EC safety data sheet

Trade name: LUKOIL NAVISYN DE 100, LUKOIL NAVISYN DE 150

Current version : 4.0.0, issued: 20.02.2019 Replaced version: 2.0.0, issued: 11.05.2015 Region: GB

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1 Product identifier
Trade name

LUKOIL NAVISYN DE 100, LUKOIL NAVISYN DE 150

1.2 Relevant identified uses of the substance or mixture and uses advised against
Relevant identified uses of the substance or mixture
Synthetic air compressor oil
Uses advised against
No data available.

1.3 Details of the supplier of the safety data sheet

Address
LUKOIL Marine Lubricants DMCC
c/o «LLK-INTERNATIONAL»
6, Malaya Yakimanka
119180 Moscow, Russia
Telephone no. +7-495-627 44 49
Fax no. +7-495-627 40 20
Information provided by / telephone
+7-495-627 44 49 (9:00 - 17:00)
Advice on Safety Data Sheet
[email protected]
Supplier
Address
LUKOIL Marine Lubricants Germany GmbH
Alsterufer 20
20354 Hamburg
Telephone no. +49 40 180 4220 0

1.4 Emergency telephone number

For medical advice (in German and English):
+49 (0)551 192 40 (Giftinformationszentrum Nord)

SECTION 2: Hazards identification

2.1 Classification of the substance or mixture
Classification in accordance with Regulation (EC) No 1272/2008 (CLP)
Aquatic Chronic 3; H412
Classification information
This product is assessed and classified using the methods and criteria below referred to in Article 9 of Regulation (EC)
n° 1272/2008:
Physical hazards: determined through assessment data based on the methods or standards referred to in part 2 of
Annex I to CLP
Health hazards and environmental hazards: determined through toxicological and ecotoxicological assessment data
based on the methods or standards referred to in Part 3, 4 and 5 of Annex I to CLP.

2.2 Label elements

Labelling according to Regulation (EC) No 1272/2008 (CLP Regulation)

Hazard pictograms
-
Signal word
-

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EC safety data sheet
Trade name: LUKOIL NAVISYN DE 100, LUKOIL NAVISYN DE 150

Current version : 4.0.0, issued: 20.02.2019 Replaced version: 2.0.0, issued: 11.05.2015 Region: GB

Hazard statement(s)
H412 Harmful to aquatic life with long lasting effects.
Hazard statements (EU)
EUH208 Contains N-1-naphthylaniline. May produce an allergic reaction.
Precautionary statement(s)
P273 Avoid release to the environment.
P501 Dispose of contents/container to a facility in accordance with
local/regional/national/international regulations.

2.3 Other hazards

No data available.

SECTION 3: Composition/information on ingredients

3.1 Substances
Not applicable. The product is not a substance.

3.2 Mixtures
Hazardous ingredients
No Substance name Additional information
CAS / EC / Index / Classification (EC) 1272/2008 (CLP) Concentration %
REACH no
1 N-1-naphthylaniline
90-30-2 Acute Tox. 4; H302 >= 0.25 - < 1.00 %-b.w.
201-983-0 Skin Sens. 1; H317
- STOT RE 2; H373
- Aquatic Acute 1; H400
Aquatic Chronic 1; H410
2 diphenylamine
122-39-4 Acute Tox. 3*; H301 < 0.25 %-b.w.
204-539-4 Acute Tox. 3*; H311
612-026-00-5 Acute Tox. 3*; H331
- Aquatic Acute 1; H400
Aquatic Chronic 1; H410
STOT RE 2*; H373**
Full Text for all H-phrases and EUH-phrases: pls. see section 16
(*,**,***,****) Detailed explanation pls. refer to CLP regulation No. 1272/2008, annex VI, 1.2

SECTION 4: First aid measures

4.1 Description of first aid measures
General information
In case of persisting adverse effects, consult a physician. Remove contaminated clothing and shoes immediately, and
launder thoroughly before reusing.
After inhalation
Remove affected persons from dangerous area by observing suitable respiratory protection measures. Irregular
breathing/no breathing: artificial respiration.
After skin contact
Wash off immediately with soap and water.
After eye contact
Separate eyelids, wash the eyes thoroughly with water (15 min.).
After ingestion
Do not induce vomiting. Call a doctor immediately. Never give anything by mouth to an unconscious person.

