BO5002844 - GB-en - Acecut 5250 Cutting Fluid

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BOHLE AG

Safety Data Sheet

according to Regulation (EC) No 1907/2006

Acecut 5250 Cutting fluid


Revision date: 21.06.2018 Product code: BO5002844 Page 1 of 9

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1. Product identifier


Acecut 5250 Cutting fluid
Further trade names
BO 5002844, 5 l
BO 5002804, 30 l
BO 5002834, 200 l
1.2. Relevant identified uses of the substance or mixture and uses advised against
Use of the substance/mixture
cutting fluid
1.3. Details of the supplier of the safety data sheet
Company name: BOHLE AG
Street: Dieselstr. 10
Place: D-42781 Haan
Telephone: +49 2129 5568-0 Telefax: +49 2129 5568-282
e-mail: [email protected]
Contact person: Klaus Nehren Telephone: +49 2129 5568-276
e-mail: [email protected]
Internet: www.bohle.com
Responsible Department: Chemie

SECTION 2: Hazards identification

2.1. Classification of the substance or mixture


Regulation (EC) No. 1272/2008
Hazard categories:
Flammable liquid: Flam. Liq. 3
Aspiration hazard: Asp. Tox. 1
Hazard Statements:
Flammable liquid and vapour.
May be fatal if swallowed and enters airways.
2.2. Label elements
Regulation (EC) No. 1272/2008
Hazard components for labelling
Hydrocarbons, C11-C14, isoalkanes, cyclics, <2% aromatics
Signal word: Danger

Pictograms:

Hazard statements
H226 Flammable liquid and vapour.
H304 May be fatal if swallowed and enters airways.
Precautionary statements
P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No
smoking.
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P301+P330+P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.

Revision No: 1,02 GB - EN Print date: 04.10.2018


BOHLE AG
Safety Data Sheet

according to Regulation (EC) No 1907/2006

Acecut 5250 Cutting fluid


Revision date: 21.06.2018 Product code: BO5002844 Page 2 of 9

P303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water
or shower.
P308+P311 IF exposed or concerned: Call a POISON CENTER/doctor.
Special labelling of certain mixtures
EUH066 Repeated exposure may cause skin dryness or cracking.

SECTION 3: Composition/information on ingredients

3.2. Mixtures
Chemical characterization
Petroleum distillates
Hazardous components
CAS No Chemical name Quantity
EC No Index No REACH No
Classification according to Regulation (EC) No. 1272/2008 [CLP]
Hydrocarbons, C11-C14, isoalkanes, cyclics, <2% aromatics 25-50%
927-285-2 01-2119480162-45
Asp. Tox. 1; H304 EUH066
Hydrocarbons, C11-C14, isoalkanes, <2% aromatics 25-50%
920-901-0 01-2119456810-40
Asp. Tox. 1; H304 EUH066
124-18-5 Decane 10-25%
204-686-4 01-2119474199-26
Flam. Liq. 3, Asp. Tox. 1; H226 H304 EUH066
5131-66-8 3-butoxypropan-2-ol, propylene glycol monobutyl ether 5-10%
225-878-4 603-052-00-8 01-2119475527-28
Skin Irrit. 2, Eye Irrit. 2; H315 H319
Hydrocarbons, C11-C14, n-alkane, isoalkanes, cyclics, <2% aromatics 2,5-10%
926-141-6 01-2119456620-43
Asp. Tox. 1; H304
Full text of H and EUH statements: see section 16.

SECTION 4: First aid measures

4.1. Description of first aid measures


General information
First aider: Pay attention to self-protection!
Move out of dangerous area.
Take off contaminated clothing and shoes immediately .
After inhalation
Remove casualty to fresh air and keep warm and at rest.
If symptoms persist, call a physician.
After contact with skin
Wash off with soap and plenty of water.
If symptoms persist, call a physician.
After contact with eyes
Rinse thoroughly with plenty of water, also under the eyelids. Remove contact lenses, if present and easy to
do. Continue rinsing.
Consult a physician.
Revision No: 1,02 GB - EN Print date: 04.10.2018
BOHLE AG
Safety Data Sheet

according to Regulation (EC) No 1907/2006

Acecut 5250 Cutting fluid


Revision date: 21.06.2018 Product code: BO5002844 Page 3 of 9

After ingestion
Rinse mouth thoroughly with water.
Do NOT induce vomiting.
Call a physician immediately.
4.2. Most important symptoms and effects, both acute and delayed
May be fatal if swallowed and enters airways.
Repeated exposure may cause skin dryness or cracking.
4.3. Indication of any immediate medical attention and special treatment needed
Treat symptomatically.

