11th Chemistry 5

INFINITY ACADEMY 11TH STD
Chapters : 5 Std 11 : Chemistry Date : 08/10/24

Marks:- 40 Unit Test Sub:- Chemistry
Section A
//X
• Write the answer of the following questions. [Each carries 1 Mark] [15]
1. Choose the correct answer. A thermodynamic state function is a quantity....

(A) used to determine heat changes. (B) whose value is independent of path.
(C) used to determine pressure volume work. (D) whose value depends on temperature only.
2. For the process to occur under adiabatic conditions, the correct condition is :
(A) DT = 0 (B) Dp = 0 (C) q = 0 (D) w = 0
3. The enthalpies of all elements in their standard states are :
(A) unity (B) zero
(C) < 0 (D) different for each element
4. DU d– of combustion of methane is – X kJ mol–1. The value of DH d– is....
(A) = DU d– (B) > DU d– (C) < DU d– (D) = 0
5. The enthalpy of combustion of methane, graphite and dihydrogen at 298 K are, –890.3 kJ mol–1 –393.5
kJ mol–1, and –285.8 kJ mol–1 respectively. Enthalpy of formation of CH4(g) will be....
(A) –74.8 kJ mol–1 (B) –52.27 kJ mol–1 (C) +74.8 kJ mol–1 (D) +52.26 kJ mol–1
6. A reaction, A + B ® C + D + q is found to have a positive entropy change. The reaction will be
(A) possible at high temperature. (B) possible only at low temperature.
(C) not possible at any temperature. (D) possible at any temperature.
7. Which of the following reaction is incorrect according to thermodynamics ?
(A) DG° = – nFE° (B) DH = DE + PDV (C) K = e–DG/RT (D) DG = DH + TDS
8. What will be value of DG° for ice at 298 K temperature ?
(A) –ve (B) 0 (C) +ve (D) (A) & (B)
9. Which of the following option is correct for the given equation ?
4NH3(g) + 5O2(g) ® 4NO(g) + 6H2O(g)
(A) DH = DU (B) DH < DU (C) DH > DU (D) DH ¹ DU
10. If the change in entropy at 353 K is 0.087 kJ mol–1 for benzene. Then calculate the heat of
vapourisation.
(A) – 6.96 kJ mol–1 (B) 6.96 kJ mol–1 (C) – 30.711 kJ mol–1 (D) 30.711 kJ mol–1
11. The change in free energy during working of pencil cell is –1372.58 cal. Calculate the equilibrium
constant of the cell under standard condition (R = 2 cal mol–1 K–1)
(A) 1.00 ´ 105 (B) 1.00 ´ 102 (C) 1.00 ´ 1010 (D) 1.00 ´ 101
12. For which reaction DS can be maximum if it is occuring at constant volume ?
(A) N2(g) + O2(g) ® 2NO(g) (B) CaCO3(s) ® CaO(s) + CO2(g)
1
(C) C(s) + O2(g) ® CO2(g) (D) Mg(s) + O ® MgO(s)
2 2(g)
13. There is change in volume of an ideal gas when pressure is changed at constant temperature. The
change in free energy associated with this can be calculated by which of the following equation ?
P2 P2
(A) DG = –RT ln (B) DG = –2.303 RT log P
P1 1
V2 P2
(C) DG = nRT ln V Shiven Shoppers near Gangeshwar
406,407-8 DG = nRT
(D)Mahadev ln Adajan Surat
Temple
1 P1
P2 P2
(A) DG = –RT ln (B) DG = –2.303 RT log P
P1 1
V2 P2
(C) DG = nRT ln V (D) DG = nRT ln
1 P1
14. A system receives 100 Joule heat and does work of 50 Joule. Calculate the change in the internal
energy ?
(A) –150 Joule (B) 50 Joule (C) –50 Joule (D) 150 Joule
15. In which phenomenon Entropy decreases ?
(A) Melting of ice (B) Crystallisation of salt (C) Evaporation of liquid (D) Diffusion
Section B
//X
• Write the answer of the following questions. [Each carries 2 Marks] [8]
16. Explain free expansion.

17. In a process, 701 J of heat is absorbed by a system and 394 J of work is done by the system. What
is the change in internal energy for the process ?
18. Calculate the entropy change in surroundings when 1.00 mol of H2O(l) is formed under standard
conditions. Df H d– = –286 kJ mol–1.
19. Prove the relationship between Cp and Cv for an ideal gas.
Section C
//X
20. Explain the relation of change in heat at constant pressure and constant temperature.
Section D
//X
21. Explain term Enthalpy and relation between DH and DU. Prove the formulas DH = DU + PDV; DH
= Hp – Hr, H and DH = DU + Dn(g)RT.
Section E
//X
22. Explain pressure volume work.

23. Explain the measurement of DU and DH by calorimetry.
406,407-8 Shiven Shoppers near Gangeshwar Mahadev Temple Adajan Surat

INFINITY ACADEMY
Chapters : 5 Std 11 : Chemistry Date : 08/10/24
Marks:- 40 Unit Test Sub:- Chemistry
Section A
//X
• Write the answer of the following questions. [Each carries 1 Mark] [15]
1.
2.
3.
4.
5.
6.
7.
8.
9.
10.
11.
12.
13.
14.
15.
Section B
//X
16.
17.
18.
19.
Section C
//X
20.
Section D
//X
21.
Section E
//X
22.
23.

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INFINITY ACADEMY 11TH STD

Chapters : 5 Std 11 : Chemistry Date : 08/10/24

1. Choose the correct answer. A thermodynamic state function is a quantity....

16. Explain free expansion.

19. Prove the relationship between Cp and Cv for an ideal gas.

22. Explain pressure volume work.

406,407-8 Shiven Shoppers near Gangeshwar Mahadev Temple Adajan Surat

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