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CONTINUUM AT3242
SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1. Product identifier
Trade name or designation CONTINUUM AT3242
of the mixture
Date of first issue 28/08/2012
Version number 3.2
Revision date 22/10/2019
Supersedes date 17/02/2018
1.2. Relevant identified uses of the substance or mixture and uses advised against
Identified uses Corrosion inhibitor
Uses advised against None known.
1.3. Details of the supplier of the safety data sheet
SUEZ Water Technologies & Solutions Belgium BVBA
Toekomstlaan 54
Industriepark Wolfstee
2200 HERENTALS
tel : +32 14 / 25 91 11
e-mail : [email protected]

1.4. Emergency telephone number

Multilingual emergency number (24/7)

Europe, Middle East, Africa, Israel (Europe and English

language speaking countries):
+44(0)1235 239670
Middle East & Africa (speaking Arabic):
+44(0)1235 239671

Official advisory body :

ANTIGIFCENTRUM
Bruynstraat 1
B-1120 BRUSSEL
+ 32 70 245 245

SECTION 2: Hazards identification

2.1. Classification of the substance or mixture
Classification according to Regulation (EC) No 1272/2008 as amended
Physical hazards
Corrosive to metals Category 1 H290 - May be corrosive to metals.
Health hazards
Acute toxicity, oral Category 4 H302 - Harmful if swallowed.
Skin corrosion/irritation Category 1B H314 - Causes severe skin burns
and eye damage.
Serious eye damage/eye irritation Category 1 H318 - Causes serious eye
damage.
2.2. Label elements
Label according to Regulation (EC) No. 1272/2008 as amended
Contains: Phosphonic acid, (1-hydroxyethylidene)bis-, Phosphoric acid

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Hazard pictograms

Signal word Danger

Hazard statements
H290 May be corrosive to metals.
H314 Causes severe skin burns and eye damage.
H302 Harmful if swallowed.
Precautionary statements
Prevention
P280 Wear protective gloves/protective clothing/eye protection/face protection.
Response
P301 + P330 + P331 IF SWALLOWED: rinse mouth. Do NOT induce vomiting.
P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water.
P304 + P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present
and easy to do. Continue rinsing.
P310 Immediately call a POISON CENTRE/doctor.
Storage Not available.
Disposal Not available.
Supplemental label information None.
2.3. Other hazards None known.

SECTION 3: Composition/information on ingredients

Mixtures
Chemical description Aqueous acidic solution of organic and inorganic acids
Chemical name % CAS-No. / EC REACH Registration No. Index No. Notes
No.

Phosphoric acid 40 - < 50 7664-38-2 01-2119485924-24 015-011-00-6 #

231-633-2
Classification: Met. Corr. 1;H290, Acute Tox. 4;H302, Skin Corr. 1B;H314 B

Phosphonic acid, 10 - < 20 2809-21-4 01-2119510391-53 -

(1-hydroxyethylidene)bis- 220-552-8
Classification: Met. Corr. 1;H290, Acute Tox. 4;H302, Eye Dam. 1;H318

The classification of the above substance(s) is given, including the hazard class, category code and hazard statements which are
assigned in accordance with their physicochemical, health and environmental hazards. Please refer to section 16 where the full text of
each relevant H-statement is listed.

SECTION 4: First aid measures

4.1. Description of first aid measures
Inhalation Move to fresh air.
Get medical attention immediately.
Skin contact Take off immediately all contaminated clothing.
Wash off immediately with plenty of water for at least 15 minutes.
Get medical attention immediately.
Eye contact Rinse immediately with plenty of water for at least 15 minutes.
Get medical attention immediately.
Ingestion Rinse mouth.
Do not give anything to eat or drink.
Do not induce vomiting.
Call a physician or poison control centre immediately.