SECTION 5: Firefighting measures

5.1. Extinguishing media


Suitable extinguishing media
Carbon dioxide (CO2)
Extinguishing powder
alcohol resistant foam
Water spray jet
Unsuitable extinguishing media
high volume water jet
5.2. Special hazards arising from the substance or mixture
Heating or fire can release toxic gas.
Carbon dioxide, Carbon monoxide
5.3. Advice for firefighters
Standard procedure for chemical fires.
Self-contained respirator (breathing apparatus) (DIN EN 133)
Additional information
Use water spray to cool unopened containers.

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures


Use personal protective equipment.
6.2. Environmental precautions
Do not flush into surface water or sanitary sewer system.
Do not allow to enter into soil/subsoil.
In case of gas escape or of entry into waterways, soil or drains, inform the responsible authorities.
6.3. Methods and material for containment and cleaning up
Provide adequate ventilation.
Prevent spread over a wide area (e.g. by containment or oil barriers).
Absorb with liquid-binding material (e.g. sand, diatomaceous earth, acid- or universal binding agents). Collect
in closed and suitable containers for disposal. Dispose of waste according to applicable legislation.
6.4. Reference to other sections
Personal protection equipment: see section 8
Disposal: see section 13

SECTION 7: Handling and storage


7.1. Precautions for safe handling
Advice on safe handling
Provide adequate ventilation as well as local exhaustion at critical locations.
To avoid risks to man and the environment, comply with the instructions for use.

Revision No: 1,02 GB - EN Print date: 04.10.2018


BOHLE AG
Safety Data Sheet

according to Regulation (EC) No 1907/2006

Acecut 5250 Cutting fluid


Revision date: 21.06.2018 Product code: BO5002844 Page 4 of 9

Advice on protection against fire and explosion


Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
Usual measures for fire prevention.
Take precautionary measures against static discharges .
Vapours can form explosive mixtures with air.
7.2. Conditions for safe storage, including any incompatibilities
Requirements for storage rooms and vessels
Keep container tightly closed in a cool, well-ventilated place.
Store in a place accessible by authorized persons only.
Protect against direct sunlight.
Advice on storage compatibility
Do not store together with oxidizing agents
Further information on storage conditions
Recommended storage temperature: 5 - 40°C
7.3. Specific end use(s)
cutting fluid

SECTION 8: Exposure controls/personal protection

8.1. Control parameters


DNEL/DMEL values

CAS No Substance
DNEL type Exposure route Effect Value
5131-66-8 3-butoxypropan-2-ol, propylene glycol monobutyl ether
Worker DNEL, long-term dermal systemic 44 mg/kg bw/day
Worker DNEL, long-term inhalation systemic 270,5 mg/m³
PNEC values
CAS No Substance
Environmental compartment Value
5131-66-8 3-butoxypropan-2-ol, propylene glycol monobutyl ether
Freshwater 0,525 mg/l
Marine water 0,0525 mg/l
Freshwater sediment 2,36 mg/kg
Marine sediment 0,236 mg/kg
Soil 0,16 mg/kg

8.2. Exposure controls


Appropriate engineering controls
Provide adequate ventilation as well as local exhaustion at critical locations.
Protective and hygiene measures
Do not breathe vapours or spray mist.
Avoid contact with skin, eyes and clothing. Take off all contaminated clothing immediately.
Wash hands before breaks and immediately after handling the product .
When using do not eat or drink. Do not smoke.
Keep away from food, drink and animal feedingstuffs.
Eye/face protection
safety glasses with side-shields conforming to EN166

