Date Printed: 05/12/2023 Product: 0148S7NL

Safety Data Sheet

Prepared in Accordance with HCS 29
C.F.R. 1910.1200

1. Identification of the Substance/Mixture and the Company/Undertaking

1.1 Product Identifier 0148S7NL Revision Date: 12/05/2022

Product Name: PYROCRETE 241 Supercedes Date: 11/11/2022

1.2 Relevant identified uses of the Fireproofing material.

substance or mixture and uses
advised against

1.3 Details of the supplier of the safety data sheet

Manufacturer: Carboline Global Inc.

2150 Schuetz Road
St. Louis, MO USA 63146

Regulatory / Technical Information:

Contact Carboline Technical Services at
1-800-848-4645

Schlereth, Ken - [email protected]

Datasheet Produced by:

1.4 CHEMTREC 1-800-424-9300 (Inside US)

Emergency telephone number:
CHEMTREC +1 703 5273887 (Outside US)
HEALTH - Pittsburgh Poison Control 1-412-681-6669

2. Hazard Identification

2.1 Classification of the substance or mixture

Carcinogenicity, category 1A
Serious Eye Damage, category 1
STOT, single exposure, category 3, RTI
Skin Irritation, category 2
Skin Sensitizer, category 1

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Date Printed: 05/12/2023 Product: 0148S7NL

2.2 Label elements

Symbol(s) of Product

Signal Word
Danger

Named Chemicals on Label

CALCIUM OXIDE, SODIUM SILICATE, MICA, MICROCRYSTALLINE SILICA, PORTLAND CEMENT

HAZARD STATEMENTS

Skin Irritation, category 2 H315 Causes skin irritation.

Skin Sensitizer, category 1 H317 May cause an allergic skin reaction.
Serious Eye Damage, category 1 H318 Causes serious eye damage.
STOT, single exposure, category 3, RTI H335 May cause respiratory irritation.
Carcinogenicity, category 1A H350-1A May cause cancer.
PRECAUTION PHRASES
P201 Obtain special instructions before use.
P202 Do not handle until all safety precautions have been read
and understood.
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P280 Wear protective gloves/protective clothing/eye protection/
face protection.
P284 Wear respiratory protection.
P301+310 IF SWALLOWED: Immediately call a POISON CENTER or
doctor/physician.
P302+352 IF ON SKIN: Wash with plenty of soap and water.
P304+340 IF INHALED: Remove victim to fresh air and keep at rest in a
position comfortable for breathing.
P305+351+338 IF IN EYES: Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do so.
Continue rinsing.
P308+313 IF exposed or concerned: Get medical advice/attention
P333+313 If skin irritation or rash occurs: Get medical advice/attention.
2.3 Other hazards
No Information

Results of PBT and vPvB assessment:

The product does not meet the criteria for PBT/VPvB in accordance with Annex XIII.

3. Composition/Information On Ingredients
3.2 Mixtures
Hazardous ingredients
Name According to EEC EINEC No. CAS-No. % Classifications
PORTLAND CEMENT 266-043-4 65997-15-1 25 - <50 H315-317-318 Eye Dam. 1, Skin Irrit. 2, Skin
Sens. 1

MICA 310-127-6 12001-26-2 10 - <25 H319-335 Eye Irrit. 2, STOT SE 3 RTI

LIMESTONE 215-279-6 1317-65-3 2.5 - <10 H315-319 Eye Irrit. 2, Skin Irrit. 2

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Date Printed: 05/12/2023 Product: 0148S7NL
CALCIUM OXIDE 1305-78-8 1.0 - <2.5 H315-318-335 Eye Dam. 1, Skin Irrit. 2,
STOT SE 3 RTI

SODIUM SILICATE 215-687-4 1344-09-8 1.0 - <2.5 H290-314-335

MICROCRYSTALLINE 238-878-4 14808-60-7 0.1 - <1.0 H350-372 Carc. 1A, STOT RE 1

SILICA

CAS-No. M-Factors
65997-15-1 0
12001-26-2 0
1317-65-3 0
1305-78-8 0
1344-09-8 0
14808-60-7 0

Additional Information: The text for GHS Hazard Statements shown above (if any) is given in Section 16.