4.2 Most important symptoms and effects, both acute and delayed
No data available.

4.3 Indication of any immediate medical attention and special treatment needed
No data available.

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EC safety data sheet
Trade name: LUKOIL NAVISYN DE 100, LUKOIL NAVISYN DE 150

Current version : 4.0.0, issued: 20.02.2019 Replaced version: 2.0.0, issued: 11.05.2015 Region: GB

SECTION 5: Firefighting measures

5.1 Extinguishing media
Suitable extinguishing media
Foam; Extinguishing powder; Water spray jet; Carbon dioxide
Unsuitable extinguishing media
High power water jet

5.2 Special hazards arising from the substance or mixture

In the event of fire, the following can be released: Carbon dioxide (CO2); Carbon monoxide (CO)

5.3 Advice for firefighters

Use self-contained breathing apparatus. Cool endangered containers with water spray jet. Wear protective clothing.

SECTION 6: Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures
For non-emergency personnel
Refer to protective measures listed in sections 7 and 8. Ensure adequate ventilation. Avoid contact with skin, eyes and
clothing.
For emergency responders
No data available. Personal protective equipment (PPE) - see Section 8.

6.2 Environmental precautions

Do not discharge into the drains/surface waters/groundwater.

6.3 Methods and material for containment and cleaning up

Prevent spread over a wide area (by containment with sand or earth). Take up with absorbent material (e.g., sand,
kieselguhr, universal binder). When picked up, treat material as prescribed under heading "Disposal considerations".

6.4 Reference to other sections

No data available.

SECTION 7: Handling and storage

7.1 Precautions for safe handling
Advice on safe handling
Provide good ventilation at the work area (local exhaust ventilation, if necessary). Product inherent handling risks must
be minimised taking the appropriate measures for protection and preventive actions. The working process should be
designed to rule out the release of hazardous substances or skin contact as far it is possible by the state of the art.
General protective and hygiene measures
Do not eat, drink or smoke during work time. Keep away from foodstuffs and beverages. Remove soiled or soaked
clothing immediately. Avoid contact with eyes and skin. Do not inhale vapours. Provide eye wash fountain in work
area. Have emergency shower available.
Advice on protection against fire and explosion
Keep away from sources of heat and ignition.

7.2 Conditions for safe storage, including any incompatibilities

Technical measures and storage conditions
Keep container tightly closed in a well-ventilated place. Protect from heat and direct sunlight.
Recommended storage temperature
Value < 50 °C
Requirements for storage rooms and vessels
Store product in closed containers. Storage rooms must be properly ventilated. Emptied containers may contain
product residues and therefore must be handled with care.
Reuse only after appropriate cleaning. Always keep in containers of same material as the original one.
Advice on storage assembly
None known

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EC safety data sheet
Trade name: LUKOIL NAVISYN DE 100, LUKOIL NAVISYN DE 150

Current version : 4.0.0, issued: 20.02.2019 Replaced version: 2.0.0, issued: 11.05.2015 Region: GB

7.3 Specific end use(s)

No data available.

SECTION 8: Exposure controls/personal protection

8.1 Control parameters
Occupational exposure limit values
No Substance name CAS no. EC no.
1 diphenylamine 122-39-4 204-539-4
List of approved workplace exposure limits (WELs) / EH40
Diphenylamine
WEL short-term (15 min reference period) 20 mg/m³
true
WEL long-term (8-hr TWA reference period) 10 mg/m³

8.2 Exposure controls

Appropriate engineering controls
No data available.
Personal protective equipment
Respiratory protection
If workplace exposure limits are exceeded, a respiration protection approved for this particular job must be worn. In
case of aerosol and mist formation, take appropriate measures for breathing protection in the event workplace
threshold values are not specified.
Eye / face protection
Safety glasses with side protection shield (EN 166)
Hand protection
Sufficient protection is given wearing suitable protective gloves checked according to i.e. EN 374, in the event of risk of
skin contact with the product. Before use, the protective gloves should be tested in any case for its specific work-
station suitability (i.e. mechanical resistance, product compatibility and antistatic properties). Adhere to the
manufacturer’s instructions and information relating to the use, storage, care and replacement of protective gloves.
Protective gloves shall be replaced immediately when physically damaged or worn. Design operations thus to avoid
permanent use of protective gloves.
Other
Normal chemical work clothing. rubber boots
Environmental exposure controls
No data available.