Revision No: 1,02 GB - EN Print date: 04.10.2018


BOHLE AG
Safety Data Sheet

according to Regulation (EC) No 1907/2006

Acecut 5250 Cutting fluid


Revision date: 21.06.2018 Product code: BO5002844 Page 5 of 9

Hand protection
The selected protective gloves have to satisfy the specifications of EU Directive 89/689/EEC and the standard
EN 374 derived from it.
Glove material: Butyl caoutchouc (butyl rubber), NBR (Nitrile rubber)
Take note of the information given by the producer concerning permeability and break through times , and of
special workplace conditions (mechanical strain, duration of contact).
Skin protection
When handling with chemical substances, protective clothing with CE-labels including the four control digits
must be worn.
DIN EN 13034 (Type 6 limited splash-tight)
Respiratory protection
In case of insufficient ventilation, wear suitable respiratory equipment. Combination filtering device (EN 14387)
Respirator with filter for organic vapour, Recommended Filter type: A-P2
Environmental exposure controls
Do not flush into surface water or sanitary sewer system.
Do not allow to enter into soil/subsoil.
In case of gas escape or of entry into waterways, soil or drains, inform the responsible authorities.

SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties


Physical state: liquid
Colour: colourless
Odour: like: Hydrocarbons
Test method
pH-Value: not applicable
Changes in the physical state
Melting point: < -20 °C
Initial boiling point and boiling range: >180 °C
Flash point: 59 °C ISO 2719
Lower explosion limits: 0,4 vol. %
Upper explosion limits: 7 vol. %
Ignition temperature: >270 °C DIN 51794
Auto-ignition temperature not auto-flammable
Vapour pressure: <2 hPa
(at 20 °C)
Density: 0,76 g/cm³ DIN 51757
Water solubility: insoluble
Viscosity / dynamic: 2 mPa·s DIN 54453
(at 20 °C)
Viscosity / kinematic: <2 mm²/s
(at 40 °C)
9.2. Other information
Vapours can form explosive mixtures with air.

SECTION 10: Stability and reactivity

10.1. Reactivity
No dangerous reaction known under conditions of normal use.

Revision No: 1,02 GB - EN Print date: 04.10.2018


BOHLE AG
Safety Data Sheet

according to Regulation (EC) No 1907/2006

Acecut 5250 Cutting fluid


Revision date: 21.06.2018 Product code: BO5002844 Page 6 of 9

10.2. Chemical stability


Stable under normal conditions.
10.3. Possibility of hazardous reactions
Vapours may form explosive mixtures with air.
10.4. Conditions to avoid
Heat, flames and sparks.
Keep away from open flames, hot surfaces and sources of ignition.
10.5. Incompatible materials
oxidizing agents
10.6. Hazardous decomposition products
No decomposition if used as directed.

SECTION 11: Toxicological information

11.1. Information on toxicological effects

Acute toxicity
CAS No Chemical name
Exposure route Dose Species Source Method
Hydrocarbons, C11-C14, isoalkanes, cyclics, <2% aromatics
oral LD50 >5000 Rat
mg/kg
dermal LD50 >5000 Rabbit
mg/kg
inhalative (4 h) vapour LC50 >5000 Rat
mg/l
5131-66-8 3-butoxypropan-2-ol, propylene glycol monobutyl ether
oral LD50 >2000 Rat OECD 423
mg/kg
dermal LD50 >2000 Rat OECD 402
mg/kg
Hydrocarbons, C11-C14, n-alkane, isoalkanes, cyclics, <2% aromatics
oral LD50 >5000 Rat OECD 401
mg/kg
dermal LD50 >5000 Rabbit OECD 402
mg/kg

Irritation and corrosivity


May cause eye irritation with susceptible persons.
Practical experience
Other observations
Repeated exposure may cause skin dryness or cracking.

SECTION 12: Ecological information


12.1. Toxicity
This product has no known eco-toxicological effects.

Revision No: 1,02 GB - EN Print date: 04.10.2018


BOHLE AG
Safety Data Sheet

according to Regulation (EC) No 1907/2006

Acecut 5250 Cutting fluid


Revision date: 21.06.2018 Product code: BO5002844 Page 7 of 9

CAS No Chemical name


Aquatic toxicity Dose [h] | [d] Species Source Method
5131-66-8 3-butoxypropan-2-ol, propylene glycol monobutyl ether
Acute fish toxicity LC50 >100 96 h Pimephales promelas
mg/l (fathead minnow)
Acute crustacea toxicity EC50 >1000 48 h Daphnia magna (Big
mg/l water flea)

12.3. Bioaccumulative potential


Bioaccumulation is unlikely.
12.4. Mobility in soil
No data available
12.5. Results of PBT and vPvB assessment
The substance in the mixture does not meet the PBT/vPvB criteria according to REACH, annex XIII.
12.6. Other adverse effects
Water hazard class (WGK) 1: slightly water endangering
Do not flush into surface water or sanitary sewer system.
Avoid subsoil penetration.