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4.2. Most important symptoms Corrosive effects.
and effects, both acute and
delayed
4.3. Indication of any Not available.
immediate medical attention
and special treatment needed

SECTION 5: Firefighting measures

5.1. Extinguishing media
Suitable extinguishing Dry chemical, CO2, water spray or regular foam.
media
Unsuitable extinguishing None.
media
5.2. Special hazards arising Oxides of carbon and phosphorus evolved in fire.
from the substance or mixture
5.3. Advice for firefighters
Special protective Self contained breathing apparatus. (CEN : EN 137)
equipment for firefighters Protective clothing (CEN : EN 469)
Protective gloves (CEN : EN 659)
Helmet (CEN : EN 443)
Special fire fighting Use standard firefighting procedures and consider the hazards of other involved materials.
procedures Prevent spillage and fire-fighting water from entering in public sewers or the immediate
environment.

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures
For non-emergency Wear protective clothing, gloves and safety goggles.
personnel
For emergency responders Use personal protection recommended in Section 8 of the SDS.
6.2. Environmental precautions Prevent from entering sewers or the immediate environment.
Accidental release of large quantities into the aquatic environment may harm aquatic organisms.
6.3. Methods and material for Absorb onto inert material and dispose of according to Hazardous Waste Regulations.
containment and cleaning up Remove small spills with plenty of water.
6.4. Reference to other Please refer also to section no. 8 'Exposure controls' for further information.
sections

SECTION 7: Handling and storage

7.1. Precautions for safe Handle in accordance with good industrial hygiene and safety procedures.
handling Avoid contact with skin and eyes.
Acidic. Do not mix with alkaline material.
7.2. Conditions for safe Store in cool, well ventilated area.
storage, including any Protect from freezing. If frozen, thaw completely and mix thoroughly prior to use.
incompatibilities Store containers closed when not in use.
7.3. Specific end use(s) Only for professional and industrial users
Shelf life 720 days

SECTION 8: Exposure controls/personal protection

8.1. Control parameters
Occupational exposure limits
Hygienic Normative 2.2.5.2439-09 "Maximum Allowable Concentrations (MAC) of Noxious Substances in the Working
Zone Air", Executive No.76 of 30 April 2003. (Including addendums No. 1, 2, 3, and 4).
Components Type Value Form
Phosphonic acid, Ceiling 2 mg/m3 Aerosol
(1-hydroxyethylidene)bis-
(CAS 2809-21-4)

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US. ACGIH Threshold Limit Values
Components Type Value
Phosphoric acid (CAS STEL 3 mg/m3
7664-38-2)
TWA 1 mg/m3
EU. Indicative Exposure Limit Values in Directives 91/322/EEC, 2000/39/EC, 2006/15/EC, 2009/161/EU
Components Type Value
Phosphoric acid (CAS STEL 2 mg/m3
7664-38-2)
TWA 1 mg/m3
Biological limit values No biological exposure limits noted for the ingredient(s).
Recommended monitoring Not available.
procedures
Derived no effect levels (DNELs)
Workers
Components Value Assessment factor Notes
Phosphonic acid, (1-hydroxyethylidene)bis- (CAS 2809-21-4)
Long-term, Systemic, Oral 13 mg/kg/day
Short-term, Systemic, Oral 13 mg/kg/day
Phosphoric acid (CAS 7664-38-2)
Long-term, Local, Inhalation 1 mg/m3 Repeated dose toxicity
Long-term, Systemic, Inhalation 10,7 mg/m3 50 Repeated dose toxicity
Short-term, Local, Inhalation 2 mg/m3
Predicted no effect concentrations (PNECs)
Components Value Assessment factor Notes
Phosphonic acid, (1-hydroxyethylidene)bis- (CAS 2809-21-4)
Freshwater 0,136 mg/l 50
Marine water 0,014 mg/l 500
Secondary poisoning 12 g/kg 30
Sediment (freshwater) 59 mg/kg
Sediment (marine water) 5,9 mg/kg
Soil 96 mg/kg
STP 20 mg/l 1
8.2. Exposure controls
Appropriate engineering Adequate ventilation to maintain air contaminants below exposure limits.
controls Eye wash facilities and emergency shower must be available when handling this product.
Individual protection measures, such as personal protective equipment
Eye/face protection Splash proof chemical goggles.
Face shield.
CEN : EN 166
Skin protection
- Hand protection Gauntlet type neoprene gloves (Protection against unintentional short-term contact)
Gauntlet type rubber gloves (Protection against unintentional short-term contact)
Gauntlet type nitrile gloves (Protection against unintentional short-term contact)
Coating thickness: 0.11 mm
Penetration time: > 480 min
CEN : EN 374-1/2/3/4; EN 420
- Other Chemical resistant apron.
CEN : EN ISO 13688; EN ISO 6530; EN ISO 6529; EN 14605
Respiratory protection In case of insufficient ventilation, use a breathing mask with filter type: P2
CEN : EN 140; EN 143; EN 149
Thermal hazards Not available.
Environmental exposure Prevent from entering in public sewers or the immediate environment.
controls