4. First-aid Measures
4.1 Description of First Aid Measures
AFTER INHALATION: Remove person to fresh air. If signs/symptoms continue, get medical attention.
AFTER SKIN CONTACT: Wash off with soap and plenty of water.
AFTER EYE CONTACT: Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician.
AFTER INGESTION: Do NOT induce vomiting. Never give anything by mouth to an unconscious person. If swallowed, call
a poison control centre or doctor immediately.

4.2 Most important symptoms and effects, both acute and delayed
Irritating to respiratory system.
4.3 Indication of any immediate medical attention and special treatment needed

No Information

5. Fire-fighting Measures
5.1 Extinguishing Media:
None Known
UNUSUAL FIRE AND EXPLOSION HAZARDS: No Information
FOR SAFETY REASONS NOT TO BE USED: No Information

5.2 Special hazards arising from the substance or mixture

No Information

5.3 Advice for firefighters

SPECIAL FIREFIGHTING PROCEDURES: The product is not flammable.
SPECIAL FIREFIGHTING PROTECTION EQUIPMENT: No Information

6. Accidental Release Measures

6.1 Personal precautions, protective equipment and emergency procedures
Use personal protective equipment. Sweep up to prevent slipping hazard. Forms slippery/greasy layers with water.
6.2 Environmental precautions
No Information

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6.3 Methods and material for containment and cleaning up

No Information
6.4 Reference to other sections

No Information

7. Handling and Storage

7.1 Precautions for safe handling

INSTRUCTIONS FOR SAFE HANDLING : Avoid breathing dust. Do not breathe vapours or spray mist. Do not get in eyes,
on skin, or on clothing. Wash thoroughly after handling.
PROTECTION AND HYGIENE MEASURES : Handle in accordance with good industrial hygiene and safety practice. Do not
breathe dust. Wash hands before eating, drinking, or smoking.

7.2 Conditions for safe storage, including any incompatibilities

CONDITIONS TO AVOID: Exposure to moisture.

STORAGE CONDITIONS: Keep containers tightly closed in a dry, cool and well-ventilated place.
7.3 Specific end use(s)

No Information

8. Exposure Controls/Personal Protection

8.1 Control parameters
Ingredients with Occupational Exposure Limits
(US)

Name CAS-No. ACGIH TWA ACGIH STEL ACGIH Ceiling

PORTLAND CEMENT 65997-15-1 1 MGM3 N/E N/E
MICA 12001-26-2 3 MGM3 N/E N/E
LIMESTONE 1317-65-3 N/E N/E N/E
CALCIUM OXIDE 1305-78-8 2 MGM3 N/E N/E
SODIUM SILICATE 1344-09-8 N/E N/E N/E
MICROCRYSTALLINE SILICA 14808-60-7 0.025 MGM3 N/E N/E

Name CAS-No. OSHA PEL OSHA STEL

PORTLAND CEMENT 65997-15-1 5 MGM3 15 MGM3

N/E

MICA 12001-26-2 20. MPPCF

N/E

LIMESTONE 1317-65-3 5 MGM3 15 MGM3 5

N/E
MGM3 15 MGM3 5
MGM3 15 MGM3

CALCIUM OXIDE 1305-78-8 5 MGM3

N/E

SODIUM SILICATE 1344-09-8 N/E

N/E

MICROCRYSTALLINE SILICA 14808-60-7 0.05 MGM3

N/E

FURTHER ADVICE: No Information

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8.2 Exposure controls

Personal Protection
RESPIRATORY PROTECTION: Effective dust mask. Use NIOSH approved respiratory protection.
EYE PROTECTION: Safety glasses with side-shields.
HAND PROTECTION: For prolonged or repeated contact use protective gloves.
OTHER PROTECTIVE EQUIPMENT: None.
ENGINEERING CONTROLS: Avoid dust accumulation in enclosed space.