SECTION 13: Disposal considerations

13.1. Waste treatment methods


Advice on disposal
Can be incinerated, when in compliance with local regulations.
Contaminated packaging
Dispose of completely emptied containers as combustible waste or metal waste depending on the material.

SECTION 14: Transport information

Land transport (ADR/RID)


14.1. UN number: UN 3295
14.2. UN proper shipping name: HYDROCARBONS, LIQUID, N.O.S. (Low boiling point hydrogen treated
naphtha, Naphtha (petroleum), hydrodesulfurized heavy)
14.3. Transport hazard class(es): 3
14.4. Packing group: III
Hazard label: 3

Classification code: F1
Limited quantity: 5L
Excepted quantity: E1
Transport category: 3
Hazard No: 30
Tunnel restriction code: D/E
Inland waterways transport (ADN)
14.1. UN number: UN 3295
14.2. UN proper shipping name: HYDROCARBONS, LIQUID, N.O.S. (Low boiling point hydrogen treated
naphtha, Naphtha (petroleum), hydrodesulfurized heavy)
14.3. Transport hazard class(es): 3

Revision No: 1,02 GB - EN Print date: 04.10.2018


BOHLE AG
Safety Data Sheet

according to Regulation (EC) No 1907/2006

Acecut 5250 Cutting fluid


Revision date: 21.06.2018 Product code: BO5002844 Page 8 of 9

14.4. Packing group: III


Hazard label: 3

Classification code: F1
Limited quantity: 5L
Excepted quantity: E1
Marine transport (IMDG)
14.1. UN number: UN 3295
14.2. UN proper shipping name: HYDROCARBONS, LIQUID, N.O.S. (Low boiling point hydrogen treated
naphtha, Naphtha (petroleum), hydrodesulfurized heavy)
14.3. Transport hazard class(es): 3
14.4. Packing group: III
Hazard label: 3

Marine pollutant: no
Special Provisions: 223
Limited quantity: 5L
Excepted quantity: E1
EmS: F-E, S-D
Air transport (ICAO-TI/IATA-DGR)
14.1. UN number: UN 3295
14.2. UN proper shipping name: HYDROCARBONS, LIQUID, N.O.S. (Low boiling point hydrogen treated
naphtha, Naphtha (petroleum), hydrodesulfurized heavy)
14.3. Transport hazard class(es): 3
14.4. Packing group: III
Hazard label: 3

Special Provisions: A3 A224


Limited quantity Passenger: 10 L
Passenger LQ: Y344
Excepted quantity: E1
IATA-packing instructions - Passenger: 355
IATA-max. quantity - Passenger: 60 L
IATA-packing instructions - Cargo: 366
IATA-max. quantity - Cargo: 220 L
14.5. Environmental hazards
ENVIRONMENTALLY HAZARDOUS: no

SECTION 15: Regulatory information

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
EU regulatory information

Revision No: 1,02 GB - EN Print date: 04.10.2018


BOHLE AG
Safety Data Sheet

according to Regulation (EC) No 1907/2006

Acecut 5250 Cutting fluid


Revision date: 21.06.2018 Product code: BO5002844 Page 9 of 9

2004/42/EC (VOC): 100%


National regulatory information
Employment restrictions: Observe restrictions to employment for juvenils according to the 'juvenile
work protection guideline' (94/33/EC).
Water contaminating class (D): 1 - slightly water contaminating
15.2. Chemical safety assessment
For this substance a chemical safety assessment has not been carried out.

SECTION 16: Other information

Relevant H and EUH statements (number and full text)


H226 Flammable liquid and vapour.
H304 May be fatal if swallowed and enters airways.
H315 Causes skin irritation.
H319 Causes serious eye irritation.
EUH066 Repeated exposure may cause skin dryness or cracking.
Further Information
The information is based on present level of our knowledge. It does not, however, give assurances of product
properties and establishes no contract legal rights. The receiver of our product is singulary responsible for
adhering to existing laws and regulations.

(The data for the hazardous ingredients were taken respectively from the last version of the sub-contractor's safety
data sheet.)

Revision No: 1,02 GB - EN Print date: 04.10.2018

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