SECTION 9: Physical and chemical properties

9.1 Information on basic physical and chemical properties
Form/Colour
liquid
270
yellow
70

Odour
30
characteristic

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EC safety data sheet
Trade name: LUKOIL NAVISYN DE 100, LUKOIL NAVISYN DE 150

Current version : 4.0.0, issued: 20.02.2019 Replaced version: 2.0.0, issued: 11.05.2015 Region: GB

Odour threshold
No data available
pH value
No data available
Boiling point / boiling range
No data available
Melting point / melting range
No data available
Decomposition point / decomposition range
No data available
Flash point
Value > 240 °C
Method
3 240
Cleveland open cup
Auto-ignition temperature
No data available
Oxidising properties
No data available
Explosive properties
No data available
Flammability (solid, gas)
No data available
Lower flammability or explosive limits
No data available
Upper flammability or explosive limits
No data available
Vapour pressure
No data available
Vapour density
No data available
Evaporation rate
No data available
Relative density
No data available
Density
Value 0.96 kg/l
Reference temperature
0.96
15 °C
Solubility in water
No data available
Solubility(ies)
No data available
Partition coefficient: n-octanol/water
No data available
Viscosity
Value 93.5 cSt
Reference temperature 40 °C 93.5

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EC safety data sheet
Trade name: LUKOIL NAVISYN DE 100, LUKOIL NAVISYN DE 150

Current version : 4.0.0, issued: 20.02.2019 Replaced version: 2.0.0, issued: 11.05.2015 Region: GB

9.2 Other information

Other information
No data available.

SECTION 10: Stability and reactivity

10.1 Reactivity
No data available.

10.2 Chemical stability

No data available.

10.3 Possibility of hazardous reactions

No data available.

10.4 Conditions to avoid

None, if handled according to intended use.

10.5 Incompatible materials

None known.

10.6 Hazardous decomposition products

No hazardous decomposition products known.

SECTION 11: Toxicological information

11.1 Information on toxicological effects
Acute oral toxicity (result of the ATE calculation for the mixture)
No Product Name
1 LUKOIL NAVISYN DE 100, LUKOIL NAVISYN DE 150
Comments The result of the applied calculation method according to the
European Regulation (EC) 1272/2008 (CLP), Paragraph 3.1.3.6,
Part 3 of Annex I is outside the values that imply a classification /
labelling of this mixture according to table 3.1.1 defining the
respective categories (ATE oral > 2000 mg/kg).
Acute oral toxicity
No data available
Acute dermal toxicity (result of the ATE calculation for the mixture)
No Product Name
1 LUKOIL NAVISYN DE 100, LUKOIL NAVISYN DE 150
Comments The result of the applied calculation method according to the
European Regulation (EC) 1272/2008 (CLP), Paragraph 3.1.3.6,
Part 3 of Annex I is outside the values that imply a classification /
labelling of this mixture according to table 3.1.1 defining the
respective categories (ATE dermal > 2000 mg/kg).
Acute dermal toxicity
No data available
Acute inhalational toxicity (result of the ATE calculation for the mixture)
No Product Name
1 LUKOIL NAVISYN DE 100, LUKOIL NAVISYN DE 150
Comments The result of the applied calculation method according to the
European Regulation (EC) 1272/2008 (CLP), Paragraph 3.1.3.6,
Part 3 of Annex I is outside the values that imply a classification /
labelling of this mixture according to table 3.1.1 defining the
respective categories (ATE for inhalation: > 20.000 ppmV (gases), >
20 mg/l (vapours), > 5 mg/l (dusts/mists).

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EC safety data sheet
Trade name: LUKOIL NAVISYN DE 100, LUKOIL NAVISYN DE 150

Current version : 4.0.0, issued: 20.02.2019 Replaced version: 2.0.0, issued: 11.05.2015 Region: GB

Acute inhalational toxicity

No data available
Skin corrosion/irritation
No data available
Serious eye damage/irritation
No data available
Respiratory or skin sensitisation
No data available
Germ cell mutagenicity
No data available
Reproduction toxicity
No data available
Carcinogenicity
No data available
STOT - single exposure
No data available
STOT - repeated exposure
No data available
Aspiration hazard
No data available
Delayed and immediate effects as well as chronic effects from short and long-term exposure
Repeated and prolonged skin contact may cause removal of natural fat from the skin and irritation of the skin. Eye
contact with the product may cause slight irritation. Inhalation of vapours from the heated product can cause irritation of
901
the respiratory tract and the eyes.

SECTION 12: Ecological information

12.1 Toxicity
Toxicity to fish (acute)
No data available
Toxicity to fish (chronic)
No data available
Toxicity to Daphnia (acute)
No data available
Toxicity to Daphnia (chronic)
No data available
Toxicity to algae (acute)
No data available
Toxicity to algae (chronic)
No data available
Bacteria toxicity
No data available

12.2 Persistence and degradability

Biodegradability
No Product Name
1 LUKOIL NAVISYN DE 100, LUKOIL NAVISYN DE 150
Evaluation not readily biodegradable

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EC safety data sheet
Trade name: LUKOIL NAVISYN DE 100, LUKOIL NAVISYN DE 150

Current version : 4.0.0, issued: 20.02.2019 Replaced version: 2.0.0, issued: 11.05.2015 Region: GB

12.3 Bioaccumulative potential

No data available.