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SECTION 9: Physical and chemical properties
9.1. Information on basic physical and chemical properties
Appearance
Colour Colourless
Physical state Liquid
Odour Mild
Odour threshold Not available.
pH (concentrated product) 1
pH in aqueous solution Not available.
Melting point/freezing point < -18 °C
Initial boiling point and boiling 104 °C
range
Flash point > 100 °C P-M(CC)
Evaporation rate < 1 (Ether = 1)
Flammability (solid, gas) Not applicable.
Upper/lower flammability or explosive limits
Flammability limit - lower Not available.
(%)
Flammability limit - upper Not available.
(%)
Vapour pressure 18 mm Hg
Vapour pressure temp. 21 °C
Vapour density < 1 (Air = 1)
Relative density 1,45
Relative density temperature 21 °C
Solubility
Solubility (water) 100 %
Partition coefficient Not available.
(n-octanol/water)
Auto-ignition temperature Not applicable.
Decomposition temperature Not available.
Viscosity 3 cps
Viscosity temperature 21 °C
Explosive properties Not available.
Oxidising properties Not available.
9.2. Other information
Pour point < -18 °C
Shelf life 720 days
VOC 0 % (Estimated)

SECTION 10: Stability and reactivity

10.1. Reactivity Not available.
10.2. Chemical stability Material is stable under normal conditions.
10.3. Possibility of hazardous Not applicable.
reactions
10.4. Conditions to avoid Protect from freezing.
10.5. Incompatible materials Avoid contact with strong oxidisers.
Avoid contact with strong bases.

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10.6. Hazardous Oxides of carbon and phosphorus evolved in fire.
decomposition products

SECTION 11: Toxicological information

11.1. Information on toxicological effects
Product Test Results
CONTINUUM AT3242 (Mixture) Acute Dermal LD50 Rabbit: > 5000 mg/kg (Calculated
according to GHS additivity formula)
Acute Oral LD50 Rat: 583 mg/kg (Calculated according to
GHS additivity formula)
Components Test Results
Phosphonic acid, (1-hydroxyethylidene)bis- (2809-21-4) Acute Dermal LD50 Rabbit: > 7940 mg/kg
Acute Oral LD50 Rat: 1878 mg/kg
Phosphoric acid (7664-38-2) Acute Dermal LD50 Rabbit: 2740 mg/kg
Acute Oral LD50 Rat: 300 mg/kg
Acute toxicity Harmful if swallowed.
Skin corrosion/irritation Causes severe skin burns and eye damage.
Serious eye Causes serious eye damage.
damage/irritation
Respiratory or skin Based on available data, the classification criteria are not met.
sensitisation
Specific target organ toxicity - Based on available data, the classification criteria are not met.
repeated exposure
Specific target organ toxicity - Based on available data, the classification criteria are not met.
single exposure
Carcinogenicity Based on available data, the classification criteria are not met.
Germ cell mutagenicity Based on available data, the classification criteria are not met.
Reproductive toxicity Based on available data, the classification criteria are not met.
Information on likely routes of exposure
Ingestion Causes digestive tract burns.
Inhalation May cause irritation to the respiratory system.
Skin contact Causes severe skin burns.
Eye contact Causes serious eye damage.
Symptoms Not available.
Aspiration hazard Based on available data, the classification criteria are not met.
Mixture versus substance None known.
information
Other information Not available.

