H2O(l)
(ΔG° of above reaction at given temperature is – 11.5 kJ mol–1)
Options:
0.01
100
0.04
0.4
Solution :
Answer (2)
/
You scored 0 of 4
For which given values of ΔS (in J mol–1K–1) and ΔH (in kJ mol–1) respectively, a process will always be spontaneous at all temperature?
Options:
– 400, – 20
– 800, 40
800, 32
400, – 20
Solution :
Answer (4)
You scored 0 of 4
For the reaction, 3A(g) + B(g) → 4D(g)
ΔU° = – 10.5 kJ and ΔS° = – 44.1 JK– 1, value of ΔG° (in kJ mol–1) at 298 K will be
Options:
2.64
– 12.64
– 7.89
– 23.64
Solution :
Answer (1)
/
You scored 0 of 4
Enthalpy change for the process CCl4(g) → C(g) + 4Cl(g), will be
(If ΔvapH°[CCl4] = 30 kJ mol–1, ΔfH° [CCl4(l)] = – 135 kJ mol–1, ΔaH[C] = 700 kJ mol–1 and ΔaH° [Cl2] = 240 kJ mol–1)
Options:
326 kJ mol–1
1285 kJ mol–1
1304 kJ mol–1
320 kJ mol–1
Solution :
Answer (2)
/
You scored 0 of 4
How many number of statement(s) among the following is/are correct?
(a) The absolute enthalpy of neutralisation of the reaction, MgO(s) + 2HCl(aq.) → MgCl2(aq) + H2O(l), will be less than – 57.33 kJ mol–1
(b) If ΔGsystem =0, the system is still moving in a particular direction
(c) If equal volumes of two monoatomic gases A and B, at same temperature and pressure are mixed then, the ratio of Cp/Cv of the mixture will be 1.5
(d) Intermixing of ideal gases at constant P and T results in increase in the entropy of the system
Options:
Solution :
Answer (2)
/
You scored 0 of 4
If 10 mol of an ideal gas at 27°C is expanded reversibly from 20 L to 200 L then the entropy change of the process will be
Options:
10R
10ln10
10Rln10
Rln10
Solution :
Answer (3)
/
You scored 0 of 4
Complete the following by filling blanks from the given options
(a) Combustion of propane releases …… heat than combustion of equimolar amount of glucose
(b) Enthalpy of atomisation of Na(s) is equal to its enthalpy of ………….
(c) At ……… temperature, ionization enthalpy and ionization energy are equal for a species
Options:
More, sublimation, 0°C
Less, vapourization, – 273°C
More, sublimation, 127°C
Less, sublimation, – 273°C
Solution :
Answer (4)
/
You scored 0 of 4
Select the correct statement among the following
Options:
Enthalpy of dilution is independent on the original concentration of the solution
Spontaneity means that a system is having the potential to proceed with the assistance of external agency
For irreversible process, ΔStotal > 0
At equilibrium, entropy change is less than zero
Solution :
Answer (3)
(Reference NCERT Page No. -181,183)
You scored 0 of 4
Select the incorrect relation among the following
Options:
G = H– TS
TΔStotal = TΔSsys – ΔHsys
ΔG = – TΔSTotal
ΔHsystem = – TΔSsurr + qsurr
Solution :
Answer (4)
/
You scored 0 of 4
If at 77°C, N2O4(g) is 40% dissociated into NO2, then the standard free energy change at given temperature and at 1 atm pressure is
Options:
791.4 kJ mol–1
79.14 kJ mol–1
80.07 kJ mol–1
8.0 kJ mol–1
Solution :
Answer (1)

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Answer keys : NCERT Booster Programme for NEET-2022_Chemistry_Poll-17

(Reference NCERT Page No. -175)

(Reference NCERT Page No. -175)

Enthalpy of atomization for H2(g) is equal to

ΔHVap (H2) + BE(H–H)

(Reference NCERT Page No. -177)

(Reference NCERT Page No. -178)

(Reference NCERT Page No. -178)

(a) Bond enthalpy of Cl2

(b) Enthalpy of atomisation of sodium atom

(c) Enthalpy of vapourization of Cl2

(d) Enthalpy of formation of NaCl

(e) Ionization enthalpy of Cl2

(Reference NCERT Page No. -179)

In which of the following entropy increases?

A liquid crystallizes into a solid

Temperature of gas decreases from 500K to 400 K

Polymerisation of ethylene molecules

2NaHCO3(s)→ Na2CO3(s) + CO2(g) + H2O(g)

(Reference NCERT Page No. -183)

Third law of thermodynamics is related with

Mass conservation in nuclear reactions

Internal energy conservation

Entropy change of a process during freezing

Entropy of any pure crystalline substance at absolute zero temperature

(Reference NCERT Page No. -185)

Select the correct statement(s)

(a) TΔSsys is the energy which is not available to do useful work

(b) ΔG term measures the net energy available to do useful work

(c) If TΔSsys – ΔHsys > 0 then process will be spontaneous

(Reference NCERT Page No. -185)

Select the incorrect thermodynamic relations among the following

ΔH° –TΔS° = – RTlnKC

(Reference NCERT Page No. -186)

2NH3(g) + CO2(g) NH2CONH2(aq) + H2O(l)

(ΔG° of above reaction at given temperature is – 11.5 kJ mol–1)

(Reference NCERT Page No. -187)

(Reference NCERT Page No. -186)

For the reaction, 3A(g) + B(g) → 4D(g)

(Reference NCERT Page No. -190)

Enthalpy change for the process CCl4(g) → C(g) + 4Cl(g), will be

(Reference NCERT Page No. -190)

How many number of statement(s) among the following is/are correct?

(b) If ΔGsystem =0, the system is still moving in a particular direction

(Reference NCERT Page No. -182)

(Reference NCERT Page No. -184)

Complete the following by filling blanks from the given options

(b) Enthalpy of atomisation of Na(s) is equal to its enthalpy of ………….

More, sublimation, 0°C

Less, vapourization, – 273°C

More, sublimation, 127°C

Less, sublimation, – 273°C

(Reference NCERT Page No. -176)

Select the correct statement among the following

Enthalpy of dilution is independent on the original concentration of the solution

For irreversible process, ΔStotal > 0

At equilibrium, entropy change is less than zero

(Reference NCERT Page No. -181,183)

Select the incorrect relation among the following

TΔStotal = TΔSsys – ΔHsys