9. Physical and Chemical Properties

9.1 Information on basic physical and chemical properties
Appearance: Grey, Speckled Powder

Physical State Solid

Odor Dusty

Odor threshold N/D

pH N/D
Melting point / freezing point (°C) N/D
Boiling point/range (°C) N/A - N/A
Flash Point (°C) None
Evaporation rate N/A

Flammability (solid, gas) Not determined

Upper/lower flammability or explosive N/A - N/A

limits
Vapour Pressure, mmHg N/A
Vapour density N/A
Relative density Not determined
Solubility in / Miscibility with water N/D
Partition coefficient: n-octanol/water Not determined
Auto-ignition temperature (°C) Not determined
Decomposition temperature (°C) Not determined
Viscosity Unknown
Explosive properties Not determined
Oxidising properties Not determined

9.2 Other information

VOC Content g/l: 0

Specific Gravity (g/cm3) 0.12

10. Stability and Reactivity

10.1 Reactivity
No Information

10.2 Chemical stability

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Date Printed: 05/12/2023 Product: 0148S7NL

Stable under normal conditions.

10.3 Possibility of hazardous reactions

Hazardous polymerisation does not occur.

10.4 Conditions to avoid

Exposure to moisture.

10.5 Incompatible materials

Strong oxidizing agents.

10.6 Hazardous decomposition products

None known.

11. Toxicological Information

11.1 Information on toxicological effects
Acute Toxicity:
Oral LD50: N/D
Inhalation LC50: N/D

Irritation: Skin irritation, category 2

Corrosivity: Serious eye damage, category 1

Sensitization: Skin sensitizer, category 1

Repeated dose toxicity: Unknown

Carcinogenicity: Carcinogenicity, category 1A

Mutagenicity: Unknown

Toxicity for reproduction: Unknown

STOT-single exposure: STOT, single exposure, category 3

STOT-repeated exposure: unknown

Aspiration hazard: Unknown

If no information is available above under Acute Toxicity then the acute effects of this product have not been tested.
Data on individual components are tabulated below:

Chemical Name Oral LD50 Dermal LD50 Vapor LC50 Gas LC50 Dust/Mist
CAS-No.
LC50
65997-15-1 PORTLAND CEMENT Not Available Not Available 0.000 0.000

12001-26-2 MICA Not Available Not Available Not Available 0.000 0.000

5,000 mg/kg,
1317-65-3 LIMESTONE Not Available Not Available 0.000 0.000
rat, oral

1305-78-8 CALCIUM OXIDE Not Available Not Available 0.000 0.000

1344-09-8 SODIUM SILICATE Not Available Not Available 0.000 0.000

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14808-60-7 MICROCRYSTALLINE SILICA 22500 mg/kg Not Available Not Available 0.000 0.000

Additional Information:
The cement contained within this product may cause dermal sensitization due to the potential presence of trace amounts of
hexavalent chromium. Constituents of this product may include crystalline silica which, if inhalable, may cause silicosis, a form or
progressive pulmonary fibrosis. Inhalable crystalline silica is listed by IARC as a group 1 carcinogen (lung) based on sufficient
evidence in occupationally exposed humans and sufficient evidence in animals. Crystalline silica is also listed by the NTP as a
known human carcinogen. This classification is relevant when exposed to Quartz (silicon dioxide) in dust or powder form only,
including cured product that is subject to sanding, grinding, cutting, or other surface preparation activities. Constituents may also
include abestiform or non-asbestiform tremolite or other silicates as impurities, and above dei minimus exposure to these impurities in
inhalable form may be carcinogenic or cause other serious lung problems.