SECTION 12: Ecological information

12.1. Toxicity
Product Species Test Results
CONTINUUM AT3242 (CAS Mixture)
Aquatic
Crustacea LC50 Daphnia magna 2216 mg/l, Acute toxicity, 48 hour,
(Estimated)
NOEL Daphnia magna 1265 mg/l, Acute toxicity, 48 hour,
(Estimated)
Fish LC50 Fathead minnow 4486 mg/l, Acute toxicity, 96 hour,
(Estimated)
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Product Species Test Results
NOEL Fathead minnow 2170 mg/l, Acute toxicity, 96 hour,
(Estimated)

12.2. Persistence and degradability

- COD (mgO2/g) 60 (calculated data)
- BOD 5 (mgO2/g) 0 (calculated data)
- BOD 28 (mgO2/g) 0 (calculated data)
- TOC (mg C/g) 14 (calculated data)
12.3. Bioaccumulative potential Not available.
Partition coefficient Not available.
n-octanol/water (log Kow)
Bioconcentration factor (BCF) Not available.
12.4. Mobility in soil Not available.
12.5. Results of PBT and vPvB Not a PBT or vPvB substance or mixture.
assessment
12.6. Other adverse effects Not available.

SECTION 13: Disposal considerations

13.1. Waste treatment methods
Contaminated packaging According to Hazardous Waste Regulations.

EWC ( European Waste Code ) recommendation : 15 01 10

15 Waste packaging; absorbents, wiping cloths, filter materials and protective clothing not
otherwise specified.
15 01 Packaging (including separately collected municipal packaging waste).
15 01 10 Packaging containing residues of or contaminated by dangerous substances.
Depending on the origin and state of the waste, other EWC numbers may be applicable too.
Disposal methods/information According to Hazardous Waste Regulations.

EWC ( European Waste Code ) recommendation : 16 03 05

16 Wastes not otherwise specified in the list.
16 03 Off-specification batches and unused products.
16 03 05 Organic wastes containing dangerous substances.
Depending on the origin and state of the waste, other EWC numbers may be applicable too.

SECTION 14: Transport information

ADR
14.1. UN number UN1760
14.2. UN proper shipping Corrosive liquid, n.o.s. (Phosphoric acid, Phosphonic acid, (1-hydroxyethylidene)bis-, Mixture)
name
14.3. Transport hazard class(es)
Class 8
Subsidiary risk -
Tunnel restriction code (E)
14.4. Packing group II
14.5. Environmental hazards No.
14.6. Special precautions Not available.
for user
RID
14.1. UN number UN1760
14.2. UN proper shipping Corrosive liquid, n.o.s. (Phosphoric acid, Phosphonic acid, (1-hydroxyethylidene)bis-, Mixture)
name
14.3. Transport hazard class(es)
Class 8
Subsidiary risk -
14.4. Packing group II

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14.5. Environmental hazards No.

14.6. Special precautions Not available.
for user
ADN
14.1. UN number UN1760
14.2. UN proper shipping Corrosive liquid, n.o.s. (Phosphoric acid, Phosphonic acid, (1-hydroxyethylidene)bis-, Mixture)
name
14.3. Transport hazard class(es)
Class 8
Subsidiary risk -
14.4. Packing group II
14.5. Environmental hazards No.
14.6. Special precautions Not available.
for user
IATA
14.1. UN number UN1760
14.2. UN proper shipping Corrosive liquid, n.o.s. (Phosphoric acid, Phosphonic acid, (1-hydroxyethylidene)bis-, Mixture)
name
14.3. Transport hazard class(es)
Class 8
Subsidiary risk -
14.4. Packing group II
14.5. Environmental hazards No.
ERG Code Not available.
14.6. Special precautions Not available.
for user
IMDG
14.1. UN number UN1760
14.2. UN proper shipping Corrosive liquid, n.o.s. (Phosphoric acid, Phosphonic acid, (1-hydroxyethylidene)bis-, Mixture)
name
14.3. Transport hazard class(es)
Class 8
Subsidiary risk -
14.4. Packing group II
14.5. Environmental hazards
Marine pollutant No.
EmS F-A, S-B
14.6. Special precautions Not available.
for user
14.7. Transport in bulk This substance/mixture is not intended to be transported in bulk.
according to Annex II of
MARPOL and the IBC Code
ADN; ADR; IATA; IMDG; RID