12.4 Mobility in soil

Mobility in soil
No Product Name
1 LUKOIL NAVISYN DE 100, LUKOIL NAVISYN DE 150
Comments A base oil component of this product floats and can migrate from
water to land.

12.5 Results of PBT and vPvB assessment

No data available.

12.6 Other adverse effects

No data available.

12.7 Other information

Other information
710
Do not discharge product unmonitored into the environment.

SECTION 13: Disposal considerations

13.1 Waste treatment methods
Product
Allocation of a waste code number, according to the European Waste Catalogue, should be carried out in agreement
with the regional waste disposal company.
Packaging
Residuals must be removed from packaging and when emptied completely disposed of in accordance with the
regulations for waste removal. Incompletely emptied packaging must be disposed of in the form of disposal specified
by the regional disposer.

SECTION 14: Transport information

14.1 Transport ADR/RID/ADN
The product is not subject to ADR/RID/ADN regulations.

14.2 Transport IMDG

The product is not subject to IMDG regulations.

14.3 Transport ICAO-TI / IATA

The product is not subject to ICAO-TI / IATA regulations.

14.4 Other information

No data available.

14.5 Environmental hazards

Information on environmental hazards, if relevant, please see 14.1 - 14.3.

14.6 Special precautions for user

No data available.

14.7 Transport in bulk according to Annex II of Marpol and the IBC Code
Not relevant

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EC safety data sheet
Trade name: LUKOIL NAVISYN DE 100, LUKOIL NAVISYN DE 150

Current version : 4.0.0, issued: 20.02.2019 Replaced version: 2.0.0, issued: 11.05.2015 Region: GB

SECTION 15: Regulatory information

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
EU regulations

Regulation (EC) No 1907/2006 (REACH) Annex XIV (List of substances subject to authorisation)
According to the data available and/or specifications supplied by upstream suppliers, this product does not contain any
substances considered as substances requiring authorisation as listed on Annex XIV of the REACH regulation (EC)
1907/2006.
REACH candidate list of substances of very high concern (SVHC) for authorisation
According to available data and the information provided by preliminary suppliers, the product does not contain
substances that are considered substances meeting the criteria for inclusion in annex XIV (List of Substances Subject
to Authorisation) as laid down in Article 57 and article 59 of REACH (EC) 1907/2006.
Regulation (EC) No 1907/2006 (REACH) Annex XVII: RESTRICTIONS ON THE MANUFACTURE, PLACING ON
THE MARKET AND USE OF CERTAIN DANGEROUS SUBSTANCES, PREPARATIONS AND ARTICLES
The product is considered being subject to REACH regulation (EC) 1907/2006 annexe No 3
XVII.
Directive 2012/18/EU on the control of major-accident hazards involving dangerous substances
This product is not subject to Part 1 or 2 of Annex I.
National regulations

National chemical inventories

USA (TSCA) listed

15.2 Chemical safety assessment

No data available.

SECTION 16: Other information

Sources of key data used to compile the data sheet:
Regulation (EC) No 1907/2006 (REACH), 1272/2008 (CLP) as amended in each case.
EC Directives 2000/39/EC, 2006/15/EC, 2009/161/EU
National Threshold Limit Values of the corresponding countries as amended in each case.
Transport regulations according to ADR, RID, IMDG, IATA as amended in each case.
The data sources used to determine physical, toxic and ecotoxic data, are indicated directly in the corresponding
chapter.
Full text of the H- and EUH- phrases drawn up in sections 2 and 3 (provided not already drawn up in these
sections)
H301 Toxic if swallowed.
H302 Harmful if swallowed.
H311 Toxic in contact with skin.
H317 May cause an allergic skin reaction.
H331 Toxic if inhaled.
H373 May cause damage to organs through prolonged or repeated exposure
H400 Very toxic to aquatic life.
H410 Very toxic to aquatic life with long lasting effects.
Department issuing safety data sheet
UMCO GmbH
Georg-Wilhelm-Str. 187, D-21107 Hamburg
Tel.: +49 40 / 555 546 300 Fax: +49 40 / 555 546 357 e-mail: [email protected]
This information is based on our present knowledge and experience.
The safety data sheet describes products with a view to safety requirements.
It does not however, constitute a guarantee for any specific product properties and shall not establish a legally valid
contractual relationship.

Document protected by copyright. Alterations or reproductions require the express written permission of UMCO GmbH.
.
Prod-ID 623974

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