12. Ecological Information

12.1 Toxicity:

EC50 48hr (Daphnia): Unknown

IC50 72hr (Algae): Unknown

LC50 96hr (fish): Unknown

12.2 Persistence and degradability: Unknown

12.3 Bioaccumulative potential: Unknown

12.4 Mobility in soil: Unknown

12.5 Results of PBT and vPvB The product does not meet the criteria for PBT/VPvB in accordance with Annex XIII.
assessment:

12.6 Other adverse effects: Unknown

CAS-No. Chemical Name EC50 48hr IC50 72hr LC50 96hr

65997-15-1 PORTLAND CEMENT No information No information No information

12001-26-2 MICA No information No information No information
1317-65-3 LIMESTONE 1,000 mg/l 200 mg/l 10,000 mg/l
1305-78-8 CALCIUM OXIDE No information No information No information
1344-09-8 SODIUM SILICATE No information No information No information
14808-60-7 MICROCRYSTALLINE SILICA No information No information No information

13. Disposal Considerations

13.1 WASTE TREATMENT METHODS: Dispose of in accordance with local regulations.

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14. Transport Information

14.1 UN number None
14.2 UN proper shipping name Not Regulated
Technical name N/A
14.3 Transport hazard class(es) None
Subsidiary shipping hazard N/A
14.4 Packing group N/A
14.5 Environmental hazards No
14.6 Special precautions for user Unknown
EmS-No.: N/A

14.7 Transport in bulk according to Annex II Unknown

of MARPOL 73/78 and the IBC code

15. Regulatory Information

15.1 Safety, health and environmental regulations/legislation for the substance or mixture:

U.S. Federal Regulations: As follows -

CERCLA - Sara Hazard Category
This product has been reviewed according to the EPA ‘Hazard Categories’ promulgated under Sections 311 and 312 of the
Superfund Amendment and Reauthorization Act of 1986 (SARA Title III) and is considered, under applicable definitions, to
meet the following categories:
Carcinogenicity, Skin Corrosion or Irritation, Respiratory or Skin Sensitization, Serious eye damage or eye irritation, Specific
target organ toxicity (single or repeated exposure)
Sara Section 313:
This product contains the following substances subject to the reporting requirements of Section 313 of Title III of the
Superfund Amendment and Reauthorization Act of 1986 and 40 CFR part 372:

No SARA 313 substances exist in this product above de

minimis concentrations.
Toxic Substances Control Act:
All components of this product are either listed on the TSCA Inventory or are exempt.

This product contains the following chemical substances subject to the reporting requirements of TSCA 12(B) if exported from
the United States:

No TSCA 12(b) components exist in this product.

U.S. State Regulations: As follows -
New Jersey Right-to-Know:

The following materials are non-hazardous, but are among the top five components in this product.

Chemical Name CAS-No.

ALUMINUM HYDROXIDE 21645-51-2
VERMICULITE 1318-00-9
AMORPHOUS SILICATE 93763-70-3

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Pennsylvania Right-To-Know

The following non-hazardous ingredients are present in the product at greater than 3%.

Chemical Name CAS-No.

ALUMINUM HYDROXIDE 21645-51-2
VERMICULITE 1318-00-9
AMORPHOUS SILICATE 93763-70-3
CALIFORNIA PROPOSITION 65

WARNING: Cancer and Reproductive Harm -- www.P65Warnings.ca.gov

International Regulations: As follows -

* Canadian DSL:

All chemical ingredients included on inventory (DSL)

15.2 Chemical Safety Assessment:

No Chemical Safety Assessment has been carried out for this substance/mixture by the supplier.

16. Other Information

Text for GHS Hazard Statements shown in Section 3 describing each ingredient:
H290 May be corrosive to metals.
H314 Causes severe skin burns and eye damage.
H315 Causes skin irritation.
H317 May cause an allergic skin reaction.
H318 Causes serious eye damage.
H319 Causes serious eye irritation.
H335 May cause respiratory irritation.
H350 May cause cancer.
H372 Causes damage to organs through prolonged or repeated exposure.

Reasons for revision

No Information

The information contained herein is, to the best of our knowledge and belief accurate. However,
since the conditions of handling and use are beyond our control, we make no guarantee of results,
and assume no liability for damages incurred by use of this material. It is the responsibility of
the user to comply with all applicable federal, state, and local laws and regulations.

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