SECTION 15: Regulatory information

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture

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EU regulations
Regulation (EC) No. 1005/2009 on substances that deplete the ozone layer, Annex I and II, as amended
Not listed.
Regulation (EC) No. 850/2004 On persistent organic pollutants, Annex I as amended
Not listed.
Regulation (EU) No. 649/2012 concerning the export and import of dangerous chemicals, Annex I, Part 1 as amended
Not listed.
Regulation (EU) No. 649/2012 concerning the export and import of dangerous chemicals, Annex I, Part 2 as amended
Not listed.
Regulation (EU) No. 649/2012 concerning the export and import of dangerous chemicals, Annex I, Part 3 as amended
Not listed.
Regulation (EU) No. 649/2012 concerning the export and import of dangerous chemicals, Annex V as amended
Not listed.
Regulation (EC) No. 166/2006 Annex II Pollutant Release and Transfer Registry, as amended
Not listed.
Regulation (EC) No. 1907/2006, REACH Article 59(10) Candidate List as currently published by ECHA
Not listed.
Authorisations
Regulation (EC) No. 1907/2006, REACH Annex XIV Substances subject to authorization, as amended
Not listed.
Restrictions on use
Regulation (EC) No. 1907/2006, REACH Annex XVII Substances subject to restriction on marketing and use as amended
Not listed.
Directive 2004/37/EC: on the protection of workers from the risks related to exposure to carcinogens and mutagens at
work, as amended.
Not listed.
Other EU regulations
Directive 2012/18/EU on major accident hazards involving dangerous substances, as amended
Not listed.
National regulations Not available.
15.2. Chemical safety Not available.
assessment
Inventory status
Country(s) or region Inventory name On inventory (yes/no)*
Europe European Inventory of Existing Commercial Chemical Yes
Substances (EINECS)
Europe European List of Notified Chemical Substances (ELINCS) No
*A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s)
A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing
country(s).

SECTION 16: Other information

List of abbreviations
COD: Chemical Oxygen Demand
EC-No: European Commission Number
IATA: International Air Transport Association
CAS: Chemical Abstract Service.
CLP: Classification, Labeling and Packaging REGULATION (EC) No 1272/2008 on classification,
labeling and packaging of substances and mixtures.
CEN: European Committee for Standardization (Comité Européen de Normalisation).
TWA: Time Weighted Average.
STEL: Short-term Exposure Limit.
LD50: Lethal Dose 50%.
LC50: Lethal Concentration 50%.
EC50: Effective Concentration 50%.
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NOEL: No observed effect level.

BOD: Biochemical oxygen demand.
TOC: Total Organic Carbon.
ADR: European agreement concerning the international carriage of dangerous goods by road
(Accord européen relatif transport des merchandises dangereuses par route).
ADN: European Agreement concerning the International Carriage of Dangerous Goods by Inland
Waterways (Accord européen relatif au transport international des marchandises dangereuses
par voies de navigation intérieures).
IMDG Code: International Maritime Dangerous Goods Code.
RID: Regulations concerning the international carriage of dangerous goods by rail (Règlement
International concernant le transport de marchandises dangereuses par chemin de fer).
References Safety data sheets of raw materials.
Information on evaluation The physical, health and environmental hazards of this mixture are assessed by applying the
method leading to the classification criteria for each hazard class or differentiation in Parts 2 to 5 of Annex I to Regulation
classification of mixture (EC) No 1272/2008 (CLP).
Full text of any H-statements
not written out in full under
Sections 2 to 15 H290 May be corrosive to metals.
H302 Harmful if swallowed.
H314 Causes severe skin burns and eye damage.
H318 Causes serious eye damage.
Revision information This document has undergone significant changes and should be reviewed in its entirety.
Training information Provide training on safe handling while considering the type of application and exposure scenarios.
Based on EC Directive / (EC) No 1907/2006 (REACH)
Regulations (EU) 2015/830
(EC) No 1272/2008
(EU) No 1357/2014
Further information Correction in Section: 2,8,11

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